A kind of microorganism sewage water processing method being inoculated with flora using activated sludge
Technical field
The invention belongs to sewage treatment fields, and in particular to a kind of to be inoculated with using activated sludge at the microorganism sewage water of flora
Reason method.
Background technology
Sewage mainly has sanitary sewage and industrial wastewater.In water pollution caused by human production activity, caused by industry
Water pollution most serious.Such as industrial wastewater, it is more containing pollutant, and complicated component is not only not easy to purify in water, but also handles
It is relatively difficult.Industrial wastewater is the most important reason that industrial pollution causes water pollution.It accounts for the pollutant of industry discharge
It is most of.Pollutant contained by industrial wastewater is multifarious because of factory's type difference, even same class factory, production process is not
Together, the quality and quantity of contained pollutant is also different.Industry in addition to the waste water of discharge be directly injected into water body cause pollution other than, solid
Waste and exhaust gas also can polluted-waters.Sanitary sewage is the sewage of generation during human lives, is the primary pollution source of water body
One of.Mainly excrement and wash water.Everyone sanitary sewage amount being discharged daily of city is 150-400L, amount and life water
It is flat to have substantial connection.Contain large amount of organic, such as cellulose, starch, carbohydrate and fat protein in sanitary sewage;Also often contain
Pathogen, virus and parasitic ovum;Chloride, sulfate, phosphate, bicarbonate and sodium, potassium, calcium, the magnesium of inorganic salts
Deng.Total feature is nitrogenous, sulfur-bearing and phosphorous height, and post-processing is relatively difficult.People should water conservation, China's actual conditions ratio
More special, water resource occupancy volume per person is few, and spatial distribution is uneven.With Chinese Urbanization's, industrialized acceleration, water resource
Demand gap also increasingly increases.In this context, sewage treatment industry becomes new industry, produced at present with tap water,
It supplies water, drain, Treated sewage reusing industry is in status of equal importance;Ammonia nitrogen is the one kind for causing body eutrophication and polluting environment
Important polluter, at present in the almost all of Polluted water area in China, ammonia nitrogen is all one of main pollutant.Water body richness is sought
Fosterization has endangered all conglomeraties such as agricultural, fishery, tourist industry, also constitutes huge prestige to drinking water hygiene and food security
The side of body.Water pollution especially body eutrophication has become the important influence factor of China's economic development.In trade effluent often
It is one of ammonia nitrogen in sewage main source containing ammonia nitrogen in high density.Therefore, the ammonia nitrogen in trade effluent how is removed at current
A major issue in Industrial Waste Water Treatments.
Currently, existing sewage water treatment method includes biochemical process and burning method, it is biochemical often all to use simple filter type, this
Kind mode device structure is simple, but filter effect unobvious;Also have using high-end reverse osmosis technology, but need to apply pressure
Power causes device structure complicated, and practicability is not strong;Burning method easy tos produce pernicious gas pollution air, and is built in sewage
In object, also it is very difficult to handle sewage composition among these.
Invention content
Flora is inoculated with using activated sludge in view of the defects and deficiencies of the prior art, the present invention intends to provide a kind of
Microorganism sewage water processing method.
To achieve the above object, the present invention uses following technical scheme:
A kind of microorganism sewage water processing method being inoculated with flora using activated sludge, is included the following steps:
(1)Prepare adsorbent:
The polyethylene glycol 400 for taking 3-4 parts by weight is added in the deionized water of 13-20 times of its weight, is kept the temperature at 50-60 DEG C
Stirring 4-10 minutes, is added the neopelex of 1-2 parts by weight, and stirring to room temperature is porogen solutions;
The ethyl orthosilicate for taking 40-50 parts by weight is added in the deionized water of 20-30 times of its weight, is added dropwise under stirring condition
The ammonium hydroxide of a concentration of 10-12%, adjusting pH are 11-12, and above-mentioned porogen solutions are added, is stirred to react 4-5 hours, obtains colloidal sol water
Solution;
The carbon dust for taking 30-36 parts by weight is added in the isopropanol of 10-15 times of its weight, stirs evenly, and 3-4 parts by weight are added
Trimethylolpropane, ultrasound 10-15 minutes, are added in above-mentioned sol solution, it is small to be stirred to react 1-2 at 75-80 DEG C
When, precipitation is washed in filtering, 1-2 hours dry at 90-95 DEG C of vacuum, is cooled to room temperature to get the adsorbent;
(2)Prepare microorganism nutriment:
The bean dregs of the potato of 2-3 parts by weight, the sugar residue of 0.1-0.2 parts by weight, 0.3-0.4 parts by weight are mixed, boiling is added to boil, are protected
Boiling 25-30 minutes is held, precipitation is blended into mud by filtering;
The stalk for taking 1-2 parts by weight is added in the sodium sulfite solution of a concentration of 1-1.3% and impregnates 2-3 hours, discharging washing,
Fine powder is worn into after drying;
Treated each raw material is mixed, the urea of mixture weight 10-15% is added, stirs evenly to get micro- life
Object nutriment;
(3)Prepare carrier:
The diatomite for taking 100-130 parts by weight is calcined 1-2 hours at 750-800 DEG C, fine powder is worn into after cooling, with 6-9 weight
The ethyl cellulose mixing of part, is added the absolute ethyl alcohol of 3-4 times of mixture weight, stirs evenly, be sent in reaction kettle, be added
The silane coupling agent Kh560 of 1-2 parts by weight, it is 65-70 DEG C to adjust temperature of reaction kettle, and insulated and stirred 2-3 hours discharges, distillation
Ethyl alcohol is removed, air drying is to get the carrier;
(4)Sewage disinfection treatment:
Sewage is passed through into solid-liquid separator first, is separated by solid-liquid separation, bulk solid particulate matter is removed, subsequent liquid enters heavy
Shallow lake pond is precipitated 10-15 hours, then liquid is removed solid floccules by circular hole filter screen;
(5)Microorganism is fixed:
Above-mentioned carrier, adsorbent are mixed, are sent in reactor, insulated and stirred 4-5 hours at 60-65 DEG C, 50-60 is added
The activated sludge of parts by weight is passed through above-mentioned pretreated sewage, and adjusting pH is 7-8, and mentioned microorganism nutriment is added, is aerated,
Until waiting for that microbial load amount reaches 20-30g/l or more;
(6)Liquid discharge after mentioned microorganism is fixed, continues to be passed through pretreated sewage, be aerated, timing water sampling is surveyed
It is fixed.
The degree of substitution of the ethyl cellulose is 2.5-2.6.
The method of the water determination is to measure ammonia-nitrogen content using Nessler's reagent photometer, is surveyed using potassium dichromate method
Determine COD.
Advantages of the present invention:
The adsorbent of the present invention is using polyethylene glycol and neopelex as pore-foaming agent, using ethyl orthosilicate as presoma,
The colloidal sol with microcellular structure is formd, which is combined with carbon dust, not only with good adsorption effect, but also due to
It can form gel rubber material in water, and good fixed effect can be played to microorganism, for remaining micro- in sewage disposal
Biological content plays good facilitation effect, and the ethyl cellulose being added in the carrier that the present invention is added can mention enhancing viscosity
The effect of absorption can effectively improve microbial load amount, itself and vitamin can be made after being handled by silane coupling agent
Bioactive molecule is coupled, and plays better fixed effect;
The activity of microorganism is high in the sewage water treatment method of the present invention, and adaptability is good, and degradation capability is strong, and biochemical degradation speed is fast,
Treatment effeciency is high, and water quality that treated is good.
Specific implementation mode
Embodiment 1
A kind of microorganism sewage water processing method being inoculated with flora using activated sludge, is included the following steps:
(1)Prepare adsorbent:
The polyethylene glycol 400 for taking 3 parts by weight is added in the deionized water of 13 times of its weight, and insulated and stirred 4 is divided at 50 DEG C
Clock, is added the neopelex of 1 parts by weight, and stirring to room temperature is porogen solutions;
The ethyl orthosilicate for taking 40 parts by weight is added in the deionized water of 20 times of its weight, is added dropwise under stirring condition a concentration of
10% ammonium hydroxide, it is 11 to adjust pH, and above-mentioned porogen solutions are added, is stirred to react 4 hours, obtains sol solution;
The carbon dust for taking 30 parts by weight is added in the isopropanol of 10 times of its weight, stirs evenly, and three hydroxyl first of 3 parts by weight are added
Base propane, ultrasound 10 minutes, are added in above-mentioned sol solution, are stirred to react 1 hour at 75 DEG C, filter, will precipitate water
It washes, it is 1 hour dry at 90 DEG C of vacuum, it is cooled to room temperature to get the adsorbent;
(2)Prepare microorganism nutriment:
The bean dregs of the potato of 2 parts by weight, the sugar residue of 0.1 parts by weight, 0.3 parts by weight are mixed, boiling is added to boil, keep 25 points of boiling
Clock, filtering, mud is blended by precipitation;
The stalk for taking 1 parts by weight is added in a concentration of 1% sodium sulfite solution and impregnates 2 hours, and discharging washing is ground after dry
At fine powder;
Treated each raw material is mixed, the urea of mixture weight 10% is added, stirs evenly to get the microorganism
Nutriment;
(3)Prepare carrier:
The diatomite for taking 100 parts by weight is calcined 1 hour at 750 DEG C, wears into fine powder after cooling, the ethyl cellulose with 6 parts by weight
Element mixing, is added the absolute ethyl alcohol of 3 times of mixture weight, stirs evenly, be sent in reaction kettle, and the silane of 1 parts by weight is added
Coupling agent Kh560, it is 65 DEG C to adjust temperature of reaction kettle, insulated and stirred 2 hours, and discharging is distilled off ethyl alcohol, air drying, i.e.,
Obtain the carrier;
(4)Sewage disinfection treatment:
Sewage is passed through into solid-liquid separator first, is separated by solid-liquid separation, bulk solid particulate matter is removed, subsequent liquid enters heavy
Shallow lake pond is precipitated 10 hours, then liquid is removed solid floccules by circular hole filter screen;
(5)Microorganism is fixed:
Above-mentioned carrier, adsorbent are mixed, are sent in reactor, insulated and stirred 4 hours at 60 DEG C, 50 parts by weight are added
Activated sludge is passed through above-mentioned pretreated sewage, and it is 7 to adjust pH, and mentioned microorganism nutriment is added, and aeration waits for that microorganism is negative
Carrying capacity reaches 21g/l;
(6)Liquid discharge after mentioned microorganism is fixed, continues to be passed through pretreated sewage, be aerated, timing water sampling is surveyed
It is fixed.
Sewage in the present embodiment measures COD using potassium dichromate method, and initial COD average values are 4165mg/l, by this
After the method processing of invention, it is 60.1mg/l to measure COD average values.
Sewage in the present embodiment measures ammonia-nitrogen content using Nessler's reagent photometer, and initial ammonia-nitrogen content average value is
505mg/l, after the processing of the method for the present invention, it is 0.24mg/l to measure ammonia-nitrogen content average value.
Embodiment 2
A kind of microorganism sewage water processing method being inoculated with flora using activated sludge, is included the following steps:
(1)Prepare adsorbent:
The polyethylene glycol 400 for taking 4 parts by weight is added in the deionized water of 20 times of its weight, and insulated and stirred 10 is divided at 60 DEG C
Clock, is added the neopelex of 2 parts by weight, and stirring to room temperature is porogen solutions;
The ethyl orthosilicate for taking 50 parts by weight is added in the deionized water of 30 times of its weight, is added dropwise under stirring condition a concentration of
12% ammonium hydroxide, it is 12 to adjust pH, and above-mentioned porogen solutions are added, is stirred to react 5 hours, obtains sol solution;
The carbon dust for taking 36 parts by weight is added in the isopropanol of 15 times of its weight, stirs evenly, and three hydroxyl first of 4 parts by weight are added
Base propane, ultrasound 15 minutes, are added in above-mentioned sol solution, are stirred to react 2 hours at 80 DEG C, filter, will precipitate water
It washes, it is 2 hours dry at 95 DEG C of vacuum, it is cooled to room temperature to get the adsorbent;
(2)Prepare microorganism nutriment:
The bean dregs of the potato of 3 parts by weight, the sugar residue of 0.2 parts by weight, 0.4 parts by weight are mixed, boiling is added to boil, keep 30 points of boiling
Clock, filtering, mud is blended by precipitation;
The stalk for taking 2 parts by weight is added in a concentration of 1.3% sodium sulfite solution and impregnates 3 hours, discharging washing, after dry
Wear into fine powder;
Treated each raw material is mixed, the urea of mixture weight 15% is added, stirs evenly to get the microorganism
Nutriment;
(3)Prepare carrier:
The diatomite for taking 130 parts by weight is calcined 2 hours at 800 DEG C, wears into fine powder after cooling, the ethyl cellulose with 9 parts by weight
Element mixing, is added the absolute ethyl alcohol of 4 times of mixture weight, stirs evenly, be sent in reaction kettle, and the silane of 2 parts by weight is added
Coupling agent Kh560, it is 70 DEG C to adjust temperature of reaction kettle, insulated and stirred 3 hours, and discharging is distilled off ethyl alcohol, air drying, i.e.,
Obtain the carrier;
(4)Sewage disinfection treatment:
Sewage is passed through into solid-liquid separator first, is separated by solid-liquid separation, bulk solid particulate matter is removed, subsequent liquid enters heavy
Shallow lake pond is precipitated 15 hours, then liquid is removed solid floccules by circular hole filter screen;
(5)Microorganism is fixed:
Above-mentioned carrier, adsorbent are mixed, are sent in reactor, insulated and stirred 5 hours at 65 DEG C, 60 parts by weight are added
Activated sludge is passed through above-mentioned pretreated sewage, and it is 8 to adjust pH, and mentioned microorganism nutriment is added, and aeration waits for that microorganism is negative
Carrying capacity reaches 31g/l;
(6)Liquid discharge after mentioned microorganism is fixed, continues to be passed through pretreated sewage, be aerated, timing water sampling is surveyed
It is fixed.
Sewage in the present embodiment measures COD using potassium dichromate method, and initial COD average values are 4165mg/l, by this
After the method processing of invention, it is 50.4mg/l to measure COD average values.
Sewage in the present embodiment measures ammonia-nitrogen content using Nessler's reagent photometer, and initial ammonia-nitrogen content average value is
505mg/l, after the processing of the method for the present invention, it is 0.21mg/l to measure ammonia-nitrogen content average value.