CN108439927A - A kind of drilling mud curing materials prepared by wet grinding - Google Patents
A kind of drilling mud curing materials prepared by wet grinding Download PDFInfo
- Publication number
- CN108439927A CN108439927A CN201810322775.9A CN201810322775A CN108439927A CN 108439927 A CN108439927 A CN 108439927A CN 201810322775 A CN201810322775 A CN 201810322775A CN 108439927 A CN108439927 A CN 108439927A
- Authority
- CN
- China
- Prior art keywords
- drilling mud
- parts
- curing materials
- wet
- materials prepared
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/14—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
- C04B28/142—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements containing synthetic or waste calcium sulfate cements
- C04B28/144—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements containing synthetic or waste calcium sulfate cements the synthetic calcium sulfate being a flue gas desulfurization product
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/50—Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Soil Conditioners And Soil-Stabilizing Materials (AREA)
Abstract
The invention discloses drilling mud curing materials prepared by a kind of wet grinding, alkaline residue, desulfurated plaster, flyash, slag dry machine grinding obtains 30 μm of mixed powder materials of average grain diameter ＜；Drilling mud wet-milling fine obtains drilling mud material to 8 μm of grain size ＜；Mixed powder material and drilling mud material mix to obtain mixture, SAP, NaOH, polycarboxylate water-reducer, ammonium persulfate, activated alumina, mixing water, cement and sand are added in mixture, and drilling mud curing materials are made after concrete mixer stirring.The present invention realizes the recycling of trade waste, reduces waste stockpiling；Solid bulky grain is changed into little particle, excites drilling mud lateral reactivity, increase the extent of reaction by wet-milling fine drilling mud；The solid waste of large dosage of the present invention utilizes, and mitigates the waste discharge pressure of enterprise, and the curing materials of preparation have high-strength, and function admirable meets property indices, is suitable for Ordinary Rd roadbed material therefor.
Description
Technical field
The invention belongs to drilling mud solidification technology fields, and in particular to a kind of drilling well mud prepared by wet grinding
Starch curing materials.
Background technology
Since the 21th century, china natural resources are continuously developed, and gradually turn to industrial power by large agricultural country, although being in
The bottom end of " smile curve ", but be also that China's economic development brings strong impetus to a certain extent.However, in extensive style
Under development of linear pattern, economic fast development is pursued simply, what is brought is that ecological environment is destroyed, and resource is constantly wasted.
The continuous development of process of industrialization, Industrial Solid Waste discharge capacity are continuously increased, and traditional stockpiling and landfill appropriation of land not only pollute
Air and river influence people's health, and seriously having ignored Industrial Solid Waste can be used as raw material to produce building material
This advantage.
In petroleum drilling operation, well drilling waste mud has the characteristics that larger dosage, complex chemical composition, type are more,
Therefore be when handling drilling well waste sludge dress it is extremely difficult, it is now relatively more to the measure taken of these mud dress, but from economy
Benefit is set out consideration, is only had sub-fraction and is recycled, and the overwhelming majority is directly discharged in environment, or take from
It so evaporates, precipitate, consolidating, being buried in the measures progress simply and easy treat such as neighbouring.About ten thousand waste sludges of discharge are betrayed every year in China according to statistics,
It is wherein directly discharged to accounting in ambient enviroment, if do not handled effectively these pollutants, it will to ecological environment
It causes to seriously threaten.
The related patents of published sludge solidifying agent in recent years：Chinese patent CN104529283A discloses a kind of oil field
Waste drilling mud curing materials, it is characterised in that the curing materials are by oilfield waste drilling mud, cement, sand, solidification
Agent and mixing water composition, the mass percent of each component are：Mud：10.0%-50.0%；Cement：10.0%-50.0%；Sand
Son：50.0%-90.0%；Curing agent：0.01%-10.0%；Mixing water：0.0%-10.0%；Chinese patent
CN101696352A discloses a kind of ground pregrouting material prepared with well drilling waste mud.The ground pregrouting material by with
Pre grouting from the surface slurries and the calcium chloride solution composition that well drilling waste mud is prepared；The pre grouting from the surface slurries are given up by drilling well
Mud, cement and structural additives composition are abandoned, structural additives account for 1%~3% (volume hundred in 1 volume pre grouting from the surface slurries
Divide ratio) volume, a concentration of 0.1~0.2g/mL of cement, surplus is drilling mud；Pre grouting from the surface slurries and calcium chloride solution
Volume ratio be 1000: (5~17).
Invention content
The purpose of the present invention is be directed to above-mentioned present situation, it is desirable to provide roadbed material intensity made of a kind of material is high, leaches
Object concentration is low, and every item is up to standard requires, green low-carbon, realizes that drilling mud prepared by the wet grinding that solid waste utilizes is solid
Change material.
The realization method of the object of the invention is that a kind of drilling mud curing materials prepared by wet grinding, are by following methods
It prepares, following each raw materials take parts by weight；Preparation is as follows：
1) 20~25 parts of 25~30 parts of alkaline residue, 15~20 parts of desulfurated plaster, 60~80 parts of flyash and miberal powder are taken, is added to
It is ground in dry mill, obtains average grain diameter<30 μm of mixed powder material；
2) it takes in 60-80 parts of addition wet milks of drilling mud, wet-milling fine to grain size<8 μm, obtain drilling mud material；
3) the mixed powder material that step 1) obtains and the drilling mud material that step 2) obtains first are mixed to get mixture,
Then 1~2 part of SAP of addition in mixture, 1~5 part of NaOH, 0.5~1.0 part of polycarboxylate water-reducer, 1~2 part of ammonium persulfate,
1~2 part of activated alumina, 10~20 parts of mixing waters, 20~25 parts of cement, 30~40 parts of sand, and stirred in concrete mixer
It mixes, drilling mud curing materials is made.
The beneficial effects of the invention are as follows：
1, with wet milling techniques, the highly viscous drilling mud particle of fine increases the mobility of drilling mud, grading
It is more excellent；In the environment of liquid phase is ground, solid particle is destroyed surface energy dissolution active ion, fully excites drilling mud
Lateral reactivity, make drilling mud when other active materials are combined, provided for the material with gelling property can be generated
Basis；
2, it can be provided using alkaline residue, miberal powder a large amount of calcareous；Flyash can provide a part of sa, after mixing with drilling well
Hydration reaction occurs for active ion of the mud in liquid phase (water) environment, generates the material with gelling property, is used as roadbed material
Material, can enhance the intensity and bearing capacity of roadbed material；
3, the heavy metal in drilling mud can be cured using SAP, and can jointly be reduced with desulfurated plaster aqueous in material
Rate；NaOH can provide alkaline environment for hydration reaction, fully excite the hydration activity of raw material；Polycarboxylate water-reducer can enhance brill
The mobility of well mud ensures that drilling mud does not consolidate during reaction；Ammonium persulfate and activated alumina respectively as
Gel breaker and adsorbent further improve the performance of drilling mud, ensure being smoothed out for hydration reaction.
The solid waste of large dosage of the present invention utilizes, and alleviates the waste discharge pressure of enterprise, reduces the stockpiling of solid waste, real
Existing green low-carbon, the process of waste circular regeneration；Curing materials prepared by the present invention are at low cost, function admirable, can meet each
Item performance indicator, is suitable for Ordinary Rd roadbed material therefor.
Specific implementation mode
Alkaline residue, desulfurated plaster, flyash, the dry machine grinding of slag are obtained 30 μm of mixed powders of average grain diameter ＜ by the present invention
Material；Drilling mud wet-milling fine obtains drilling mud material to 8 μm of grain size ＜；Mixed powder material and drilling mud material are mixed
Close to obtain mixture, in mixture plus SAP, NaOH, polycarboxylate water-reducer, ammonium persulfate, activated alumina, mixing water, cement and
Sand, is stirred in JS1000 type concrete mixers, and drilling mud curing materials are made in mixing speed 25.5r/m.
Alkaline residue used is the white solid waste material by being generated during ammonia-soda process soda ash, then through centrifugal dehydration treatment institute
The alkaline residue obtained.
Drilling mud Leaching analysis result used:Moisture content be 75%, COD contents be 1635mg/L, pH=12.6,
Petroleum content is 80mg/L, and coloration, extension rate 400, Cu, Zn, Pb, Hg, Cd, As are detected, but not exceeded；Through wet
After grinding fine, 8 μm of solid particle average grain diameter ＜.
SAP used is containing strongly hydrophilic group carboxyl, hydroxyl or amino, water-swellable and to have three-dimensional space network knot
The macromolecule super absorbent polymer of structure.
Desulfurated plaster used is by the industry byproduct that desulfurated plaster is FGD processes.
Cement used is Portland cement, and sand is normal sand, and mixing water is tap water.
Flyash used is the primary solids waste of coal-burning power plant's discharge；The miberal powder be by mined ore into
Obtained miberal powder after row crushing and processing.
NaOH used, polycarboxylate water-reducer, ammonium persulfate, activated alumina are commercially available.
The present invention is described in detail with specific embodiment below.
Embodiment 1,
1) 20 parts of 25 parts of parts by weight alkaline residue, 15 parts of desulfurated plaster, 60 parts of flyash and miberal powder are taken, is added in dry mill
It is ground, obtains mixed powder material, the average grain diameter of powder body material particle<30μm；
2) take in 60 parts of addition wet milks of parts by weight drilling mud wet-milling fine to grain size<8 μm hereinafter, obtain drilling well
Material-mud；
3) the mixed powder material that step 1) obtains and the drilling mud material that step 2) obtains first are mixed to get mixture,
Then 1 part of SAP of addition parts by weight, 1 part of NaOH, 0.5 part of polycarboxylate water-reducer, 1 part of ammonium persulfate, 1 part of work in mixture
Property aluminium oxide, 10 parts of mixing waters, 20 parts of cement, 30 parts of sand stir in JS1000 type concrete mixers, and mixing speed is
Drilling mud curing materials are made in 25.5r/m.
Embodiment 2, with embodiment 1, unlike,
1) 22 parts of 26 parts of parts by weight alkaline residue, 16 parts of desulfurated plaster, 65 parts of flyash and miberal powder are taken, is added in dry mill
It is ground；
2) take in 62 parts of addition wet milks of parts by weight drilling mud wet-milling fine to grain size<8 μm hereinafter, obtain drilling well
Material-mud；
3) 1 part of SAP of addition parts by weight in mixture, 1 part of NaOH, 0.5 part of polycarboxylate water-reducer cross 1 part of ammonium sulfate,
1.2 parts of activated aluminas, 12 parts of mixing waters, 21 parts of cement, 32 parts of sand are stirred in JS1000 type concrete mixers, mixing speed
For 25.5r/m, drilling mud curing materials are made.
Embodiment 3, with embodiment 1, unlike
1) 24 parts of 27 parts of parts by weight alkaline residue, 17 parts of desulfurated plaster, 67 parts of flyash and miberal powder are taken, is added in dry mill
It is ground；
2) take in 67 parts of addition wet milks of parts by weight drilling mud wet-milling fine to grain size<8 μm hereinafter, obtain drilling well
Material-mud；
3) 1.2 parts of SAP of addition parts by weight, 3 parts of NaOH, 0.5 part of polycarboxylate water-reducer, 1.2 parts of over cures in mixture
Sour ammonium, 1.2 parts of activated aluminas, 20 parts of mixing waters, 20 parts of cement, 40 parts of sand are stirred in JS1000 type concrete mixers, are stirred
It is 25.5r/m to mix speed, and drilling mud curing materials are made.
Embodiment 4, with embodiment 1, unlike
1) 20 parts of 30 parts of parts by weight alkaline residue, 20 parts of desulfurated plaster, 80 parts of flyash and miberal powder are taken, is added in dry mill
It is ground；
2) take in 80 parts of addition wet milks of parts by weight drilling mud wet-milling fine to grain size<8 μm hereinafter, obtain drilling well
Material-mud；
3) 1.2 parts of SAP of addition parts by weight, 2 parts of NaOH, 0.5 part of polycarboxylate water-reducer, 2 parts of persulfuric acid in mixture
Ammonium, 2 parts of activated aluminas, 15 parts of mixing waters, 25 parts of cement, 30 parts of sand are stirred in JS1000 type concrete mixers, stirring speed
Degree is 25.5r/m, and drilling mud curing materials are made.
Embodiment 5, with embodiment 1, unlike
1) 25 parts of 28 parts of parts by weight alkaline residue, 15 parts of desulfurated plaster, 70 parts of flyash and miberal powder are taken, is added in dry mill
It is ground；
2) take in 75 parts of addition wet milks of parts by weight drilling mud wet-milling fine to grain size<8 μm hereinafter, obtain drilling well
Material-mud；
3) 1.2 parts of SAP of addition parts by weight, 5 parts of NaOH, 0.5 part of polycarboxylate water-reducer, 1.5 parts of over cures in mixture
Sour ammonium, 1.5 parts of activated aluminas, 16 parts of mixing waters, 25 parts of cement, 35 parts of sand are stirred in JS1000 type concrete mixers, are stirred
It is 25.5r/m to mix speed, and drilling mud curing materials are made.
Embodiment 6, with embodiment 1, unlike
1) 23 parts of 25 parts of parts by weight alkaline residue, 17 parts of desulfurated plaster, 75 parts of flyash and miberal powder are taken, is added in dry mill
It is ground；
2) take in 75 parts of addition wet milks of parts by weight drilling mud wet-milling fine to grain size<8 μm hereinafter, obtain drilling well
Material-mud；
3) 2 parts of SAP of addition parts by weight in mixture, 4 parts of NaOH, 1 part of polycarboxylate water-reducer, 1.6 parts of ammonium persulfates,
1.6 parts of activated aluminas, 15 parts of mixing waters, 23 parts of cement, 30 parts of sand are stirred in JS1000 type concrete mixers, mixing speed
For 25.5r/m, and drilling mud curing materials are made.
The applicant is to the pH value in the solidification material prepared by embodiment 1-6, COD contents, coloration, petroleum content, liquid
Limit, plastic limit, plasticity index, California bearing ratio and 7d unconfined compressive strengths are detected, and testing result see the table below.
As seen from the table, the curing materials that prepared by six groups of embodiments of the invention can meet JTG D30-2004, D50-
Relevant criterion in 2006 and GB8978-1996.
Claims (8)
1. drilling mud curing materials prepared by a kind of wet grinding, it is characterised in that：It is to be prepared by following methods, following each originals
Material takes parts by weight；Preparation is as follows：
1) 20~25 parts of 25~30 parts of alkaline residue, 15~20 parts of desulfurated plaster, 60~80 parts of flyash and miberal powder are taken, dry grinding is added to
It is ground in machine, obtains average grain diameter<30 μm of mixed powder material；
2) it takes in 60-80 parts of addition wet milks of drilling mud, wet-milling fine to grain size<8 μm, obtain drilling mud material；
3) the mixed powder material that step 1) obtains and the drilling mud material that step 2) obtains first are mixed to get mixture, then
1~2 part of SAP of addition in mixture, 1~5 part of NaOH, 0.5~1.0 part of polycarboxylate water-reducer, 1~2 part of ammonium persulfate, 1~2
Part activated alumina, 10~20 parts of mixing waters, 20~25 parts of cement, 30~40 parts of sand, and stirred in concrete mixer, it makes
Obtain drilling mud curing materials.
2. drilling mud curing materials prepared by a kind of wet grinding according to claim 1, it is characterised in that：Step 1) institute
It is the white solid waste material by being generated during ammonia-soda process soda ash with alkaline residue, then through the alkaline residue obtained by centrifugal dehydration treatment.
3. drilling mud curing materials prepared by a kind of wet grinding according to claim 1, it is characterised in that：Step 2) institute
With drilling mud Leaching analysis result:Moisture content is that 75%, COD contents are 1635mg/L, pH=12.6, petroleum content
For 80mg/L, coloration, extension rate 400, Cu, Zn, Pb, Hg, Cd, As are detected, but not exceeded；Through wet-milling fine it
Afterwards, 8 μm of solid particle average grain diameter ＜.
4. drilling mud curing materials prepared by a kind of wet grinding according to claim 1, it is characterised in that：Step 3) institute
It is to contain strongly hydrophilic group carboxyl, hydroxyl or amino, water-swellable and the macromolecule for having three-dimensional space network structure with SAP
Super absorbent polymer.
5. drilling mud curing materials prepared by a kind of wet grinding according to claim 1, it is characterised in that：Step 3) institute
It is the industry byproduct of FGD processes by desulfurated plaster with desulfurated plaster.
6. drilling mud curing materials prepared by a kind of wet grinding according to claim 1, it is characterised in that：Step 3) institute
It is Portland cement with cement, sand is normal sand, and mixing water is tap water.
7. drilling mud curing materials prepared by a kind of wet-milling according to claim 1, it is characterised in that：Step 3) is used
Flyash is the primary solids waste of coal-burning power plant's discharge；The miberal powder is after mined ore is crushed processing
Obtained miberal powder.
8. drilling mud curing materials prepared by a kind of wet-milling according to claim 1, it is characterised in that：Concrete stirs
Machine is JS1000 type concrete mixers, mixing speed 25.5r/m.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810322775.9A CN108439927A (en) | 2018-04-11 | 2018-04-11 | A kind of drilling mud curing materials prepared by wet grinding |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810322775.9A CN108439927A (en) | 2018-04-11 | 2018-04-11 | A kind of drilling mud curing materials prepared by wet grinding |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108439927A true CN108439927A (en) | 2018-08-24 |
Family
ID=63199636
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810322775.9A Pending CN108439927A (en) | 2018-04-11 | 2018-04-11 | A kind of drilling mud curing materials prepared by wet grinding |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108439927A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109942236A (en) * | 2019-03-27 | 2019-06-28 | 广东清大同科环保技术有限公司 | A kind of construction material of alkaline residue preparation |
| CN111303890A (en) * | 2020-01-21 | 2020-06-19 | 新疆盛洁环境技术有限责任公司 | Curing agent for solid waste treatment and application thereof |
| CN112028612A (en) * | 2020-09-02 | 2020-12-04 | 江苏苏嘉集团新材料有限公司 | Magnesia carbon brick applying reinforcing material |
| CN112500101A (en) * | 2020-10-26 | 2021-03-16 | 张夏艇 | Anti-cracking drilling fluid rock debris curing agent and using method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102153265A (en) * | 2011-02-10 | 2011-08-17 | 刘华伟 | No-pollution treatment technique of well-drilling waste sludge |
| CN103570318A (en) * | 2013-10-24 | 2014-02-12 | 延长油田股份有限公司西区采油厂 | Curing material for drilling waste slurries as well as method thereof for curing drilling waste slurries |
| CN104529283A (en) * | 2014-12-15 | 2015-04-22 | 上海三瑞高分子材料有限公司 | Oilfield waste drilling mud solidified material |
| US20150175481A1 (en) * | 2012-03-09 | 2015-06-25 | Halliburton Energy Services, Inc. | Set-Delayed Cement Compositions Comprising Pumice and Associated Methods |
| CN105776780A (en) * | 2016-03-07 | 2016-07-20 | 南京乾庚新材料科技有限公司 | Shale gas well drilling waste-oil-based mud curing material |
-
2018
- 2018-04-11 CN CN201810322775.9A patent/CN108439927A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102153265A (en) * | 2011-02-10 | 2011-08-17 | 刘华伟 | No-pollution treatment technique of well-drilling waste sludge |
| US20150175481A1 (en) * | 2012-03-09 | 2015-06-25 | Halliburton Energy Services, Inc. | Set-Delayed Cement Compositions Comprising Pumice and Associated Methods |
| CN103570318A (en) * | 2013-10-24 | 2014-02-12 | 延长油田股份有限公司西区采油厂 | Curing material for drilling waste slurries as well as method thereof for curing drilling waste slurries |
| CN104529283A (en) * | 2014-12-15 | 2015-04-22 | 上海三瑞高分子材料有限公司 | Oilfield waste drilling mud solidified material |
| CN105776780A (en) * | 2016-03-07 | 2016-07-20 | 南京乾庚新材料科技有限公司 | Shale gas well drilling waste-oil-based mud curing material |
Non-Patent Citations (2)
| Title |
|---|
| 地质矿产部地质技术经济研究中心等编: "《国内优势矿产资源开发利用现状发展远景及主要矿产品进出口情况研究报告》", 31 October 1988, 地质矿产部地质技术经济研究中心 * |
| 王中华等编著: "《油田化学品实用手册》", 31 July 2004, 中国石化出版社 * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109942236A (en) * | 2019-03-27 | 2019-06-28 | 广东清大同科环保技术有限公司 | A kind of construction material of alkaline residue preparation |
| CN111303890A (en) * | 2020-01-21 | 2020-06-19 | 新疆盛洁环境技术有限责任公司 | Curing agent for solid waste treatment and application thereof |
| CN111303890B (en) * | 2020-01-21 | 2022-03-08 | 新疆盛洁环境技术有限责任公司 | Curing agent for solid waste treatment and application thereof |
| CN112028612A (en) * | 2020-09-02 | 2020-12-04 | 江苏苏嘉集团新材料有限公司 | Magnesia carbon brick applying reinforcing material |
| CN112500101A (en) * | 2020-10-26 | 2021-03-16 | 张夏艇 | Anti-cracking drilling fluid rock debris curing agent and using method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN108439927A (en) | A kind of drilling mud curing materials prepared by wet grinding | |
| CN113307591B (en) | Multi-source solid waste composite high-flow-state backfill material and preparation method and application thereof | |
| CN110627391B (en) | High-activity anhydrous phosphogypsum cementing material and preparation method thereof | |
| CN105819798B (en) | A kind of quick setting and high strength sludge consolidating agent and preparation method thereof | |
| CN101805161B (en) | Bonding agent of baking-free bricks prepared from drilling well solid waste materials | |
| CN103613303A (en) | Modified limestone powder high-performance mineral admixture and preparation method thereof | |
| CN106495581B (en) | Grouting material reinforced for road and preparation method thereof | |
| CN108117358A (en) | A kind of curing of waste soil combined processing | |
| CN107686322A (en) | A kind of method that artificial stone useless slurry recycles | |
| CN104692720A (en) | Copper tailing baking-free brick and preparation method thereof | |
| CN113149589A (en) | Soil body curing agent doped with sludge incineration ash and preparation method thereof | |
| CN108178580A (en) | Mixing pile and rotary churning pile curing agent | |
| CN103319067A (en) | Environment-friendly type mud solidification method | |
| CN108192623A (en) | Bayer process red mud roadbed microorganism curing and application process | |
| CN114525136A (en) | Red mud-based soil curing agent and preparation method thereof | |
| CN103965918A (en) | Curing agent for water quenching manganese slag mollisol | |
| CN103708705A (en) | Silt curing agent and production method thereof | |
| CN109503073A (en) | A kind of high-moisture percentage riverway sludge rapid curing curing agent and preparation method thereof | |
| CN104876515A (en) | Aluminum base gelling and curing agent, preparation method and application thereof | |
| CN110218073A (en) | Dredging silt dehydrating and curing calcium and magnesium based composites and the preparation method and application thereof | |
| CN1887456A (en) | Bauxite tail piling method | |
| CN107140907B (en) | A kind of concrete adulterating quartz artificial stone waste residue and flyash | |
| CN117303808A (en) | Soft soil curing agent utilizing lithium slag, preparation method and application thereof | |
| CN107698182A (en) | A kind of dirty mud environment protection type binder materials and preparation method thereof | |
| CN113136213A (en) | Soil stabilizer prepared from bauxite tailings |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180824 |