CN108431198A - The cleaning compositions of liposoluble constituent containing high-content - Google Patents
The cleaning compositions of liposoluble constituent containing high-content Download PDFInfo
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- CN108431198A CN108431198A CN201680058914.0A CN201680058914A CN108431198A CN 108431198 A CN108431198 A CN 108431198A CN 201680058914 A CN201680058914 A CN 201680058914A CN 108431198 A CN108431198 A CN 108431198A
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- Prior art keywords
- cleaning compositions
- acid
- weight
- parts
- soap
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Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/22—Organic compounds, e.g. vitamins
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/22—Organic compounds, e.g. vitamins
- C11D9/26—Organic compounds, e.g. vitamins containing oxygen
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
- Cosmetics (AREA)
Abstract
Subject description discloses a kind of cleaning compositions, the composition includes the cross-linked polymer of acrylate and C10 C30 alkyl acrylates, therefore a kind of cleaning compositions can be provided, the cleaning compositions realize that salubrious sense, Simultaneous Stabilization can realize the liposoluble constituent of abundant foam and the high-content in excellent rinsability soap type system when rinsing due to excellent foaming capacity and defoaming capacity.
Description
Technical field
The invention discloses a kind of cleaning compositions.
Background technology
Cleaning compositions can be classified as soap type composition, soap-free composition and half soap type composition extensively.Soap type combines
Object is obtained by in basifier with aliphatic acid, and soap-free composition includes then faintly acid synthetic surfactant, half soap
Type composition is obtained by mixing soap type composition with synthetic surfactant.It is known that soap type cleaning compositions exist
Abundant foam can be formed when cleaning, and has many advantages, such as excellent flushing performance.
However, in and in soap type cleaning systems that aliphatic acid by obtains, when such system include such as butter or
When the liposoluble constituent of the high-contents such as oil, a problem is will produce, i.e. liposoluble constituent can play the effect of antifoaming agent and make hair
Bubble interrupts, thus causes to have smooth use feeling when rinsing.Reason is as follows：It is a kind of material being known as dross (scum)
Material, the material realize salubrious use feeling when rinsing, and the material be by anion surfactant carboxyl (COO-) with
Caused by bivalent metal ion (magnesium or potassium) in water combines.In the feelings of this soap type cleaning systems for thering are a large amount of drosses to generate
It is the liposoluble constituent being difficult to by stablizing high-content with the fatty acid preparation of neutralization under condition.In other words, contain comprising height
In the soap type cleaning systems of the liposoluble constituent of amount, it is impossible to form dross and prepare the system of the liposoluble constituent containing high-content
Agent, and smooth use feeling caused by liposoluble constituent itself and salubrious use feeling during rinsing can not be provided.
Therefore, in the case of the conventional detergents of the liposoluble constituent containing high-content, a kind of system has been used, it should
System is emulsified with being free of the surfactant of carboxyl (carboxyl, COO-) group as matrix, and another root
It has then been exposed in Korean Patent Publication No. 10-0760973 bulletins according to the cleaning compositions of related art.
Invention content
Technical problem
Technical problem to be solved by the present invention lies in providing a kind of cleaning compositions, it includes stable emulsifying systems,
The emulsifying systems of the stabilization include a kind of fat that abundant foam and the high-content in the excellent soap type system for rinsing performance can be achieved
Soluble components.
Another technical problem to be solved by this invention is to provide a kind of cleaning compositions, is stablizing soap type system
In high-content liposoluble constituent while, moreover it is possible to provided by excellent foaming capacity and defoaming capacity during rinsing clear
Refreshing sense.
Technical solution
Generally speaking, the cleaning compositions of foaming capacity and defoaming capacity can be improved when the present invention provides a kind of flushing, it should
Cleaning compositions include：Liposoluble constituent；Anion surfactant；And acrylate (acrylate) and C10-C30 alkane
The cross-linked polymer of base acrylate (C10-C30 alkyl acrylate) (hand over by acrylate/C10-C30 alkyl acrylates
Linked polymer).
According to an embodiment, amount of the liposoluble constituent in total cleaning compositions of 100 parts by weight can be
0.01-50 parts by weight.
According to another embodiment, the liposoluble constituent can be in the group being made of oil, butter and wax
It is at least one.
According to yet another embodiment, the anion surfactant can have carboxyl.
According to yet another embodiment, the anion surfactant can be selected from by laureth ammonium sulfate
(ammonium laureth sulfate), alkyl amido betaine (cocoamidopropylbetaine), lauryl sulfate
At least one of the group that ammonium (ammonium lauryl sulfate) and fatty acid soaps (fatty acid soap) are constituted.
According to yet another embodiment, the fatty acid soaps can be selected from by lauric acid soap (lauric acid soap), meat
Myristic acid soap (myristic acid soap), palmitic acid soap (palmitic acid soap), stearate soap (stearic
Acid soap), bitter soap (caprylic acid soap), capric acid soap (capric acid soap) and oleate soap (oleic
Acid soap) at least one of the group that is constituted.
According to yet another embodiment, the fatty acid soaps may include at least one aliphatic acid (fatty acid), be selected from
By lauric acid (lauric acid), myristic acid (myristic acid), palmitic acid (palmitic acid), stearic acid
(stearic acid), sad (caprylic acid), capric acid (capric acid) and oleic acid (oleic acid) are constituted
Group；And at least one basifier (alkalinizing agent), selected from by potassium hydroxide (potassium
Hydroxide), sodium hydroxide (sodium hydroxide), triethanolamine (triethanolamine) and methylglucosamine
(methylglucamine) group constituted.
According to still another embodiment, the anion surfactant and acrylate and C10-C30 alkyl acrylates
Cross-linked polymer (acrylate/C10-C30 alkyl acrylate cross-linked polymers) in total cleaning compositions of 100 parts by weight
In amount respectively can be 0.01-30 parts by weight and 0.01-2 parts by weight.
Advantageous effect
According to an embodiment of the invention, the present invention provides a kind of cleaning compositions, and it includes stable emulsifying systems, this is steady
Fixed emulsifying systems include the liposoluble constituent that can realize abundant foam and the high-content in the excellent soap type system for rinsing performance.
The present invention also provides a kind of cleaning compositions, the liposoluble constituent of the high-content in stablizing soap type system it is same
When, moreover it is possible to provide salubrious sense during rinsing by excellent foaming capacity and defoaming capacity.
Specific implementation mode
Hereinafter, exemplary embodiment will be described more fully.
On the one hand, the cleaning compositions of foaming capacity and defoaming capacity can be improved when the present invention provides a kind of flushing, this is clear
Cleansing composition includes：Liposoluble constituent；Anion surfactant；And acrylate and C10-C30 alkyl acrylates
Cross-linked polymer (acrylate/C10-C30 alkyl acrylate cross-linked polymers).
On the other hand, the present invention provides a kind of clean method comprising：Composition is applied to subject, the composition
Include the cross-linked polymer of liposoluble constituent, anion surfactant and acrylate and C10-C30 alkyl acrylates
(acrylate/C10-C30 alkyl acrylate cross-linked polymers).For example, which includes applying the composition
Skin for subject.
Another aspect, the present invention provide a kind of composition for cleaning subject, it includes：Liposoluble constituent, the moon
Cross-linked polymer (the acrylate/C10-C30 of ionic surface active agent and acrylate and C10-C30 alkyl acrylates
Alkyl acrylate cross-linked polymer).For example, the composition can be applied to the skin of subject.
According to an embodiment, the cleaning compositions can be suitable for a kind of clear of body integral part (including face)
(cleaning), washing (washing) or cleaning (cleansing) composition are washed, for cleaning or the purpose of beauty therapeutic.
According to another embodiment, the liposoluble constituent can be selected from by naturally occurring vegetable oil (naturally
Occurred vegetable oils), synthetic oil (synthetic oils), naturally occurring butter (naturally
Occurred butters), synthesis butter (synthetic butters), naturally occurring wax (naturally occurred
) and at least one of the group that is formed of synthetic wax (synthetic waxes) waxes.
According to yet another embodiment, the anion surfactant can have carboxyl.
According to yet another embodiment, the anion surfactant can be selected from by laureth ammonium sulfate, alkyl
At least one of the group that amide betaine, Texapon Special and fatty acid soaps are constituted.
According to yet another embodiment, the fatty acid soaps can be a kind of by basifier and aliphatic acid and the aliphatic acid that generates
Soap, and can include the soap caused by C4-C28 aliphatic acid, specifically, the soap caused by C12 or higher fatty acids.
According to yet another embodiment, the fatty acid soaps can be selected from by lauric acid soap, myristic acid soap, palmitic acid soap,
At least one of the group that stearate soap, bitter soap, capric acid soap and oleate soap are constituted.
According to yet another embodiment, the fatty acid soaps may include：At least one aliphatic acid, selected from by lauric acid, meat
The group that myristic acid, palmitic acid, stearic acid, octanoic acid, capric acid and oleic acid are constituted；And at least one basifier, selected from by
The group that potassium hydroxide, sodium hydroxide, triethanolamine and methylglucosamine are constituted.
According to yet another embodiment, amount of the liposoluble constituent in total cleaning compositions of 100 parts by weight can be
0.01-50 parts by weight.In a change case, presence of the liposoluble constituent in total cleaning compositions of 100 parts by weight
Amount can be at least 0.01 parts by weight, at least 0.1 parts by weight, at least 1 parts by weight, at least 5 parts by weight, at least 10 parts by weight, at least
15 parts by weight, at least 20 parts by weight, at least 25 parts by weight or at least 30 parts by weight, and most 50 parts by weight, most 45 parts by weight,
Most 40 parts by weight, most 35 parts by weight or most 30 parts by weight.Specifically, the liposoluble constituent is in the total of 100 parts by weight
Amount in cleaning compositions can be the high-content of 10-50 parts by weight, 15-45 parts by weight or 20-40 parts by weight.
According to yet another embodiment, presence of the anion surfactant in total cleaning compositions of 100 parts by weight
Amount can be 0.01-30 parts by weight.In a change case, total cleaning group of the anion surfactant in 100 parts by weight
The amount closed in object can be at least 0.01 parts by weight, at least 0.1 parts by weight, at least 1 parts by weight, at least 5 parts by weight, at least 10
Parts by weight, at least 15 parts by weight or at least 20 parts by weight, and most 30 parts by weight, most 25 parts by weight or most 20 parts by weight.
Specifically, amount of the anion surfactant in total cleaning compositions of 100 parts by weight can be 5-30 parts by weight
Or 10-25 parts by weight.
According to yet another embodiment, the cross-linked polymer (acrylic acid of the acrylate and C10-C30 alkyl acrylates
Ester/C10-C30 alkyl acrylate cross-linked polymers) amount in total cleaning compositions of 100 parts by weight can be 0.01-
2 parts by weight.In a change case, the cross-linked polymer of the acrylate/C10-C30 alkyl acrylates is in 100 weight
Part total cleaning compositions in amount can be at least 0.01 parts by weight, at least 0.05 parts by weight, at least 0.1 parts by weight, extremely
Few 0.2 parts by weight, at least 0.3 parts by weight, at least 0.4 parts by weight or at least 0.5 parts by weight, and most 2 parts by weight, most 1.5
Parts by weight, most 1.4 parts by weight, most 1.3 parts by weight, most 1.2 parts by weight, most 1.1 parts by weight, most 1 parts by weight, most
More 0.9 parts by weight, most 0.8 parts by weight, most 0.7 parts by weight, most 0.6 parts by weight or most 0.5 parts by weight.Specifically,
Amount of the acrylate/C10-C30 alkyl acrylate cross-linked polymers in total cleaning compositions of 100 parts by weight
Can be 0.1-2 parts by weight, 0.1-1.5 parts by weight or 0.1-1 parts by weight, with the liposoluble constituent of the such high-content of stabilization, and
Improve foaming capacity during rinsing and defoaming capacity.
According to still another embodiment, the composition can be cosmetic composition.
Cleaning compositions according to the present invention include to be neutralized to the aliphatic acid of 70-80%, and with unneutralized fat
Acid is stablized.Therefore, the liposoluble constituent of the high-content in stablizing soap type system and generate enrich foam while, moreover it is possible to rely on
It is quickly defoamed to realize the performance of Rapid Cleaning, to provide use feeling salubrious caused by smooth use feeling when flushing.
The implementation of invention
Hereinafter, will the present invention is described in detail with reference to embodiment.However, it will be understood to those of skill in the art that following
Embodiment is only used as illustration purpose, is not limited to the scope of the present invention.
Embodiment
Face cleaning compositions are prepared according to the following table 1, are mutually compared face's cleaning combination then according to following test method
The foaming capacity of object, defoaming capacity during rinsing and salubrious sense during rinsing.
Specifically, face's cleaning compositions can be obtained according to conventional methods, which includes：In blender
Under conditions of 300-500rpm, in acrylate/C10-C30 alkyl acrylate cross-linked polymers and aliphatic acid, and emulsify
Oil, butter or the wax of high-content.
The results show that in soap type cleaning systems, it is different from other compositions, it is not added with acrylate/C10-C30 alkyl
The comparing embodiment 3 of acrylate crosspolymers cannot form preparation.Therefore, it can be seen that acrylate/C10-C30 alkyl
Acrylate crosspolymers stablize the emulsifying systems in soap type cleaning systems.
Table 1
1. foaming capacity of testing example
By forming face's cleaning compositions of 250ml 1% at a temperature of 25-30 DEG C, and determined using SITA instruments
Foaming capacity.With 800m per minute-1Rotating speed, every time 20 seconds mixings time stir face's cleaning compositions 10 times, last
After secondary stirring (the 10th stirring), foam height is measured, result is shown in the following table 2.
Table 2
The results show that adding acrylate/C10-C30 alkane in the soap type cleaning systems containing high-content liposoluble constituent
Base acrylate crosspolymers, its foaming capacity are equivalent to conventional anion surfactant (comparing embodiment
And the foaming capacity of the cleaning compositions without liposoluble constituent (comparing embodiment 2) 1).Specifically, embodiment 1 is shown aobvious
The high-foaming ability of work.
2. defoaming capacity during rinsing of testing example
Five groups that sensory testing to being subjected to face's detergent practices measure defoaming capacity during rinsing, and defoam energy
Power washes one's hands number to indicate during rinsing until lather collapse.Specifically, 1g is taken out from above-described embodiment with hand
Each obtained face's cleaning compositions are used in combination the tap water of 0.2-0.3g so that it is foamed 15 times with both hands, then, with flowing
Originally water washing both hands, measure the time point of lather collapse.The result for rinsing the number of both hands is shown in the following table 3.
Table 3
The results show that adding acrylate/C10-C30 alkane in the soap type cleaning systems containing high-content liposoluble constituent
Base acrylate crosspolymers so that though there are the liposoluble constituents of high-content, but when being contacted with water, it also can be significantly
Quickly defoaming, to realize quick clean-up performance.In addition, its is not added with propylene higher than comparing embodiment 1 with obvious effectsly
The conventional anion surface activator composition of acid esters/C10-C30 alkyl acrylate cross-linked polymers.
The salubrious sense during rinsing of testing example 3.
Five groups to being subjected to face detergent sensory testing practice measure salubrious sense during rinsing, and are used in test
After sense, to be indicated according to the assessed degree of salubrious sense during rinsing.Specifically, 1g is taken out from above-described embodiment with hand
Each obtained face's cleaning compositions are used in combination the tap water of 0.2-0.3g so that it is foamed 15 times with both hands, then, with flowing
Originally water washing both hands, measure its salubrious sense (i.e. pleasant feeling) revealed out.The result for the degree clearly felt is shown in
The following table 4 evaluates salubrious use feeling with the grade of 1 (clearly feeling weak) to 15 (salubrious sense is strong).
Table 4
The results show that adding acrylate/C10-C30 alkane in the soap type cleaning systems containing high-content liposoluble constituent
Base acrylate crosspolymers clearly feel degree and are equivalent to the composition (comparing embodiment 2) without liposoluble constituent
Salubrious sense degree.In addition, its is not added with acrylate/C10-C30 alkyl acrylics higher than comparing embodiment 1 with obvious effectsly
The conventional anion surface activator composition of ester cross-linked polymer.
Although shown and illustrate exemplary embodiment, those skilled in the art it is understood that do not depart from by
In the case of the open scope defined by attached claim scope, the various changes in form and details can be carried out to it.
Therefore, the scope of the present invention means to include all embodiments fallen into the spirit and scope of attached claim scope.
Claims (8)
1. a kind of cleaning compositions, it includes：
Liposoluble constituent；
Anion surfactant；And
Cross-linked polymer (the acrylate/C10-C30 alkyl acrylates friendship of acrylate and C10-C30 alkyl acrylates
Linked polymer).
2. cleaning compositions according to claim 1, which is characterized in that the liposoluble constituent is total 100 parts by weight
Amount in cleaning compositions is 0.01-50 parts by weight.
3. cleaning compositions according to claim 1, which is characterized in that the liposoluble constituent is selected from by oil, butter
And at least one of the group that wax is constituted.
4. cleaning compositions according to claim 1, which is characterized in that the anion surfactant has carboxyl.
5. cleaning compositions according to claim 1, which is characterized in that the anion surfactant is selected from by the moon
At least one of the group that laureth ammonium sulfate, alkyl amido betaine, Texapon Special and fatty acid soaps are constituted.
6. cleaning compositions according to claim 5, which is characterized in that the fatty acid soaps be selected from by lauric acid soap,
At least one of the group that myristic acid soap, palmitic acid soap, stearate soap, bitter soap, capric acid soap and oleate soap are constituted.
7. cleaning compositions according to claim 6, which is characterized in that the fatty acid soaps include：
At least one aliphatic acid, selected from by lauric acid, myristic acid, palmitic acid, stearic acid, octanoic acid, capric acid and oleic acid institute structure
At group；With
At least one basifier, selected from the group being made of potassium hydroxide, sodium hydroxide, triethanolamine and methylglucosamine.
8. cleaning compositions according to claim 1, which is characterized in that the anion surfactant and acrylic acid
Amount of the ester/C10-C30 alkyl acrylate cross-linked polymers in total cleaning compositions of 100 parts by weight be respectively
0.01-30 parts by weight and 0.01-2 parts by weight.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020150137680A KR102045878B1 (en) | 2015-09-30 | 2015-09-30 | Cleansing composition comprising higt content of fat-soluble ingredients |
| KR10-2015-0137680 | 2015-09-30 | ||
| PCT/KR2016/010643 WO2017057874A1 (en) | 2015-09-30 | 2016-09-23 | Detergent composition containing high contents of fat-soluble ingredients |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108431198A true CN108431198A (en) | 2018-08-21 |
Family
ID=58424199
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201680058914.0A Pending CN108431198A (en) | 2015-09-30 | 2016-09-23 | The cleaning compositions of liposoluble constituent containing high-content |
Country Status (6)
| Country | Link |
|---|---|
| KR (1) | KR102045878B1 (en) |
| CN (1) | CN108431198A (en) |
| HK (1) | HK1251608A1 (en) |
| SG (1) | SG11201801398WA (en) |
| TW (1) | TWI733697B (en) |
| WO (1) | WO2017057874A1 (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1184417A (en) * | 1995-04-12 | 1998-06-10 | 普罗克特和甘保尔公司 | Cleansing emulsions |
| CN1411339A (en) * | 1999-10-19 | 2003-04-16 | 宝洁公司 | Antimicrobial composition comprising benzoic acid analog and metal salt |
| KR101105810B1 (en) * | 2004-03-24 | 2012-01-17 | 주식회사 엘지생활건강 | Body cleanse compositiom |
| CN103200926A (en) * | 2010-10-05 | 2013-07-10 | 路博润高级材料公司 | Acrylate copolymer thickeners |
| CN103379889A (en) * | 2010-09-30 | 2013-10-30 | 路博润高级材料公司 | Structured acrylate copolymer for use in multi-phase systems |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5543074A (en) * | 1994-02-18 | 1996-08-06 | Chesebrough-Pond's Usa Co., Div. Of Conopco, Inc. | Personal washing compositions |
| US6207763B1 (en) * | 1998-06-12 | 2001-03-27 | Bridgestone Corporation | Application of disubstituted ethylene-maleimide copolymers in rubber compounds |
| FR2780278B1 (en) * | 1998-06-24 | 2001-01-19 | Oreal | CONDITIONING AND DETERGENT COMPOSITION AND USE |
| KR20050019288A (en) * | 2003-08-18 | 2005-03-03 | 씨제이 주식회사 | Toilet Soap Composition |
| KR100760973B1 (en) | 2006-03-27 | 2007-10-04 | 전익홍 | Manufacture method cleaning solution composition and cleaning solution composition |
| KR101912966B1 (en) * | 2011-03-22 | 2018-10-29 | 헨켈 아게 운트 코. 카게아아 | Liquid laundry detergent comprising capsules |
-
2015
- 2015-09-30 KR KR1020150137680A patent/KR102045878B1/en active IP Right Grant
-
2016
- 2016-09-19 TW TW105130157A patent/TWI733697B/en active
- 2016-09-23 CN CN201680058914.0A patent/CN108431198A/en active Pending
- 2016-09-23 WO PCT/KR2016/010643 patent/WO2017057874A1/en active Application Filing
- 2016-09-23 SG SG11201801398WA patent/SG11201801398WA/en unknown
-
2018
- 2018-08-29 HK HK18111125.5A patent/HK1251608A1/en unknown
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1184417A (en) * | 1995-04-12 | 1998-06-10 | 普罗克特和甘保尔公司 | Cleansing emulsions |
| CN1411339A (en) * | 1999-10-19 | 2003-04-16 | 宝洁公司 | Antimicrobial composition comprising benzoic acid analog and metal salt |
| KR101105810B1 (en) * | 2004-03-24 | 2012-01-17 | 주식회사 엘지생활건강 | Body cleanse compositiom |
| CN103379889A (en) * | 2010-09-30 | 2013-10-30 | 路博润高级材料公司 | Structured acrylate copolymer for use in multi-phase systems |
| CN103200926A (en) * | 2010-10-05 | 2013-07-10 | 路博润高级材料公司 | Acrylate copolymer thickeners |
Also Published As
| Publication number | Publication date |
|---|---|
| TW201716565A (en) | 2017-05-16 |
| KR102045878B1 (en) | 2019-11-18 |
| WO2017057874A1 (en) | 2017-04-06 |
| TWI733697B (en) | 2021-07-21 |
| HK1251608A1 (en) | 2019-02-01 |
| KR20170038381A (en) | 2017-04-07 |
| SG11201801398WA (en) | 2018-04-27 |
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