CN105997546A - Body cleansing composition - Google Patents

Body cleansing composition Download PDF

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Publication number
CN105997546A
CN105997546A CN201610192116.9A CN201610192116A CN105997546A CN 105997546 A CN105997546 A CN 105997546A CN 201610192116 A CN201610192116 A CN 201610192116A CN 105997546 A CN105997546 A CN 105997546A
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composition
formula
mass
fatty acid
carbon number
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CN105997546B (en
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山仲蓝子
松尾谕
藤田博也
上田龙
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NOF Corp
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NOF Corp
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/42—Amides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36—Carboxylic acids; Salts or anhydrides thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36—Carboxylic acids; Salts or anhydrides thereof
    • A61K8/361—Carboxylic acids having more than seven carbon atoms in an unbroken chain; Salts or anhydrides thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/58—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing atoms other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur or phosphorus
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/04—Carboxylic acids or salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/667—Neutral esters, e.g. sorbitan esters
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
    • A61K2800/28—Rubbing or scrubbing compositions; Peeling or abrasive compositions; Containing exfoliants

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Dermatology (AREA)
  • Emergency Medicine (AREA)
  • Cosmetics (AREA)
  • Detergent Compositions (AREA)

Abstract

The invention provides a body cleaning composition which is capable of obtaining good rapid foaming performance and foam quality even if hard water is used, inhibiting or eliminating the uptight feel after washing and providing a fresh and cool feel. The body cleaning composition is characterized in that the body cleaning composition comprises an (a) component: 0.1-20 mass% of surfactant expressed by a formula (1); a (b) component: 10-50 mass% of fatty acid with a carbon number 8-22, and a (a) component: 0.1-40 mass% of surfactant expressed by a formula (2), wherein the mass ratio ((a)/(b)) of the (a) component to the (b) component is 0.01-0.8, the mass ratio ((a)/(c)) of the (a) component to the (c) component is 0.05-1, in the formula (1), each symbol is defined in the specification, and in the formula (2), each symbol is defined in the specification.

Description

Body detergent composition
Technical field
The present invention relates to a kind of body detergent composition, even if it also can obtain good quickly rising when using hard water Bubble property and foam quality, and can suppress or eliminate tight sense after washing, give salubrious sense.
Background technology
Body detergent composition not only payes attention to the cleaning force of dirt, more payes attention to foam situation.Such as, superfine greasy dense Close foam, as the padded coaming between skin and hands or the towel etc. when wiping skin, has and alleviates the friction to skin Effect, and dirt easily taken out of from pore by superfine greasy foam, so the effects such as cleaning force increase can be expected, further, Require by quickly causing abundant foam to obtain the good foaming characteristics such as gratification.Make an addition to as due to above-mentioned factor Cleansing in body detergent composition, (the most superfine greasy dense owing to can quickly obtain good foam quality Foam) reason, be widely used for soap.
But, if containing the mineral such as a large amount of calcium ions or magnesium ion in the water used, then exist because of fatty acid and this A little metal ions form salt and bubble easy degree and the problem of foam quality reduction.
Therefore, attempt by combining various compound in soap, to solve this technical problem.Additionally, The cleaning force of soap is high, but another side, degreasing power height is also one of problem.To this, become as the cleaning gentle to skin Point, acylamino acid analog anion surfactants can be listed.
But, although acylamino acid analog anion surfactants can alleviate the burden to skin, but and soap Comparing, easy degree of bubbling or foam quality cannot attain full and complete satisfaction.
Additionally, in body detergent composition, in addition to cleaning force or foam, the skin state after washing is the heaviest Want.As the feature of soap, can list after a procedure skin feel to tight sense.Further, if the water used During hardness height, tight sense is stronger.This tight sense is a kind of usual undesirable thoughts and feelings.If it is additionally, right alleviating The acylamino acid analog anion surfactants of the burden of skin is as principal cleaning ingredients, although do not tend to have tight sense, but Can feel sticky, this sticky be also a kind of usual undesirable thoughts and feelings.That is, for body detergent composition, except cleaning Beyond power and foam, after washing, it is difficult to feel tight sense and sticky the most critically important, such as, requires that the skin after washing is clearly sense The state touched.
Such as, in patent documentation 1, disclose one be added with fatty acid, coconut oil fat acid methyl taurine sodium or The skin of the water insoluble solid powder such as acylated amino acids surfactant, Muscovitum or Talcum such as sodium lauroyl sarcosine is clear Clean compositions.Though said composition inhibits the tight sense after washing, but when the hardness of water height used, quick foaming characteristic and bubble Foam quality is insufficient.
Additionally, in patent documentation 2, disclose a kind of powder shower use being added with soap and acylglycine salt Compositions.Though said composition inhibits the tight sense after washing, and can obtain good foam quality, but in the hardness of water used Gao Shi, quick foaming characteristic is insufficient.
In patent documentation 3, disclose the combination by soap Yu sugar alcohol and edetic acid etc., improve when the water used Foaming during hardness height, it is possible to suppress tight sense.But, the salubrious sense after washing in the method is insufficient.
As mentioned above, it is difficult to develop a kind of quick foaming characteristic, good foam quality met when using hard water and press down Make tight sense, give the body detergent composition clearly felt simultaneously.
Prior art literature
Patent documentation
Patent documentation 1: Unexamined Patent 8-3030 publication
Patent documentation 2: JP 2007-302625 publication
Patent documentation 3: JP 2007-39350 publication
Summary of the invention
The technical problem to be solved in the present invention
It is an object of the invention to provide a kind of body detergent composition, even if it also can obtain good when using hard water Good quick foaming characteristic and foam quality, and can suppress or eliminate tight sense after washing, give salubrious sense.
Additionally, " can obtain good quick foaming characteristic " in the present invention also can be excellent in other words as easy degree of bubbling, " good foam quality can be obtained " and such as refer to obtain the foam of superfine greasy dense (creaminess).
Solve the technological means of technical problem
Present inventors etc. find after conscientiously research, contain specific anionic surface with specific ratio and live Property agent and the body detergent composition of specific soap be capable of above-mentioned purpose.
That is, the present invention is a kind of body detergent composition, it is characterised in that contain:
(a) composition: surfactant 0.1～20 mass % represented by formula (1),
(b) composition: soap 10～50 mass % of carbon number 8～22,
(c) composition: surfactant 0.1～40 mass % represented by formula (2),
A () composition is 0.01～0.8 with the mass ratio ((a)/(b)) of (b) composition, (a) composition and the mass ratio of (c) composition ((a)/(c)) is 0.05～1,
[chemical formula 1]
In formula (1), R1CO represents the aliphatic acyl radical of carbon number 8～22, R2Represent the straight of singly-bound or carbon number 1～4 Chain or the alkylidene of side chain, R3Represent the alkylidene of the straight or branched of carbon number 1～4, M1Represent alkali metal atom, alkane Hydramine (ア Le カ ノ Le ア ミ Application),
[chemical formula 2]
In formula (2), R4CO represents the aliphatic acyl radical of carbon number 8～22, and n represents the integer of 1～2, M2Represent alkali metal Atom, alkanolamine.
Invention effect
According to the body detergent composition of the present invention, even if good quick foaming characteristic also can be obtained when using hard water And foam quality, and can suppress or eliminate tight sense after washing, give salubrious sense.
Additionally, " hard water " in this specification refers to the water that Unite States Standard hardness is more than 120ppm.
Detailed description of the invention
Hereinafter, embodiments of the present invention are illustrated.
The body detergent composition of the present invention at least contains following (a) composition, (b) composition and (c) composition.
[(a) composition]
(a) composition used in the present invention is the surfactant represented by formula (1).
R in formula (1)1CO represents carbon number 8～22, the aliphatic acyl radical of preferred carbon number 8～18.In aliphatic In acyl group, not only include that satisfied fatty acid or unsaturated fatty acid with carbon number 8～22 are the acyl group originated, also include coming The acyl group of the two or more fatty acid mixed in these fatty acids self-contained.Include, for example out coco-nut oil fatty acid acyl group, Palm kernel fatty acid acyl group, caproyl, lauroyl, myristoyl, palmityl, stearyl, oleoyl, behenyl acyl Base (ベ ヘ ニ Le base) etc..It is preferably lauroyl, myristoyl, coco-nut oil fatty acid acyl group, palm kernel fatty acid acyl Base.Particularly preferably lauroyl, coco-nut oil fatty acid acyl group, palm kernel fatty acid acyl group.
R in formula (1)2Represent the alkylidene of the straight or branched of singly-bound or carbon number 1～4.As R2, such as, can arrange Enumerate methylene, ethylidene, positive propylidene, isopropylidene, positive butylidene, isobutylene etc., preferably ethylidene, positive Asia third Base.That is, as the R in formula (1)2OH, include, for example out monohydroxy ethyl, monohydroxy propyl group, monohydroxy isopropyl, monohydroxy Butyl, 2-hydroxybutyl etc..It is preferably monohydroxy ethyl, monohydroxy propyl group.
Additionally, the R in formula (1)3Represent the alkylidene of the straight or branched of carbon number 1～4.As R3, include, for example Go out methylene, ethylidene, positive propylidene, isopropylidene, positive butylidene, isobutylene etc., preferably ethylidene, positive propylidene. That is, the R in formula (1)3It is different that COOH include, for example out mono carboxylic methylene, mono carboxylic ethylidene, mono carboxylic propylidene, mono carboxylic Propylidene, mono carboxylic butylidene, mono carboxylic isobutylene etc..It is preferably mono carboxylic ethylidene.
M in formula (1)1Represent alkali metal atom, alkanolamine.As alkali metal atom, include, for example out sodium, potassium Deng.Additionally, as alkanolamine, monoethanolamine, diethanolamine, triethanolamine etc. can be listed.Wherein, preferably sodium, potassium, three Ethanolamine.
As the concrete example of the surfactant represented by formula (1), include, for example out lauroyl hydroxyethyl alanine Sodium, lauroyl hydroxyethyl alanine triethanolamine, lauroyl hydroxypropyl alanine triethanolamine, cocoyl hydroxyethyl Sodium L-alaninate etc..
(a) composition of the present invention can suitably select in the compound comprised in described formula (1) one or more make With.
[(b) composition]
(b) composition used in the present invention is the soap of carbon number 8～22.
The carbon number of fatty acid is preferably 10～20, particularly preferably 12～18.Additionally, as carbon number 8～22 Fatty acid, include, for example lauric acid, myristic acid, Palmic acid, different Palmic acid, stearic acid, isostearic acid, oleic acid etc..This Outward, the fatty acid mixed of the mixture as fatty acid can be used, as this fatty acid mixed, include, for example out Cortex cocois radicis oils and fats Fat acid, palm kernel fatty acid, tallow fatty acids etc..It is preferably lauric acid, myristic acid, Palmic acid, stearic acid, oleic acid, coconut palm Seed oil fatty acid, palm kernel fatty acid, particularly preferably lauric acid, myristic acid, Palmic acid, stearic acid.
Additionally, as the counter ion (counterion) of formation salt, the alkali metal atom such as sodium, potassium, Dan Yi can be listed The organic amines such as hydramine, diethanolamine, triethanolamine.It is preferably sodium, potassium, triethanolamine, particularly preferably potassium.
(b) composition of the present invention, can suitably select to use in described soap one or more.
[(c) composition]
(c) composition used in the present invention is the surfactant represented by formula (2), for sulfonylmethyl monocarboxylate.
R in formula (2)4Aliphatic acyl radical that CO represents carbon number 8～22, that be preferably expression carbon number 8～18. In aliphatic acyl radical, not only include that satisfied fatty acid or unsaturated fatty acid with carbon number 8～22 are the acyl group originated, also Acyl group including the two or more fatty acid mixed come in self-contained described fatty acid.Include, for example out coco-nut oil fatty acid Acyl group, palm kernel fatty acid acyl group, caproyl, lauroyl, myristoyl, palmityl, stearyl, oleoyl, Behenyl acyl group etc..It is preferably lauroyl, myristoyl, coco-nut oil fatty acid acyl group, palm kernel fatty acid acyl group, especially It is preferably lauroyl, coco-nut oil fatty acid acyl group, palm kernel fatty acid acyl group.
N in formula (2) represents the integer of 1～2.
M2Represent alkali metal atom, alkanolamine.As alkali metal atom, include, for example out sodium, potassium etc..Additionally, make For alkanolamine, monoethanolamine, diethanolamine, triethanolamine etc. can be listed.Wherein, preferably sodium, potassium, triethanolamine.
As the concrete example of the surfactant represented by formula (2), include, for example out lauroyl methyl alanine three second Hydramine, lauroyl methyl Sodium L-alaninate, lauroyl methyl glycine triethanolamine, Hamposyl L triethanolamine, Semen Myristicae Acyl methylalanine triethanolamine, myristoyl methyl Glycine sodium, coco-nut oil fatty acid methylalanine sodium, coconut oil fat Acid sodium sarcosinate, coco-nut oil fatty acid methylglycine triethanolamine etc..
(c) composition of the present invention can suitably select to use in the compound comprised in described formula (2) one or both with On.
Then, the content for each composition of the body detergent composition of the present invention illustrates.
Relative to body detergent composition, the content of (a) composition is 0.1～20 mass %, preferably 0.5～15 matter Amount %, particularly preferably 1～10 mass %.Foamy body in the case of the content of (a) composition is too little or too much, during cleaning It is deteriorated.
Relative to body detergent composition, the content of (b) composition is 10～50 mass %, preferably 20～40 matter Amount %, particularly preferably 25～35 mass %.B the content of () composition is very few in the case of, easy degree of bubbling or foam thin Greasy property reduces, the content of (b) composition too much in the case of, surfactant can be caused to separate out when low temperature, stability reduction etc. Problem.
Relative to body detergent composition, the content of (c) composition is 0.1～40 mass %, preferably 0.5～30 matter Amount %, particularly preferably 1～20 mass %.C the content of () composition is very few in the case of, quick foaming characteristic during cleaning is not filled Point, the content of (c) composition too much in the case of, surfactant can be caused to separate out when low temperature, the problem such as stability reduction.
The mass ratio ((a)/(b)) of (a) composition of the body detergent composition of the present invention and (b) composition be 0.01～ 0.8, preferably 0.1～0.4.In the case of mass ratio ((a)/(b)) is excessive, the suppression to tight sense is the most abundant.Mass ratio In the case of ((a)/(b)) is too small, salubrious sense is insufficient.
Additionally, the mass ratio ((a)/(c)) of (a) composition and (c) composition is 0.05～1, preferably 0.15～0.6.Quality In the case of more excessive than ((a)/(c)), quick foaming characteristic or foamy body are insufficient.The situation that mass ratio ((a)/(c)) is too small Under, foamy body is insufficient.
The body detergent composition of the present invention can be according to usual way manufacture.The body detergent composition of the present invention Solvent can also be contained.As solvent, the lower alcohol such as water outlet, ethanol or aqueous lower alcoholic solutions, particularly preferably water can be enumerated.
Each composition of (a)～(c) of the body detergent composition of the present invention and the total content of water equal solvent are 100 matter Amount below %.
If the body detergent composition of the present invention is for the purpose of clean body, then it is not limited to aqueous, gel etc. Occupation mode, such as, can be used as bath gel, cleansing milk, handwashing liquid.
Additionally, the body detergent composition of the present invention can be in the range of the effect not damaging the present invention, as required Containing other surfactants normally used or wetting agent in the cleaning agent of hair or health, oil point, water soluble polymer, The various compositions such as preservative, antibacterial, pH adjusting agent.
As other surfactants, can list cationic surfactant, anionic surfactant (except (a) and (c) composition.), amphoteric surfactant, nonionic surfactant, wherein preferably comprise amphoteric surfactant or Nonionic surfactant.
As amphoteric surfactant, include, for example out cocos nucifera oil acyl both sexes base sodium acetate, lauroylamidopropyl betaine, Cocamido propyl betaine, Laurel imines (ラ ウ ラ ミ ノ) sodium diacelate etc., as nonionic surfactant, such as Sorbitol anhydride laurate, sorbitol anhydride cetylate, sorbitan oleate, sorbitan tristearate can be listed, gather Oxygen ethylene sorbitol anhydride laurate, polyoxyethylene sorbitol acid anhydride cetylate, polyoxyethylene sorbitol acid anhydride oleate, polyoxy second The sorbitan carboxylic esters classes such as alkene sorbitan tristearate；The fatty acid glycerides such as tristerin；Polyglycereol Laurel Acid esters；Polyglycereol Laurel ether；The sucrose-fatty esters such as Surfhope SE Cosme C 1216, sucrose stearate；Laureth-4 grade is gathered Oxyalkylene alkyl ether；The polyoxy alkylidene esters such as PEG-4 laurate or PEG-7 glyceryl cocoate；Can enumerate further Go out the alkanolamide classes etc. such as cocoanut fatty acid diethanolamide.Even if especially in nonionic surfactant, stearic Acid glyceride can make the formula system stabilisation of body detergent compositions such as washing one's face, therefore exists and is preferably added with this mesh Situation.
Relative to body detergent composition, the content of other surfactants is 0.1～20 mass %, preferably 0.5 ～15 mass %, particularly preferably 1～10 mass %.
As wetting agent, include, for example out glycerol, propylene glycol, 1,3 butylene glycol, two glycerol, Sorbitol etc..
Divide as oil, include, for example out the hydrocarbon ils such as liquid paraffin, hard paraffin, vaseline；Isopropyl myristate, meat The ester oils such as myristic acid octyldodecyl, isopropyl palmitate, Dermol DIPS；The pure silicon oil such as dimethyl polysiloxane The silicone oil etc. such as (straight silicone oil) or the modified silicon oil being imported with polyether-based, amino, fatty acid acyl amido etc..
As water soluble polymer, include, for example out starch, methylcellulose, hydroxyethyl cellulose, hydroxy propyl cellulose The nonionic macromolecules such as element, guar gum, xanthan gum；Carboxymethyl starch, carboxymethyl cellulose, alginic acid, Radix Acaciae senegalis etc. Anionic property macromolecule；Cationic starch；Dimethyl diallyl ammonium chloride acrylamide copolymer (polyquaternary ammonium salt-7), Poise C-80M (Polyquaternium-10), dimethyl diallyl ammonium chloride acrylic copolymer (Merquat 280), The cationic macromolecules etc. such as acrylamide acrylic acid dimethyl diallyl ammonium chloride copolymer (polyquaternary ammonium salt-39).
As preservative and antibacterial, include, for example out benzoic acid or its salt, p-Hydroxybenzoate, para hydroxybenzene The parabens such as methyl formate, propyl p-hydroxybenzoate, phenoxyethanol etc..
As pH adjusting agent, include, for example out the organic acid such as citric acid, sodium citrate and salt, potassium hydroxide, hydrogen-oxygen Change sodium, triethanolamine etc..
Embodiment
[embodiment 1～12 and comparative example 1～8]
Hereinafter, by embodiment and comparative example, the present invention is specifically described.
According to interpolation ratio (quality %) described in table 1 and table 2, prepare body detergent composition according to usual method.
Using the body detergent composition that obtains in embodiment and comparative example as sample, carry out following evaluation, its result It is summarized in table 1 and table 2.
(1) quick foaming characteristic (the easy degree of foaming when using hard water to be cleaned)
Using 20 men and women (24～47 years old) as participant, use the water of hardness 150,40 DEG C, evaluate 5g sample in hands Lather quickness during foaming.Feel that the fast situation of lather quickness is calculated as 2 points, feel that the fastest situation of lather quickness is calculated as 1 point, sense To bubbling, slow situation is calculated as 0 point, obtains the total score of 20 participants, evaluates as follows:
◎: total score is more than 35 points；Bubble the fastest.
Zero: total score is more than 30 points, less than 35 points；Bubble fast.
△: total score is more than 20 points, less than 30 points；Bubble slow.
×: total score is less than 20 points；Bubble the slowest.
(2) bubble density
The body detergent composition aqueous solutions of the 40 of 200g DEG C (1 mass % dilutes with the water of hardness 150) are put into basin In, rotate into row by hand-held mixer (Bei Yin Co., Ltd. system, DK5031) with per minute 800 and bubble for 1 minute.By in basin Inclusions moves to 500mL graduated cylinder, is placed on bubble by the buoy (fluorescence synthesis ball 15, weight 10g) of band sliding weight of steelyard (5g), measures floating Mark centrage sinks down into time when being equivalent to 100mL scale, steeps density with following benchmark evaluation.
◎: by more than 15 seconds time；Bubble density is the highest.
Zero: by more than 10 seconds time less than 15 seconds；Bubble density is high.
△: by more than 5 seconds time less than 10 seconds；Bubble density is low.
×: by more than 0 second time less than 4 seconds；Bubble density is the lowest.
(3) clearly feel
Using 20 men and women (24～47 years old) as participant, 5g sample is placed in hands, uses the water of hardness 150,40 DEG C Wash one's hands, after wiping aqueous vapor with towel, by making participant's number that the salubrious sense of skin is evaluated, with following benchmark evaluation.
◎: 18～20；Feel strong salubrious sense.
Zero: 11～17；Feel fraction of salubrious sense.
△: 7～10；It is difficult to feel clearly to feel.
×: 0～6；Do not feel completely clearly to feel.
(4) suppression of tight sense
Using 20 men and women (24～47 years old) as participant, 5g sample is placed in hands, uses the water of hardness 150,40 DEG C Wash one's hands, after wiping aqueous vapor with towel, by making the participant's number not having the tight sense of skin to evaluate, with following benchmark evaluation.
◎: 18～20；Do not feel tight sense.
Zero: 11～17；It is difficult to feel tight sense.
△: 7～10；Feel a little tight sense.
×: 0～6；Feel strong tight sense.
Embodiment 1～12 is good evaluation in arbitrary project.
On the other hand, owing to comparative example 1 is without (a) composition, thus while salubrious sense is good, but quickly foaming characteristic, steep close Degree, tight sense suppress insufficient.
Owing to comparative example 2 is without (c) composition, thus while tight sense can be suppressed, but quickly foaming characteristic, bubble density, clear Refreshing sense is insufficient.
Owing to comparative example 3 does not contains (b) composition, thus while salubrious sense, tight sense suppression are well, but quickly foaming characteristic, bubble Density is insufficient.
Comparative example 4, without (a) composition, replaces containing acyl methyl taurine salt, and salubrious sense is good.But quickly rise Bubble property, bubble density, tight sense suppress the most insufficient.
Comparative example 5 is without (a) composition, containing (b) composition, (c) composition, other silicon dioxide etc., quick foaming characteristic, steep close Degree, salubrious sense, tight sense suppress the most insufficient.
Comparative example 6 is containing (a) composition and as the lauryl dimethyl amine guanidine-acetic acid glycine betaine of other compositions or sucrose-fatty Ester, although tight sense can be suppressed, but quickly foaming characteristic, bubble density and salubrious sense are insufficient.
(a) composition of comparative example 7 has exceeded, with the mass ratio ((a)/(c)) of (c) composition, the higher limit that present invention provide that, because of Although this tight sense suppression is good, but quickly foaming characteristic or bubble density, salubrious sense are insufficient.
(a) composition of comparative example 8 has exceeded, with the mass ratio ((a)/(b)) of (b) composition, the higher limit that present invention provide that, because of Although this tight sense suppression is good, but quickly foaming characteristic or bubble density are insufficient.
Further, the Formulation Example of the body detergent composition of the present invention is represented in detail below.
[table 3] Formulation Example 1
Composition Add than (quality %)
Lauroyl hydroxyethyl Sodium L-alaninate 3
Potassium laurate 1
Potassium myristate 10
Potassium palmitate 8
Lauroyl methyl alanine triethanolamine 9
Glycerol 3
HYDROXY PROPYL METHYLCELLULOSE 0.2
Polyquaternary ammonium salt-7 (5.5%) 1.5
Methyl parahydroxybenzoate 0.2
Propyl p-hydroxybenzoate 0.1
Spice 0.1
Water 63.9
[table 4] Formulation Example 2
[table 5] Formulation Example 3
Composition Add than (quality %)
Lauroyl hydroxyethyl Sodium L-alaninate 2
Potassium laurate 6
Potassium myristate 3
Potassium palmitate 2
Potassium stearate 1
Lauroyl methyl alanine triethanolamine 6
Glyceryl monostearate 2
Propylene glycol 6
Glycerol 10
Liquid paraffin 5
Vaseline 1
Hard paraffin 1
Water 55
[table 6] Formulation Example 4
Composition Add than (quality %)
Lauroyl hydroxyethyl Sodium L-alaninate 2
Potassium laurate 1
Potassium myristate 10
Potassium palmitate 8
Lauroyl methyl Sodium L-alaninate 8
Lauryl dimethyl oxyneurine 2
Glycerol 3
Isopropyl methyl phenol 0.1
Hydroxypropyl methyl cellulose 0.2
Polyquaternium-10 0.1
Phenoxyethanol 0.5
Sodium benzoate 0.5
Spice 0.1
Water 64.5
Even if the body detergent composition of these Formulation Examples is when using hard water, it is also possible to obtain good quick foaming Property and foam quality, the suppression of the tight sense of the skin after washing or eliminate and good in terms of the imparting of salubrious sense.
Industrial applicibility
When the body detergent composition of the present invention is suitable to take a shower, it is particularly suitable for when using hard water to take a shower using, even if When using hard water, it is also possible to obtain good quick foaming characteristic and foam quality, and can suppress or eliminate after washing tight Stretch tight sense, give salubrious sense.

Claims (1)

1. a body detergent composition, it is characterised in that contain:
(a) composition: surfactant 0.1～20 mass % represented by formula (1),
(b) composition: soap 10～50 mass % of carbon number 8～22,
(c) composition: surfactant 0.1～40 mass % represented by formula (2),
A () composition is 0.01～0.8 with the mass ratio ((a)/(b)) of (b) composition,
A () composition is 0.05～1 with the mass ratio ((a)/(c)) of (c) composition,
[chemical formula 1]
In formula (1), R1CO represents the aliphatic acyl radical of carbon number 8～22, R2Represent singly-bound or the straight chain of carbon number 1～4 or The alkylidene of side chain, R3Represent the alkylidene of the straight or branched of carbon number 1～4, M1Represent alkali metal atom, alkanolamine,
[chemical formula 2]
In formula (2), R4CO represents the aliphatic acyl radical of carbon number 8～22, and n represents the integer of 1～2, M2Represent that alkali metal is former Son, alkanolamine.
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JP2007169175A (en) * 2005-12-20 2007-07-05 Lion Corp Biphenyl ether derivative or its salt, and external preparation composition
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