CN108409432A - The micro- fertilizer of rich selenium germanium multielement humic acid - Google Patents
The micro- fertilizer of rich selenium germanium multielement humic acid Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
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- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F17/00—Preparation of fertilisers characterised by biological or biochemical treatment steps, e.g. composting or fermentation
- C05F17/20—Preparation of fertilisers characterised by biological or biochemical treatment steps, e.g. composting or fermentation using specific microorganisms or substances, e.g. enzymes, for activating or stimulating the treatment
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- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
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Abstract
It is to belong to the micro- fertile preparation technique field of Huinong's science and technology humic acid the invention discloses a kind of micro- fertilizer of rich selenium germanium multielement humic acid.By the micro- fertilizer of the rich selenium germanium zinc humic acid sodium boron magnesium phosphorus, the micro- fertilizer of rich selenium germanium humic acid ferrisodium ammonia phosphorus boron magnesium, rich selenium germanium medical stone multielement humic acid compound trace element fertilizer, the micro- fertilizer composition of rich selenium germanium release element anion potassium calcium sodium boron magnesium.Trace element is photosynthesis in plant mostly; breathing and substance transformation; it is the component part of " enzyme " or " coenzyme "; it is very active in plant; due to the element shortage or deficiency plant appearance morbid state in soil; also correspondingly there is morbid state as people and animals take in this food; wherein especially selenium Germanium lacks easily raw cancer; so the micro- fertilizer of reasonable development application rich selenium germanium multielement humic acid; agricultural output, quality are not only improved, health, function of anti-cancer and cancer prevention are improved; strong people power, promotes the well-being of mankind.
Description
Technical field
It is to belong to the micro- fertilizer of Huinong's science and technology humic acid to prepare life the invention discloses a kind of micro- fertilizer of rich selenium germanium multielement humic acid
Produce technical field.
Background technology
The humic acid of the micro- fertilizer of humic acid is to be decomposed through microorganism and chemical action by dead animals and plants and formed
A kind of amorphous macromolecule compound, is widely present in peat soil and weathered coal, humic acid contain aromatic radical, carboxyl, carbonyl,
Methoxyl group isoreactivity gene has acidity, hydrophily, cation exchangeability and physiological activity etc., in low fertility, low yield area,
Crop early period there is fertilizer efficiency relatively certainly.
China produces at present and the humic acid chelating trace-element fertilizer used has sodium humate boric magnesium fertilizer, sodium humate boron
Phosphate fertilizer, sodium humate boron magnesium nitrogen phosphorus fertilizer, humic acid various trace elements composite fertilizer and fulvic acid diamines iron etc..
The micro- fertilizer of humic acid chelating can be spread fertilizer over the fields, band is applied, can also be sprayed with water dissolution.It can make top dressing, to rice, sweet
The crops such as sugarcane, tobacco, vegetables, fruit tree have apparent effect.
The micro- fertilizer of rich selenium germanium multielement humic acid is in dead animals and plants waste, is with rich selenium germanium, ganoderma lucidum, ferment
Mother, spirulina, vinasse are fermented cultivates.
It is understood that free radical excessive in human body is the major reason that canceration occurs for cell.Selenium has powerful anti-oxidant energy
Power can remove extra free radical, and the tumor suppressor gene in energy active cell, prevent normal cell carcinogenesis.Selenium can improve
The immune function of human body, killing or the growth and transfer for inhibiting cancer cell.Selenium can inhibit tumor vascular formation, and it is thin to limit cancer
Born of the same parents obtain the source of nutrition, to delay the growth of cancer cell.Selenium can inhibit drug resistance of the cancer cell to chemotherapeutics.Usualization
It is longer to treat drug usage time, cancer cell often will produce drug resistance, and curative effect declines, this is a difficult point for the treatment of of cancer.And selenium
Cancer cell can be made to restore the sensibility to chemotherapeutics, thus improve curative effect.
A large amount of animality experiment and clinical research verified organic germanium and life have it is important contact, and can be applied to
The antioxidant of nutraceutical, just causing the world of medicine, nutrition circle attention.Japanese Scientists water island etc. is once to the effect of Ge-132
It is studied, the experimental results showed that Ge-132 is not only a kind of immunopotentiator, and is a kind of immunomodulator.It is anti-
Cancer, anti-hypertension, anti-aging effects are to induce interferon and the work of enhancing natural killer cells, macrophage activation reality by body
Existing.Germanium can induce interferon, activate the cell for being responsible for defendance body, to adjust immune system, therefore have to all kinds of cancers
Significant effect.
Organic germanium has synergistic effect with selenium, can prevent artery sclerosis, and clinically germanium and selenium can be with antitumor, preventions
Hepatopathy, anti-aging.
Therefore, the application of the micro- fertilizer of rich selenium germanium multielement humic acid increases the multielement of germanium containing selenium of agri-foodstuffs fruit and vegetable,
Promote human elementary balanced, health lengthens one's life, and is power's matter of fundamental importance, is worthy of popularization.
Invention content
The purpose of the present invention is to provide a kind of micro- fertilizer of rich selenium germanium multielement humic acid.
Technical solution of the invention is：
1, a kind of micro- fertilizer of rich selenium germanium multielement humic acid, it is characterized in that：The micro- fertilizer of the rich selenium germanium zinc humic acid sodium boron magnesium phosphorus, is pressed
Row quality proportioning forms %
Se-rich lucid ganoderma bacterium 0.2-0.6；Germanium-rich glossy ganoderma 0.2-0.6；
Montmorillonite powder 1-3；Boron mud 2-6；
Zinc sodium boron magnesium ground phosphate rock 1-3；Useless schlempe 3-9；
Yeast powder 1-3；Animal waste wool skin 5-15；
Turf 10-30；Water adds to 100.
Preparation method：
After mixing in top ratio, 70 DEG C are warmed to after adding water, 5-7d is stacked, allows it fully to ferment more to get rich selenium germanium
The micro- fertilizer of element zinc humic acid sodium boron magnesium phosphorus.Product pH is 7-8, which can make base fertilizer or top dressing, and amount of application reaches 7500kg/hm2, right
Sorghum, soybean, corn have positive effect.
2, a kind of micro- fertilizer of rich selenium germanium multielement humic acid, it is characterized in that：The rich selenium germanium humic acid ferrisodium ammonia phosphorus boron magnesium is micro-
Fertilizer forms % by following quality proportioning
Yeast rich in selenium 0.2-0.6；Germanium-enriched yeast bacterium 0.2-0.6；
Zeolite powder 1-3；Turf 0.5-1.5；
Ammonium bicarbonate 0.7-2.1；Ferrisodium ammonia phosphorus boron magnesium ore powder 0.7-2.1；
Pine needle series extract 2-6；Yeast powder 1-3；
Boron mud 1.2-3.6；Water adds to 100.
Preparation method：
After being mixed evenly in top ratio, water is added to be heated up to 80 DEG C, heap side's time is to allow within 1 week or so its abundant decomposing and fermenting
Up to micro- fertilizer.
The fertilizer is particularly evident to corn yield increasing, using 375kg/hm2, 50% or so can be increased production.
3, a kind of micro- fertilizer of rich selenium germanium multielement humic acid, it is characterized in that：The rich selenium germanium medical stone multielement humic acid is multiple
Hefei forms % by following quality proportioning
Nanometer selenium 0.2-0.6；Organic germanium 0.2-0.6；
Medical stone fine powder 1-3；Boric acid 0.3-0.9；
Magnesium sulfate 0.3-0.9；Zinc sulfate 0.3-0.9；
Molybdenum trioxide 0.3-0.9；Copper sulphate 0.3-0.9；
Ferrous sulfate 3-9；Potassium chloride 4-12；
Dipotassium hydrogen phosphate 6-18；Peat 5-15；
Composite fertilizer adds to 100.
Preparation method：
The micro- fertilizer of rich selenium germanium multielement humic acid is mixed the peat containing humic acid and several trace elements by above-mentioned charge ratio
It is even, it banks up 1-2 months, re-compacted slabbing is finished product.
4, a kind of micro- fertilizer of rich selenium germanium multielement humic acid, it is characterized in that：The rich selenium germanium discharges element anion humic acid
The micro- fertilizer of potassium calcium sodium boron magnesium forms % by following quality proportioning
Selenium enriched Spirulina bacterium 0.2-0.6；Rich germanium spiral phycomycete 0.2-0.6；
Salkali waste ground-slag 1-3；Rich selenium germanium beer yeast powder 1-3；
Wheat bran 2-6；Calcium superphosphate 1-3；
Useless potassium calcium sodium boron magnesium ferromanganese ground-slag 1-3；Manure of livestock and poultry 2-6；
Boron mud 2-6；Turf 10-30；
Tourmaline nano powder 1-3；Water adds to 100.
Preparation method：
By top quality than mixing, a small amount of water is added, heats 2-3d in the high temperature environment, then after stacking a couple of days, the sodium in turf
It is reacted with humic acid and generates sodium humate to get the micro- fertilizer of rich selenium germanium humic acid potassium calcium sodium boron magnesium.
Product is in neutrality, and generally makees base fertilizer application, and application can be mixed with farm manure, and amount of application is 2250-3750kg/
hm2。
The fertilizer is preferable to soybean and corn fertilizer efficiency, can increase production 10% or more.
In addition the micro- fertilizer of fulvic acid diamines iron can be produced：Production method is using fulvic acid, urea and ferrous sulfate as raw material three
The ratio of person is：m（Fulvic acid sterling）+m（Urea）+m（Ferrous sulfate）=100+4+0.4.Urea is first dissolved in temperature and is higher than 90
DEG C hot water in, add ferrous sulfate, generate diamine solution, the fulvic acid solution that temperature is higher than 90 DEG C is then added, fully
After mixing, cooling is got product.
The product is novel complexing iron fertilizer, and fertilizer efficiency is good, and stability is high, can supply plant iron nutrient, valence in a long time
Lattice are that EDTA chelated irons are low, and the fertilising of the field crops such as " yellowtop " and wheat, general fruit tree blade face occurs for crop iron deficiency
Horizontal sprinkling is 0.3%, and winter wheat seed soaking, level is 0.02%.It has been reported that in northern area, prevention apple is sprayed with fulvic acid iron
The chlorosis yellow such as fruit, poplar, willow, cypress, oriental plane tree, deodar, Malus spectabilis, 3-5d i.e. effect after spraying, Chlorisis index turn green, new raw cook
Also it is green.
After the 1970s, various countries pay attention to trace element use, containing trace element commercial fertilizer meet the tendency of and
It is raw, such as the potash magnesium sulphate fertilizer that IMC fertilizer Co., Ltd of the U.S. produces, sold to countries in the world by Liu Jiamei exporter's associations of the U.S.
It sells；" the full element fertilizer " of BASF Corp. of Germany's production, contains the nutrition such as nitrogen, phosphorus, potassium, silicon, calcium, magnesium, sulphur, copper, zinc, boron, molybdenum
Element.
Trace element be mostly promote in plant " enzymes " such as photosynthesis, respiration and substance transformations or
The component part of " coenzyme ", very active in plant, when certain trace element is insufficient in soil, plant, which will appear, " to be lacked
Weary symptom ", makes crop yield reduce, quality decline, and even No kernels or seeds are gathered, as in a year of scarcity when serious, in this case, using micro member
Fertilizer often obtains extremely apparent the effect of increasing income.
Since the micro- deficiency in plant causes shortage micro- in people and animals, caused by micro- fertilizer is insufficient in
Property disease in side's occurs repeatedly, in the ecological balance of nature, though in micro- fertilizer amount it is small, be equally very important.
Soil is the basis of plant nutrient system balance, it directly affects the height of crop yield and the quality of kind, is put down
Weighing apparatus fertilising is to maintain the important means of soil fertility, and Germanization Lee scholar works as nutrition than western earliest proposition " law of minimum nourishment "
When lacking some indispensable element in environment, crop yield is restricted by this element first, the output increased with its increase.
In due course microelement-supplementing has caused the common concern of countries in the world, due to ecology, environmental science, Biogeochemistry, enzyme
Learn, the development of endemiology, in micro- fertilizer have become the growing point of soil science, micro- reasonable application is also at modernizing
The important symbol of agriculture intensive production.
In order to overcome the wide nitrogen fertilizer application of soil crops and chemical fertilizer in the last hundred years, and make element beneficial in soil that cannot answer
Some supplements, and cause prodigious damage to the health of crowd.The present invention is adapted under element balance health care theoretical direction
So, it promotes the well-being of mankind and develops the micro- fertilizer of rich selenium germanium multielement humic acid, reach volume increase, increase income, increase peasant economy income, improve rural area
The predicament of backward makees the agriculture that the composition alkaline residue nutrition base fertilizer such as base-material and trace element and ferment plants element balance with alkaline residue
Crop, people reach in-vivo element by food chain and balance health.According to analysis, there is bioactive enzyme ring in this base manure
Ferment is protected, is that people, the basis of animal and plant all life and life are lived until determining up to 1000 kinds or more so far
Dynamic root is the basis of medical and health care, can activate and constitute 60,000,000 cell of human body, repairs the cell for mending damage aging breakage,
Accelerate the ability of cell normal healing.Alkaline residue is 231.44% according to analysis calcium, magnesium 5.83%, potassium 4.02%, sodium 0.78%, aluminium 0.51%,
Iron 0.33%, manganese 446mg/kg, P 32 8.5mg/kg, titanium 293.8mg/kg, vanadium 18.6mg/kg, cobalt 13.51mg/kg, solvable silicon
It is conventional not only to contain nitrogen, phosphorus, potassium etc. in 11.6mg/kg, strontium 123.9mg/kg, zinc 220.5mg/kg, chromium 87.8mg/kg etc. alkaline residues
Fertilizer goes back calcic, magnesium, chlorine, sodium macroelement, also contains the plants such as iron, zinc, manganese, iron, vanadium, chromium, nickel, strontium, boron, beryllium, copper, cobalt, silicon
The required trace element that is required for people, harmful element content are small, cannot constitute and endanger to human body, alkaline residue match as base manure
System not only improves beneficiating ingredient in soil, and crops absorb trace element, will produce wholesome effect to health, it
PH value be 11, the acid-base balance of soil can be improved, alkaline residue is as the other trace element fertilizers of base manure cooperation to cereal and vegetable
Dish, melon and fruit based food can increase production, increase income, and increase the micronutrient levels of cereal gourd, fruit and vegetable, and people has used corresponding after these foods
Ground supplement is adjusted, the element balance of antagonism human body, is enhanced the immunity of people, is improved the ability resisted the disease, keep fit and healthy raising
National health constitution, and increase the income of peasant.
Large cereal product such as rice, wheat, corn, long market is slow, inexpensive, inefficiencies, but selenium-rich is big
Rice and other Se-rich farm products but cause consumer to be willing to that the heat purchase that outbids, some places even sell fire, retailers on the market
It even asks someone to give a present and thinks to set this selenium-rich rice, selenium-rich scented rice, Se-rich wheat, flour, selenium-rich corn, selenium-rich gourd, fruit and vegetable etc. more
All it is the product of people's heat purchase, or even exports to Italy and be driven into the easy just lotus flower of supermarket of Wal-Mart of the U.S., Thailand, therefore
Exploitation has a high potential rich in micro- agricultural product, and economic benefit is the abundantest again, as rich selenium germanium paddy, melon fruits and vegetables, greatly
Garlic, ganoderma lucidum, ginseng, they are all the strongest excellent carriers of Rich in Trace Element ability, and especially fresh garlic, selenium-rich amount is in vegetable
It ranks the first in dish, up to 278mg/kg, and general vegetables are only 10mg/kg, and also garlic has many specific functions again, resists
Bacterium, antiviral, blood pressure lowering, antiplatelet, anticoagulant collection, antiatherosclerosis are stronger to anti-aging, preventing tumor.And I
State's garlic resource is very rich, and annual output accounts for the world 1/4, carries out garlic water planting lotus lattice solution, blue moral solution, and control group adds selenium,
1mmol/L Na are pressed in processing2SeO3It is added, 10-15 DEG C of result garlic selenium contents of cultivation temperature reach 5530mg/kg, and garlic weight
Amount for up to 61.68%, the ability of ganoderma lucidum edible mushroom rich selenium germanium is most strong, and Na is added in culture medium2SeO3, concentration is with 50mg/kg
Preferably, selenium-rich amount in Ganoderma lucidum mycelium body can be made to be up to the minimum selenium contents of 8000mg/kg. also not less than 5000mg/kg, so exploitation is rich
Selenium germanium glossy ganoderma agricultural product have fine future, and by selenium rice 0.1-0.3mg/kg of content, average 0.2mg/kg is calculated, and such as presses selenium-rich
Content only 5000mg/kg is compared, it is higher by selenium-rich rice 25000 or so, is especially higher by 100 times of selenium Wei Er, even more " Beijing University's selenium-rich
10000 times of health " are just think for preparing one bottle 100, and " the selenium Wei Er " of 55 yuan of value only needs 1g, and 2 bottles are prepared with it
" the Beijing University's selenium-rich health " of 100ml only needs its 1/5g.Recently the one kind " bio-red selenium " developed, its content is up to 15000mg/
L is produced by microbial fermentation, zymotic fluid is by original during the fermentation rich in the selenium-rich product of Chinese independent intellectual property right
It is light yellow become red, red color visible ZM bacterium are ceaselessly moving under microscope, bag of each mycelium as a Sheng selenium
Son is inside loaded with red Biological Selenium, and rich selenium germanium multielement in agricultural product is improved by rich selenium germanium multielement compound nutritional base manure
Content is to increase the total constituent content of soil to make agricultural product, the crops such as corn, barley, wheat, rice, soya bean, melon fruits and vegetables
The content of each element of rich selenium germanium meets level, method necessary to Human Physiology：Inorganic selenium germanium each element is given birth to plant
Object converts, and produces biologically active Organic Selenium, each element of germanium is stored in plant, and Organic Selenium is mainly with solubility
Protein form exists, water soluble selenium content 70% in rice according to the study in phytoprotein, water soluble selenium content 75% in soybean,
Selenium removes excessive free radicals in plant, prevents from playing a significant role in terms of peroxidating, takes part in the conjunction of protein in plant
At, energy metabolism, promote the anabolism of regulation and control plant chlorophyll, antagonism heavy metal nuisance, selenium can reduce romaine lettuce,
Wheat is decreased obviously the absorption of cadmium, and for selenite to the antagonism of cadmium, this selenate is more effective, and applying selenium fertilizer can also reduce greatly
Chinese cabbage is to cadmium uptuke, moreover it is possible to absorption and transhipment to radish root to mercury, to alleviate toxicity of the mercury to radish, according to section
Experiment is ground, the selenium in rice culture solution is in 0-1 × 10-6mol·L-1When concentration range, selenium has the work of antagonism rice arsenic species
With when selenium is more than or particularly greater than 1 × 10-6mol·L-1Or 5 × 10-6mol·L-1When, selenium can aggravate poison of the arsenic to rice instead
Evil can obviously reduce the content of beary metal such as palladium in rice, chromium, in Chinese cabbage and romaine lettuce using the selenium of low concentration compared with control
In apply selenium, also can significantly reduce absorption or accumulation of two kinds of vegetables to palladium, selenium and sulphur are congeners, SO4 2-With SeO4 2-There is phase
As chemical property, plant roots absorb nutriment when, sulphur influence selenium absorption, apply selenium can promote barley, rice, seedling inhale
Receive SO4 2-.Sulphur lacks the absorption and transport that can promote tomato root to selenium, can increase selenium Organic Selenium in blade, rhizome and fruit
Content, so there is the mutual collaboration mutual relationships of antagonism again for selenium and sulphur.Between phosphorus selenium there is also mutually promote and mutually
The application of the relationship of phase antagonism, pot experiment, zinc, manganese, copper has little effect Garlic Absorption selenium, and selenium can significantly inhibit
Absorption of the garlic to zinc, manganese, copper, in a word since the injury of the adverse circumstances such as plant raying, arid, low temperature, pest and disease damage makes in plant
Excessive free radical is generated, and selenium is the street cleaner for being known as free radical rubbish, is the direct scavenger of free radical, germanium can also have
The removing free radical of effect, is acted on by biological antioxidant, improves plant immune mechanism, enhances plant disease-resistant insect pest and various degeneration-resistant
The resistance in border, pine tree " needle " series extract is the most potent natural free radical scavenger found so far, through in the world
The hundreds of secondary scientific research and testing of tens authoritative institutions constantly confirm, pine tree " needle " extract be find so far it is best compound
Type antioxidant, most potent free radical scavenger, its Green Tea Extract oxidability is 50 times of vitamin E, ascorbic
20 times, extract from pine needles is a variety of amino acid and the special selenium Germanium of various trace elements, more rich in carbohydrate, crude protein, crude fat
Kind vitamin, antibiotic, biological flavone substance, ferment, essential oil, chlorophyll, unsaturated fatty acid, enzyme and coenzyme isoreactivity object
Matter and natural water soluble bioflavonoids concentrate, this is a kind of potent antioxidants and before Scavenging ability is strong
Anthocyanidin, while can also promote the generation of antioxidative enzyme in plant cell, the rosin of pine needle are excellent anti-corrosion pest repellant, pine
Son is highly beneficial to plant growth containing oleic acid, linoleic acid, protein, vitamin, mineral element.
Medical stone, montmorillonite, tourmaline, zeolite, they all have absorption, release, decomposability, porous cave property, extremely strong
It is beneficial to crops that minerals adsorb plant internal rubbish impurity heavy metal lead as harmful matter, mercury, arsenic, cadmium, thallium release and dissolution
Trace element and anion medical stone and tourmaline its ingredient in SiO containing silica259.6% is accounted for, rice is China's agriculture
One of crop, is the plant of representative happiness silicon, and Applying silicon fertilizer makes high economic, the high social benefit of rice, high-environmental, high health care
Deng the rice special foliar fertilizer of four high benefit features, with the high element silicon of content.Alundum (Al2O3) Al2O3It is each in medical stone
16.50% is accounted in kind ingredient, is the representative of Far infrared radiation type sterilization, di-iron trioxide Fe2O3, iron oxide FeO be effectively to shield
The material of Contamination of Electromagnetic Wave, titanium dioxide TiO2It is the representative of photo-catalyst, this composite sterilizing is to crops germ worm
Evil can be killed effectively, at the same also contain magnesia, calcium, potassium, sodium, manganese, phosphorus pentoxide, zinc, molybdenum, cobalt, copper, tin, vanadium, selenium,
More than 40 kinds of germanium, fluorine, iodine, chromium, lithium, strontium etc. element beneficial to people and plant, it has unique porous class formation.
According to medical research, 325 mesh fine-powder below is made in medical stone, one grain is taken to see under an electron microscope
It examines, it, as coral reef, spongy, is in porous clearly to find this particle completely.325 thicknesses are any concepts, as everybody knows
Cocoa power is a kind of food auxiliary material, and a cocoa power only has mesh more than 200, a grain powder there was only mesh more than 100, and medical stone is tiny
Particle in, be really comparable marvellous still it can be seen that many pores.The specific surface area of medical stone is very big, so its absorption
Power is especially strong；Japanese Yokkaichi workshop will contain mercury（Mercury）The draining 130ml of 0.0064ppm, is sent to Mie Prefecture, Japan ring
Border health inspection center is handled for 5 grams with medical stone, and absorption situation experimental result is measured after three days it has surprisingly been found that not only
Various nutritional ingredients are increased in water, and the adsorbance of mercury is 85.875%, show that the input amount of medical stone is in adsorbance
Positive correlation may be adsorbed all if the amount of medical stone increases；They also study（1）In the solution of the cyanogen containing 1ppm, it is added
1% medical stone is tested, and as a result 2h is adsorbed and removed 18.2%, 4h and is adsorbed and removed 20.8%, is adsorbed and removed 44.0% for 24 hours.（2）
In the solution of the cadmium containing 0.1ppm, 10% medical stone is added, adsorbable removing 43.2% is measured after 3h, is adsorbed and removed 61.4% for 24 hours,
48h is adsorbed and removed 84.0%.（3）New water pollution problems is phthalic acid ester, and adsorption treatment, adsorption capacity are carried out with medical stone
It is 50% or so.The result of above-mentioned several experiments is it can be shown that medical stone has very strong adsorption capacity, adsorption capacity to heavy metal
It is in direct ratio with the input amount of medical stone and time, medical stone can inhibit bacterial reproduction and it have peculiar water purification effect by
All there is similar ingredient with tourmaline in medical stone, both combines the effect to agricultural crops more preferable and can release to planting
Object and the beneficial anion of people promote growth and development of plants to yield positive results, and are to be known as " air vitamin or atmospheric growth element ",
And air can be purified, make the air of pollution become, rich in the fresh air more than anion, to adsorb and purify in addition, decomposable harmful substances
The effect of matter powerful montmorillonite, sepiolite, the nanostructure of superfine penetrate into sky of the plant cell intramolecular similar to superfine
Gas purifier eliminates bacterial virus poisonous and harmful heavy metallic and gas in plant and promotes to ensure the robust growth of plant.
Spirulina polysaccharide also has several functions, and current practice is complex polysaccharide, it, which has, improves immunity
Effect, to maintaining specific immunity and having positive effect to circulating antibody level.Also there is antitumor, antivirus action.
Spirulina is apparent to the concentration effect of selenium, germanium.Essential trace element contained by spirulina is in addition to iron is abundant, and other contents are not
Height if thinking the collective effect of performance spirulina and certain essential trace element, and can select the ideal bio-carrier of trace element, i.e.,
Spirulina and trace element should be combined together, it is such as that selenium, germanium is in connection.It is micro- that spirulina is important excellent biological concentration
The raw material or carrier of secondary element.Its cell wall is made of peptide, polysaccharide, phosphatide, albumen etc., has viscosity and negative electrical charge, to element
With adsorption capacity and affinity.It is combined there are many modes of element：To alkali metal, the formed less stable of alkaline-earth metal
Cooperation.Stable cooperation is formed with wherein O, N, S to transition metal tendency.Noble metal is strong to wherein N, S affinity.It influences
The factor of enriched in metals includes：PHValue, temperature, light, incubation time, element species, ion concentration and race condition, culture medium
Composition etc..The primary condition of SPIRULINA CULTIVATION：100mg/L selenium is added in Zarrouk culture mediums（With Na2SeO3Stock solutions supply
It gives）, intensity of illumination 2500lx, fluorescent light source, periodicity of illumination, light：Secretly=12:12h.Reciprocal shaker culture, frequency 90r/
The bottled 200ml culture solutions of min, 500ml triangle.Specific incubation：In the culture solution that spirulina is in exponential phase, add
Enter selenium, or germanium is added, culture harvests after 10 days, is filtered, washed, and 70 DEG C of dryings are practical to be enriched with to get selenium-rich or rich germanium spirulina
In culture, when illumination is 40001 × when, phycocyanin matter content highest, that is, element absorption, pH value 9.3 can be promoted by improving light intensity
When be conducive to algae growth, but when pH value 8.0, be conducive to enrichment of element.Enriched element polysaccharide also plays an important role.Pass through improvement
Former condition of culture increase light intensity to 40001 × to become pH be 8.0, improve and cultivate selenium-rich, the amount of germanium.According to reports indicate that, state
The method of inside and outside most of selenium-supplies is Na2SeO3, way is：By Na2SeO3It is made into various concentration, or soaks seed or sprays, is made
Selenium is absorbed by crops, produces the agricultural product of certain selenium content, and crop species include rice, corn and soybean, tealeaves, cigarette
The crops such as leaf, vegetables.Since plant is to Na2SeO3Utilization rate has a certain difference, some entity and individual also develop respectively
The fertilizer of kind selenium-rich, such as selenium-rich board full-service fluid fertilizer, selenium-rich health, Se-rich agent for promoting growth of crops, there is certain effect.Spirit is cultivated
The water-soluble germanium of specially treated 1% is added in the matrix of cotton seed hull and wheat bran primary raw material, mixes thoroughly, is packed into culture for sesame germanium
Bottle is inoculated with Ganoderma Lucidum after sterilizing, 25 DEG C are cultivated one month, and fructification is cultivated in 28 DEG C of culturing room.Culture medium adds germanium 1:1000
Group increases by 4 times than control group germanium germanium.Mycelium Rich in Trace Element is better, with Mycelium culture germanium-enriched glossy ganoderma mycelium,
In culture solution plus the germanium dioxide solution of various concentration, after sterilizing with 28 DEG C, 802pm cultures, using delayed fermentation method, as a result silk
Thalline dry powder germanium is up to 497-3300ug/g（Compare 13.2ug/g）Increase by 40-250 times, is enriched with compared with fructification superior.
With reference to embodiment, the invention will be further described
Specific embodiment：
Embodiment 1：A kind of micro- fertilizer of rich selenium germanium multielement humic acid, it is characterized in that：The rich selenium germanium zinc humic acid sodium boron magnesium phosphorus is micro-
Fertilizer forms % by following quality proportioning
Se-rich lucid ganoderma bacterium 0.2-0.6；Germanium-rich glossy ganoderma 0.2-0.6；
Montmorillonite powder 1-3；Boron mud 2-6；
Zinc sodium boron magnesium ground phosphate rock 1-3；Useless schlempe 3-9；
Yeast powder 1-3；Animal waste wool skin 5-15；
Turf 10-30；Water adds to 100.
Embodiment 2：A kind of micro- fertilizer of rich selenium germanium multielement humic acid, it is characterized in that：The rich selenium germanium humic acid ferrisodium ammonia phosphorus
The micro- fertilizer of boron magnesium forms % by following quality proportioning
Yeast rich in selenium 0.2-0.6；Germanium-enriched yeast bacterium 0.2-0.6；
Zeolite powder 1-3；Turf 0.5-1.5；
Ammonium bicarbonate 0.7-2.1；Ferrisodium ammonia phosphorus boron magnesium ore powder 0.7-2.1；
Pine needle series extract 2-6；Yeast powder 1-3；
Boron mud 1.2-3.6；Water adds to 100.
Embodiment 3：A kind of micro- fertilizer of rich selenium germanium multielement humic acid, it is characterized in that：The rich selenium germanium medical stone multielement is rotten
Phytic acid composite fertilizer forms % by following quality proportioning
Nanometer selenium 0.2-0.6；Organic germanium 0.2-0.6；
Medical stone fine powder 1-3；Boric acid 0.3-0.9；
Magnesium sulfate 0.3-0.9；Zinc sulfate 0.3-0.9；
Molybdenum trioxide 0.3-0.9；Copper sulphate 0.3-0.9；
Ferrous sulfate 3-9；Potassium chloride 4-12；
Dipotassium hydrogen phosphate 6-18；Peat 5-15；
Composite fertilizer adds to 100.
Embodiment 4：A kind of micro- fertilizer of rich selenium germanium multielement humic acid, it is characterized in that：The rich selenium germanium discharges element anion
The micro- fertilizer of humic acid potassium calcium sodium boron magnesium forms % by following quality proportioning
Selenium enriched Spirulina bacterium 0.2-0.6；Rich germanium spiral phycomycete 0.2-0.6；
Salkali waste ground-slag 1-3；Rich selenium germanium beer yeast powder 1-3；
Wheat bran 2-6；Calcium superphosphate 1-3；
Useless potassium calcium sodium boron magnesium ferromanganese ground-slag 1-3；Manure of livestock and poultry 2-6；
Boron mud 2-6；Turf 10-30；
Tourmaline nano powder 1-3；Water adds to 100.
Claims (4)
1. a kind of micro- fertilizer of rich selenium germanium multielement humic acid, it is characterized in that：The micro- fertilizer of the rich selenium germanium zinc humic acid sodium boron magnesium phosphorus, is pressed
Row quality proportioning forms %
Se-rich lucid ganoderma bacterium 0.2-0.6；Germanium-rich glossy ganoderma 0.2-0.6；
Montmorillonite powder 1-3；Boron mud 2-6；
Zinc sodium boron magnesium ground phosphate rock 1-3；Useless schlempe 3-9；
Yeast powder 1-3；Animal waste wool skin 5-15；
Turf 10-30；Water adds to 100.
2. a kind of micro- fertilizer of rich selenium germanium multielement humic acid, it is characterized in that：The micro- fertilizer of the rich selenium germanium humic acid ferrisodium ammonia phosphorus boron magnesium, is pressed
Following masses proportioning composition %
Yeast rich in selenium 0.2-0.6；Germanium-enriched yeast bacterium 0.2-0.6；
Zeolite powder 1-3；Turf 0.5-1.5；
Ammonium bicarbonate 0.7-2.1；Ferrisodium ammonia phosphorus boron magnesium ore powder 0.7-2.1；
Pine needle series extract 2-6；Yeast powder 1-3；
Boron mud 1.2-3.6；Water adds to 100.
3. a kind of micro- fertilizer of rich selenium germanium multielement humic acid, it is characterized in that：The rich selenium germanium medical stone multielement humic acid complex fertilizer,
% is formed by following quality proportioning
Nanometer selenium 0.2-0.6；Organic germanium 0.2-0.6；
Medical stone fine powder 1-3；Boric acid 0.3-0.9；
Magnesium sulfate 0.3-0.9；Zinc sulfate 0.3-0.9；
Molybdenum trioxide 0.3-0.9；Copper sulphate 0.3-0.9；
Ferrous sulfate 3-9；Potassium chloride 4-12；
Dipotassium hydrogen phosphate 6-18；Peat 5-15；
Composite fertilizer adds to 100.
4. a kind of micro- fertilizer of rich selenium germanium multielement humic acid, it is characterized in that：The rich selenium germanium discharges element anion humic acid potassium calcium
The micro- fertilizer of sodium boron magnesium forms % by following quality proportioning
Selenium enriched Spirulina bacterium 0.2-0.6；Rich germanium spiral phycomycete 0.2-0.6；
Salkali waste ground-slag 1-3；Rich selenium germanium beer yeast powder 1-3；
Wheat bran 2-6；Calcium superphosphate 1-3；
Useless potassium calcium sodium boron magnesium ferromanganese ground-slag 1-3；Manure of livestock and poultry 2-6；
Boron mud 2-6；Turf 10-30；
Tourmaline nano powder 1-3；Water adds to 100.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN112919978A (en) * | 2021-04-15 | 2021-06-08 | 安徽硒无忧现代农业科技有限公司 | Germanium-rich organic nutrient solution and preparation method thereof |
| JP7354457B2 (en) | 2020-01-28 | 2023-10-02 | ヨン カン、ユン | Method for cultivating functional crops using nanoorganic germanium and nanoorganic selenium |
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| CN103396196A (en) * | 2013-08-06 | 2013-11-20 | 成进学 | High selenium and germanium broccoli |
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| CN105541447A (en) * | 2015-11-09 | 2016-05-04 | 南通蛇类治疗研究所 | Fertilizer powder for cultivating health tea with low fluorine content and high selenium and germanium content |
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| US6372007B1 (en) * | 1999-01-29 | 2002-04-16 | Rafael Munoz | Organic compost |
| CN103204734A (en) * | 2013-03-15 | 2013-07-17 | 成钢 | Nanometer rare earth selenium silicon titanium macro-trace element composite nutrition fertilizer |
| CN103396196A (en) * | 2013-08-06 | 2013-11-20 | 成进学 | High selenium and germanium broccoli |
| CN103435400A (en) * | 2013-08-06 | 2013-12-11 | 成进学 | High-selenium-germanium cancer prevention garlic oil |
| CN105541447A (en) * | 2015-11-09 | 2016-05-04 | 南通蛇类治疗研究所 | Fertilizer powder for cultivating health tea with low fluorine content and high selenium and germanium content |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| JP7354457B2 (en) | 2020-01-28 | 2023-10-02 | ヨン カン、ユン | Method for cultivating functional crops using nanoorganic germanium and nanoorganic selenium |
| CN112919978A (en) * | 2021-04-15 | 2021-06-08 | 安徽硒无忧现代农业科技有限公司 | Germanium-rich organic nutrient solution and preparation method thereof |
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