CN108408851A - A kind of high-efficiency antimicrobial deodorant - Google Patents
A kind of high-efficiency antimicrobial deodorant Download PDFInfo
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- CN108408851A CN108408851A CN201810356930.9A CN201810356930A CN108408851A CN 108408851 A CN108408851 A CN 108408851A CN 201810356930 A CN201810356930 A CN 201810356930A CN 108408851 A CN108408851 A CN 108408851A
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/50—Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/283—Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2303/00—Specific treatment goals
- C02F2303/02—Odour removal or prevention of malodour
Abstract
The invention discloses a kind of high-efficiency antimicrobial deodorant, are made of by weight following components：5 20 parts of di-bromonitrilopropiona,ide, 10 30 parts of chlorine dioxide powder, copper are modified modified 5 10 parts of the antibacterial zeolite particles of 2 10 parts of antibacterial zeolite particles, silver, 16 parts of zinc modification antibacterial zeolite particles, 38 parts of titanium zinc compound bactericide, 5 10 parts of sodium hypochlorite, 26 parts of sodium chloride, 10 20 parts of activated carbon, 7 15 parts of iron hydroxide, 5 15 parts of biogenic organic acid.Advantageous effect is：Sterilizing ability with high-efficiency broad spectrum, it is applied widely and nontoxic, secondary pollution will not be caused, hydrogen sulfide, ammonia and sulfurous organic compound in sewage etc. cause smelly ingredient effectively to be removed and degraded by the modes such as reacting, adsorbing, and have preferable deodorizing effect.
Description
Technical field
The present invention relates to water treatment fields, more particularly to a kind of high-efficiency antimicrobial deodorant.
Background technology
With the aggravation of socio-economic development and water pollution, the mankind require increasingly to increase for quality of water environment, sewage
The safety problem being discharged after regeneration and sewage disposal causes the extensive concern of people, current city sewage to pass through two stage treatment
Afterwards, water quality has had apparent change, but the absolute quantity of bacterium still has, and with the possibility of pathogen, removes this
Biology is the emphasis key of sewage discharge and recycling slightly, therefore the tail water disinfection of sewage treatment plant has become sewage disposal
In important procedure, sewage is generally also provided with stimulation niff, this is because containing the change of volatile different smell in sewage
Object is closed, through mechanical movements such as equipment agitation, overturnings so that these compounds evaporate, and generate different smell, meanwhile, sewage exists
Because of microbial action during conveying, storage etc., different smell can be also discharged, in sewage disposal process, because of process conditions and requirement
The foreign odor molecule for causing the generation of different smell to be generated in sewage disposal process, mainly nitrogenous, sulfur-bearing compound, such as ammonia
Gas, hydrogen sulfide etc., currently, the medicament kind for being used to carry out sewage antimicrobial treatment on the market is less, and use condition is more
Harshness, but also secondary pollution can be caused, the medicament that deodorizing process is carried out to sewage mainly removes ammonia, hydrogen sulfide etc. mostly,
Poor to elimination effects such as sulfurous organic compounds, the elimination of sewage stink is not thorough.
Invention content
The purpose of the present invention is that solve the above-mentioned problems and provides a kind of high-efficiency antimicrobial deodorant.
The present invention is achieved through the following technical solutions above-mentioned purpose：
A kind of high-efficiency antimicrobial deodorant is made of by weight following components：5-20 parts of di-bromonitrilopropiona,ide, dioxy
Change 10-30 parts of chlorine pulvis, copper is modified 2-10 parts of antibacterial zeolite particles, modified 5-10 parts of the antibacterial zeolite particles of silver, zinc modification antibacterial zeolite particles 1-6
Part, 3-8 parts of titanium zinc compound bactericide, 5-10 parts of sodium hypochlorite, 2-6 parts of sodium chloride, 10-20 parts of activated carbon, iron hydroxide 7-15
Part, 5-15 parts of biogenic organic acid.
The biogenic organic acid be citric acid, malic acid, lactic acid it is one or more.
The preparation method of the high-efficiency antimicrobial deodorant, includes the following steps：
(1) certain density copper-bath is configured at room temperature, natural zeolite is crushed, and with sieve, then will
Natural zeolite is weighed with copper-bath according to certain mass ratio, and natural zeolite is added in copper-bath, is shaken
Reaction certain time is swung, then solid-liquid centrifugation detaches, and precipitation is dried at a certain temperature, obtains the copper and is modified antibacterial boiling
Stone；
(2) certain density silver nitrate solution is configured at room temperature, takes the natural zeolite after sieving in step (1), then
Natural zeolite is weighed with silver nitrate solution according to certain mass ratio, natural zeolite is added in silver nitrate solution,
Oscillating reactions certain time, then solid-liquid centrifugation separation dry precipitation at a certain temperature, obtain the modified antibacterial boiling of the silver
Stone；
(3) certain density liquor zinci chloridi is configured at room temperature, takes the natural zeolite after sieving in step (1), then
Natural zeolite is weighed with liquor zinci chloridi according to certain mass ratio, natural zeolite is added in liquor zinci chloridi,
Oscillating reactions certain time, then solid-liquid centrifugation separation dry precipitation at a certain temperature, obtain the zinc modification antibacterial boiling
Stone；
(4) titania powder, zinc nitrate, sodium hydroxide are weighed according to certain mass ratio, is then added and goes
Ionized water stirs certain time at a certain temperature, and natural cooling cools down after reaction, precipitation is collected after centrifugation, with distillation
Water, ethyl alcohol, distilled water wash successively to be precipitated and is collected by centrifugation, and dries certain time at a certain temperature, it is multiple to obtain the titanium zinc
Close antiseptic；
(5) di-bromonitrilopropiona,ide, chlorine dioxide powder, copper are modified antibacterial zeolite particles according to formula ratio, silver is modified and resists
Bacterium zeolite, zinc modification antibacterial zeolite particles, titanium zinc compound bactericide, sodium hypochlorite, sodium chloride, activated carbon, iron hydroxide, biological organic
Acid is uniformly mixed, and obtains the high-efficiency antimicrobial deodorant.
In step (1) copper-bath concentration be 0.01-0.1mol/L, sieve mesh number be 50-150 mesh, natural zeolite with
Copper-bath mass ratio is 1: 2-8, when oscillating reactions a length of 3-8h, drying temperature is 70-130 DEG C.
A concentration of 0.05-0.15mol/L of silver nitrate solution in step (2), natural zeolite are 1 with silver nitrate solution mass ratio
: 1-6, when oscillating reactions a length of 1-6h, drying temperature is 80-150 DEG C.
A concentration of 0.5-3.5mol/L of liquor zinci chloridi in step (3), natural zeolite are 1 with silver nitrate solution mass ratio:
1-10, when oscillating reactions a length of 2-8h, drying temperature is 60-120 DEG C.
Titania powder in step (4), zinc nitrate, sodium hydroxide mass ratio be 1: 3-8: 5-12, temperature when stirring
Degree is 60-120 DEG C, stirs duration 6-15h, 50-100 DEG C of drying temperature, dry duration 6-24h.
The function analysis of instant component：
Di-bromonitrilopropiona,ide can readily penetrate through the cell membrane of microorganism, and act on certain protein groups, make thin
The normal oxidation reduction of born of the same parents stops, and so as to cause cell death, has high-efficiency broad spectrum, is easy degradation, noresidue residual hazard, to environment
The features such as pollution-free；Chlorine dioxide powder can kill all microorganisms, including bacterial propagule, bacterial spore, fungi, virus
Deng, and these bacteriums will not develop immunity to drugs, high-efficiency broad spectrum, and it is nontoxic non-stimulated；Copper is modified the modified antibacterial boiling of antibacterial zeolite particles, silver
The metal ion that stone, zinc modification antibacterial zeolite particles carry after modification can be adsorbed on bacterium surface or even endosmosis and albumen
Matter combines, and so that it is played the enzyme of respiration and is catalyzed turning property, leads to bacterial death；Titanium zinc compound bactericide has stronger sterilization
Ability, and it is environmentally safe；Sodium hypochlorite, sodium chloride can cause smelly ingredient to be reacted with inorganics such as hydrogen sulfide, ammonia, from
And achieve the purpose that deodorization；Activated carbon can adsorb ammonia, hydrogen sulfide and sulfurous organic compound；Iron hydroxide can be with hydrogen sulfide
Ferrous sulfide, ferrous disulfide, elemental sulfur are generated, to remove hydrogen sulfide；Biogenic organic acid is that strength goes peculiar smell agent, and
Per se with pure and fresh smell.
Advantageous effect is：Di-bromonitrilopropiona,ide, chlorine dioxide powder, copper are modified the modified antibacterial of antibacterial zeolite particles, silver
Zeolite, zinc modification antibacterial zeolite particles, titanium zinc compound bactericide, the sterilizing ability with high-efficiency broad spectrum is applied widely, and nothing
Poison, will not cause secondary pollution, and sodium hypochlorite, sodium chloride, activated carbon, iron hydroxide, biogenic organic acid can will be in sewage
Hydrogen sulfide, ammonia and sulfurous organic compound etc. cause smelly ingredient by the modes such as reacting, adsorbing effectively remove and degrade, and have preferable
Deodorizing effect.
Specific implementation mode
Principles and features of the present invention are described below in conjunction with specific example, example is served only for explaining this hair
It is bright, it is not intended to limit the scope of the present invention, unless otherwise specified, conventional prior completion is all made of in following embodiments.
Embodiment one
A kind of high-efficiency antimicrobial deodorant is made of by weight following components：10 parts of di-bromonitrilopropiona,ide, titanium dioxide
15 parts of chlorine pulvis, copper are modified modified 6 parts of the antibacterial zeolite particles of 4 parts of antibacterial zeolite particles, silver, 2 parts of zinc modification antibacterial zeolite particles, titanium zinc composite antibacterial
3 parts of agent, 6 parts of sodium hypochlorite, 6 parts of sodium chloride, 15 parts of activated carbon, 7 parts of iron hydroxide, 5 parts of biogenic organic acid.
The biogenic organic acid is citric acid.
The preparation method of the high-efficiency antimicrobial deodorant, includes the following steps：
(1) copper-bath for configuring 0.05mol/L at room temperature, natural zeolite is crushed, with the sieve of 50 mesh,
Then natural zeolite and copper-bath are weighed according to the two mass ratio 1: 6, it is molten that natural zeolite is added to copper sulphate
In liquid, oscillating reactions 6h, then solid-liquid centrifugation separation will be deposited in drying at 80 DEG C, obtains the copper and is modified antibacterial zeolite particles；
(2) silver nitrate solution for configuring 0.1mol/L at room temperature takes the natural zeolite after sieving in step (1), then
Natural zeolite and silver nitrate solution are weighed according to the two mass ratio 1: 2, natural zeolite is added in silver nitrate solution,
Oscillating reactions 5/h, then solid-liquid centrifugation separation will be deposited in drying at 90 DEG C, obtain the modified antibacterial zeolite particles of the silver；
(3) liquor zinci chloridi for configuring 2mol/L at room temperature takes the natural zeolite after sieving in step (1), then will
Natural zeolite is weighed with liquor zinci chloridi according to the two mass ratio 1: 2, and natural zeolite is added in liquor zinci chloridi, is shaken
Reaction 3h is swung, then solid-liquid centrifugation detaches, and will be deposited in drying at 100 DEG C, obtains the zinc modification antibacterial zeolite particles；
(4) titania powder, zinc nitrate, sodium hydroxide are weighed according to three's mass ratio 1: 6: 10, is then added
Enter deionized water, 8h is stirred at 90 DEG C, natural cooling cools down after reaction, precipitation is collected after centrifugation, with distilled water, second
Alcohol, distilled water wash successively to be precipitated and is collected by centrifugation, and dry 10h, obtains the titanium zinc compound bactericide at 60 DEG C；
(5) di-bromonitrilopropiona,ide, chlorine dioxide powder, copper are modified antibacterial zeolite particles according to formula ratio, silver is modified and resists
Bacterium zeolite, zinc modification antibacterial zeolite particles, titanium zinc compound bactericide, sodium hypochlorite, sodium chloride, activated carbon, iron hydroxide, biological organic
Acid is uniformly mixed, and obtains the high-efficiency antimicrobial deodorant.
Embodiment two
A kind of high-efficiency antimicrobial deodorant is made of by weight following components：15 parts of di-bromonitrilopropiona,ide, titanium dioxide
20 parts of chlorine pulvis, copper are modified modified 8 parts of the antibacterial zeolite particles of 8 parts of antibacterial zeolite particles, silver, 5 parts of zinc modification antibacterial zeolite particles, titanium zinc composite antibacterial
6 parts of agent, 10 parts of sodium hypochlorite, 5 parts of sodium chloride, 20 parts of activated carbon, 10 parts of iron hydroxide, 8 parts of biogenic organic acid.
The biogenic organic acid is malic acid.
The preparation method of the high-efficiency antimicrobial deodorant, includes the following steps：
(1) copper-bath for configuring 0.02mol/L at room temperature, natural zeolite is crushed, with the sieve of 70 mesh,
Then natural zeolite and copper-bath are weighed according to the two mass ratio 1: 8, it is molten that natural zeolite is added to copper sulphate
In liquid, oscillating reactions 8h, then solid-liquid centrifugation separation will be deposited in drying at 90 DEG C, obtains the copper and is modified antibacterial zeolite particles；
(2) silver nitrate solution for configuring 0.15mol/L at room temperature takes the natural zeolite after sieving in step (1), then
Natural zeolite and silver nitrate solution are weighed according to the two mass ratio 1: 5, natural zeolite is added in silver nitrate solution,
Oscillating reactions 1-6h, then solid-liquid centrifugation separation will be deposited in drying at 100 DEG C, obtain the modified antibacterial zeolite particles of the silver；
(3) liquor zinci chloridi for configuring 3mol/L at room temperature takes the natural zeolite after sieving in step (1), then will
Natural zeolite is weighed with liquor zinci chloridi according to the two mass ratio 1: 5, and natural zeolite is added in liquor zinci chloridi, is shaken
Reaction 5h is swung, then solid-liquid centrifugation detaches, and will be deposited in drying at 120 DEG C, obtains the zinc modification antibacterial zeolite particles；
(4) titania powder, zinc nitrate, sodium hydroxide are weighed according to three's mass ratio 1: 8: 12, is then added
Enter deionized water, 15h is stirred at 100 DEG C, natural cooling cools down after reaction, precipitation is collected after centrifugation, with distilled water, second
Alcohol, distilled water wash successively to be precipitated and is collected by centrifugation, and dry 12h, obtains the titanium zinc compound bactericide at 80 DEG C；
(5) di-bromonitrilopropiona,ide, chlorine dioxide powder, copper are modified antibacterial zeolite particles according to formula ratio, silver is modified and resists
Bacterium zeolite, zinc modification antibacterial zeolite particles, titanium zinc compound bactericide, sodium hypochlorite, sodium chloride, activated carbon, iron hydroxide, biological organic
Acid is uniformly mixed, and obtains the high-efficiency antimicrobial deodorant.
Embodiment three
A kind of high-efficiency antimicrobial deodorant is made of by weight following components：5 parts of di-bromonitrilopropiona,ide, titanium dioxide
It is compound anti-that 30 parts of chlorine pulvis, copper are modified modified 10 parts of the antibacterial zeolite particles of 10 parts of antibacterial zeolite particles, silver, 6 parts of zinc modification antibacterial zeolite particles, titanium zinc
7 parts of microbial inoculum, 5 parts of sodium hypochlorite, 3 parts of sodium chloride, 18 parts of activated carbon, 12 parts of iron hydroxide, 10 parts of biogenic organic acid.
The biogenic organic acid is lactic acid.
The preparation method of the high-efficiency antimicrobial deodorant, includes the following steps：
(1) copper-bath for configuring 0.1mol/L at room temperature, natural zeolite is crushed, with the sieve of 100 mesh,
Then natural zeolite and copper-bath are weighed according to the two mass ratio 1: 5, it is molten that natural zeolite is added to copper sulphate
In liquid, oscillating reactions 5h, then solid-liquid centrifugation separation will be deposited in drying at 100 DEG C, obtains the copper and is modified antibacterial zeolite particles；
(2) silver nitrate solution for configuring 0.05mol/L at room temperature takes the natural zeolite after sieving in step (1), then
Natural zeolite and silver nitrate solution are weighed according to the two mass ratio 1: 6, natural zeolite is added in silver nitrate solution,
Oscillating reactions 3h, then solid-liquid centrifugation separation will be deposited in drying at 80 DEG C, obtain the modified antibacterial zeolite particles of the silver；
(3) liquor zinci chloridi for configuring 3.5mol/L at room temperature takes the natural zeolite after sieving in step (1), then
Natural zeolite and liquor zinci chloridi are weighed according to the two mass ratio 1: 8, natural zeolite is added in liquor zinci chloridi,
Oscillating reactions 8h, then solid-liquid centrifugation separation will be deposited in drying at 80 DEG C, obtain the zinc modification antibacterial zeolite particles；
(4) titania powder, zinc nitrate, sodium hydroxide are weighed according to three's mass ratio 1: 3: 7, is then added
Deionized water stirs 10h at 120 DEG C, and natural cooling cools down after reaction, precipitation is collected after centrifugation, with distilled water, second
Alcohol, distilled water wash successively to be precipitated and is collected by centrifugation, and dry 18h, obtains the titanium zinc compound bactericide at 100 DEG C；
(5) di-bromonitrilopropiona,ide, chlorine dioxide powder, copper are modified antibacterial zeolite particles according to formula ratio, silver is modified and resists
Bacterium zeolite, zinc modification antibacterial zeolite particles, titanium zinc compound bactericide, sodium hypochlorite, sodium chloride, activated carbon, iron hydroxide, biological organic
Acid is uniformly mixed, and obtains the high-efficiency antimicrobial deodorant.
Example IV
A kind of high-efficiency antimicrobial deodorant is made of by weight following components：20 parts of di-bromonitrilopropiona,ide, titanium dioxide
25 parts of chlorine pulvis, copper are modified modified 5 parts of the antibacterial zeolite particles of 6 parts of antibacterial zeolite particles, silver, 3 parts of zinc modification antibacterial zeolite particles, titanium zinc composite antibacterial
5 parts of agent, 8 parts of sodium hypochlorite, 2 parts of sodium chloride, 10 parts of activated carbon, 15 parts of iron hydroxide, 13 parts of biogenic organic acid.
The biogenic organic acid is citric acid, malic acid, and the two mass ratio is 1: 1.
The preparation method of the high-efficiency antimicrobial deodorant, includes the following steps：
(1) copper-bath for configuring 0.08mol/L at room temperature, natural zeolite is crushed, with the sieve mistake of 120 mesh
Then natural zeolite and copper-bath are weighed according to the two mass ratio 1: 2, natural zeolite are added to copper sulphate by sieve
In solution, oscillating reactions 3h, then solid-liquid centrifugation separation will be deposited in drying at 120 DEG C, obtains the copper and is modified antibacterial boiling
Stone；
(2) silver nitrate solution for configuring 0.12mol/L at room temperature takes the natural zeolite after sieving in step (1), then
Natural zeolite is weighed with silver nitrate solution according to the two mass ratio 1, natural zeolite is added in silver nitrate solution, is shaken
Reaction 2h is swung, then solid-liquid centrifugation detaches, and will be deposited in drying at 110 DEG C, obtains the modified antibacterial zeolite particles of the silver；
(3) liquor zinci chloridi for configuring 2.5mol/L at room temperature takes the natural zeolite after sieving in step (1), then
Natural zeolite is weighed with liquor zinci chloridi according to the two mass ratio 4, natural zeolite is added in liquor zinci chloridi, is shaken
Reaction 2h is swung, then solid-liquid centrifugation detaches, and will be deposited in drying at 60 DEG C, obtains the zinc modification antibacterial zeolite particles；
(4) titania powder, zinc nitrate, sodium hydroxide are weighed according to three's mass ratio 1: 5: 5, is then added
Deionized water stirs 6h at 70 DEG C, after reaction natural cooling cool down, precipitation is collected after centrifugation, with distilled water, ethyl alcohol,
Distilled water washs successively to be precipitated and is collected by centrifugation, and dry 20h, obtains the titanium zinc compound bactericide at 90 DEG C；
(5) di-bromonitrilopropiona,ide, chlorine dioxide powder, copper are modified antibacterial zeolite particles according to formula ratio, silver is modified and resists
Bacterium zeolite, zinc modification antibacterial zeolite particles, titanium zinc compound bactericide, sodium hypochlorite, sodium chloride, activated carbon, iron hydroxide, biological organic
Acid is uniformly mixed, and obtains the high-efficiency antimicrobial deodorant.
Embodiment five
A kind of high-efficiency antimicrobial deodorant is made of by weight following components：8 parts of di-bromonitrilopropiona,ide, titanium dioxide
10 parts of chlorine pulvis, copper are modified modified 7 parts of the antibacterial zeolite particles of 2 parts of antibacterial zeolite particles, silver, 1 part of zinc modification antibacterial zeolite particles, titanium zinc composite antibacterial
8 parts of agent, 7 parts of sodium hypochlorite, 4 parts of sodium chloride, 12 parts of activated carbon, 9 parts of iron hydroxide, 15 parts of biogenic organic acid.
The biogenic organic acid is citric acid, lactic acid, and the two mass ratio is 2: 1.
The preparation method of the high-efficiency antimicrobial deodorant, includes the following steps：
(1) copper-bath for configuring 0.01mol/L at room temperature, natural zeolite is crushed, with the sieve mistake of 150 mesh
Then natural zeolite and copper-bath are weighed according to the two mass ratio 1: 4, natural zeolite are added to copper sulphate by sieve
In solution, oscillating reactions 7h, then solid-liquid centrifugation separation will be deposited in drying at 70 DEG C, obtains the copper and is modified antibacterial zeolite particles；
(2) silver nitrate solution for configuring 0.08mol/L at room temperature takes the natural zeolite after sieving in step (1), then
Natural zeolite and silver nitrate solution are weighed according to the two mass ratio 1: 3, natural zeolite is added in silver nitrate solution,
Oscillating reactions 4h, then solid-liquid centrifugation separation will be deposited in drying at 130 DEG C, obtain the modified antibacterial zeolite particles of the silver；
(3) liquor zinci chloridi for configuring 1mol/L at room temperature takes the natural zeolite after sieving in step (1), then will
Natural zeolite is weighed with liquor zinci chloridi according to the two mass ratio 1: 10, and natural zeolite is added in liquor zinci chloridi,
Oscillating reactions 6h, then solid-liquid centrifugation separation will be deposited in drying at 70 DEG C, obtain the zinc modification antibacterial zeolite particles；
(4) titania powder, zinc nitrate, sodium hydroxide are weighed according to three's mass ratio 1: 4: 9, is then added
Deionized water stirs 12h at 60 DEG C, after reaction natural cooling cool down, precipitation is collected after centrifugation, with distilled water, ethyl alcohol,
Distilled water washs successively to be precipitated and is collected by centrifugation, and is dried for 24 hours at 70 DEG C, is obtained the titanium zinc compound bactericide；
(5) di-bromonitrilopropiona,ide, chlorine dioxide powder, copper are modified antibacterial zeolite particles according to formula ratio, silver is modified and resists
Bacterium zeolite, zinc modification antibacterial zeolite particles, titanium zinc compound bactericide, sodium hypochlorite, sodium chloride, activated carbon, iron hydroxide, biological organic
Acid is uniformly mixed, and obtains the high-efficiency antimicrobial deodorant.
The basic principles, main features and advantages of the invention have been shown and described above.The technical staff of the industry should
Understand, the present invention is not limited to the above embodiments, and the above embodiments and description only describe the originals of the present invention
Reason, without departing from the spirit and scope of the present invention, various changes and improvements may be made to the invention, these changes and improvements
It all fall within the protetion scope of the claimed invention.
Claims (7)
1. a kind of high-efficiency antimicrobial deodorant, which is characterized in that be made of by weight following components：Di-bromonitrilopropiona,ide 5-
20 parts, 10-30 parts of chlorine dioxide powder, copper be modified 2-10 part of antibacterial zeolite particles, silver modification 5-10 parts of antibacterial zeolite particles, zinc modification antibacterial
1-6 parts of zeolite, 3-8 parts of titanium zinc compound bactericide, 5-10 parts of sodium hypochlorite, 2-6 parts of sodium chloride, 10-20 parts of activated carbon, hydroxide
7-15 parts of iron, 5-15 parts of biogenic organic acid.
2. a kind of high-efficiency antimicrobial deodorant according to claim 1, which is characterized in that the biogenic organic acid is lemon
Acid, malic acid, lactic acid it is one or more.
3. a kind of preparation method of high-efficiency antimicrobial deodorant according to claim 1, which is characterized in that including following step
Suddenly：
(1) certain density copper-bath is configured at room temperature, and natural zeolite is crushed, it, then will be natural with sieve
Zeolite is weighed with copper-bath according to certain mass ratio, and natural zeolite is added in copper-bath, and oscillation is anti-
It answers certain time, then solid-liquid centrifugation detaches, and precipitation is dried at a certain temperature, obtains the copper and is modified antibacterial zeolite particles；
(2) certain density silver nitrate solution is configured at room temperature, the natural zeolite after sieving in step (1) is taken, then by day
Right zeolite is weighed with silver nitrate solution according to certain mass ratio, and natural zeolite is added in silver nitrate solution, is vibrated
Certain time is reacted, then solid-liquid centrifugation detaches, and precipitation is dried at a certain temperature, obtains the modified antibacterial zeolite particles of the silver；
(3) certain density liquor zinci chloridi is configured at room temperature, the natural zeolite after sieving in step (1) is taken, then by day
Right zeolite is weighed with liquor zinci chloridi according to certain mass ratio, and natural zeolite is added in liquor zinci chloridi, is vibrated
Certain time is reacted, then solid-liquid centrifugation detaches, and precipitation is dried at a certain temperature, obtains the zinc modification antibacterial zeolite particles；
(4) titania powder, zinc nitrate, sodium hydroxide are weighed according to certain mass ratio, deionization is then added
Water stirs certain time at a certain temperature, and natural cooling cools down after reaction, precipitation is collected after centrifugation, with distilled water, second
Alcohol, distilled water wash successively to be precipitated and is collected by centrifugation, and is dried certain time at a certain temperature, is obtained the titanium zinc composite antibacterial
Agent；
(5) di-bromonitrilopropiona,ide, chlorine dioxide powder, copper are modified the modified antibacterial boiling of antibacterial zeolite particles, silver according to formula ratio
Stone, zinc modification antibacterial zeolite particles, titanium zinc compound bactericide, sodium hypochlorite, sodium chloride, activated carbon, iron hydroxide, biogenic organic acid are mixed
It closes uniformly, obtains the high-efficiency antimicrobial deodorant.
4. a kind of preparation method of high-efficiency antimicrobial deodorant according to claim 3, which is characterized in that sulphur in step (1)
Sour a concentration of 0.01-0.1mol/L of copper solution, sieve mesh number are 50-150 mesh, and natural zeolite is 1 with copper-bath mass ratio:
2-8, when oscillating reactions a length of 3-8h, drying temperature is 70-130 DEG C.
5. a kind of preparation method of high-efficiency antimicrobial deodorant according to claim 3, which is characterized in that nitre in step (2)
Sour silver solution concentration is 0.05-0.15mol/L, and natural zeolite is 1: 1-6 with silver nitrate solution mass ratio, and when oscillating reactions is a length of
1-6h, drying temperature are 80-150 DEG C.
6. a kind of preparation method of high-efficiency antimicrobial deodorant according to claim 3, which is characterized in that chlorine in step (3)
Change a concentration of 0.5-3.5mol/L of zinc solution, natural zeolite and silver nitrate solution mass ratio are 1: 1-10, and when oscillating reactions is a length of
2-8h, drying temperature are 60-120 DEG C.
7. a kind of preparation method of high-efficiency antimicrobial deodorant according to claim 3, which is characterized in that two in step (4)
Titanium dioxide powder, zinc nitrate, sodium hydroxide mass ratio be 1: 3-8: 5-12, temperature when stirring is 60-120 DEG C, when stirring
Long 6-15h, 50-100 DEG C of drying temperature, dry duration 6-24h.
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| CN111111627A (en) * | 2019-12-25 | 2020-05-08 | 南京大学（溧水）生态环境研究院 | Garbage deodorant and preparation method thereof |
| CN112591906A (en) * | 2021-01-21 | 2021-04-02 | 欣格瑞（山东）环境科技有限公司 | Multifunctional slime stripping agent for zero-pollution discharge and preparation method thereof |
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| CN110270219A (en) * | 2019-06-26 | 2019-09-24 | 江苏瑞丰科技实业有限公司 | A kind of trimethylamine high-efficient purification processing material |
| CN111111627A (en) * | 2019-12-25 | 2020-05-08 | 南京大学（溧水）生态环境研究院 | Garbage deodorant and preparation method thereof |
| CN111111627B (en) * | 2019-12-25 | 2023-02-28 | 南京大学（溧水）生态环境研究院 | Garbage deodorant and preparation method thereof |
| CN112591906A (en) * | 2021-01-21 | 2021-04-02 | 欣格瑞（山东）环境科技有限公司 | Multifunctional slime stripping agent for zero-pollution discharge and preparation method thereof |
| CN112591906B (en) * | 2021-01-21 | 2022-10-28 | 欣格瑞（山东）环境科技有限公司 | Multifunctional slime stripping agent for zero-pollution discharge and preparation method thereof |
| CN112831068A (en) * | 2021-03-02 | 2021-05-25 | 宁波福尔达智能科技有限公司 | Preparation method of novel antibacterial composite material |
| CN116571072A (en) * | 2023-07-12 | 2023-08-11 | 生态环境部华南环境科学研究所(生态环境部生态环境应急研究所) | Malodorous waste gas water-based composite absorbent and preparation method and application thereof |
| CN116571072B (en) * | 2023-07-12 | 2023-11-07 | 生态环境部华南环境科学研究所(生态环境部生态环境应急研究所) | Malodorous waste gas water-based composite absorbent and preparation method and application thereof |
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