CN108396356A - A kind of preparation process of the coloured electrophoresis aluminium sheet of wire drawing - Google Patents

A kind of preparation process of the coloured electrophoresis aluminium sheet of wire drawing Download PDF

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Publication number
CN108396356A
CN108396356A CN201810128428.2A CN201810128428A CN108396356A CN 108396356 A CN108396356 A CN 108396356A CN 201810128428 A CN201810128428 A CN 201810128428A CN 108396356 A CN108396356 A CN 108396356A
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CN
China
Prior art keywords
aluminium sheet
wire drawing
pure water
coloured
electrophoresis
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810128428.2A
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Chinese (zh)
Inventor
陈献忠
严雄伟
周坤勇
贾建均
潘旭丰
杨泽能
谢智慧
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhejiang Xin Xiang Aluminum Ltd Co
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Zhejiang Xin Xiang Aluminum Ltd Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zhejiang Xin Xiang Aluminum Ltd Co filed Critical Zhejiang Xin Xiang Aluminum Ltd Co
Priority to CN201810128428.2A priority Critical patent/CN108396356A/en
Publication of CN108396356A publication Critical patent/CN108396356A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D13/00Electrophoretic coating characterised by the process
    • C25D13/22Servicing or operating apparatus or multistep processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24BMACHINES, DEVICES, OR PROCESSES FOR GRINDING OR POLISHING; DRESSING OR CONDITIONING OF ABRADING SURFACES; FEEDING OF GRINDING, POLISHING, OR LAPPING AGENTS
    • B24B19/00Single-purpose machines or devices for particular grinding operations not covered by any other main group
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D13/00Electrophoretic coating characterised by the process
    • C25D13/20Pretreatment

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Road Signs Or Road Markings (AREA)
  • Paints Or Removers (AREA)
  • Materials For Photolithography (AREA)

Abstract

The invention discloses a kind of preparation processes of the coloured electrophoresis aluminium sheet of wire drawing, first pass through greasy dirt, natural oxide film, the slight open defect etc. on mechanical wire drawing removal surface, the surface after wire drawing uniformly applies and feels about in the dark slurry again, after carry out striped wire drawing again, the stereovision of black cosmetic striped is shown.Directly carry out coloured electrophoretic coating after washing, the color of coloured enamel is close to copper so that surface of aluminum plate color shows close to red metal color and the blackstreak that has a sense of hierarchy, meets the demand of decoration.The preparation process needs not move through traditional anodic oxidation and electrolytic colouring technology, saves a large amount of energy consumption, and the generation without all kinds of contaminant metal ions and discharge, environmental benefit are good.

Description

A kind of preparation process of the coloured electrophoresis aluminium sheet of wire drawing
Technical field:
The present invention relates to the preparation process field of the coloured electrophoresis aluminium sheet of wire drawing, the preparation of specifically a kind of coloured electrophoresis aluminium sheet of wire drawing Technique.
Background technology:
The smooth color of traditional surface of aluminum plate is single, cannot be satisfied demand of the people to decoration, and simple dyeing needs to consume big The chemical substance of amount, high energy consumption, and affect to environment, and the class of aluminium sheet is declined.
Invention content:
The purpose of the present invention provides a kind of preparation process of the coloured electrophoresis aluminium sheet of wire drawing exactly in order to solve existing issue.
The technology solution of the present invention is as follows:
A kind of preparation process of the coloured electrophoresis aluminium sheet of wire drawing, the preparation process of the coloured electrophoresis aluminium sheet of wire drawing includes following step Suddenly:
S1:Check and accept aluminium sheet:Choose up-to-standard aluminium sheet;
S2:Planar drawing:Uniform wire drawing process is carried out to surface of aluminum plate using aluminium sheet wire drawing machine, slurry processing is touched convenient for subsequent;
S3:Touch slurry:Black wash is uniformly applied in the wire drawing lines through planar drawing aluminium sheet;
S4:Striped wire drawing:Wire drawing process is carried out again to the surface of aluminum plate after touching slurry using aluminium sheet wire drawing machine, removal part is black Slurry, leaves chequered with black and white wire drawing decorative pattern;
S5:First of pure water is washed:Aluminium sheet is cleaned with the pure water of room temperature pH >=5,90 μ s/cm of conductivity <;
S6:Second pure water is washed:Aluminium sheet is cleaned with the pure water of room temperature pH >=6,60 μ s/cm of conductivity <;
S7:Imitative copper electrophoresis:Aluminium sheet electrophoretic process in the electrolytic solution, is arranged 19-23 DEG C of operating temperature, processing time 2-4min, Surface of aluminum plate forms one layer of electrodeposited paint film;
S8:Third road pure water is washed:Aluminium is cleaned with the pure water of room temperature pH8.2-8.6,100 μ s/cm of solid < 1%, conductivity < Plate washes away the remaining electrophoretic paint of aluminium sheet;
S9:4th pure water is washed:Aluminium is cleaned with the pure water of room temperature pH8.4-8.8,50 μ s/cm of solid < 0.3%, conductivity < Plate washes away the remaining electrophoretic paint of aluminium sheet;
S10:It drains:Aluminium sheet after cleaning is drained;
S11:Baking and curing:Aluminium sheet after draining is placed in drying tunnel and is cured, 180-200 DEG C of temperature, hardening time 30- are set 40min;
S12:Blanking inspection:Check whether the aluminium sheet after solidification is up-to-standard;
S13:Packaging and storage:By qualified aluminium sheet packaging and storage.
Preferably, the step S7:The electrolyte pH7.9-8.3 of imitative copper electrophoresis, solid(%)8.0 ± 0.5, conductance Rate(μs/cm)600 ± 150, acid value 37 ± 2, appropriate solvent.
The beneficial effects of the present invention are:The greasy dirt, natural oxide film, slight appearance that surface is removed by mechanical wire drawing lack Fall into, then the surface after wire drawing uniformly applies and feels about in the dark slurry, after carry out striped wire drawing again, the stereovision of black cosmetic striped is shown It is existing.Directly carry out coloured electrophoretic coating after washing, the color of coloured enamel is close to copper so that surface of aluminum plate color is close The red metal color and blackstreak having a sense of hierarchy shows, meets the demand of decoration, which needs not move through traditional Anodic oxidation and electrolytic colouring technology, simple dyeing, save a large amount of energy consumption, and without the generation of all kinds of contaminant metal ions And discharge, environmental benefit are good.
Specific implementation mode:
Embodiment 1
A kind of preparation process of the coloured electrophoresis aluminium sheet of wire drawing, the preparation process of the coloured electrophoresis aluminium sheet of wire drawing includes following step Suddenly:
S1:Check and accept aluminium sheet:Choose up-to-standard aluminium sheet;
S2:Planar drawing:Uniform wire drawing process is carried out to surface of aluminum plate using aluminium sheet wire drawing machine, slurry processing is touched convenient for subsequent;
S3:Touch slurry:Black wash is uniformly applied in the wire drawing lines through planar drawing aluminium sheet;
S4:Striped wire drawing:Wire drawing process is carried out again to the surface of aluminum plate after touching slurry using aluminium sheet wire drawing machine, removal part is black Slurry, leaves chequered with black and white wire drawing decorative pattern;
S5:First of pure water is washed:With room temperature pH=5, the pure water of the μ s/cm of conductivity=85 cleans aluminium sheet;
S6:Second pure water is washed:With room temperature pH=6, the pure water of the μ s/cm of conductivity=55 cleans aluminium sheet;
S7:Imitative copper electrophoresis:19 DEG C, processing time 2min of operating temperature is arranged, in aluminium sheet table in aluminium sheet electrophoretic process in the electrolytic solution Face forms one layer of electrodeposited paint film;
S8:Third road pure water is washed:With room temperature pH8.2, the pure water of solid=0.9%, the μ s/cm of conductivity=95 cleans aluminium sheet, washes Remove the remaining electrophoretic paint of aluminium sheet;
S9:4th pure water is washed:With room temperature pH8.4, the pure water of solid=0.28%, the μ s/cm of conductivity=45 cleans aluminium sheet, Wash away the remaining electrophoretic paint of aluminium sheet;
S10:It drains:Aluminium sheet after cleaning is drained;
S11:Baking and curing:Aluminium sheet after draining is placed in drying tunnel and is cured, 180 DEG C of temperature, hardening time 30min are set;
S12:Blanking inspection:Check whether the aluminium sheet after solidification is up-to-standard;
S13:Packaging and storage:By qualified aluminium sheet packaging and storage.
Specifically, the step S7:The electrolyte pH7.9 of imitative copper electrophoresis, solid(%)7.5, conductivity(μs/cm) 450, acid value 35, appropriate solvent.
Embodiment 2
A kind of preparation process of the coloured electrophoresis aluminium sheet of wire drawing, the preparation process of the coloured electrophoresis aluminium sheet of wire drawing includes following step Suddenly:
S1:Check and accept aluminium sheet:Choose up-to-standard aluminium sheet;
S2:Planar drawing:Uniform wire drawing process is carried out to surface of aluminum plate using aluminium sheet wire drawing machine, slurry processing is touched convenient for subsequent;
S3:Touch slurry:Black wash is uniformly applied in the wire drawing lines through planar drawing aluminium sheet;
S4:Striped wire drawing:Wire drawing process is carried out again to the surface of aluminum plate after touching slurry using aluminium sheet wire drawing machine, removal part is black Slurry, leaves chequered with black and white wire drawing decorative pattern;
S5:First of pure water is washed:With room temperature pH=6, the pure water of the μ s/cm of conductivity=80 cleans aluminium sheet;
S6:Second pure water is washed:With room temperature pH=7, the pure water of the μ s/cm of conductivity=50 cleans aluminium sheet;
S7:Imitative copper electrophoresis:20 DEG C, processing time 3min of operating temperature is arranged, in aluminium sheet table in aluminium sheet electrophoretic process in the electrolytic solution Face forms one layer of electrodeposited paint film;
S8:Third road pure water is washed:With room temperature pH8.4, the pure water of solid=0.85%, the μ s/cm of conductivity=90 cleans aluminium sheet, Wash away the remaining electrophoretic paint of aluminium sheet;
S9:4th pure water is washed:With room temperature pH8.6, the pure water of solid=0.26%, the μ s/cm of conductivity=40 cleans aluminium sheet, Wash away the remaining electrophoretic paint of aluminium sheet;
S10:It drains:Aluminium sheet after cleaning is drained;
S11:Baking and curing:Aluminium sheet after draining is placed in drying tunnel and is cured, 190 DEG C of temperature, hardening time 35min are set;
S12:Blanking inspection:Check whether the aluminium sheet after solidification is up-to-standard;
S13:Packaging and storage:By qualified aluminium sheet packaging and storage.
Specifically, the step S7:The electrolyte pH8 of imitative copper electrophoresis, solid(%)8.0, conductivity(μs/cm)600, Acid value 37, appropriate solvent.
Embodiment 3
A kind of preparation process of the coloured electrophoresis aluminium sheet of wire drawing, the preparation process of the coloured electrophoresis aluminium sheet of wire drawing includes following step Suddenly:
S1:Check and accept aluminium sheet:Choose up-to-standard aluminium sheet;
S2:Planar drawing:Uniform wire drawing process is carried out to surface of aluminum plate using aluminium sheet wire drawing machine, slurry processing is touched convenient for subsequent;
S3:Touch slurry:Black wash is uniformly applied in the wire drawing lines through planar drawing aluminium sheet;
S4:Striped wire drawing:Wire drawing process is carried out again to the surface of aluminum plate after touching slurry using aluminium sheet wire drawing machine, removal part is black Slurry, leaves chequered with black and white wire drawing decorative pattern;
S5:First of pure water is washed:With room temperature pH=7, the pure water of the μ s/cm of conductivity=75 cleans aluminium sheet;
S6:Second pure water is washed:With room temperature pH=8, the pure water of the μ s/cm of conductivity=45 cleans aluminium sheet;
S7:Imitative copper electrophoresis:23 DEG C, processing time 4min of operating temperature is arranged, in aluminium sheet table in aluminium sheet electrophoretic process in the electrolytic solution Face forms one layer of electrodeposited paint film;
S8:Third road pure water is washed:With room temperature pH8.6, the pure water of solid=0.8%, the μ s/cm of conductivity=85 cleans aluminium sheet, washes Remove the remaining electrophoretic paint of aluminium sheet;
S9:4th pure water is washed:With room temperature pH8.8, the pure water of solid=0.24%, the μ s/cm of conductivity=35 cleans aluminium sheet, Wash away the remaining electrophoretic paint of aluminium sheet;
S10:It drains:Aluminium sheet after cleaning is drained;
S11:Baking and curing:Aluminium sheet after draining is placed in drying tunnel and is cured, 200 DEG C of temperature, hardening time 40min are set;
S12:Blanking inspection:Check whether the aluminium sheet after solidification is up-to-standard;
S13:Packaging and storage:By qualified aluminium sheet packaging and storage.
Specifically, the step S7:The electrolyte pH8.3 of imitative copper electrophoresis, solid(%)8.5, conductivity(μs/cm) 750, acid value 39, appropriate solvent.
The coloured electrophoresis aluminium sheet of wire drawing that the technique of the present embodiment 2 makes removes greasy dirt, the nature on surface by mechanical wire drawing Oxidation film, slight open defect etc., then surface after wire drawing uniformly apply slurry of feeling about in the dark, after carry out striped wire drawing again, by black The stereovision of decorative stripe shows.Coloured electrophoretic coating is directly carried out after washing, the color of coloured enamel makes close to copper Surface of aluminum plate color shows close to red metal color and the blackstreak that has a sense of hierarchy, meet the demand of decoration, avoid simple Energy consumption waste and environmental pollution caused by dyeing.
It should be noted that above-described embodiment is only presently preferred embodiments of the present invention, there is no for the purpose of limiting the invention Protection domain, the equivalent replacement or replacement made on the basis of the above all belong to the scope of protection of the present invention.

Claims (5)

1. a kind of preparation process of the coloured electrophoresis aluminium sheet of wire drawing, it is characterised in that:The preparation work of the coloured electrophoresis aluminium sheet of wire drawing Skill includes the following steps:
S1:Check and accept aluminium sheet:Choose up-to-standard aluminium sheet;
S2:Planar drawing:Uniform wire drawing process is carried out to surface of aluminum plate using aluminium sheet wire drawing machine, slurry processing is touched convenient for subsequent;
S3:Touch slurry:Black wash is uniformly applied in the wire drawing lines through planar drawing aluminium sheet;
S4:Striped wire drawing:Wire drawing process is carried out again to the surface of aluminum plate after touching slurry using aluminium sheet wire drawing machine, removal part is black Slurry, leaves chequered with black and white wire drawing decorative pattern;
S5:First of pure water is washed:Aluminium sheet is cleaned with the pure water of room temperature pH >=5,90 μ s/cm of conductivity <;
S6:Second pure water is washed:Aluminium sheet is cleaned with the pure water of room temperature pH >=6,60 μ s/cm of conductivity <;
S7:Imitative copper electrophoresis:Aluminium sheet electrophoretic process in the electrolytic solution, is arranged 19-23 DEG C of operating temperature, processing time 2-4min, Surface of aluminum plate forms one layer of electrodeposited paint film;
S8:Third road pure water is washed:Aluminium is cleaned with the pure water of room temperature pH8.2-8.6,100 μ s/cm of solid < 1%, conductivity < Plate washes away the remaining electrophoretic paint of aluminium sheet;
S9:4th pure water is washed:Aluminium is cleaned with the pure water of room temperature PH8.4-8.8,50 μ s/cm of solid < 0.3%, conductivity < Plate washes away the remaining electrophoretic paint of aluminium sheet;
S10:It drains:Aluminium sheet after cleaning is drained;
S11:Baking and curing:Aluminium sheet after draining is placed in drying tunnel and is cured, 180-200 DEG C of temperature, hardening time 30- are set 40min;
S12:Blanking inspection:Check whether the aluminium sheet after solidification is up-to-standard;
S13:Packaging and storage:By qualified aluminium sheet packaging and storage.
2. the preparation process of the coloured electrophoresis aluminium sheet of wire drawing according to claim 1, it is characterised in that:The step S7:It is imitative The electrolyte pH7.9-8.3 of copper electrophoresis, solid(%)8.0 ± 0.5, conductivity(μs/cm)600 ± 150, acid value 37 ± 2 is molten Appropriate agent.
3. the preparation process of the coloured electrophoresis aluminium sheet of wire drawing according to claim 1, it is characterised in that:Carry out step S2, S3 With S6 in total needed for time≤3 day.
4. the preparation process of the coloured electrophoresis aluminium sheet of wire drawing according to claim 1, it is characterised in that:The step S2 is also wrapped Include available 200 mesh sand paper polishing surface of aluminum plate.
5. the preparation process of the coloured electrophoresis aluminium sheet of wire drawing according to claim 1, it is characterised in that:The step S2 is also wrapped Available steel wire lump is included to be modified aluminium sheet wire drawing lines.
CN201810128428.2A 2018-02-08 2018-02-08 A kind of preparation process of the coloured electrophoresis aluminium sheet of wire drawing Pending CN108396356A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810128428.2A CN108396356A (en) 2018-02-08 2018-02-08 A kind of preparation process of the coloured electrophoresis aluminium sheet of wire drawing

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Application Number Priority Date Filing Date Title
CN201810128428.2A CN108396356A (en) 2018-02-08 2018-02-08 A kind of preparation process of the coloured electrophoresis aluminium sheet of wire drawing

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105951150A (en) * 2016-05-18 2016-09-21 安徽省安庆市金誉金属材料有限公司 Surface treatment process for aluminum plate
CN106086999A (en) * 2016-08-31 2016-11-09 山东豪门铝业有限公司 A kind of ability cathode electrophoresis double-colored bronze wire drawing element aluminium section bar preparation technology
CN107345310A (en) * 2017-08-08 2017-11-14 浙江新祥铝业股份有限公司 A kind of processing method of imitative copper electrophoresis decoration bar section
CN107354499A (en) * 2017-08-08 2017-11-17 浙江新祥铝业股份有限公司 A kind of processing method of the coloured electrophoresis section bar of wire drawing

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105951150A (en) * 2016-05-18 2016-09-21 安徽省安庆市金誉金属材料有限公司 Surface treatment process for aluminum plate
CN106086999A (en) * 2016-08-31 2016-11-09 山东豪门铝业有限公司 A kind of ability cathode electrophoresis double-colored bronze wire drawing element aluminium section bar preparation technology
CN107345310A (en) * 2017-08-08 2017-11-14 浙江新祥铝业股份有限公司 A kind of processing method of imitative copper electrophoresis decoration bar section
CN107354499A (en) * 2017-08-08 2017-11-17 浙江新祥铝业股份有限公司 A kind of processing method of the coloured electrophoresis section bar of wire drawing

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Application publication date: 20180814