CN108396096A - A kind of extremely low temperature, the method for ultra-high-sulfur(UHS) molten iron converter desulfuration in furnace - Google Patents

A kind of extremely low temperature, the method for ultra-high-sulfur(UHS) molten iron converter desulfuration in furnace Download PDF

Info

Publication number
CN108396096A
CN108396096A CN201710068962.4A CN201710068962A CN108396096A CN 108396096 A CN108396096 A CN 108396096A CN 201710068962 A CN201710068962 A CN 201710068962A CN 108396096 A CN108396096 A CN 108396096A
Authority
CN
China
Prior art keywords
steel
molten iron
sulfur
added
uhs
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201710068962.4A
Other languages
Chinese (zh)
Other versions
CN108396096B (en
Inventor
栾花冰
朱晓雷
杨辉
徐延浩
高立超
秦海山
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Angang Steel Co Ltd
Original Assignee
Angang Steel Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Angang Steel Co Ltd filed Critical Angang Steel Co Ltd
Priority to CN201710068962.4A priority Critical patent/CN108396096B/en
Publication of CN108396096A publication Critical patent/CN108396096A/en
Application granted granted Critical
Publication of CN108396096B publication Critical patent/CN108396096B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C5/00Manufacture of carbon-steel, e.g. plain mild steel, medium carbon steel or cast steel or stainless steel
    • C21C5/28Manufacture of steel in the converter
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C1/00Refining of pig-iron; Cast iron
    • C21C1/02Dephosphorising or desulfurising
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C7/00Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
    • C21C7/04Removing impurities by adding a treating agent
    • C21C7/064Dephosphorising; Desulfurising
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Carbon Steel Or Casting Steel Manufacturing (AREA)

Abstract

The present invention relates to a kind of extremely low temperature, the methods of ultra-high-sulfur(UHS) molten iron converter desulfuration in furnace, include the following steps:1) pneumatic steelmaking is packed into system:Molten iron silicon content≤0.30% is smelted using full iron;Molten iron silicon content > 0.30%, adding amount of scrap steel≤5kg/t steel;2) smelting operation:Initial smelting period is blown using low rifle position, first slag charge is added after 5min, second batch slag charge, blowing to blunderbuss slagging after 13min are added after 10min;Ferromanganese is added after slagging, opens and third batch slag charge is added after blowing, blowing end point rifle position is operated, tapped in time after blowing end point blunderbuss according to " height is low " pattern.The present invention realizes the target that extremely low temperature, ultra-high-sulfur(UHS) molten iron desulfurization degree in Converter reach 70% or more, steel and ladle cleanliness factor can be improved, reduce production cost by the adjustment and control to converter loading system and converter smelting process process.

Description

A kind of extremely low temperature, the method for ultra-high-sulfur(UHS) molten iron converter desulfuration in furnace
Technical field
The present invention relates to technical field of ferrous metallurgy, more particularly to a kind of extremely low temperature, ultra-high-sulfur(UHS) molten iron converter desulfuration in furnace Method.
Background technology
Sulfur content is more than 0.07% (reaching as high as 0.2%), and molten iron of the temperature less than 1200 DEG C is referred to as smelting iron off-iron, It does not have molten iron pretreatment desulfurizing condition.Extremely low temperature of the present invention, ultra-high-sulfur(UHS) molten iron refer to temperature and are less than 1200 DEG C, and sulphur contains Molten iron of the amount more than 0.10%, such molten iron can cause tapping sulfur content high after being blended into converter, to steel, ladle cleanliness factor, life Production cost etc. is affected;In addition it returns to ladle when the tops production LF slag needs to make acid slag class steel grade, big due to increasing sulfur content, It causes to change steel cold recovery increased risk;In the prior art, desulfurization is added before generally using iron making for such low temperature high-sulphur molten iron The method desulfurization of ferromanganese, but effect is undesirable, maximum desulphurizing ability can only achieve 40%~50%, has both increased and has been produced into This, and the target of converter desulfurization to greatest extent cannot be reached.
Invention content
The present invention provides a kind of extremely low temperature, the methods of ultra-high-sulfur(UHS) molten iron converter desulfuration in furnace, are made by being packed into converter The adjustment and control of degree and converter smelting process process realize that extremely low temperature, ultra-high-sulfur(UHS) molten iron desulfurization degree in Converter reach Steel and ladle cleanliness factor can be improved in 70% or more target, reduces production cost.
In order to achieve the above object, the present invention is realized using following technical scheme:
A kind of extremely low temperature, the method for ultra-high-sulfur(UHS) molten iron converter desulfuration in furnace, the extremely low temperature, ultra-high-sulfur(UHS) molten iron are sulfur content > 0.1%, temperature are less than 1200 DEG C of molten iron;Include the following steps:
1) pneumatic steelmaking is packed into system:
According to extremely low temperature, the rational loading system of the molten iron condition of ultra-high-sulfur(UHS) molten iron selection, molten iron condition is according to silicone content It is divided into two classes:
Molten iron condition one:Molten iron silicon content≤0.30% is smelted using full iron, is not added with steel scrap;
Molten iron condition two:Molten iron silicon content > 0.30%, adding amount of scrap steel≤5kg/t steel, it is ensured that the heating of initial smelting period Rate improves desulfurization rate in converter;
2) smelting operation:
Initial smelting period is blown using the low rifle position of 1.8~2.0m, and molten iron is made to be rapidly heated, first is added after the 5min that blows Slag charge, including lime 18~22kg/t steel, dolomite 18~22kg/t steel;
It blowing and second batch slag charge is added after 10min, second batch slag charge includes lime 10~15kg/t steel, dolomite 3~ 5kg/t steel, alternately according to " high-low-high ", blowing to blunderbuss slagging after 13min, slagging amount is total quantity of slag for rifle position operation 1/3 or more;
Ferromanganese is added after slagging, opens and third batch slag charge is added after blowing, third batch slag charge includes lime 5~10kg/t steel;
Blowing end point operates:Rifle position is operated according to " high-low-low " pattern, it is therefore an objective to be reduced iron oxide content in slag, be reached The purpose of further desulfurization;Blowing end point target carbon content 0.08~0.10%, temperature >=1685 DEG C, sulfur content≤0.025%;
It taps in time after blowing end point blunderbuss, anti-non-return sulphur.
The addition of ferromanganese is specially after slagging:
When molten steel sulfur content 0.07%~0.10%, ferromanganese addition 1.8~2.1kg/t steel;
When molten steel sulfur content 0.10%~0.15%, ferromanganese addition 3.6~4.2kg/t steel;
When molten steel sulfur content > 0.15%, ferromanganese addition 5.8~6.3kg/t steel.
Compared with prior art, the beneficial effects of the invention are as follows:
By being packed into the adjustment and control of system and converter smelting process process to converter, extremely low temperature, ultra-high-sulfur(UHS) iron are realized Water desulfurization degree in Converter reaches 70% or more target, and steel and ladle cleanliness factor can be improved, and reduces production cost.
Description of the drawings
Fig. 1 is implementation group and control group tapping sulfur content average value comparison diagram in the embodiment of the present invention.
Specific implementation mode
A kind of extremely low temperature of the present invention, the method for ultra-high-sulfur(UHS) molten iron converter desulfuration in furnace, the extremely low temperature, ultra-high-sulfur(UHS) iron Water is sulfur content > 0.1%, and temperature is less than 1200 DEG C of molten iron;Include the following steps:
1) pneumatic steelmaking is packed into system:
According to extremely low temperature, the rational loading system of the molten iron condition of ultra-high-sulfur(UHS) molten iron selection, molten iron condition is according to silicone content It is divided into two classes:
Molten iron condition one:Molten iron silicon content≤0.30% is smelted using full iron, is not added with steel scrap;
Molten iron condition two:Molten iron silicon content > 0.30%, adding amount of scrap steel≤5kg/t steel, it is ensured that the heating of initial smelting period Rate improves desulfurization rate in converter;
2) smelting operation:
Initial smelting period is blown using the low rifle position of 1.8~2.0m, and molten iron is made to be rapidly heated, first is added after the 5min that blows Slag charge, including lime 18~22kg/t steel, dolomite 18~22kg/t steel;
It blowing and second batch slag charge is added after 10min, second batch slag charge includes lime 10~15kg/t steel, dolomite 3~ 5kg/t steel, alternately according to " high-low-high ", blowing to blunderbuss slagging after 13min, slagging amount is total quantity of slag for rifle position operation 1/3 or more;
Ferromanganese is added after slagging, opens and third batch slag charge is added after blowing, third batch slag charge includes lime 5~10kg/t steel;
Blowing end point operates:Rifle position is operated according to " high-low-low " pattern, it is therefore an objective to be reduced iron oxide content in slag, be reached The purpose of further desulfurization;Blowing end point target carbon content 0.08~0.10%, temperature >=1685 DEG C, sulfur content≤0.025%;
It taps in time after blowing end point blunderbuss, anti-non-return sulphur.
The addition of ferromanganese is specially after slagging:
When molten steel sulfur content 0.07%~0.10%, ferromanganese addition 1.8~2.1kg/t steel;
When molten steel sulfur content 0.10%~0.15%, ferromanganese addition 3.6~4.2kg/t steel;
When molten steel sulfur content > 0.15%, ferromanganese addition 5.8~6.3kg/t steel.
Following embodiment is being implemented down based on the technical solution of the present invention, gives detailed embodiment and tool The operating process of body, but protection scope of the present invention is not limited to following embodiments.Method therefor is such as without spy in following embodiments It is conventional method not mentionlet alone bright.
【Embodiment】
In the present embodiment, implementation group uses the method for the invention, control group each to smelt 9 tanks using conventional smelting process Extremely low temperature, ultra-high-sulfur(UHS) molten iron, two groups of each tank molten steel sulfur content and molten iron temperature correspond, and molten steel sulfur content is ranging from 0.1~0.15%, molten iron temperature≤1200 DEG C.Specific smelting process is as follows:
1) pneumatic steelmaking is packed into system:
It is 0.1~0.15%, respectively less than 0.30% by molten iron silicon content in this present embodiment, therefore uses full iron smelting Refining, is not added with steel scrap.
2) smelting operation:
Initial smelting period is blown using the low rifle position of 2.0m, and molten iron is made to be rapidly heated, first slag charge is added after the 5min that blows, Including lime 18~22kg/t steel, dolomite 18~22kg/t steel;(each tank molten steel determines within this range according to actual needs to be added Enter amount, following technological parameter is identical with this when being value range).
It blowing and second batch slag charge is added after 10min, second batch slag charge includes lime 10~15kg/t steel, dolomite 3~ 5kg/t steel, alternately according to " high-low-high ", blowing to blunderbuss slagging after 13min, slagging amount is total quantity of slag for rifle position operation 1/3;
Ferromanganese is added after slagging, the addition of ferromanganese is:
When molten steel sulfur content 0.07%~0.10%, ferromanganese addition 1.8~2.1kg/t steel;
When molten steel sulfur content 0.10%~0.15%, ferromanganese addition 3.6~4.2kg/t steel;
When molten steel sulfur content > 0.15%, ferromanganese addition 5.8~6.3kg/t steel.
It opens and third batch slag charge is added after blowing, third batch slag charge includes lime 5~10kg/t steel.
Blowing end point operates:Rifle position is operated according to " high-low-low " pattern, it is therefore an objective to be reduced iron oxide content in slag, be reached The purpose of further desulfurization;Blowing end point target carbon content 0.08~0.10%, temperature >=1685 DEG C, sulfur content≤0.025%;
After blowing end point blunderbuss, furnace superintendent combination clinker situation and see full-page proof (judge tapping carbon) as a result, rule of thumb judging Whether have tapping condition, tap in time or corresponding treatment measures, the samples time such as reduction is taken to prevent equal samples process from returning in time Sulphur.
As shown in Figure 1, the tapping sulfur content average value of implementation group is 0.024%, the tapping sulfur content average value of control group It is 0.059%, i.e., the tapping sulfur content before the method for the invention is relatively implemented after implementing averagely reduces 0.035%.
After the method for the invention is implemented, desulfurization degree is improved to 75.26% in extremely low temperature, ultra-high-sulfur(UHS) molten iron Converter.
Before the method for the invention is implemented, 2 tank of cord steel cold recovery is caused since high-sulfur returns to ladle, is not occurred after implementation Such accident.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto, Any one skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.

Claims (2)

1. a kind of method of extremely low temperature, ultra-high-sulfur(UHS) molten iron converter desulfuration in furnace, the extremely low temperature, ultra-high-sulfur(UHS) molten iron are sulfur content > 0.1%, temperature is less than 1200 DEG C of molten iron;It is characterised in that it includes following steps:
1) pneumatic steelmaking is packed into system:
According to extremely low temperature, the rational loading system of the molten iron condition of ultra-high-sulfur(UHS) molten iron selection, molten iron condition is divided into according to silicone content Two classes:
Molten iron condition one:Molten iron silicon content≤0.30% is smelted using full iron, is not added with steel scrap;
Molten iron condition two:Molten iron silicon content > 0.30%, adding amount of scrap steel≤5kg/t steel, it is ensured that the heating rate of initial smelting period, Improve desulfurization rate in converter;
2) smelting operation:
Initial smelting period is blown using the low rifle position of 1.8~2.0m, and molten iron is made to be rapidly heated, first slag is added after the 5min that blows Material, including lime 18~22kg/t steel, dolomite 18~22kg/t steel;
Second batch slag charge is added after blowing 10min, second batch slag charge includes lime 10~15kg/t steel, 3~5kg/t of dolomite Steel, rifle position operation according to " high-low-high " alternately, blowing to blunderbuss slagging after 13min, slagging amount be the 1/3 of total quantity of slag with On;
Ferromanganese is added after slagging, opens and third batch slag charge is added after blowing, third batch slag charge includes lime 5~10kg/t steel;
Blowing end point operates:Rifle position is operated according to " high-low-low " pattern, it is therefore an objective to be reduced iron oxide content in slag, be reached into one Walk the purpose of desulfurization;Blowing end point target carbon content 0.08~0.10%, temperature >=1685 DEG C, sulfur content≤0.025%;
It taps in time after blowing end point blunderbuss, anti-non-return sulphur.
2. the method for a kind of extremely low temperature according to claim 1, ultra-high-sulfur(UHS) molten iron converter desulfuration in furnace, which is characterized in that The addition of ferromanganese is specially after slagging:
When molten steel sulfur content 0.07%~0.10%, ferromanganese addition 1.8~2.1kg/t steel;
When molten steel sulfur content 0.10%~0.15%, ferromanganese addition 3.6~4.2kg/t steel;
When molten steel sulfur content > 0.15%, ferromanganese addition 5.8~6.3kg/t steel.
CN201710068962.4A 2017-02-08 2017-02-08 A kind of extremely low temperature, the method for ultra-high-sulfur(UHS) molten iron converter desulfuration in furnace Active CN108396096B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710068962.4A CN108396096B (en) 2017-02-08 2017-02-08 A kind of extremely low temperature, the method for ultra-high-sulfur(UHS) molten iron converter desulfuration in furnace

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710068962.4A CN108396096B (en) 2017-02-08 2017-02-08 A kind of extremely low temperature, the method for ultra-high-sulfur(UHS) molten iron converter desulfuration in furnace

Publications (2)

Publication Number Publication Date
CN108396096A true CN108396096A (en) 2018-08-14
CN108396096B CN108396096B (en) 2019-09-20

Family

ID=63093948

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710068962.4A Active CN108396096B (en) 2017-02-08 2017-02-08 A kind of extremely low temperature, the method for ultra-high-sulfur(UHS) molten iron converter desulfuration in furnace

Country Status (1)

Country Link
CN (1) CN108396096B (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06240327A (en) * 1993-02-16 1994-08-30 Nisshin Steel Co Ltd Production of low si-low s-high mn molten iron accompanied with smelting reduction of mn ore
CN101294233A (en) * 2007-04-25 2008-10-29 宝山钢铁股份有限公司 Desilication demanganization method at same time of preprocessing hot metal
CN102776313A (en) * 2012-08-20 2012-11-14 武汉钢铁(集团)公司 Method for smelting high-phosphorus steel by low-temperature low-silicon molten iron in converter
CN103397146A (en) * 2013-08-02 2013-11-20 首钢总公司 Production method of pipeline steel

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06240327A (en) * 1993-02-16 1994-08-30 Nisshin Steel Co Ltd Production of low si-low s-high mn molten iron accompanied with smelting reduction of mn ore
CN101294233A (en) * 2007-04-25 2008-10-29 宝山钢铁股份有限公司 Desilication demanganization method at same time of preprocessing hot metal
CN102776313A (en) * 2012-08-20 2012-11-14 武汉钢铁(集团)公司 Method for smelting high-phosphorus steel by low-temperature low-silicon molten iron in converter
CN103397146A (en) * 2013-08-02 2013-11-20 首钢总公司 Production method of pipeline steel

Also Published As

Publication number Publication date
CN108396096B (en) 2019-09-20

Similar Documents

Publication Publication Date Title
CN102304606B (en) Slag former and slagging method for semisteel steelmaking
CN109022664B (en) Method for smelting Ti-IF steel by using vanadium-titanium-containing molten iron
CN106148630A (en) A kind of method of converter smelting low-phosphorous low-sulfur molten steel
CN102382925A (en) Manufacturing method of ultrapurity armco iron
CN106148631B (en) A kind of method of the ultralow nitrogen molten steel of converter smelting low-sulfur
CN107201421B (en) A kind of production method of super-low sulfur molten steel
CN104195290A (en) Molten steel dephosphorization agent and molten steel dephosphorization refining method
CN108998613A (en) Free oxygen control method in a kind of low aluminum steel of Ultra-low carbon
CN109161634A (en) The low silicon high phosphorus hot metal of manganese proposes the preparation method that carbon protects manganese in a kind of converter smelting
CN105132611B (en) Method for producing ultra-low phosphorous steel through single slag of converter
CN112210638A (en) Converter smelting method for medium and high silicon molten iron
CN103642969B (en) A kind of hot metal containing V-Ti smelts the method that electrical steel process returns sulphur control
CN102808061B (en) Method for smelting nickel-containing steel by using low-nickel pig iron in converter
CN103215406B (en) Low-carbon and ultralow sulfur steel smelting method
CN107663562A (en) The increased method of silicone content is prevented during Ultra-low carbon ultra-low silicon steel smelting
CN107868858A (en) A kind of production method of low S and low P steel
CN104531940A (en) Converter final slag thickening method
CN106566908A (en) Production method of converter smelted low-sulphur steel
CN104109727B (en) The method of half steel converter smelting Low-phosphorus Steel
CN103555886A (en) Method for smelting ultralow-sulfur steel by using vanadium-containing molten iron
CN104232845A (en) Argon oxygen decarburization (AOD) slag-making method during smelting of sulfur-containing free-cutting stainless steel
CN104328240A (en) Method for smelting high-carbon and low-phosphorus steel by adopting converter
CN108570528B (en) Control method for improving steelmaking converter blowing end point temperature
CN108396096B (en) A kind of extremely low temperature, the method for ultra-high-sulfur(UHS) molten iron converter desulfuration in furnace
CN103773916A (en) Method for smelting weather resistant steel through high-phosphorus-content steel discharging by converter

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant