CN108360268A - A kind of preparation method of indoor curtain using insulating moulding coating - Google Patents
A kind of preparation method of indoor curtain using insulating moulding coating Download PDFInfo
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- CN108360268A CN108360268A CN201810028726.4A CN201810028726A CN108360268A CN 108360268 A CN108360268 A CN 108360268A CN 201810028726 A CN201810028726 A CN 201810028726A CN 108360268 A CN108360268 A CN 108360268A
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- insulating moulding
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06N3/042—Acrylic polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0063—Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/06—Properties of the materials having thermal properties
- D06N2209/065—Insulating
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2211/00—Specially adapted uses
- D06N2211/12—Decorative or sun protection articles
- D06N2211/122—Curtains
Abstract
The present invention provides a kind of preparation method for the indoor curtain using insulating moulding coating.The insulating moulding coating is to disperse the heat-insulated powder with heat-proof quality and auxiliary agent in organic solvent, then this dispersion liquid and resin are mixed to prepare insulating moulding coating by certain way, and anchor on casement, makes it have heat insulating function, reduces indoor temperature.
Description
Technical field
The invention belongs to heat-insulated textile material technical field, it particularly relates to it is a kind of using insulating moulding coating it is indoor every
The preparation method of hot curtain.
Background technology
With the development of society, high buildings and large mansions continue to bring out, modern architecture largely uses glass, plastics etc. slim, transparent
Exterior material, these materials inevitably lead to sunray and inject interior, cause interior while improving indoor lighting
Temperature rise.Indoor temperature rises caused by being injected for balance sunlight, and people are generally cooled down using air-conditioning, this is also China's summer
Season energy consumption a big source.According to incompletely statistics, the energy consumption of Effect of Residential Windows occupies the 30% ~ 50% of residence entirety energy consumption, this
In the case of, physiological comfort and economic benefit that Thermal insulation curtain is brought just are particularly important.
So-called Thermal insulation curtain makes it to sunlight that is, by the heat-insulated final finishing to curtain（Mainly near infrared band,
Account for the 50% of sunlight total amount of heat）It is obstructed, to inhibit the raising of indoor temperature, improves the comfort level of people, reduce the energy
Consumption and CO2 emission.The powders such as caesium tungsten bronze, tin-antiomony oxide, tin indium oxide, zinc oxide aluminum, zinc-gallium oxide all have excellent
Different infrared shielding performance, plays heat-insulated effect.When these heat-insulated powders are nanoscale, to the absorptivity pole of visible light
It is weak, there is very high transparency, is transparent heat-insulated preferred material.One or more of these heat-insulated powders are used for curtain
Final finishing, so that it may obtain the curtain with heat insulation and heat control function.Have a few class Thermal insulation curtains both at home and abroad at present to come out, but deposits
In some defects, such as：
1. the Chinese patent of Publication No. CN204532002U discloses a kind of aeration insulating Thermal insulation curtain, the outside of curtain body
Heat reflection coating is coated, electric reel, inflation asepwirator pump connect the air bag that is internally provided with of curtain body with processor, and air bag fills
It is internal to form several independent air chambers after gas, to achieve the effect that heat-insulation and heat-preservation.But the internal structure of air bag is excessively
It is complicated.
2. the Chinese patent of Publication No. CN203399947U discloses a kind of heat-insulation window cord, its base fabric is by warp
What metallic reflection silk and the weaving of weft nanofibers were constituted, it is anti-to be converted to infra-red radiation after being heated using far-infrared emission material
It is emitted back towards the external world, makes casement that there is heat-proof quality.But warp wires reflecting filament is aluminium foil strand or aluminium film strand, and aluminium foil is metal
Material forms infrared ray to room internal leakage, stretches easy to aging, demoulding for a long time after heat absorption.
3. the Chinese patent of Publication No. CN2102561039A disclose a kind of insulating moulding coating for outdoor textile and
Preparation method and application, ingredient are mainly silica, alundum (Al2O3), zinc oxide, rutile type titanium white, glue, divide
Powder, toluene, acetone etc..The coating is applied on the synthetic fibers such as terylene, eyeball synthetic fibre, can obtain apparent cooling-down effect.But it needs
150 DEG C of drying, and the rutile type titanium white larger since grain size is added, wash durability allow of no optimist.
Advantage of the invention is that：The heat-insulated powder used has good near infrared light shielding character, directly blocks
Heat is to indoor transmission；Meanwhile the high visible light transmissivity of heat insulation nano powder influences the thin permeability of curtain little, solution
Part curtain is every the not heat-insulated problem of light；The use of G01 nano silicon oxides can make insulating moulding coating have anti-caking, resist sagging
Characteristic.Titanium dioxide（P25）The adhesion strength of coating, anti-aging, scrub performance can be improved well；Solvent-type acrylic tree
The addition of fat greatly improves the wash durability of Thermal insulation curtain；It can dry at room temperature, and coating operation is easy.
Since easily dry and wash durability is good, insulating moulding coating provided by the invention may also be fabricated which spray, direct spraying in
On clothing, clothing is made to have the effect of heat insulation and heat control.
Invention content
The object of the present invention is to provide a kind of preparation methods of the indoor Thermal insulation curtain using insulating moulding coating, it is characterised in that
With following process and step:
A, the preparation of insulating moulding coating
A, the preparation of the dispersion liquid of heat-insulated powder
Heat-insulated powder uses any one of caesium tungsten bronze nano powder, tin indium oxide nano powder, tin-antiomony oxide nano powder or two kinds,
Most preferably it is to use caesium tungsten bronze and tin indium oxide nano powder；
In addition, nano silicon oxide（G01）, titanium dioxide（P25）；
Above multiple heat-insulated powders are dispersed in organic solvent toluene or absolute ethyl alcohol or any solvent of n-butanol, obtain every
Hot powder dispersion；
Mass percent of the heat-insulated powder in the dispersion liquid is 2.5 ~ 25%, be most preferably caesium tungsten bronze nano powder account for 1 ~ 10%,
Tin indium oxide nano powder accounts for 1 ~ 5%；The mass percent of G01 nano silicon oxides is 0.1~5%, titanium dioxide（P25）Quality hundred
Divide than being 0.1~5%, the mass percent of dispersant is 1~10%, and jitter time is 10~50h；
B, the preparation of acrylic resin organic solution
Solvent type acrylic resin is added in absolute ethyl alcohol and is dissolved, wherein the mass percent of acrylic resin be 1~
15%, it is prepared into acrylic resin organic solution；
C, the preparation of insulating moulding coating
Above-mentioned heat-insulated powder dispersion is added in above-mentioned acrylic resin organic solution, the ratio of the two is 1:1~1:2, mixing
To get insulating moulding coating after uniformly.
B, the preparation of Thermal insulation curtain
Casement is cut into 35cm × 55cm sizes by a, is immersed in 1 ~ 2 in the sodium hydrate aqueous solution that mass percent is 15%
It, takes out for use；
B is ultrasonically treated 1~10 minute by above-mentioned casement dip-coating and at 20~600W, make insulating moulding coating completely with curtain base
Body combines；
C after taking-up, waits for that the surplus liquid on casement is flow to end, and natural air drying or is dried up to get to Thermal insulation curtain with cold wind.
Description of the drawings
Fig. 1 is ultraviolet-visible-near-infrared optical transmitance collection of illustrative plates of Thermal insulation curtain prepared by embodiment 1.
Fig. 2 is the wash durability test of Thermal insulation curtain prepared by embodiment 1.
Fig. 3 is the practical thermoregulation effect simulation test of Thermal insulation curtain prepared by embodiment 1.
Fig. 4 is the heat-insulated difference curve figure of Thermal insulation curtain prepared by embodiment 1.
Fig. 5 is the wash durability test of Thermal insulation curtain prepared by comparative example 1.
Specific implementation mode
It is further illustrated the present invention below by way of following embodiments.
It is matrix that the present invention, which is using sunlight cloth,（The material of matrix can be nylon, terylene etc.）, then will by certain way
Heat-insulated powder（Any one in the heat-insulated powder with infrared shielding performance such as caesium tungsten bronze, tin-antiomony oxide, tin indium oxide is more
The mixture of kind）It is anchored on matrix with the insulating moulding coating based on solvent type acrylic resin, becomes Thermal insulation curtain, had
There is the function of heat insulation and heat control.The Thermal insulation curtain includes curtain matrix and uniform adhesion in the heat-insulated of described matrix fiber surface
Powder.Wherein, the powder content of the curtain matrix fiber surface adhesion is 1~25%.Content is too low, and heat insulation is poor；Content
Excessively high, Thermal insulation curtain visible light transmittance declines, and colors of curtain is deepened, and visual effect is influenced.Wherein, the grain of the heat-insulated powder
Diameter is 1~3000nm.Preferably, the grain size of the heat-insulated powder is 1~100nm.
Illustrate to following exemplary the preparation method with heat insulation and heat control curtain provided by the invention.
The preparation of caesium tungsten bronze nano-powder.Using solid sintering technology, caesium tungsten bronze nano-powder is prepared.
Tin indium oxide nano-powder is commercially available.
The preparation of dispersion liquid.By caesium tungsten bronze that grain size is 1~100nm and tin indium oxide nano-powder, have in the present invention
Solvent, dispersant, nano silicon oxide（G01）, titanium dioxide（P25）It is uniformly mixed with certain proportion, zirconia ball is added and grinds
20~50h is ground, zirconia ball is filtered off, obtains nano dispersion fluid.The addition of dispersant and zirconia ball contributes to particle to crush simultaneously
Prevent broken particle reunite and keep the stabilization of dispersion liquid.
The preparation of insulating moulding coating.Solvent type acrylic resin is dissolved in organic solvent in the present invention, wherein acrylic acid tree
Fat is with organic solvent with 1：20（I.e. 5%）Mass ratio uniformly mix, add dispersion liquid obtained above, wherein powder point
Mass percent of the dispersion liquid in insulating moulding coating is 30 ~ 50%.
Illustrate to following exemplary that dip coating provided by the invention prepares Thermal insulation curtain.
Curtain matrix after cleaning is completely submerged in gained insulating moulding coating.1~10 is ultrasonically treated at 20~600W
Minute, so that insulating moulding coating is combined completely with curtain matrix.After taking-up, wait for that surplus liquid is flow to end on curtain, natural air drying or with cold
Wind is dry.
Embodiment 1
A kind of preparation method with heat insulation and heat control curtain, its step are as follows：
（1）To 36g absolute ethyl alcohols, 4g dispersants and 6g caesium tungsten bronze nano-powders and 4g tin indium oxide nano-powders is added, then
Nano silicon oxide is added successively（G01）0.5g, with titanium dioxide（P25）0.5g is used in combination zirconia ball to be sanded for 24 hours, obtains caesium tungsten
The nano dispersion fluid that bronze is mixed with tin indium oxide；
（2）Into 463g absolute ethyl alcohols, 25g acrylic resins are added, after resin is completely dissolved, 55g is added（1）Middle preparation
Insulating moulding coating is made in good dispersion liquid, magnetic agitation 1h；
（3）After the sunlight cloth of 35cm × 55cm is cleaned up, it is immersed in（2）In the insulating moulding coating of middle configuration, surpass at 600W
Sonication 5 minutes, makes finishing agent be combined completely with curtain matrix.After taking-up, wait for that the surplus liquid on curtain is flow to end, natural air drying
Or it is dried up with cold wind.
Ultraviolet-visible-near infrared light transmitance, practical temperature control effect and fastness to washing have been carried out to obtained Thermal insulation curtain
Test, the results showed that：Collated dose of treated curtain, it is seen that light area transmitance reduces little, but the transmission of near-infrared region
Rate decreased significantly, i.e., has apparent shield effectiveness to near-infrared region；Reality is can be very good in practical temperature control measure of merit
Regulate and control solar energy, compare untreated curtain, indoor temperature is substantially reduced；The water-fastness degree of Thermal insulation curtain enhances.
Fig. 1 is ultraviolet-visible-near-infrared optical transmitance collection of illustrative plates of Thermal insulation curtain made from embodiment 1, and test result is aobvious
Show：Collated dose of treated curtain is compared with untreated curtain, it is seen that light area transmitance has and reduces by a small margin, near-infrared region
Then it is substantially reduced（Fig. 1）, illustrate that solar energy regulation and control efficiency is higher, can not be influenced as possible while shielding near infrared light visible
The transmission of light.
Fig. 2 be Thermal insulation curtain made from embodiment 1 wash durability test, in order to detect textile thermoregulation effect and
Thermal insulation curtain is accelerated ablution, use washable by water-fastness degree by AATCC test method 61-1996, test no. 2A.
Degree tester washs 0,4,8,12 time respectively（It cleans 1 time and is equivalent to household laundry machine washing 5 times）, then with ultraviolet-visible-near-infrared
Spectrophotometer measures the variation of its transmitance（Fig. 2）.The result shows that：Washing before compared with after washing, Thermal insulation curtain it is close red
The areas Wai Guang transmitance slightly rises, but still has good near-infrared shield effectiveness, illustrates that wash durability is good.
Fig. 3 is the practical thermoregulation effect simulation test of Thermal insulation curtain made from embodiment 1.By not locating for 35cm × 55cm
Reason sunlight cloth is attached on the closet of the right and left respectively with Thermal insulation curtain.The sunlight in summer is simulated with the infrared light irradiation of high power
Irradiation, is observed after ten minutes, due to the near-infrared shield effectiveness of heat insulation nano powder, so left side inner temperature of room is significantly lower than the right side
Room（Fig. 3）, the temperature difference is up to 4.9 DEG C（Fig. 4）.
Comparative example 1
The nano dispersion fluid for only taking caesium tungsten bronze to be mixed with tin indium oxide, with absolute ethyl alcohol with 1：10 mass ratio is uniformly mixed,
Dressing liquid is attached on curtain matrix with dip coating.Ultraviolet-visible-near infrared light is carried out to obtained Thermal insulation curtain to penetrate
Rate and fastness to washing test, the results showed that：Before not washing, compared with the Thermal insulation curtain for adding acrylic resin, near infrared region penetrates
Rate is significantly raised.After control sample is washed 4 times by AATCC test method 61-2003 Test No. 2A., infrared band
The curve of transmitance and untreated curtain matrix are almost be overlapped, without apparent difference, illustrate the increase curtain with wash number
The ability of blocking solar energy rapidly reduces, and almost disappears to the regulation and control efficiency of solar energy（Fig. 5）.
Claims (1)
1. a kind of preparation method of indoor Thermal insulation curtain using insulating moulding coating, it is characterised in that have following process and step
Suddenly:
A, the preparation of insulating moulding coating
A, the preparation of the dispersion liquid of heat-insulated powder
Heat-insulated powder uses any one of caesium tungsten bronze nano powder, tin indium oxide nano powder, tin-antiomony oxide nano powder or two kinds,
Most preferably it is to use caesium tungsten bronze and tin indium oxide nano powder；
In addition, nano silicon oxide（G01）, titanium dioxide（P25）；
Above multiple heat-insulated powders are dispersed in organic solvent toluene or absolute ethyl alcohol or any solvent of n-butanol, obtain every
Hot powder dispersion；
Mass percent of the heat-insulated powder in the dispersion liquid is 2.5 ~ 25%, be most preferably caesium tungsten bronze nano powder account for 1 ~ 10%,
Tin indium oxide nano powder accounts for 1 ~ 5%；The mass percent of G01 nano silicon oxides is 0.1~5%, titanium dioxide（P25）Quality hundred
Divide than being 0.1~5%, the mass percent of dispersant is 1~10%, and jitter time is 10~50h；
B, the preparation of acrylic resin organic solution
Solvent type acrylic resin is added in absolute ethyl alcohol and is dissolved, wherein the mass percent of acrylic resin be 1~
15%, it is prepared into acrylic resin organic solution；
C, the preparation of insulating moulding coating
Above-mentioned heat-insulated powder dispersion is added in above-mentioned acrylic resin organic solution, the ratio of the two is 1:1~1:2, mixing
To get insulating moulding coating after uniformly；
B, the preparation of Thermal insulation curtain
Casement is cut into 35cm × 55cm sizes by a, is immersed in 1 ~ 2 in the sodium hydrate aqueous solution that mass percent is 15%
It, takes out for use；
B is ultrasonically treated 1~10 minute by above-mentioned casement dip-coating and at 20~600W, make insulating moulding coating completely with curtain base
Body combines；
C after taking-up, waits for that the surplus liquid on casement is flow to end, and natural air drying or is dried up to get to Thermal insulation curtain with cold wind.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810028726.4A CN108360268B (en) | 2018-01-12 | 2018-01-12 | Preparation method of indoor curtain adopting heat-insulating coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810028726.4A CN108360268B (en) | 2018-01-12 | 2018-01-12 | Preparation method of indoor curtain adopting heat-insulating coating |
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| CN108360268A true CN108360268A (en) | 2018-08-03 |
| CN108360268B CN108360268B (en) | 2021-06-04 |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110117911A (en) * | 2019-05-17 | 2019-08-13 | 宁波先锋新材料股份有限公司 | A kind of coating composite material and preparation method thereof |
| CN110328932A (en) * | 2019-06-25 | 2019-10-15 | 杭州科能新材料科技有限公司 | A kind of insulation pack pack and its preparation method and application |
| CN112210844A (en) * | 2020-10-16 | 2021-01-12 | 中国科学技术大学先进技术研究院 | Composite silk and preparation method thereof |
| CN112519341A (en) * | 2020-11-19 | 2021-03-19 | 常熟市正太纺织有限公司 | Fiber fur material with waterproof function |
| CN116004114A (en) * | 2022-04-29 | 2023-04-25 | 重庆深盟新材料科技有限公司 | Light reflection heat-preservation weather-resistant coating and preparation method and application thereof |
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| CN107513293B (en) * | 2017-08-10 | 2019-12-27 | 广州市黑本新材料科技有限公司 | Preparation method of cesium tungsten bronze modified powder and slurry thereof |
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| CN110117911A (en) * | 2019-05-17 | 2019-08-13 | 宁波先锋新材料股份有限公司 | A kind of coating composite material and preparation method thereof |
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| CN110328932A (en) * | 2019-06-25 | 2019-10-15 | 杭州科能新材料科技有限公司 | A kind of insulation pack pack and its preparation method and application |
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| CN112210844A (en) * | 2020-10-16 | 2021-01-12 | 中国科学技术大学先进技术研究院 | Composite silk and preparation method thereof |
| CN112519341A (en) * | 2020-11-19 | 2021-03-19 | 常熟市正太纺织有限公司 | Fiber fur material with waterproof function |
| CN116004114A (en) * | 2022-04-29 | 2023-04-25 | 重庆深盟新材料科技有限公司 | Light reflection heat-preservation weather-resistant coating and preparation method and application thereof |
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| Publication number | Publication date |
|---|---|
| CN108360268B (en) | 2021-06-04 |
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