CN108342311A - A kind of chemical reaction equipment - Google Patents
A kind of chemical reaction equipment Download PDFInfo
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- CN108342311A CN108342311A CN201810361030.3A CN201810361030A CN108342311A CN 108342311 A CN108342311 A CN 108342311A CN 201810361030 A CN201810361030 A CN 201810361030A CN 108342311 A CN108342311 A CN 108342311A
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- Prior art keywords
- chamber
- chemical reaction
- biofermentation
- water
- end wall
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- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12M—APPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
- C12M41/00—Means for regulation, monitoring, measurement or control, e.g. flow regulation
- C12M41/12—Means for regulation, monitoring, measurement or control, e.g. flow regulation of temperature
- C12M41/18—Heat exchange systems, e.g. heat jackets or outer envelopes
- C12M41/22—Heat exchange systems, e.g. heat jackets or outer envelopes in contact with the bioreactor walls
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12M—APPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
- C12M21/00—Bioreactors or fermenters specially adapted for specific uses
- C12M21/04—Bioreactors or fermenters specially adapted for specific uses for producing gas, e.g. biogas
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
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- Organic Chemistry (AREA)
- Bioinformatics & Cheminformatics (AREA)
- Zoology (AREA)
- Genetics & Genomics (AREA)
- Microbiology (AREA)
- General Health & Medical Sciences (AREA)
- Sustainable Development (AREA)
- Biotechnology (AREA)
- Biomedical Technology (AREA)
- Biochemistry (AREA)
- General Engineering & Computer Science (AREA)
- Molecular Biology (AREA)
- Analytical Chemistry (AREA)
- Thermal Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Apparatus Associated With Microorganisms And Enzymes (AREA)
Abstract
The invention discloses a kind of chemical reaction equipments, including body, the internal body left upper end is provided with a biological fermentation tank, the biofermentation slot is internally provided with biofermentation chamber, it is installed with thermal detector in the upper end wall of the biofermentation chamber, the biofermentation slot outer wall horizontal homogeneous is installed with wound form temperature adjutage, lower end is provided with a water storage cavity on the left of the internal body, upper end is provided with a chemical reaction chamber on the right side of the internal body, the upper surface of the body is fixedly connected with a seal box, the seal box is internally provided with a seal chamber, a dismountable air storing cavity is provided on the left of the body upper surface.In present invention work, while ensureing that equipment safety uses, realize biofermentation reaction and chemical reaction, the chemical reaction for the carbon dioxide gas that fermentation generates has the function that oxygen processed, reduce the discharge of carbon dioxide, the recycling for ensureing the energy, is conducive to the sustainable development of resource, reduces environmental pollution.
Description
Technical field
The present invention relates to fermentation chemistries to react field, specially a kind of chemical reaction equipment.
Background technology
Fermentation is the biochemical chemical reaction that the mankind contact earliest, is nowadays applied in biological industry, biology, chemical industry
Extensively, the process of fermentation refers to that complicated organic compound resolves into fairly simple substance, such as wine under the action of microorganism
Or the fermentation of food, a small amount of alcohol and carbon dioxide are generated under the action of saccharomycete, many industry at present generate fermentation
Carbon dioxide is directly discharged in air, and Carbon Dioxide in Air content is caused to increase, and to pollute the environment, and is caused
A series of environmental problems.
Invention content
The purpose of the present invention is to provide a kind of chemical reaction equipments, to solve the problems mentioned in the above background technology.
To achieve the above object, the present invention provides the following technical solutions：A kind of chemical reaction equipment, including body, it is described
Internal body left upper end is provided with a biological fermentation tank, and the biofermentation slot is internally provided with biofermentation chamber, the biology
It is installed with thermal detector in the upper end wall of fermentation chamber, the upper end of the body left side is provided with a feed pipe, in the feed pipe
Portion is provided with a feed opening, the feed opening connection biofermentation slot and free surrounding space, equipped with one the on the feed pipe tube body
One sealing valve, internal body left side lower end are provided with a water storage cavity, and the left side below the body is provided with an outlet pipe,
The outlet pipe is internally provided with an apopore, the apopore connection water storage cavity and free surrounding space, on the outlet pipe tube body
Equipped with an outlet valve, the left end wall of the water storage cavity is fixedly connected with a cold water hydraulic pump, and one is provided in water storage cavity left end wall
The first water-supply-pipe upwardly extended, the first water hole is provided in first water-supply-pipe, and first water hole is connected to cold water
The right end wall of hydraulic pump, the water storage cavity is fixedly connected with hot water hydraulic pump, is provided in the right end wall of the water storage cavity upwards
The second water-supply-pipe extended, the second water hole is provided in second water-supply-pipe, and second water hole is connected to hot water hydraulic pressure
Pump, the biofermentation slot outer wall horizontal homogeneous are installed with wound form temperature adjutage, are arranged inside the temperature adjutage
There are a temperature adjustment hole, first water hole upper end to extend and be connected to the right the left end of temperature adjustment hole, second water delivery
Hole upper end extends and is connected to the right end of the temperature adjustment hole to the left, and upper end is provided with a chemical reaction on the right side of the internal body
Case is provided with chemical reaction chamber in the chemical reaction case, and the left end wall of the chemical reaction chamber is installed with air channel, described logical
The other end of air drain is connect with the biofermentation slot, and the first venthole, first venthole are provided in the air channel
It is connected to the biofermentation chamber and the chemical reaction chamber, the chemical reaction chamber lower end wall is installed with chemical reactor and contains
The upper surface of cabinet, the body is fixedly connected with a seal box, and the seal box is internally provided with a seal chamber, and the chemistry is anti-
It answers and is provided with second venthole upwardly extended on the upside of chamber left end wall, second venthole connection chemical reaction chamber and close
Chamber is sealed, the second sealing valve is installed on second venthole, the center position of the seal box upper surface is provided with one and adds
Indent, the pressurized tank communication seals chamber and free surrounding space, the pressurized tank are internally provided with guarantor's piezo electric valve, the seal chamber
It is internally provided with a sealed thin block, a dismountable air storing cavity is provided on the left of the body upper surface, the air storing cavity is right
The lower end of end face is provided with a connecting pipe, is provided with connecting hole in the connecting pipe, the connecting hole communication seals chamber and
Air storing cavity is provided with bearing assembly on the body lower face.
Preferably, the chemical reaction chamber lower end wall, which is installed with chemical reactor, contains cabinet, described contain in slot is placed
Sodium oxide molybdena solid, first venthole are arranged in the downside of the left end wall of the chemical reaction chamber.
Preferably, the thickness of the sealed thin block is more than the height of connecting pipe, voltage stabilizing is housed inside the seal chamber
The pressure value of gas, voltage stabilizing gas is less than the maximum pressure value that chemical reaction intracavitary part device can bear.
Preferably, the bearing assembly includes the carrying for four angular positions for being fixed at the body lower face
Upright bar, each carrying bottom of upright rod are fixedly installed non-slip mat.
Compared with prior art, the beneficial effects of the invention are as follows：By opening the first sealing valve, by feed pipe in biology
It is packed into biofermentation raw material and leavening in fermentation chamber, closes first sealing valve, the biofermentation intracavitary occurs at this time
Fermentation reaction, meanwhile, the temperature of biofermentation intracavitary described in the thermal detector real time reaction, when temperature is less than fermentation required temperature
When, the water in water storage cavity described in the hot water hydraulic pump heating enters the temperature adjutage by second water hole again
Interior, hot water is flowed into from second water hole in the water storage cavity again, in the process, completes the displacement of energy, will be described
The temperature of biofermentation intracavitary is improved to required temperature, if the temperature of the biofermentation intracavitary is higher than fermentation required temperature,
Cold water is reduced the temperature of the biofermentation intracavitary to suitable for temperature by the cold water hydraulic pump works by the temperature adjutage
Degree, at this point, the carbon dioxide that biofermentation intracavitary fermentation generates enters the chemical reaction by first venthole
Intracavitary is chemically reacted with sodium oxide molybdena solid, and reaction generates oxygen and sodium carbonate, when the chemical reaction production of chemical reaction intracavitary portion
When raw oxygen pressure value is larger, under the effect of the pressure, sealed thin block can move up, what the chemical reaction intracavitary generated
Oxygen can enter air storing cavity by connecting hole, while ensureing that equipment safety uses, realize the carbon dioxide that fermentation generates
The chemical reaction of gas has the function that oxygen processed, reduces the discharge of carbon dioxide, ensures the recycling of the energy, the water in water storage cavity
It can be discharged and be collected by outlet pipe, be conducive to the sustainable development of resource, reduce environmental pollution.
Description of the drawings
Fig. 1 is a kind of main structure diagram of chemical reaction equipment entirety complete section of the present invention；
Fig. 2 is A-A direction structure schematic diagrames in a kind of chemical reaction equipment of the present invention.
Specific implementation mode
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete
Site preparation describes, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.It is based on
Embodiment in the present invention, it is obtained by those of ordinary skill in the art without making creative efforts every other
Embodiment shall fall within the protection scope of the present invention.
It please refers to Fig.1 shown in -2, a kind of embodiment provided by the invention：A kind of chemical reaction equipment, including body 1, institute
It states 1 inside left upper end of body and is provided with a biological fermentation tank 2, the biofermentation slot 2 is internally provided with biofermentation chamber 3, institute
It states and is installed with thermal detector 22 in the upper end wall of biofermentation chamber 3, the upper end of 1 left side of the body is provided with a feed pipe 5, institute
It states feed pipe 5 and is internally provided with a feed opening 6, the feed opening 6 is connected to biofermentation slot 2 and free surrounding space, the feed pipe 5
One first sealing valve 7 is housed, 1 inside left lower end of the body is provided with a water storage cavity 8, below the body 1 on tube body
Left side is provided with an outlet pipe 9, and the outlet pipe 9 is internally provided with an apopore 10, and the apopore 10 is connected to 8 He of water storage cavity
Free surrounding space, an outlet valve 11 is equipped on 9 tube body of the outlet pipe, and the left end wall of the water storage cavity 8 is fixedly connected with a cold water
Hydraulic pump 12, is provided with first water-supply-pipe 14 upwardly extended in 8 left end wall of water storage cavity, setting in first water-supply-pipe 14
There are the first water hole 13, first water hole 13 to be connected to cold water hydraulic pump 12, the right end wall of the water storage cavity 8 is fixedly connected with
Hot water hydraulic pump 16 is provided with the second water-supply-pipe 17 upwardly extended, second water-supply-pipe in the right end wall of the water storage cavity 8
The second water hole 18 is provided in 17, second water hole 18 is connected to hot water hydraulic pump 16,2 outer wall water of the biofermentation slot
Flat to be uniformly installed with wound form temperature adjutage 4, the temperature adjutage 14 is internally provided with a temperature adjustment hole 15, described
First water hole, 13 upper end extends and is connected to the right the left end of temperature adjustment hole 15, and 18 upper end of the second water hole extends to the left
And it is connected to the right end of the temperature adjustment hole 15,1 inner right side upper end of the body is provided with a chemical reaction case 33, describedization
It learns and is provided with chemical reaction chamber 19 in reaction chamber 33, the left end wall of the chemical reaction chamber 19 is installed with air channel 20, described logical
The other end of air drain 20 is connect with the biofermentation slot 2, is provided with the first venthole 21 in the air channel 20, and described
One venthole 21 is connected to the biofermentation chamber 3 and the chemical reaction chamber 19, and 19 lower end wall of chemical reaction chamber is installed with
Chemical reactor contains cabinet 31, and the upper surface of the body 1 is fixedly connected with a seal box 36,36 inside setting of the seal box
There is a seal chamber 37, second venthole 38 upwardly extended is provided on the upside of the chemical reaction 19 left end wall of chamber, it is described
The connection of second venthole 38 chemically reacts chamber 19 and seal chamber 37, and the second sealing valve 30 is installed on second venthole 38,
The center position of 36 upper surface of the seal box is provided with a pressurized tank 39,39 communication seals chamber 37 of the pressurized tank and the external world
Space, the pressurized tank 39 are internally provided with guarantor's piezo electric valve 40, and the seal chamber 37 is internally provided with a sealed thin block 41, institute
It states and is provided with a dismountable air storing cavity 42 on the left of 1 upper surface of body, the lower end of 42 right side of the air storing cavity is provided with one
Connecting pipe 43 is provided with connecting hole 23,23 communication seals chamber 37 of the connecting hole and air storing cavity 42 in the connecting pipe 43,
The body is provided with bearing assembly on 1 lower face.
Valuably, 19 lower end wall of chemical reaction chamber is installed with chemical reactor and contains cabinet 31, described to contain in slot 31
Sodium oxide molybdena solid is placed, first venthole 21 is arranged in the downside of the left end wall of the chemical reaction chamber 19, due to fermentation
Original atmospheric density is big in chemical reaction case 33 described in the carbon dioxide gas density ratio of generation, ensure that carbon dioxide gas
With fully reacting for sodium oxide molybdena, the efficiency for chemically reacting oxygen processed is improved.
Valuably, the thickness of the sealed thin block 41 is more than the height of connecting pipe 43, and 37 inside of the seal chamber is equipped with
The pressure value of voltage stabilizing gas, voltage stabilizing gas is less than the maximum pressure value that chemical reaction 19 interior arrangement of chamber can bear.It is acted on
It is, when the oxygen pressure value for chemically reacting the reaction generation of 19 internal chemical of chamber is larger, under the effect of the pressure, sealed thin block 41
It can move up, the oxygen generated in the chemical reaction chamber 19 can enter air storing cavity 42 by connecting hole 23, ensure device
While safe handling, the chemical reaction for realizing the carbon dioxide gas that fermentation generates has the function that oxygen processed, reduces dioxy
The discharge for changing carbon, ensures the recycling of the energy.
Valuably, the bearing assembly includes the carrying for four angular positions for being fixed at 1 lower face of the body
Upright bar 101, each 101 bottom of carrying upright bar are fixedly installed non-slip mat 102, and four carrying upright bars 101 are propping up
The body 1 is supportted, the non-slip mat 102 is to prevent the carrying upright bar 101 from skidding, to increase the stabilization of the present apparatus
Property.
Specifically used mode：In present invention work, the first sealing valve 7 is opened, by feed pipe 5 in biofermentation chamber 2
It is packed into biofermentation raw material and leavening, closes first sealing valve, it is anti-that fermentation occurs in the biofermentation chamber 3 at this time
It answers, meanwhile, the temperature in biofermentation chamber 3 described in 22 real time reaction of the thermal detector, when temperature is less than fermentation required temperature,
The hot water hydraulic pump 16 heats the water in the water storage cavity 8 and enters the temperature adjutage by second water hole 28 again
In 4, hot water is flowed into from second water hole 13 in the water storage cavity 8 again, in the process, completes the displacement of energy, will
Temperature in the biofermentation chamber 3 is improved to required temperature, if the temperature in the biofermentation chamber 3 is higher than temperature needed for fermentation
When spending, the cold water hydraulic pump 12 works, and cold water is reduced by the temperature adjutage 4 to the temperature in the biofermentation chamber 3
Degree is to preference temperature, at this point, the carbon dioxide that fermentation generates in the biofermentation chamber 3 is entered by first venthole 21
It is chemically reacted with sodium oxide molybdena solid in the chemical reaction chamber 19, reaction generates oxygen and sodium carbonate, when chemical reaction chamber
When the oxygen pressure value that the reaction of 19 internal chemicals generates is larger, under the effect of the pressure, sealed thin block 41 can move up, described
Air storing cavity 42 can be entered by connecting hole 23 by chemically reacting the oxygen generated in chamber 19, while ensureing that equipment safety uses,
The chemical reaction for realizing the carbon dioxide gas that fermentation generates has the function that oxygen processed, reduces the discharge of carbon dioxide, ensures
The recycling of the energy, the water in water storage cavity 8 can be discharged by outlet pipe 9 to be collected, and is conducive to the sustainable development of resource, is reduced
Environmental pollution.
It is obvious to a person skilled in the art that invention is not limited to the details of the above exemplary embodiments, Er Qie
In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter
From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power
Profit requires rather than above description limits, it is intended that all by what is fallen within the meaning and scope of the equivalent requirements of the claims
Variation is included within the present invention.Any reference signs in the claims should not be construed as limiting the involved claims.
Claims (4)
1. a kind of chemical reaction equipment, including body, it is characterised in that：The internal body left upper end is provided with a biofermentation
Slot, the biofermentation slot are internally provided with biofermentation chamber, are installed with thermal detector in the upper end wall of the biofermentation chamber, institute
The upper end for stating body left side is provided with a feed pipe, and the feed pipe is internally provided with a feed opening, the feed opening connection
Biofermentation slot and free surrounding space are equipped with one first sealing valve on the feed pipe tube body, and lower end is set on the left of the internal body
It is equipped with a water storage cavity, the left side below the body is provided with an outlet pipe, and the outlet pipe is internally provided with an apopore, institute
Apopore connection water storage cavity and free surrounding space are stated, an outlet valve, the left end wall of the water storage cavity are housed on the outlet pipe tube body
It is fixedly connected with a cold water hydraulic pump, first water-supply-pipe upwardly extended is provided in water storage cavity left end wall, described first is defeated
The first water hole is provided in water pipe, first water hole is connected to cold water hydraulic pump, and the right end wall of the water storage cavity, which is fixed, to be connected
It is connected to hot water hydraulic pump, the second water-supply-pipe upwardly extended, second water-supply-pipe are provided in the right end wall of the water storage cavity
It is inside provided with the second water hole, second water hole is connected to hot water hydraulic pump, the biofermentation slot outer wall horizontal homogeneous
It is installed with wound form temperature adjutage, the temperature adjutage is internally provided with a temperature adjustment hole, on first water hole
End extends and is connected to the right the left end of temperature adjustment hole, and second water hole upper end extends and is connected to the temperature to the left to be adjusted
The right end in hole, internal body right side upper end are provided with a chemical reaction case, are provided in the chemical reaction case chemical anti-
Chamber, the left end wall of the chemical reaction chamber is answered to be installed with air channel, the other end of the air channel connects with the biofermentation slot
It connects, the first venthole is provided in the air channel, first venthole is connected to the biofermentation chamber and the chemistry is anti-
Chamber, the chemical reaction chamber lower end wall is answered to be installed with chemical reactor and contain cabinet, the upper surface of the body is fixedly connected with one
Seal box, the seal box are internally provided with a seal chamber, and be provided with one on the upside of the chemical reaction chamber left end wall prolongs upwards
The second venthole stretched, second venthole connection chemical reaction chamber and seal chamber are installed with the on second venthole
Two sealing valves, the center position of the seal box upper surface are provided with a pressurized tank, the pressurized tank communication seals chamber and outer
Boundary space, the pressurized tank are internally provided with guarantor's piezo electric valve, and the seal chamber is internally provided with a sealed thin block, the body
A dismountable air storing cavity is provided on the left of upper surface, the lower end of the air storing cavity right side is provided with a connecting pipe, institute
It states and is provided with connecting hole in connecting pipe, the connecting hole communication seals chamber and air storing cavity are provided on the body lower face
Bearing assembly.
2. a kind of chemical reaction equipment according to claim 1, it is characterised in that：The chemical reaction chamber lower end wall is fixed
There is chemical reactor to contain cabinet, described contain places sodium oxide molybdena solid in slot, the first venthole setting is anti-in the chemistry
Answer the downside of the left end wall of chamber.
3. a kind of chemical reaction equipment according to claim 1, it is characterised in that：The thickness of the sealed thin block, which is more than, to be connected
The height in take over road, the seal chamber inside are equipped with voltage stabilizing gas, and the pressure value of voltage stabilizing gas is less than chemical reaction intracavitary portion dress
Set the maximum pressure value that can bear.
4. a kind of chemical reaction equipment according to claim 1, it is characterised in that：The bearing assembly includes fixed setting
In the carrying upright bar of four angular positions of the body lower face, each carrying bottom of upright rod is fixedly installed anti-skidding
Pad.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810361030.3A CN108342311A (en) | 2018-04-20 | 2018-04-20 | A kind of chemical reaction equipment |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810361030.3A CN108342311A (en) | 2018-04-20 | 2018-04-20 | A kind of chemical reaction equipment |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108342311A true CN108342311A (en) | 2018-07-31 |
Family
ID=62955707
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810361030.3A Pending CN108342311A (en) | 2018-04-20 | 2018-04-20 | A kind of chemical reaction equipment |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108342311A (en) |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5737400B2 (en) * | 1979-08-08 | 1982-08-09 | ||
| JP5190320B2 (en) * | 2008-09-30 | 2013-04-24 | 株式会社神鋼環境ソリューション | Methane gas recovery method and energy conversion system |
| CN105202368A (en) * | 2015-11-02 | 2015-12-30 | 沈阳航天新光集团有限公司 | Supply buffering system |
| CN205473801U (en) * | 2016-01-26 | 2016-08-17 | 江苏农林职业技术学院 | Automatic accuse temperature biogas fermentation device |
| CN205576116U (en) * | 2016-04-28 | 2016-09-14 | 瑞安市善德生物科技有限公司 | Take carbon dioxide processing apparatus's fermentation cylinder |
| CN107789974A (en) * | 2017-12-20 | 2018-03-13 | 南京菱亚汽车技术研究院 | A kind of industrial production carbonaceous gas purifying processing device |
-
2018
- 2018-04-20 CN CN201810361030.3A patent/CN108342311A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5737400B2 (en) * | 1979-08-08 | 1982-08-09 | ||
| JP5190320B2 (en) * | 2008-09-30 | 2013-04-24 | 株式会社神鋼環境ソリューション | Methane gas recovery method and energy conversion system |
| CN105202368A (en) * | 2015-11-02 | 2015-12-30 | 沈阳航天新光集团有限公司 | Supply buffering system |
| CN205473801U (en) * | 2016-01-26 | 2016-08-17 | 江苏农林职业技术学院 | Automatic accuse temperature biogas fermentation device |
| CN205576116U (en) * | 2016-04-28 | 2016-09-14 | 瑞安市善德生物科技有限公司 | Take carbon dioxide processing apparatus's fermentation cylinder |
| CN107789974A (en) * | 2017-12-20 | 2018-03-13 | 南京菱亚汽车技术研究院 | A kind of industrial production carbonaceous gas purifying processing device |
Non-Patent Citations (1)
| Title |
|---|
| 陆培文等: "《阀门选用手册》", 31 May 2001, 机械工业出版社 * |
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Application publication date: 20180731 |
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| RJ01 | Rejection of invention patent application after publication |