CN108308190A - The bactericidal composition and application thereof of pyraclostrobin-containing and quinolinone - Google Patents
The bactericidal composition and application thereof of pyraclostrobin-containing and quinolinone Download PDFInfo
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- CN108308190A CN108308190A CN201711415911.0A CN201711415911A CN108308190A CN 108308190 A CN108308190 A CN 108308190A CN 201711415911 A CN201711415911 A CN 201711415911A CN 108308190 A CN108308190 A CN 108308190A
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- Prior art keywords
- pyraclostrobin
- quinolinone
- bactericidal composition
- garpe
- downy mildew
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/24—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing the groups, or; Thio analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
- A01N43/42—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings condensed with carbocyclic rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/16—Heavy metals; Compounds thereof
- A01N59/20—Copper
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to the bactericidal composition of pyraclostrobin and quinolinone, the quality parts ratio of pyraclostrobin and quinolinone is 1~20:30~1.The bactericidal composition of the present invention is suitable for prevention downy mildew of garpe.Pyraclostrobin and quinolinone mixture have apparent synergistic effect, reduce Pesticide use amount, and promoting and applying has larger economic benefit and social benefit.
Description
Technical field
The present invention relates to pesticide field more particularly to the bactericidal compositions and application thereof of pyraclostrobin-containing and quinolinone.
Background technology
Pyraclostrobin (pyraclostrobin) is new-type wide-spectrum bactericide.The mechanism of action：Inhibit for mitochondrial respiratory
Agent in being synthesized in cytochromes i.e. by preventing electronics transfer.Conduction is permeated with protection, treatment, blade.Pyrazoles ether bacterium
Emulsifiable concentrate shows have to powdery mildew of cucumber, downy mildew and banana freckle, leaf spot, sclerotiniose etc. through field control effectiveness test result
Preferable control effect.
Copper 8-hydroxyquinolinate (oxine-copper) is a kind of quinolines low toxicity protective fungicide, belongs to organic copper chelate, wide spectrum,
Efficiently, low-residual, it is safe to use, good preventive and therapeutic action is all had to fungoid, bacterial disease.It is being planted after spraying
Object surface forms one layer of strict protection medicine film, and the copper ion of slow release inhibits germ to sprout and invade, to reach diseases prevention
The purpose cured the disease；Copper 8-hydroxyquinolinate is mainly used in the plants such as tomato, capsicum, cucumber, cucurbita pepo, potato and grape, to late blight,
Epidemic disease, phytophthora rot, downy mildew etc. have good control effect；It can also be used for wheat seed dressing prevention smut.
For many years a large amount of uses of single dose and conventional complex preparation, cause such drug resistance increased, due to agriculture
Expense improves during the promoting the use of of medicine new product, and farmer's production cost is consequently increased, and it is potential how to develop old product
Value, is allowed to continue to play a greater role, and is a project for being worth research,
Downy mildew of garpe is a kind of Common Diseases during wine-growing, and the harm phase is long, it is fast to propagate, and serious period often makes
At the grape significantly underproduction, quality and economic benefit are seriously affected, developing its related prevention product has the great market space.
Invention content
The object of the present invention is to provide the bactericidal composition of a kind of pyraclostrobin-containing and quinolinone, the bactericidal composition with
Pyraclostrobin and quinolinone are active ingredient, and the different pyraclostrobin of the mechanism of action and quinolinone are compounded, had
Synergistic effect, efficient, low toxicity, low-residual.
In bactericidal composition of the present invention, the quality parts ratio of pyraclostrobin and quinolinone is 1~20:30~1.
In the bactericidal composition of the present invention, can be added in pesticide allow using and acceptable auxiliary element, be made each
Kind dosage form, e.g., water dispersible granules and suspending agent.
The auxiliary agent used in bactericidal composition of the present invention includes surfactant, dispersant, filler etc. and other are beneficial to
The known substance of drug effect is stablized and played to active ingredient in the formulation, be all commonly use in pesticidal preparations or allow to use it is various at
Point, it is not particularly limited, specific ingredient and dosage are according to recipe requirements by simply testing determination.
The dispersant is naphthalene sulfonate, lignosulfonates, polycarboxylate, cyclohexanone formaldehyde condensation products, benzene sulfonamide
Hydrochlorate, alkyl phenol polyoxyethylene ether, fatty alcohol polyoxyethylene ether, castor oil polyoxyethylene ether, fatty alcohol polyoxyethylene ether formaldehyde
It is one or more in condensation polymer sulfate.
The surfactant is selected from calcium dodecyl benzene sulfonate and aliphatic acid polyethenoxy ether, alkylphenol-polyethenoxy
Ether sulfosuccinates, styrylphenol polyoxyethylene ether, nonylphenol polyoxyethylene ether, castor oil polyoxyethylene ether, fat
Any one of sour polyoxyethylene base ester, polyoxyethylene aliphatic alcohol ether or more than one mixtures formed with arbitrary proportion.
The filler is white carbon, urea, sodium sulphate, ammonium sulfate, kaolin, precipitated calcium carbonate, bentonite, in diatomite
It is one or more.
The active ingredient is 2~50% by the quality accounting of pyraclostrobin and quinolinone.
Above-mentioned bactericidal composition is in prevention downy mildew of garpe and prepares on prevention downy mildew of garpe pesticide with significant
Cooperative synergism effect.
Product described in the invention can be provided in the form of finished product preparation, i.e., each substance has mixed in composition, group
Close object ingredient can also single dose form provide, directly mixed, be then diluted to required dense in tank or bucket using preceding
Degree.The frequency of administration of the present composition and amount of application change with weather condition and crop condition and are changed, can be by using
Dosage form appropriate achievees the purpose that prevention.
The beneficial effects of the present invention are：1, two kinds of active ingredient compoundings have apparent synergistic effect, improve prevention
Effect；2, two kinds of active ingredient compoundings, mechanism of action uniqueness are not present cross resistance, Pesticide use amount are reduced, to reduce
Cost and reduce the pollution to environment, is conducive to the resistance management of disease, promoting and applying has larger economic benefit
And social benefit.
Specific implementation mode
Present disclosure is described in further detail with reference to embodiment, the content mentioned in embodiment is not to this
The restriction of invention, material prescription selection can adaptation to local conditions and to result without substantive influence.In these embodiments, except as otherwise
Outside illustrating, all percentages are weight percentage.
Embodiment 1：Pyraclostrobin is compounded with copper 8-hydroxyquinolinate different proportion to downy mildew of garpe Toxicity Determination
Test method：Test method refers to《People's Republic of China (PRC) agricultural industry mark NY/T1156.2-2006》.First will
Single dose and each Mixed Pharmacy are arranged 5 various concentration gradients and (on the basis of pilot study result, combine and match according to different agents
Than difference, concentration gradient setting is also different, and bacteriostasis rate is set in the range of 5%-90% by geometric progression).If clear water
Control group, in triplicate.Using mycelial growth rate method, by cultured pathogen, diameter 5mm punchings are aseptically used
Device cuts bacteria cake from colony edge, and bacteria cake is connected to the culture medium flat plate center of different agents concentration with transfer needle, and mycelia faces
On, ware lid is covered, is placed in the baking oven of preference temperature and cultivates；It is single with calliper colony diameter when control group bacterium colony covers with
Position is millimeter (mm).Each bacterium colony diameter is measured perpendicularly using the crisscross method, takes its average value.According to measurement result meter
The mycelial growth inhibition rate for calculating each chemicals treatment, according to each drug concentration logarithm and corresponding mycelial growth inhibition rate niqueMin
Regression analysis is done, the EC of each medicament is found out50, the toxicity index grade co-toxicity coefficient (CTC) of medicament is calculated according to Sun Yunpei's Method.
Survey toxicity index (ATI)=(standard agent EC50/ for reagent effect EC50)×100
The toxicity index of the percentage composition+B medicaments of A in toxicity index × mixture of theoretical virulence coefficient (TTI)=A medicaments
The percentage composition of B in × mixture.
Co-toxicity coefficient (CTC)=[mixture surveys toxicity index (ATI)/mixtures theoretical toxicity index (TTI)] × 100.
Work as CTC<When 80, composition shows as antagonism；When 80<CTC<When 120, composition shows as summation action；
Work as CTC>When 120, composition shows as synergistic effect.
1 pyraclostrobin of table is compounded with copper 8-hydroxyquinolinate different proportion to downy mildew of garpe Toxicity Determination
| Reagent agent | Proportioning | EC50It is worth (mg/L) | CTC |
| Pyraclostrobin (A) | 3.08 | ||
| Copper 8-hydroxyquinolinate (B) | 2.33 | ||
| A:B | 20:1 | 2.83 | 125.8 |
| A:B | 16:1 | 2.59 | 132.5 |
| A:B | 12:1 | 2.41 | 145.3 |
| A:B | 8:1 | 2.05 | 158.4 |
| A:B | 4:1 | 1.58 | 176.2 |
| A:B | 1:3 | 1.42 | 185.9 |
| A:B | 1:6 | 1.47 | 174.5 |
| A:B | 1:12 | 2.13 | 169.3 |
| A:B | 1:18 | 2.46 | 158.5 |
| A:B | 1:24 | 2.87 | 151.1 |
| A:B | 1:30 | 7.96 | 139.7 |
As shown in Table 1, pyraclostrobin, copper 8-hydroxyquinolinate are to the EC of downy mildew of garpe50Respectively 3.08mg/L and 2.33mg/L
The toxicity index of pyraclostrobin is higher than the toxicity index of copper 8-hydroxyquinolinate, and pyraclostrobin is with copper 8-hydroxyquinolinate mixed ratio 1~20:30
When~1, co-toxicity coefficient (CTC) is all higher than 120, shows good synergistic effect, wherein when the two presses 1:It is right after 3 ratios compounding
The synergistic effect of downy mildew of garpe is especially pronounced.
Embodiment 2：The field control effectiveness test to downy mildew of garpe such as 20% pyrrole quinoline suspending agent, water dispersible granules
Pyraclostrobin 5%, quinolinone 15%, lauryl sodium sulfate (surfactant) 2%, white carbon (filler)
4%, sodium lignin sulfonate (dispersant) 5%, bentonite (filler) complements to 100%.By above-mentioned formula in proportion dry pulverization process,
It is granulated, is dry, screening obtains 20% pyraclostrobin quinolinone water dispersible granules.
Pyraclostrobin 5%, the quinolinone 15%, (surfaces methyl naphthalene sulfonate formaldehyde condensate (dispersant) 5%, 0203B
Activating agent) 6%, white carbon (filler) 5%, aluminium-magnesium silicate (suspending agent) 0.4%, ethylene glycol (antifreezing agent) 3%, tricresyl phosphate fourth
Ester (antifoaming agent) 1.5%, deionized water complements to 100%.Above-mentioned formula is crushed in advance in proportion, adds sand mill
Middle grinding is allocated after high shear mixing and 20% pyraclostrobin quinolinone suspending agent is made.
Pyraclostrobin 5%, quinolinone 15%, neopelex 3%, isopropyl naphthalene sulfonate 5%, white carbon
4%, anhydrous sodium sulphate 15%, kaolin supplies 100%.Material is weighed by above-mentioned mass percent, by pyraclostrobin, quinolinone,
Alkylnaphthalene sulfonate formaldehyde condensation products, isopropyl naphthalene sulfonate, white carbon, anhydrous sodium sulphate, kaolin put into mixing and blending machine stirring
Uniformly, up to 20% pyraclostrobin quinolinone wettable powder below air-flow crushing to 800 mesh.
Pyraclostrobin 5%, quinolinone 15%, methyl oleate 20%, succinate 5%, sulfonation of fatty alcohol object 8%, second
Glycol 5%, aluminium-magnesium silicate 0.9%, xanthans 0.23%, organic silicon defoamer 0.5%, water supplies 100%.By above-mentioned quality hundred
That divides ratio weighs material, first thoroughly dissolves pyraclostrobin with methyl oleate, is sufficiently mixed with sulfonate and oil phase uniformly is made
A, then by water, sulfonation of fatty alcohol object, ethylene glycol, aluminium-magnesium silicate, xanthans, antifoaming agent is uniformly mixed, is then added while stirring
Quinolinone, is made B mixtures, and A is mixed with B.Above-mentioned material is mixed into shearing 30 minutes, material is made to be uniformly mixed.In sand mill
In be ground to grain size D90 less than 5 microns to get 20% pyraclostrobin quinolinone suspension emulsion.
Pyraclostrobin 5%, quinolinone 15%, succinate emulsifier 5%, sulfonic acid dipersant 10%, organic swelling
Soil 2%, soybean oil supplies 100%.Material is weighed by above-mentioned mass percent, by succinate emulsifier, sulfonic acid dipersant,
Soybean oil stirring is uniformly mixed and obtains oil phase, pyraclostrobin is added, quinolinone and organobentonite carry out high speed shear 30 and divide
Clock makes material be uniformly mixed.Grain size D90 is ground in sand mill less than 5 microns to get to 20% pyraclostrobin quinoline
The dispersible oil-suspending agent of ketone.
The field control effectiveness test to downy mildew of garpe such as 2 20% pyrrole quinoline suspending agent of table, water dispersible granules
Pyraclostrobin and quinolinone complex preparation can effectively prevent downy mildew of garpe as can be seen from Table 2, compare three groups
Comparison medicament, complex preparation preventive effect is higher, illustrates that making dispersible granule and suspending agent after two kinds of active ingredients compounding has well
Synergistic effect.
Embodiment 3：Field control effectiveness test of the 20% pyraclostrobin quinolinone water dispersible granules to downy mildew of garpe
Test site：Experiment is located at Ningxia grape growing region, and soil property is sandy loam, and fertility is better-than-average, and management level is preferable.
Controlling object：Downy mildew of garpe
Processing setting and dispenser set 4 processing altogether, wherein 3 chemicals treatments, 1 clear water control treatment, reagent agent is such as
Under：Water dispersible granules prepared by embodiment 2,30% quinoline copper water dispersion granula, 20% pyraclostrobin water dispersible granule.Everywhere
4 repetitions are managed, totally 16 cells, per plot area 15m2, 10 vines are planted per cell, the random district's groups arrangement of cell removes
Outside chemicals treatment factor, other management measures are consistent.
The downy mildew of garpe state of an illness is investigated before medicine respectively, in state of an illness first time at initial stage medication, every dispenser in seven days is primary, dispenser altogether
Three times.
Field investigation and calculating：7d, 14d, 21d distinguish investigation prevention effect after last dispenser, are randomly selected per cell
10 new branches, investigate whole blades and the sick number of sheets on each branch, and morbidity severity point is carried out to sick leaf by 0~4 grade of standard
Grade is recorded, and disease index and control effect are calculated.
Seriousness gradation standard：
It is 0 grade, disease-free；
1 grade：Scab accounts for 1/4 or less whole leaf area；
2 grades：Spot accounts for the 1/4~1/2 of whole leaf area；
3 grades：Spot accounts for the 1/2~3/4 of whole leaf area；
4 grades：Spot accounts for 3/4 or more of whole leaf area.
Calculation formula：
Disease index before disease index growth rate (%)=(disease index before disease index-dispenser after dispenser)/dispenser ×
100%
Relative control effect (%)=(check plot disease index growth rate-treatment region disease index growth rate)/check plot state of an illness
Exponential growth rate × 100%
Experimental result is as follows：
Field control effectiveness test of the 3 20% pyraclostrobin quinolinone water dispersible granules of table to downy mildew of garpe
Experiments have shown that 20% pyraclostrobin quinolinone water dispersible granules have good control effect to downy mildew of garpe,
Better than corresponding single dose, and dosage reduces.
Embodiment 4：Field control effectiveness test of the 20% pyraclostrobin quinolinone suspending agent to downy mildew of garpe
Test site：Experiment is located at Ningxia grape growing region, and soil property is sandy loam, and fertility is better-than-average, and management level is preferable.
Controlling object：Downy mildew of garpe
Processing setting and dispenser set 4 processing altogether, wherein 3 chemicals treatments, 1 clear water control treatment, reagent agent is such as
Under：Suspending agent prepared by embodiment 2,30% quinoline copper water dispersion granula, 20% pyraclostrobin water dispersible granule.Each processing 4
Secondary repetition, totally 16 cells, per plot area 15m2, 10 vines are planted per cell, the random district's groups arrangement of cell removes medicament
Outside processing factor, other management measures are consistent.
The downy mildew of garpe state of an illness is investigated before medicine respectively, in state of an illness first time at initial stage medication, every dispenser in seven days is primary, dispenser altogether
Three times.
Field investigation and calculating：7d, 14d, 21d distinguish investigation prevention effect after last dispenser, are randomly selected per cell
10 new branches, investigate whole blades and the sick number of sheets on each branch, and morbidity severity point is carried out to sick leaf by 0~4 grade of standard
Grade is recorded, and disease index and control effect are calculated.
Seriousness gradation standard：
It is 0 grade, disease-free；
1 grade：Scab accounts for 1/4 or less whole leaf area；
2 grades：Spot accounts for the 1/4~1/2 of whole leaf area；
3 grades：Spot accounts for the 1/2~3/4 of whole leaf area；
4 grades：Spot accounts for 3/4 or more of whole leaf area.
Calculation formula：
Disease index before disease index growth rate (%)=(disease index before disease index-dispenser after dispenser)/dispenser ×
100%
Relative control effect (%)=(check plot disease index growth rate-treatment region disease index growth rate)/check plot state of an illness
Exponential growth rate × 100%
Experimental result is as follows：
Field control effectiveness test of the 4 20% pyraclostrobin quinolinone suspending agent of table to downy mildew of garpe
Experiments have shown that 20% pyraclostrobin quinolinone suspending agent has good control effect to downy mildew of garpe, it is better than
Corresponding single dose, and dosage reduces.
Claims (4)
1. the bactericidal composition of a kind of pyraclostrobin-containing and quinolinone, it is characterised in that：Active ingredient by pyraclostrobin and
Quinolinone forms, and the quality parts ratio of pyraclostrobin and quinolinone is 1~20:30~1.
2. the bactericidal composition of pyraclostrobin according to claim 1 and quinolinone, it is characterised in that when practical application
Water dispersible granules and suspending agent are made.
3. the bactericidal composition of pyraclostrobin according to claim 1 and quinolinone, it is characterised in that it is described effectively at
It is 2~50% to divide by the quality accounting of pyraclostrobin and quinolinone.
4. the bactericidal composition of pyraclostrobin according to claim 1,2 or 3 and quinolinone is in prevention downy mildew of garpe
And prepare the purposes prevented on downy mildew of garpe pesticide.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711415911.0A CN108308190A (en) | 2017-12-25 | 2017-12-25 | The bactericidal composition and application thereof of pyraclostrobin-containing and quinolinone |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711415911.0A CN108308190A (en) | 2017-12-25 | 2017-12-25 | The bactericidal composition and application thereof of pyraclostrobin-containing and quinolinone |
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| CN108308190A true CN108308190A (en) | 2018-07-24 |
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| CN201711415911.0A Withdrawn CN108308190A (en) | 2017-12-25 | 2017-12-25 | The bactericidal composition and application thereof of pyraclostrobin-containing and quinolinone |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111226923A (en) * | 2020-03-09 | 2020-06-05 | 上海生农生化制品股份有限公司 | Pyraclostrobin-oxine-copper microcapsule suspension-suspending agent and preparation method thereof |
| CN112841210A (en) * | 2021-01-15 | 2021-05-28 | 上海生农生化制品股份有限公司 | Dispersing wetting agent composition |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101785464A (en) * | 2010-03-25 | 2010-07-28 | 青岛瀚生生物科技股份有限公司 | Oxine-copper composite bactericide |
| CN107006505A (en) * | 2017-04-19 | 2017-08-04 | 兴农药业（中国）有限公司 | A kind of composition pesticide of copper 8-hydroxyquinolinate and pyraclostrobin |
-
2017
- 2017-12-25 CN CN201711415911.0A patent/CN108308190A/en not_active Withdrawn
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101785464A (en) * | 2010-03-25 | 2010-07-28 | 青岛瀚生生物科技股份有限公司 | Oxine-copper composite bactericide |
| CN107006505A (en) * | 2017-04-19 | 2017-08-04 | 兴农药业（中国）有限公司 | A kind of composition pesticide of copper 8-hydroxyquinolinate and pyraclostrobin |
Non-Patent Citations (3)
| Title |
|---|
| 李长松等: "吡唑醚菌酯等对番茄灰叶斑病菌的抑菌活性与防治试验", 《山东农业科学》 * |
| 杨平华主编: "《农田常用杀菌剂使用技术》", 31 January 2009, 四川科学技术出版社 * |
| 马安民等主编: "《园林植物杀菌剂应用技术》", 31 October 2016, 河南科学技术出版社 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111226923A (en) * | 2020-03-09 | 2020-06-05 | 上海生农生化制品股份有限公司 | Pyraclostrobin-oxine-copper microcapsule suspension-suspending agent and preparation method thereof |
| CN111226923B (en) * | 2020-03-09 | 2022-04-22 | 上海生农生化制品股份有限公司 | Pyraclostrobin-oxine-copper microcapsule suspension-suspending agent and preparation method thereof |
| CN112841210A (en) * | 2021-01-15 | 2021-05-28 | 上海生农生化制品股份有限公司 | Dispersing wetting agent composition |
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Application publication date: 20180724 |