CN108301070A - A kind of preparation method of double-layer nested nanofiber - Google Patents
A kind of preparation method of double-layer nested nanofiber Download PDFInfo
- Publication number
- CN108301070A CN108301070A CN201810284958.6A CN201810284958A CN108301070A CN 108301070 A CN108301070 A CN 108301070A CN 201810284958 A CN201810284958 A CN 201810284958A CN 108301070 A CN108301070 A CN 108301070A
- Authority
- CN
- China
- Prior art keywords
- nanofiber
- preparation
- ammonium
- fiber
- molecular weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
- D01F9/08—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/0007—Electro-spinning
- D01D5/0015—Electro-spinning characterised by the initial state of the material
- D01D5/003—Electro-spinning characterised by the initial state of the material the material being a polymer solution or dispersion
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/10—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one other macromolecular compound obtained by reactions only involving carbon-to-carbon unsaturated bonds as constituent
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Nanotechnology (AREA)
- General Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Composite Materials (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Physics & Mathematics (AREA)
- Manufacturing & Machinery (AREA)
- Dispersion Chemistry (AREA)
- Mechanical Engineering (AREA)
- Artificial Filaments (AREA)
- Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
Abstract
A kind of preparation method of double-layer nested nanofiber, it is characterised in that:The fiber has inside and outside two layers, is configured to uniform precursor sol liquid by the polymer and metal salt of different molecular weight, high-voltage electrostatic spinning obtains nanofiber.
Description
The application is a kind of entitled double-layer nested nanofiber and its preparation application No. is 2016106289118
Method, the divisional application for the application for a patent for invention that the applying date is 20160803.
Technical field
The invention belongs to technical field of nanometer material preparation.
Background technology
With the reach of science, great research finds that the structure of microcosmic multistage can make material possess many excellent property
Matter.Due to the development of modern synthetic technology and analysis test, microcosmic nano material also undergoes this and is drilled from simple to complicated structure
Become.In turn, many science greatly be have stimulated in the third generation micrometer/nanometer material for possessing more complicated interior structure in recent years
The research interest of family, because these structures possess more excellent performance.In addition, one-dimensional nano structure, because of its unique property
Cause the broad interest of researcher, and achieves very excellent chemical property.Electrostatic spinning has in all preparation methods
It has a clear superiority.Electrostatic spinning is simple with its manufacturing device, cost of spinning is cheap, it is various to spin substance classes, technique is controllable etc.
Advantage, it has also become effectively prepare one of main path of nano-fiber material.It is abundant that electrostatic spinning technique has been prepared for type
Nanofiber, including organic, organic/inorganic is compound and inorganic nano-fiber.For example, Xiang et al. is also with the technology
CuO doughnuts have been synthesized, and have further obtained porous hollow Cu fibers by hydrogen reduction process on this basis
(CrystEngComm, 2011, 13(15): 4856-4860).In addition, beading chain nanofiber, loose porous Nanowire
Dimension and tasselled shape nanofiber also have been reported.It is needed however, preparing nanofiber using electrostatic spinning technique and being also faced with some
It solves the problems, such as.First, in terms of preparing organic nanofibers, the natural polymer kind for electrostatic spinning also extremely has
Limit, incomplete to the research of structure of title compound and performance, the application of final products is mostly only at the experimental stage, especially
There is also larger problems for the industrialization production of these products.Secondly, the performance of Static Spinning organic/inorganic composite nano fiber is not
It is only related with the structure of nano-particle, also with the clustered pattern of nano-particle and synergisticing performance, polymeric matrix structural behaviour,
The interfacial structure performance and processing combination process of particle and matrix etc. are related.How to prepare and is suitble to needs, high-performance, more work(
The composite nano fiber of energy is the key that research.In addition, the research of Static Spinning inorganic nano-fiber is substantially at initial period, nothing
Machine nanofiber has latent in multiple fields such as high temperature filtration, efficient catalytic, bioengineered tissue, photoelectric device, space flight equipment
Purposes, still, the larger brittleness of Static Spinning inorganic nano-fiber limits its application performance and range, therefore, exploitation tool
Simple production process, flexibility, continuity, the nano material of structural integrity are a technological difficulties.
Invention content
To solve the above-mentioned problems, technical scheme is as follows:
The present invention is configured to uniform precursor sol liquid by the polymer and metal salt of different molecular weight, and high-voltage electrostatic spinning obtains
Nanofiber is heat-treated (gradient increased temperature rate and gradient temperature) process in conjunction with gradient, obtains the adjustable interior of the contraction of high quality
The inorganic nano material of structure, the decomposable process of the ingenious heating rate control composite fibre different using two stages, accurately
And convenient control forms nested structure and the double-deck inside pattern.
The preparation method of the fiber, it is characterised in that:
1) weigh respectively the polyacrylamide of the high molecular weight of 0.3 ~ 1.5g, the middle-molecular-weihydroxyethyl of 0.78 ~ 1g polyacrylamide,
The polyacrylamide of the low molecular weight of 0.4 ~ 0.8g and the precipitating reagent of the metal salt of 2 ~ 3mmol and 4 ~ 7mmol are added to 28 simultaneously
~ 39mL deionized waters, putting it to magnetic agitation 6h in 70 ~ 88 DEG C of thermostat water bath makes it all dissolve, and is formed transparent
Solution;One kind in nitrate, sulfate, acetate, chloride and oxalates of the metal salt selected from Mg, Al, Zn, Zr and Fe
Or it is a variety of;In the precipitating reagent selected from phosphoric acid, ammonium phosphate, ammonium dihydrogen phosphate, diammonium hydrogen phosphate, ammonium hydroxide, ammonium fluoride, ammonium carbonate,
It is one or more in ammonium hydrogen carbonate and oxalic acid;
2) step 1) precursor solution is added in injection, in 17 ~ 20kV of positive high voltage, the condition of negative high voltage -1.1 ~ 1.9kV
Lower carry out electrostatic spinning receives nanofiber with aluminium foil, and syringe needle is adjusted to 13 ~ 18 cm at a distance from receiver board, and spinning solution promotes
1 ~ 1.5mL/h of speed;
3) nanofiber obtained to step 2) is positioned in 120 DEG C of baking ovens dry 5h;
4) the compound nanofiber for obtaining electrostatic spinning in step 3), under inert gas atmosphere first with 20 DEG C of min-1Soon
Heating rate to 380 DEG C, 1.5h is kept the temperature, then with 2 DEG C of min-1Slow heating rate is to 550 DEG C and keeps the temperature 4h, you can obtain by
The nested nanofiber of small nano particle composition;
A length of 5~15 μm of obtained nanofiber is formed by inside and outside two layer nestings, is between layers hollow-core construction, outer layer
A diameter of 200~400 nm, a diameter of 80~120nm of internal layer, inside and outside interlamellar spacing are 40~70 nm, layer wall thickness 20~30
nm.With more than or equal to 130m2The specific surface area of/g.
Inert gas is preferably nitrogen.Metal salt is preferably selected from one in the nitrate, sulfate and oxalates of Mg, Fe
Kind is a variety of;Selected from phosphoric acid, ammonium phosphate, ammonium dihydrogen phosphate, diammonium hydrogen phosphate in the precipitating reagent.
The Molecular Weight for Polyacrylamide of high molecular weight is 300-2,200 ten thousand, the Molecular Weight for Polyacrylamide of middle-molecular-weihydroxyethyl is
100-200 ten thousand, low molecular weight polyacrylamide molecular weight be less than 1,000,000.
Since high, medium and low molecular weight polyisoprene propylene milling amine has different viscosity and surface tension, in the work of high-pressure electrostatic
Under, three nano wire in the radial direction be in layered distribution, formed three coaxial configurations (i.e. high molecular weight outermost layer, low point
Son amount center, middle-molecular-weihydroxyethyl therebetween).However inorganic salts are uniformly distributed in nanofiber.First, electrospun nanofiber is fine
Dimension is with 20 DEG C of min-1Fast heating rate is to 380 DEG C, and the crystalline rate Vc of inorganic salts is less than Polymer-pyrolysis rate Vp, this will lead
It causes moving direction by internal layer outer layers, is formed hollow.Then, 1.5h is kept the temperature at 380 DEG C, because capillary force and polymer pipe are soft
Essence will cause outer polymeric layer to shrink.Finally with 2 DEG C of min-1Heating rate be heated to 550 DEG C, keep the temperature 4h.Because low
Heating rate under Vp be more than Vc, moving direction forms bivalve from centre to both sides.Finally, at high temperature, inorganic matter is further
Crystallization, forms the nanostructure of contraction.
Nanofiber and preparation method thereof in the present invention has following advantageous effect compared with the prior art:
(1)The present invention has prepared the metal composite oxide nanofiber with double-layer nested structure, and inside and outside wall is inwardly received
Contracting, can integrally improve the tap density of nanofiber, and diameter is distributed in relatively narrow region, have preferable structural integrity and one
Fixed magnetism;
(2)The present invention is configured to uniform precursor sol liquid, high-voltage electrostatic spinning by the polymer and metal salt of different molecular weight
Nanofiber is obtained, is heat-treated (gradient increased temperature rate and gradient temperature) process in conjunction with gradient, obtain the contraction of high quality can
The inorganic nano material of structure in adjusting, the decomposable process of the ingenious heating rate control composite fibre different using two stages,
Accurate and convenient control forms the pattern of nested structure.
Description of the drawings
Fig. 1 is nanofiber stereoscan photograph of the present invention
Specific implementation mode
Embodiment 1
1) weigh respectively the polyacrylamide of the high molecular weight of 1.1g, the polyacrylamide of the middle-molecular-weihydroxyethyl of 0.8g, 0.8g it is low
The polyacrylamide of molecular weight and the precipitating reagent of the metal salt of 2.3mmol and 4.7mmol are added to 2.9mL deionized waters simultaneously,
Putting it to magnetic agitation 6h in 70 ~ 88 DEG C of thermostat water bath makes it all dissolve, and forms transparent solution;Metal salt is selected from
Ferric nitrate;Phosphoric acid is selected from the precipitating reagent;
2) step 1) precursor solution is added in injection, is carried out under conditions of positive high voltage 18kV, negative high voltage -1.8kV
Electrostatic spinning receives nanofiber with aluminium foil, and syringe needle is adjusted to 18 cm, spinning solution fltting speed at a distance from receiver board
1.4mL/h;
3) nanofiber obtained to step 2) is positioned in 120 DEG C of baking ovens dry 5h;
4) the compound nanofiber for obtaining electrostatic spinning in step 3), under inert gas atmosphere first with 20 DEG C of min-1Soon
Heating rate to 380 DEG C, 1.5h is kept the temperature, then with 2 DEG C of min-1Slow heating rate is to 550 DEG C and keeps the temperature 4h, you can obtain by
The nested nanofiber of small nano particle composition;
A length of 13 μm of obtained nanofiber is formed by inside and outside two layer nestings, is between layers hollow-core construction, outer layer diameter
For 300nm, a diameter of 100nm of internal layer, inside and outside interlamellar spacing is 55 nm, 21 nm of layer wall thickness.
Embodiment 2
1) low molecule of the polyacrylamide of the high molecular weight of 1g, the polyacrylamide of the middle-molecular-weihydroxyethyl of 1g, 0.8g is weighed respectively
The polyacrylamide of amount and the precipitating reagent of the metal salt of 2mmol and 5mmol are added to 30mL deionized waters simultaneously, put it to
Magnetic agitation 6h makes it all dissolve in 70 DEG C of thermostat water bath, forms transparent solution;Metal salt is selected from magnesium chloride;Institute
It states and is selected from diammonium hydrogen phosphate in precipitating reagent;
2) step 1) precursor solution is added in injection, is carried out under conditions of positive high voltage 18kV, negative high voltage -1.4kV
Electrostatic spinning receives nanofiber with aluminium foil, and syringe needle is adjusted to 15 cm, spinning solution fltting speed 1mL/ at a distance from receiver board
h;
3) nanofiber obtained to step 2) is positioned in 120 DEG C of baking ovens dry 5h;
4) the compound nanofiber for obtaining electrostatic spinning in step 3), under inert gas atmosphere first with 20 DEG C of min-1Soon
Heating rate to 380 DEG C, 1.5h is kept the temperature, then with 2 DEG C of min-1Slow heating rate is to 550 DEG C and keeps the temperature 4h, you can obtain by
The nested nanofiber of small nano particle composition;
A length of 11 μm of obtained nanofiber is formed by inside and outside two layer nestings, is between layers hollow-core construction, outer layer diameter
For 255 nm, a diameter of 85nm of internal layer, inside and outside interlamellar spacing is 48nm, layer wall thickness 25nm.
Comparative example 1
1) low molecule of the polyvinyl alcohol of the high molecular weight of 1g, the polyvinyl alcohol of the middle-molecular-weihydroxyethyl of 0.75g, 0.35g is weighed respectively
The polyvinyl alcohol molecule amount of amount and the four water manganese acetates of the four water cobalt acetates of 1.5mmol and 3mmol are added to 20mL simultaneously
Ionized water, putting it to magnetic agitation 6h in 80 DEG C of thermostat water bath makes it all dissolve, and forms transparent solution;
2) step 1) precursor solution is added in injection, is carried out under conditions of positive high voltage 15kV, negative high voltage -2kV quiet
Electrospun receives nanofiber with aluminium foil;
3) nanofiber obtained to step 2) is positioned in 120 DEG C of baking ovens dry 5h;
4) the compound nanofiber for obtaining electrostatic spinning in step 3), in air atmosphere first with 1 DEG C of min-1Slow liter
Warm rate keeps the temperature 1h, then with 10 DEG C of min to 280 DEG C-1Fast heating rate is to 500 DEG C and keeps the temperature 3h, you can obtains by small
Nano particle composition contraction nanofiber.
Comparative example 2
(1)2 solution of Mn (NO3) addition for weighing 0.4000g Fe2 (SO4) 3 and 0.36g 50wt% respectively fills 6 mL DMF's
In beaker, stirring obtains the solution of clear homogeneous until all dissolving, and adds 1g PVP, is mixed evenly, obtains transparent
Sticky spinning solution;
(2)By step(1)The spinning solution of preparation is poured into the syringe with the stainless steel syringe needle that outer diameter is 0.8 mm and is carried out
Electrostatic spinning controls indoor temperature and relative humidity respectively in 15 DEG C and 35% or so, and syringe needle is adjusted at a distance from receiver board
20 cm, spinning solution fltting speed are 0.9 mL/h, and the voltage of electrostatic spinning process is 16 kV, collects to obtain iron using receiver board
The composite nano fiber of manganese Metal salt and polyvinylpyrrolidone;
(3)By step(2)The composite fibre of preparation carries out calcine by steps, and the first stage with the heating rate of 1 DEG C/min, is warming up to
250 DEG C, second stage is warming up to 600 DEG C from 250 DEG C, and using the heating rate of 10 DEG C/min, soaking time is 4 h, then with
Stove is cooled to room temperature to get to iron-manganese metal composite oxide magnetic Nano fiber.
Material prepared by the present invention is as active material, according to active material:Acetylene black:Graphene oxide (binder)
Mass ratio be 7:2.5:0.5.In view of electrode reaction binary channels process (ion and electronics) and preferably play its structure
Advantage, graphene oxide are used to the adhesive instead of insulation, and the conductivity of electrode can but be increased by only accounting for the 5% of entire electrode.
Active material and acetylene black are sufficiently mixed first, while suitable isopropanol grinding is added uniformly, is eventually adding graphite oxide
Alkene makes active material be bonded together with acetylene black.Then mixture is pressed into diaphragm in homogeneous thickness on twin rollers, then cut
It is about 0.8cm to be cut into the same size, area2Small pieces, be put into 70 DEG C of baking oven it is dry for 24 hours.It is just with the diaphragm after tabletting
Pole, metal lithium sheet are cathode, stainless (steel) wire is collector, and shell is CR2016 type battery cases, and diaphragm paper is that Celgard2400 is micro-
Hole polypropylene screen, electrolyte are ethylene carbonate (EC)/dimethyl carbonate (DMC) (VEC of 1.0mol/LLiPF6:VDMC=
1:1) solution assembles lithium ion battery in the glove box (moisture is controlled in 8ppm or less) full of argon gas and seals, will be made
Standby battery standing can carry out electrochemical property test after one day.
Average size under the different current densities of table 1
The experimental results showed that the present invention has excellent high rate performance.
2 200mA g of table-1Current density under cycle performance, by 140 times cycle after, discharge capacity 200mA g-1's
Cycle performance under current density
Embodiment 1 | Embodiment 2 | Comparative example 1 | Comparative example 2 | |
Discharge capacity(mAh/g) | 938 | 940 | 924 | 925 |
Claims (4)
1. a kind of preparation method of double-layer nested nanofiber, it is characterised in that:The fiber has inside and outside two layers, passes through difference
The polymer and metal salt of molecular weight are configured to uniform precursor sol liquid, and high-voltage electrostatic spinning obtains nanofiber.
2. the preparation method of fiber as described in claim 1, it is characterised in that:In conjunction with gradient heat treatment (gradient increased temperature rate and
Gradient temperature) process, the inorganic nano material of the adjustable interior structure of the contraction of high quality is obtained, it is ingenious to utilize two stage differences
Heating rate control composite fibre decomposable process, accurate and convenient control forms nested structure and double-deck inside
Pattern.
3. the preparation method of fiber as described in claim 1, it is characterised in that:The high-molecular-weight poly third of 0.3 ~ 1.5g is weighed respectively
Acrylamide, the middle-molecular-weihydroxyethyl polyacrylamide of 0.78 ~ 1g, the low molecular weight polyacrylamide of 0.4 ~ 0.8g and the gold of 2 ~ 3mmol
The precipitating reagent for belonging to salt and 4 ~ 7mmol is added to 28 ~ 39mL deionized waters simultaneously, puts it in 70 ~ 88 DEG C of thermostat water bath
Magnetic agitation 6h makes it all dissolve, and forms transparent solution;Metal salt is selected from nitrate, the sulfuric acid of Mg, Al, Zn, Zr and Fe
It is one or more in salt, acetate, chloride and oxalates;Selected from phosphoric acid, ammonium phosphate, biphosphate in the precipitating reagent
It is one or more in ammonium, diammonium hydrogen phosphate, ammonium hydroxide, ammonium fluoride, ammonium carbonate, ammonium hydrogen carbonate and oxalic acid.
4. preparation method as claimed in claim 2, it is characterised in that:Fiber ectonexine wall obtained has to contract
More than or equal to 130m2The specific surface area of/g.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201810284958.6A CN108301070A (en) | 2016-08-03 | 2016-08-03 | A kind of preparation method of double-layer nested nanofiber |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201810284958.6A CN108301070A (en) | 2016-08-03 | 2016-08-03 | A kind of preparation method of double-layer nested nanofiber |
CN201610628911.8A CN106222799B (en) | 2016-08-03 | 2016-08-03 | A kind of double-layer nested nanofiber and preparation method thereof |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201610628911.8A Division CN106222799B (en) | 2016-08-03 | 2016-08-03 | A kind of double-layer nested nanofiber and preparation method thereof |
Publications (1)
Publication Number | Publication Date |
---|---|
CN108301070A true CN108301070A (en) | 2018-07-20 |
Family
ID=57536501
Family Applications (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201810284958.6A Pending CN108301070A (en) | 2016-08-03 | 2016-08-03 | A kind of preparation method of double-layer nested nanofiber |
CN201810594833.3A Pending CN108728935A (en) | 2016-08-03 | 2016-08-03 | A kind of metal composite oxide nanofiber |
CN201610628911.8A Active CN106222799B (en) | 2016-08-03 | 2016-08-03 | A kind of double-layer nested nanofiber and preparation method thereof |
Family Applications After (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201810594833.3A Pending CN108728935A (en) | 2016-08-03 | 2016-08-03 | A kind of metal composite oxide nanofiber |
CN201610628911.8A Active CN106222799B (en) | 2016-08-03 | 2016-08-03 | A kind of double-layer nested nanofiber and preparation method thereof |
Country Status (1)
Country | Link |
---|---|
CN (3) | CN108301070A (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106731229B (en) * | 2016-12-30 | 2019-01-15 | 东华大学 | The electret nano-fiber air filter material and preparation method thereof for having water-proof function |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2008303514A (en) * | 2007-06-11 | 2008-12-18 | Japan Vilene Co Ltd | Method for producing electrospun nonwoven fabric |
CN102068917A (en) * | 2010-11-17 | 2011-05-25 | 无锡中科光远生物材料有限公司 | Double-layer hollow fiber nano-filtration membrane and preparation method thereof |
CN102071541A (en) * | 2010-11-17 | 2011-05-25 | 无锡中科光远生物材料有限公司 | Nested nanostructured electrostatic spinning fiber membrane and preparation method thereof |
CN104389037A (en) * | 2014-11-26 | 2015-03-04 | 魏保平 | Nested spinning body |
CN105375028A (en) * | 2015-12-08 | 2016-03-02 | 武汉理工大学 | Contractive inner-structure-adjustable mesoporous inorganic salt nanotube material, preparation method therefor and application thereof |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2204480B1 (en) * | 2008-12-25 | 2013-03-20 | Shinshu University | Process of manufacturing inorganic nanofibers |
KR20110099475A (en) * | 2010-03-02 | 2011-09-08 | 건국대학교 산학협력단 | Manufacturing method of gradient nanofiber materials using coaxial multinozzle and the gradient nanofiber materials thereof |
CN101787580B (en) * | 2010-03-12 | 2011-08-17 | 浙江大学 | Method for preparing coaxial micrometer fibers by utilizing combined drawing and filament forming device |
CN102234846B (en) * | 2010-04-28 | 2013-08-21 | 中国科学院化学研究所 | Core/shell fiber with nanowire-embedded microtube structure and preparation method thereof |
CN103132163B (en) * | 2013-03-12 | 2016-01-27 | 东南大学 | A kind of preparation method with the fiber of multi-kernel shell structure |
CN103966680A (en) * | 2014-05-04 | 2014-08-06 | 东华大学 | Method for preparing drug sustained release nanofibers |
-
2016
- 2016-08-03 CN CN201810284958.6A patent/CN108301070A/en active Pending
- 2016-08-03 CN CN201810594833.3A patent/CN108728935A/en active Pending
- 2016-08-03 CN CN201610628911.8A patent/CN106222799B/en active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2008303514A (en) * | 2007-06-11 | 2008-12-18 | Japan Vilene Co Ltd | Method for producing electrospun nonwoven fabric |
CN102068917A (en) * | 2010-11-17 | 2011-05-25 | 无锡中科光远生物材料有限公司 | Double-layer hollow fiber nano-filtration membrane and preparation method thereof |
CN102071541A (en) * | 2010-11-17 | 2011-05-25 | 无锡中科光远生物材料有限公司 | Nested nanostructured electrostatic spinning fiber membrane and preparation method thereof |
CN104389037A (en) * | 2014-11-26 | 2015-03-04 | 魏保平 | Nested spinning body |
CN105375028A (en) * | 2015-12-08 | 2016-03-02 | 武汉理工大学 | Contractive inner-structure-adjustable mesoporous inorganic salt nanotube material, preparation method therefor and application thereof |
Also Published As
Publication number | Publication date |
---|---|
CN106222799A (en) | 2016-12-14 |
CN108728935A (en) | 2018-11-02 |
CN106222799B (en) | 2018-09-21 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN108315834B (en) | Preparation method of array type magnetic reduced graphene oxide-carbon nanofiber | |
Weng et al. | Electrospun carbon nanofiber-based composites for lithium-ion batteries: structure optimization towards high performance | |
KR20140120861A (en) | Graphite negative electrode material for lithium ion batteries and preparing method thereof | |
CN106784745A (en) | The sodium-ion battery method for manufacturing electric spinning of cobaltosic oxide carbon nano-fiber | |
CN106571451A (en) | Lithium ion battery anode material, and preparation method thereof | |
CN113073426B (en) | Porous multi-hollow flexible composite nanofiber membrane material and preparation method thereof | |
CN106941167A (en) | A kind of porous composite negative pole material of lithium ion battery and preparation method thereof | |
CN109065808B (en) | Preparation method of functional interlayer for lithium-sulfur battery | |
CN108923035A (en) | A kind of preparation method of lithium ion battery nano-silicone wire/carbon composite negative pole material | |
CN109659519B (en) | TiO2Preparation method of nanofiber-coated lithium ion battery ternary cathode material and product | |
KR101438065B1 (en) | Hybrid nano-complex, method for producing the same, and electrode for supercapacitor comprising the same | |
CN113044840B (en) | Active carbon loaded molybdenum and nitrogen double-doped carbon nano-sheet array composite material and preparation method and application thereof | |
CN110400916A (en) | A kind of carbon fibre composite preparation method of two selenizings molybdenum nanometer sheet modification | |
CN111952577B (en) | C/Si/CNTs composite carbon nanofiber membrane, preparation method and application thereof | |
CN106222799B (en) | A kind of double-layer nested nanofiber and preparation method thereof | |
CN109698330A (en) | A kind of lithium ion battery | |
CN114823155B (en) | Three-dimensional conductive material and preparation method and application thereof | |
CN115036480B (en) | Lithium-sulfur battery positive electrode material, preparation method thereof and lithium-sulfur battery | |
CN106099117A (en) | A kind of electrode with excellent high rate performance and current cycle performance | |
CN109305697A (en) | A kind of preparation method of nitrogenous grading-hole carbon nano-tube film | |
CN115020707A (en) | Flexible lithium metal battery lithium-philic carbon nanofiber framework material and preparation method and application thereof | |
CN108281591A (en) | A kind of preparation method of lithium ion battery ceramic coating composite diaphragm | |
CN114899382A (en) | N-doped porous carbon double-shell microsphere structure coated Co 3 O 4 Material, preparation method and application thereof | |
CN114068872A (en) | Polymer nanofiber metal lithium composite negative electrode with double lithium affinity and preparation method thereof | |
CN108574096B (en) | NiO/rGO composite nano material, preparation method thereof and lithium battery anode material |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
WD01 | Invention patent application deemed withdrawn after publication | ||
WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20180720 |