CN108298605A - A kind of life water purification material - Google Patents

A kind of life water purification material Download PDF

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Publication number
CN108298605A
CN108298605A CN201810110446.8A CN201810110446A CN108298605A CN 108298605 A CN108298605 A CN 108298605A CN 201810110446 A CN201810110446 A CN 201810110446A CN 108298605 A CN108298605 A CN 108298605A
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CN
China
Prior art keywords
parts
auxiliary agent
life water
water purification
purification material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810110446.8A
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Chinese (zh)
Inventor
陈俊
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Study On Water Structure Of Wuhan Shizhen Ltd
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Study On Water Structure Of Wuhan Shizhen Ltd
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Publication date
Application filed by Study On Water Structure Of Wuhan Shizhen Ltd filed Critical Study On Water Structure Of Wuhan Shizhen Ltd
Priority to CN201810110446.8A priority Critical patent/CN108298605A/en
Publication of CN108298605A publication Critical patent/CN108298605A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/281Treatment of water, waste water, or sewage by sorption using inorganic sorbents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/30Organic compounds
    • C02F2101/306Pesticides

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Compositions Of Oxide Ceramics (AREA)

Abstract

The invention discloses a kind of life water purification materials, including component and each component parts by weight be quartz 50 60 parts, 30 40 parts of albite, 4 parts of montmorillonite 2, purify 5 10 parts of auxiliary agent, it is described purification auxiliary agent chemical general formula be RbTmCl3.The life water purification material of the present invention is placed in domestic water 10~20 minutes, you can the pesticide residue in agricultural product such as water fruits and vegetables in water is placed in absorption, processing, to achieve the purpose that purify life water, simple and convenient practicality.

Description

A kind of life water purification material
Technical field
The invention belongs to daily water consumption purification techniques fields, more particularly to a kind of life water purification material.
Background technology
China's most area has been enter into fairly comfortable life, is become more concerned with to health, strong on environment, influence body The various aspects factors dictate of health is higher and higher, other than to the air of drinking water, breathing, such as to agricultural product in living and diet Persticide residue in veterinary antibiotics etc. is also to pay close attention to.The method for removing vegetable and fruit surface pesticide residue is more, ozone And it is currently used method to use the detergent based on nonionic surfactant.Such as Beijing Agricultural College CN 103637031 B utilizes the immersion of waste water stoste, the cleaning vegetables water that starch or vermicelli and food enterprise are produced with miscellaneous beans (mung bean, pea or broad bean) Fruit removes pesticide residue in vegetable and fruit, and 101695345 B of Zhejiang Polytechnical University CN are to be added surfactant, ozone in water And the pH for adjusting water is 6.0~9.0, is then turned on bubbling device, under the conditions of 25~40 DEG C of temperature cleaning carry out pesticides removal, Although these patented technologies can theoretically reach the technique effect of removal pesticide, it is difficult to have item that practical application, which is got up, Part.
Invention content
The present invention is directed at least solve one of the technical problems existing in the prior art.For this purpose, the present invention proposes one kind Life water purification material, including component and each component parts by weight be 50-60 part of quartz, 30-40 parts of albite, illiteracy take off 2-4 parts of stone purifies 5-10 parts of auxiliary agent.
Further, the chemical general formula of the purification auxiliary agent is RbTmCl3.
Further, the preparation of the purification auxiliary agent includes the following steps:
A, it is 1 in molar ratio:1 weighs Tm2O3 and Rb2CO3 powders;
B, the powder weighed in step a is added in the hydrochloric acid of a concentration of 5~5.5mol/L, and dispersant is added, from And it is configured to the solution A of 0.5~1mol/L;
C, the solution A obtained by step b is imported in spray dryer, to obtain granule B;
D, by the granule B obtained by step c at 1400~1500 DEG C 1~3h of vacuum-sintering, be then placed in air in 1000~1200 DEG C of 2~3h of annealing are to get the purification auxiliary agent that the chemical general formula is RbTmCl3.
Further, the solution A and the volume ratio of hydrochloric acid are 7~8.5:1.
Further, the dispersant is the polyethylene glycol of a concentration of 0.012~0.014mol/L.
A kind of life water purification material of the present invention is placed in domestic water 10~20 minutes, you can absorption, processing The pesticide residue in agricultural product such as water fruits and vegetables in water is placed, it is simple and convenient to achieve the purpose that purify life water It is practical.
Specific implementation mode
The embodiment of the present invention is described below in detail, in which the same or similar labels are throughly indicated identical or classes As element or element with the same or similar functions.The embodiments described below is exemplary, and is only used for explaining this hair It is bright, and be not considered as limiting the invention.
Embodiment 1
A kind of life water purification material, including component and each component parts by weight be quartz 50 parts, albite 30 Part, 3 parts of montmorillonite purifies 8 parts of auxiliary agent, and the chemical general formula of the purification auxiliary agent is RbTmCl3, the preparation of the purification auxiliary agent Include the following steps:
A, it is 1 in molar ratio:1 weighs Tm2O3 and Rb2CO3 powders;
B, the powder weighed in step a is added in the hydrochloric acid of a concentration of 5mol/L, and dispersant is added, to match It is set to the solution A of 0.75mol/L;
C, the solution A obtained by step b is imported in spray dryer, to obtain granule B;
D, by the granule B obtained by step c at 1400 DEG C vacuum-sintering 3h, be then placed in air and moved back in 1000 DEG C Fiery 2h is to get the purification auxiliary agent that the chemical general formula is RbTmCl3.
The volume ratio of the powder and hydrochloric acid that are wherein weighed in step a in solution A is 7:1;The dispersant is a concentration of The polyethylene glycol of 0.012mol/L.
Embodiment 2
A kind of life water purification material, including component and each component parts by weight be quartz 60 parts, albite 35 Part, montmorillonite 2 part purifies 5 parts of auxiliary agent, and the chemical general formula of the purification auxiliary agent is RbTmCl3, the preparation of the purification auxiliary agent Include the following steps:
A, it is 1 in molar ratio:1 weighs Tm2O3 and Rb2CO3 powders;
B, the powder weighed in step a is added in the hydrochloric acid of a concentration of 5.2mol/L, and dispersant is added, to It is configured to the solution A of 0.7mol/L;
C, the solution A obtained by step b is imported in spray dryer, to obtain granule B;
D, by the granule B obtained by step c at 1450 DEG C vacuum-sintering 2h, be then placed in air and moved back in 1100 DEG C Fiery 2.5h is to get the purification auxiliary agent that the chemical general formula is RbTmCl3.
The volume ratio of the powder and hydrochloric acid that are wherein weighed in step a in solution A is 8:1;The dispersant is a concentration of The polyethylene glycol of 0.013mol/L.
Embodiment 3
A kind of life water purification material, including component and each component parts by weight be quartz 55 parts, albite 40 Part, 4 parts of montmorillonite purifies 10 parts of auxiliary agent, and the chemical general formula of the purification auxiliary agent is RbTmCl3, the preparation of the purification auxiliary agent Include the following steps:
A, it is 1 in molar ratio:1 weighs Tm2O3 and Rb2CO3 powders;
B, the powder weighed in step a is added in the hydrochloric acid of a concentration of 5.5mol/L, and dispersant is added, to It is configured to the solution A of 1mol/L;
C, the solution A obtained by step b is imported in spray dryer, to obtain granule B;
D, by the granule B obtained by step c at 1500 DEG C vacuum-sintering 1h, be then placed in air and moved back in 1200 DEG C Fiery 3h is to get the purification auxiliary agent that the chemical general formula is RbTmCl3.
The volume ratio of the powder and hydrochloric acid that are wherein weighed in step a in solution A is 8.5:1;The dispersant is a concentration of The polyethylene glycol of 0.014mol/L.
Montmorillonite main component is (Na, Ca) 0.33 (Al, Mg)2(Si4O10)(OH)2·nH2O has superpower absorption Function, controlled release agent function, cation exchange property etc.;The common chemical molecular formula of albite is Na2O·Al2O3·6SiO2, In the case of a high temperature, montmorillonite is heat-fused in albite, can preferably produce shaped article, and purification auxiliary agent is added RbTmCl3, negative ion decomposition remains of pesticide is generated, by life water purification material and vegetables or fruit made from embodiment 1 to 3 It is placed in the vegetable bowl for containing tap water 10~20 minutes, after testing, the persticide residue of vegetables or fruit is clear after cleaning 13~21% before washing, achieve preferable pesticides removal effect.
Although an embodiment of the present invention has been shown and described, it will be understood by those skilled in the art that:Not In the case of being detached from the principle of the present invention and objective a variety of change, modification, replacement and modification can be carried out to these embodiments, The scope of the present invention is limited by claim and its equivalent.

Claims (5)

1. a kind of life water purification material, which is characterized in that including component and each component parts by weight be quartz 50-60 Part, 30-40 parts of albite, -4 parts of montmorillonite 2 purifies 5-10 parts of auxiliary agent.
2. life water purification material according to claim 1, which is characterized in that it is described purification auxiliary agent chemical general formula be RbTmCl3
3. life water purification material according to claim 2, which is characterized in that the preparation of the purification auxiliary agent includes as follows Step:
A, it is 1 in molar ratio:1 weighs Tm2O3And Rb2CO3Powder;
B, the powder weighed in step a is added in the hydrochloric acid of a concentration of 5~5.5mol/L, and dispersant is added, to match It is set to the solution A of 0.5~1mol/L;
C, the solution A obtained by step b is imported in spray dryer, to obtain granule B;
D, by the granule B obtained by step c at 1400~1500 DEG C 1~3h of vacuum-sintering, be then placed in air in 1000 ~1200 DEG C of 2~3h of annealing are RbTmCl to get the chemical general formula3Purification auxiliary agent.
4. life water purification material according to claim 3, which is characterized in that the solution A and the volume ratio of hydrochloric acid are 7 ~8.5:1.
5. life water purification material according to claim 3, which is characterized in that the dispersant be a concentration of 0.012~ The polyethylene glycol of 0.014mol/L.
CN201810110446.8A 2018-02-05 2018-02-05 A kind of life water purification material Pending CN108298605A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810110446.8A CN108298605A (en) 2018-02-05 2018-02-05 A kind of life water purification material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810110446.8A CN108298605A (en) 2018-02-05 2018-02-05 A kind of life water purification material

Publications (1)

Publication Number Publication Date
CN108298605A true CN108298605A (en) 2018-07-20

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CN201810110446.8A Pending CN108298605A (en) 2018-02-05 2018-02-05 A kind of life water purification material

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009048552A1 (en) * 2007-10-10 2009-04-16 Northwestern University Chalcogenide compounds with a clay-like cation-exchange capacity and methods of use
CN101909714A (en) * 2007-10-31 2010-12-08 莫利康普矿物有限责任公司 Be used to handle the apparatus and method of the aqueous solution that contains chemical pollutant
CN101918324A (en) * 2007-10-31 2010-12-15 莫利康普矿物有限责任公司 Aggregate composition for treating a contaminanted fluid
CN102180535A (en) * 2011-03-25 2011-09-14 中国科学院南京土壤研究所 Method for removing phosphorus in organophosphorus pesticide waste water by using metal compound complex mineral material

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009048552A1 (en) * 2007-10-10 2009-04-16 Northwestern University Chalcogenide compounds with a clay-like cation-exchange capacity and methods of use
CN101909714A (en) * 2007-10-31 2010-12-08 莫利康普矿物有限责任公司 Be used to handle the apparatus and method of the aqueous solution that contains chemical pollutant
CN101918324A (en) * 2007-10-31 2010-12-15 莫利康普矿物有限责任公司 Aggregate composition for treating a contaminanted fluid
CN102180535A (en) * 2011-03-25 2011-09-14 中国科学院南京土壤研究所 Method for removing phosphorus in organophosphorus pesticide waste water by using metal compound complex mineral material

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Address after: 442400 Hubei Shennongjia forest region pine and pines Town Water Ecological Industrial Park

Applicant after: Shennongjia Shi Zhen Water Structure Research Institute Co., Ltd.

Address before: 430223 Jiangxia Jiangxia Economic Development Zone, Wuhan, Hubei, Jiangxia road Private Industrial Park, Wuhan City, the 1-6 floor of the six factory building of the de song science and technology research and development center.

Applicant before: Study on water structure of Wuhan Shizhen Limited

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WD01 Invention patent application deemed withdrawn after publication
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Application publication date: 20180720