CN108231843A - A kind of flexible OLED display and preparation method thereof - Google Patents

A kind of flexible OLED display and preparation method thereof Download PDF

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Publication number
CN108231843A
CN108231843A CN201711489195.0A CN201711489195A CN108231843A CN 108231843 A CN108231843 A CN 108231843A CN 201711489195 A CN201711489195 A CN 201711489195A CN 108231843 A CN108231843 A CN 108231843A
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CN
China
Prior art keywords
anode
flexible
layer
electrode
oled display
Prior art date
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Pending
Application number
CN201711489195.0A
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Chinese (zh)
Inventor
舒红林
盛磊
刘静
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Yunnan Jing Jing Liquid Metal Heat Control Technology Research And Development Co Ltd
Original Assignee
Yunnan Jing Jing Liquid Metal Heat Control Technology Research And Development Co Ltd
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Application filed by Yunnan Jing Jing Liquid Metal Heat Control Technology Research And Development Co Ltd filed Critical Yunnan Jing Jing Liquid Metal Heat Control Technology Research And Development Co Ltd
Priority to CN201711489195.0A priority Critical patent/CN108231843A/en
Publication of CN108231843A publication Critical patent/CN108231843A/en
Pending legal-status Critical Current

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    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K59/00Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
    • H10K59/10OLED displays
    • H10K59/12Active-matrix OLED [AMOLED] displays

Abstract

The present invention relates to display areas, disclose a kind of flexible OLED display and preparation method thereof, including:Flexible base board, anode, cathode and organic luminous layer, the organic luminous layer is between the anode and the cathode, the anode is covered in the flexible base board upper end, the electrode of the anode and the electrode of cathode are made of liquid metal, the flexible base board is fabricated from a flexible material, a kind of flexible OLED display provided by the invention and preparation method thereof, utilize liquid metal electronic circuit printing technique, cathode electrode and anode electrode are directly printed on flexible substrates, it makes simple, it is easy to be molded, technical difficulty is low, large-scale mass production can be achieved, reduce cost, simultaneously, independent design and rational collocation, original equipment is run without influence, and suitable for almost all operating mode.

Description

A kind of flexible OLED display and preparation method thereof
Technical field
The present invention relates to display area, more particularly to a kind of flexible OLED display.
Background technology
As display technology develops very fast, requirement of the consumer to display performance is continuously improved, and traditional LCD shows skill Art can not be fully met.In the case where the new market demand pushes, OLED display technologies are as a kind of novel display technology It comes into being.OLED display screen is to utilize display screen made of organic electroluminescent LED.OLED has than LCD more preferably Performance and wider array of application range, " third generation display technology " being referred to as after LCD.OLED display technologies are than LCD more It is frivolous, brightness is high, low in energy consumption, response is fast, clarity is high, flexible, luminous efficiency is high, consumer can be met to display technology New demand.At present, global panel vendor all tries to be the first increases Innovation Input in OLED, accelerates layout, the technology is more and more Applied in the intelligent terminals such as tablet, smart mobile phone, computer, TV wearable device.Just as current year LCD replaces CRT monitor Equally, OLED replaces the inexorable trend that LCD is future development.
Due to OLED and difference of the TFT-LCD devices on structure, material properties and principle of luminosity, OLED luminescent devices It is more suitable for manufacturing flexible screen.Current flexible screen is also widely referred to as Curved screen, because it only shows a fixed song Face, it appears that " flexibility " is not included also, this is because safeguarded since screen also needs to glass, and glass material has it that can not exceed Bending obstacle more.The most commonly used is glass or the metal cover board envelopes using glass as substrate at present for the encapsulation that OLED shields firmly at present Dress, and flexible device is then encapsulated with individual layer and plural layers.Therefore, current flexible OLED display makes difficult, and technology is difficult Degree is high, is not easy to large-scale mass production.
Invention content
(1) technical problems to be solved
The object of the present invention is to provide a kind of flexible OLED displays and preparation method thereof, solve flexible in the prior art OLED display screen makes difficult, and technical difficulty is high, the problem of being not easy to large-scale mass production.
(2) technical solution
In order to solve the above technical problem, the present invention provides a kind of flexible OLED displays, which is characterized in that including:It is soft Property substrate, anode, cathode and organic luminous layer, the organic luminous layer is between the anode and the cathode, the sun Pole is covered in the flexible base board upper end, and the electrode of the anode and the electrode of cathode are made of liquid metal, the flexibility Substrate is fabricated from a flexible material.
Wherein, the flexible base board is made of polyimide plastic, polyether-ether-ketone or electrically conducting transparent terylene.
Wherein, the anode includes the first driving circuit, the second driving circuit, anode electrode, TFT matrixes, and is liquid State metal electron circuit printing technique prints.
Wherein, the organic luminous layer includes electron transfer layer, hole transmission layer and luminescent layer, the electron transfer layer Including electronic barrier layer, electron injecting layer and electron transfer layer, the hole transmission layer includes hole injection layer, hole transport Layer and hole blocking layer.
Invention additionally discloses a kind of production methods of flexible OLED display, which is characterized in that including:
Flexible base board is selected as base material;
Anode electrode is printed on flexible substrates using liquid metal electronic circuit printing technique;
Cathode electrode is printed upon on anode using liquid metal electronic circuit printing technique.
Wherein, the first driving circuit of OLED matrix circuits, second are driven using liquid metal electronic circuit printing technique Dynamic circuit, anode electrode, the printing of TFT matrixes are on flexible substrates.
(3) advantageous effect
A kind of flexible OLED display provided by the invention and preparation method thereof is printed using liquid metal electronic circuit Cathode electrode and anode electrode are directly printed on flexible substrates, make simply, be easy to be molded by technology, and technical difficulty is low, Large-scale mass production can be achieved, reduce cost, meanwhile, independent design and rational collocation run without shadow original equipment It rings, and suitable for almost all operating mode.
Description of the drawings
Fig. 1 is a kind of structure diagram of flexible OLED display of the present invention;
Fig. 2 is the structure diagram of OLED matrix circuits of the present invention.
In figure, 1, cathode;2nd, electron injecting layer;3rd, electron transfer layer;4th, hole blocking layer;5th, luminescent layer;6th, flexible base Plate;7th, anode;8th, hole injection layer;9th, power supply;10th, hole transmission layer;11st, electronic barrier layer;12nd, conducting wire;13;Organic hair Photosphere;14th, the first driving circuit;15th, the second driving circuit;16th, anode electrode;17th, TFT matrixes;18th, cathode electrode.
Specific embodiment
With reference to the accompanying drawings and examples, the specific embodiment of the present invention is described in further detail.Following instance For illustrating the present invention, but it is not limited to the scope of the present invention.
In the description of the present invention, it should be noted that unless otherwise clearly defined and limited, term " installation ", " connected ", " connection " should be interpreted broadly, for example, it may be being fixedly connected or being detachably connected or integrally connect It connects;Can be mechanical connection or electrical connection;It can be directly connected, can also be indirectly connected by intermediary, It can be the connection inside two elements.For the ordinary skill in the art, can be understood with concrete condition above-mentioned The concrete meaning of term in the present invention.
As depicted in figs. 1 and 2, the present invention discloses a kind of flexible OLED display, which is characterized in that including:Flexible base board 6th, anode 7, cathode 1 and organic luminous layer 13, the organic luminous layer 13 is between the anode 7 and the cathode 1, institute It states anode 7 and is covered in 6 upper end of flexible base board, the electrode of the anode 7 and the electrode of the cathode 1 are liquid metal It is made, the flexible base board 6 is fabricated from a flexible material.
Specifically, because of the high conductivity of liquid metal, it can be as the anode electrode of OLED display screen and cathode electrode material Material;Again because liquid metal has liquid flowable, bending will not be easily snapped off as traditional electrode material, be flexible OLED The only selection of display screen.Because organic luminous layer can realize flexibility, therefore the present invention uses flexible base board in the prior art 6, and anode 7, cathode 1 and organic luminous layer 13 are respectively provided with flexibility, form the flexible OLED display of complete set.Anode 7 include anode electrode 16 and OLED matrix circuits, and cathode includes cathode electrode 18.In the prior art, mushroom configuration is generally used Method, the present invention is using liquid metal electronic circuit printing technique, by cathode electrode 18, anode electrode 16 and OLED matrixes electricity Road is directly printed upon on flexible base board 6, it can be achieved that produce in batches, utilizes the flowable of liquid metal and the spy of high conductivity Point so that OLED display screen has good flexibility, and power supply 9 is connected to anode and cathode by conducting wire 12.
A kind of flexible OLED display provided by the invention and preparation method thereof is printed using liquid metal electronic circuit Cathode electrode and anode electrode are directly printed on flexible substrates, make simply, be easy to be molded by technology, and technical difficulty is low, Large-scale mass production can be achieved.
Wherein, the flexible base board 6 is made or of polyimide plastic, polyether-ether-ketone or electrically conducting transparent terylene by other Wait high molecular materials be made, feature include it is light-weight, thickness is thin, soft flexible.
As shown in Fig. 2, the anode includes the first driving circuit 14, the second driving circuit 15, anode electrode 16, TFT squares Battle array 17, and is that liquid metal electronic circuit printing technique prints, i.e. OLED matrix circuits.This matrix circuit is formed The pixel circuit of OLED, realizes screen flexibility using liquid metal electronic circuit printing technique, is easy to be molded, be easy to Large-scale production, moreover it is possible to reduce cost, reduce thickness.
Wherein, the organic luminous layer 13 includes electron transfer layer 3, hole transmission layer 10 and luminescent layer 5, the electronics Transmitting layer 3 includes electronic barrier layer 11, electron injecting layer 2 and electron transfer layer 3, and the hole transmission layer 10 is noted including hole Enter layer 8, hole transmission layer 10 and hole blocking layer 4.Its principle of luminosity:When element is by forward bias voltage drop, applied voltage will Drive electron injecting layer 2 and hole transmission layer 10 respectively by cathode 1 and 7 injection element of anode, when the two meets in conduction, With reference to it is compound to form so-called electron-hole.And after chemical molecular is excited by extraneous energy, if electron spin and base State electronics is pairs of, then is singlet state, and the light discharged is so-called fluorescence;Conversely, if excitation state electronics and ground state electron are certainly Rotation is not pairs of and parallel, then referred to as triplet, the light discharged are so-called phosphorescence.
Invention additionally discloses a kind of production methods of flexible OLED display, which is characterized in that including:
Flexible base board is selected as base material;
Anode electrode is printed on flexible substrates using liquid metal electronic circuit printing technique;
Cathode electrode is printed upon on anode using liquid metal electronic circuit printing technique.
Liquid metal electronic circuit printing technique be it is a kind of by low-melting-point metal or its alloy by special facture, formed It is a kind of to write printable liquid metal ink, in the printer using speciality, required electronic circuit is printed to specified Technology in substrate.Anode and cathode are printed upon flexible base by the present invention using this liquid metal electronic circuit printing technique On plate, realize that OLED display screen has flexibility, and is easy to large-scale mass production.
Wherein, the first driving circuit of OLED matrix circuits, second are driven using liquid metal electronic circuit printing technique Dynamic circuit, anode electrode, the printing of TFT matrixes are on flexible substrates.
A kind of flexible OLED display disclosed by the invention and preparation method thereof is printed using liquid metal electronic circuit Cathode and anode are directly printed on flexible substrates, make simply, be easy to be molded by technology, and technical difficulty is low, it can be achieved that big Scale is produced in batches, reduces cost, meanwhile, independent design and rational collocation are run without influence original equipment, and be applicable in In almost all operating mode.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all essences in the present invention With within principle, any modification, equivalent replacement, improvement and so on should all be included in the protection scope of the present invention god.

Claims (6)

1. a kind of flexible OLED display, which is characterized in that including:Flexible base board (6), anode (7), cathode (1) and organic hair Photosphere (13), between the anode (7) and the cathode (1), the anode (7) is covered in the organic luminous layer (13) Flexible base board (6) upper end, the electrode of the anode (7) and the electrode of the cathode (1) are that liquid metal is made, described Flexible base board (6) is fabricated from a flexible material.
2. flexible OLED display as described in claim 1, which is characterized in that the flexible base board (6) is moulded for polyimides Material, polyether-ether-ketone or electrically conducting transparent terylene are made.
3. flexible OLED display as described in claim 1, which is characterized in that the anode includes the first driving circuit (14), the second driving circuit (15), anode electrode (16), TFT matrixes (17), and be liquid metal electronic circuit printing technique It prints.
4. flexible OLED display as described in claim 1, which is characterized in that the organic luminous layer (13) passes including electronics Defeated layer (3), hole transmission layer (10) and luminescent layer (5), the electron transfer layer (3) are noted including electronic barrier layer (11), electronics Enter layer (2) and electron transfer layer (3), the hole transmission layer (10) includes hole injection layer (8), hole transmission layer (10) and sky Cave barrier layer (4).
5. a kind of production method of flexible OLED display, which is characterized in that including:
Flexible base board is selected as base material;
Anode electrode is printed on flexible substrates using liquid metal electronic circuit printing technique;
Cathode electrode is printed upon on anode using liquid metal electronic circuit printing technique.
6. the production method of flexible OLED display as claimed in claim 5, which is characterized in that utilize liquid metal electronics electricity First driving circuit of OLED matrix circuits, the second driving circuit, anode electrode, TFT matrixes are printed upon soft by road printing technique On property substrate.
CN201711489195.0A 2017-12-30 2017-12-30 A kind of flexible OLED display and preparation method thereof Pending CN108231843A (en)

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Application Number Priority Date Filing Date Title
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115407555A (en) * 2022-08-17 2022-11-29 合肥合纵光电科技有限公司 Flexible quantum dot direct display device

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060066224A1 (en) * 2004-07-30 2006-03-30 Dai Nippon Printing Co., Ltd. Organic functional element, organic EL element, organic semiconductor element, organic TFT element and method for producing the same
CN104576692A (en) * 2014-11-24 2015-04-29 深圳市华星光电技术有限公司 Conductive flexible substrate, manufacturing method of conductive flexible substrate, OLED display device and manufacturing method of OLED (organic light emitting diode) display device
CN105741696A (en) * 2016-02-18 2016-07-06 云南科威液态金属谷研发有限公司 Flexible display control device and preparation method
CN106374046A (en) * 2016-09-12 2017-02-01 Tcl集团股份有限公司 Positively-arranged structure quantum dot light-emitting diode and fabrication method thereof
CN107323089A (en) * 2017-08-10 2017-11-07 上海幂方电子科技有限公司 Three-dimensional printer

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060066224A1 (en) * 2004-07-30 2006-03-30 Dai Nippon Printing Co., Ltd. Organic functional element, organic EL element, organic semiconductor element, organic TFT element and method for producing the same
CN104576692A (en) * 2014-11-24 2015-04-29 深圳市华星光电技术有限公司 Conductive flexible substrate, manufacturing method of conductive flexible substrate, OLED display device and manufacturing method of OLED (organic light emitting diode) display device
CN105741696A (en) * 2016-02-18 2016-07-06 云南科威液态金属谷研发有限公司 Flexible display control device and preparation method
CN106374046A (en) * 2016-09-12 2017-02-01 Tcl集团股份有限公司 Positively-arranged structure quantum dot light-emitting diode and fabrication method thereof
CN107323089A (en) * 2017-08-10 2017-11-07 上海幂方电子科技有限公司 Three-dimensional printer

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115407555A (en) * 2022-08-17 2022-11-29 合肥合纵光电科技有限公司 Flexible quantum dot direct display device

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Application publication date: 20180629

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