CN108220595A - 利用木薯干粉和甲醛还原浸出氧化锰矿的方法 - Google Patents
利用木薯干粉和甲醛还原浸出氧化锰矿的方法 Download PDFInfo
- Publication number
- CN108220595A CN108220595A CN201711262556.8A CN201711262556A CN108220595A CN 108220595 A CN108220595 A CN 108220595A CN 201711262556 A CN201711262556 A CN 201711262556A CN 108220595 A CN108220595 A CN 108220595A
- Authority
- CN
- China
- Prior art keywords
- manganese oxide
- manganese
- oxide ore
- leaching
- dry powder
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 title claims abstract description 183
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 title claims abstract description 104
- 238000002386 leaching Methods 0.000 title claims abstract description 70
- 239000000843 powder Substances 0.000 title claims abstract description 70
- 235000016735 Manihot esculenta subsp esculenta Nutrition 0.000 title claims abstract description 53
- 238000000034 method Methods 0.000 title claims abstract description 46
- 241000658379 Manihot esculenta subsp. esculenta Species 0.000 title 1
- 239000011572 manganese Substances 0.000 claims abstract description 57
- 240000003183 Manihot esculenta Species 0.000 claims abstract description 52
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims abstract description 50
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 50
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Inorganic materials O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 claims abstract description 16
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 15
- 238000006243 chemical reaction Methods 0.000 claims description 17
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 14
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 14
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 14
- 239000011259 mixed solution Substances 0.000 claims description 14
- 229940099596 manganese sulfate Drugs 0.000 claims description 11
- 239000011702 manganese sulphate Substances 0.000 claims description 11
- 235000007079 manganese sulphate Nutrition 0.000 claims description 11
- SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 claims description 11
- 238000003756 stirring Methods 0.000 claims description 9
- 239000000243 solution Substances 0.000 claims description 8
- 238000001914 filtration Methods 0.000 claims description 7
- 239000013055 pulp slurry Substances 0.000 claims description 7
- 239000002994 raw material Substances 0.000 claims description 5
- 239000000470 constituent Substances 0.000 claims description 3
- 239000003638 chemical reducing agent Substances 0.000 abstract description 12
- 238000005516 engineering process Methods 0.000 abstract description 7
- 238000005868 electrolysis reaction Methods 0.000 abstract description 4
- 239000012535 impurity Substances 0.000 abstract description 2
- 239000004615 ingredient Substances 0.000 abstract description 2
- 238000004519 manufacturing process Methods 0.000 description 7
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 238000004458 analytical method Methods 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 238000011161 development Methods 0.000 description 4
- 238000011160 research Methods 0.000 description 4
- 239000002028 Biomass Substances 0.000 description 3
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 239000002699 waste material Substances 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 244000061456 Solanum tuberosum Species 0.000 description 2
- 235000002595 Solanum tuberosum Nutrition 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 229940075933 dithionate Drugs 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 239000008103 glucose Substances 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229940093474 manganese carbonate Drugs 0.000 description 2
- 239000011656 manganese carbonate Substances 0.000 description 2
- 235000006748 manganese carbonate Nutrition 0.000 description 2
- 229910001655 manganese mineral Inorganic materials 0.000 description 2
- 229910000016 manganese(II) carbonate Inorganic materials 0.000 description 2
- XMWCXZJXESXBBY-UHFFFAOYSA-L manganese(ii) carbonate Chemical compound [Mn+2].[O-]C([O-])=O XMWCXZJXESXBBY-UHFFFAOYSA-L 0.000 description 2
- 239000002609 medium Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- GDSOZVZXVXTJMI-SNAWJCMRSA-N (e)-1-methylbut-1-ene-1,2,4-tricarboxylic acid Chemical compound OC(=O)C(/C)=C(C(O)=O)\CCC(O)=O GDSOZVZXVXTJMI-SNAWJCMRSA-N 0.000 description 1
- USFZMSVCRYTOJT-UHFFFAOYSA-N Ammonium acetate Chemical compound N.CC(O)=O USFZMSVCRYTOJT-UHFFFAOYSA-N 0.000 description 1
- 239000005695 Ammonium acetate Substances 0.000 description 1
- 241000790917 Dioxys <bee> Species 0.000 description 1
- 229910000914 Mn alloy Inorganic materials 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 229940043376 ammonium acetate Drugs 0.000 description 1
- 235000019257 ammonium acetate Nutrition 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 150000004982 aromatic amines Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 231100000086 high toxicity Toxicity 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 230000036632 reaction speed Effects 0.000 description 1
- 238000011946 reduction process Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 231100000701 toxic element Toxicity 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/04—Extraction of metal compounds from ores or concentrates by wet processes by leaching
- C22B3/16—Extraction of metal compounds from ores or concentrates by wet processes by leaching in organic solutions
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B47/00—Obtaining manganese
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Geochemistry & Mineralogy (AREA)
- Geology (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Manufacture And Refinement Of Metals (AREA)
Abstract
Description
Claims (4)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201711262556.8A CN108220595B (zh) | 2017-12-05 | 2017-12-05 | 利用木薯干粉和甲醛还原浸出氧化锰矿的方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201711262556.8A CN108220595B (zh) | 2017-12-05 | 2017-12-05 | 利用木薯干粉和甲醛还原浸出氧化锰矿的方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN108220595A true CN108220595A (zh) | 2018-06-29 |
CN108220595B CN108220595B (zh) | 2019-11-05 |
Family
ID=62653178
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201711262556.8A Active CN108220595B (zh) | 2017-12-05 | 2017-12-05 | 利用木薯干粉和甲醛还原浸出氧化锰矿的方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN108220595B (zh) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108928853A (zh) * | 2018-08-15 | 2018-12-04 | 广西锰华新能源科技发展有限公司 | 一种锰矿浸出渣的综合回收利用方法 |
CN113957483A (zh) * | 2021-11-08 | 2022-01-21 | 田世超 | 用羟基组合液相还原制备电解锰合格液的方法 |
CN114015899A (zh) * | 2021-11-08 | 2022-02-08 | 田世超 | 一种用羟基组合液相还原处理氧化锰矿的方法 |
CN115108588A (zh) * | 2022-07-26 | 2022-09-27 | 贵州金瑞新材料有限责任公司 | 一种氧化锰矿浸出工艺 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2005012582A1 (en) * | 2003-07-30 | 2005-02-10 | Hitec Energy Limited | Improved hydrometallurgical processing of manganese containing materials |
CN103805774A (zh) * | 2014-02-17 | 2014-05-21 | 广西民族大学 | 一种低碳数有机物协同还原软锰矿的方法 |
CN103937973A (zh) * | 2014-04-16 | 2014-07-23 | 广西民族大学 | 一种有机-无机复合还原软锰矿的方法 |
CN106399724A (zh) * | 2016-10-27 | 2017-02-15 | 中南大学 | 一种氧化锰矿的微波还原焙烧与提取方法 |
-
2017
- 2017-12-05 CN CN201711262556.8A patent/CN108220595B/zh active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2005012582A1 (en) * | 2003-07-30 | 2005-02-10 | Hitec Energy Limited | Improved hydrometallurgical processing of manganese containing materials |
CN103805774A (zh) * | 2014-02-17 | 2014-05-21 | 广西民族大学 | 一种低碳数有机物协同还原软锰矿的方法 |
CN103937973A (zh) * | 2014-04-16 | 2014-07-23 | 广西民族大学 | 一种有机-无机复合还原软锰矿的方法 |
CN106399724A (zh) * | 2016-10-27 | 2017-02-15 | 中南大学 | 一种氧化锰矿的微波还原焙烧与提取方法 |
Non-Patent Citations (2)
Title |
---|
卢友志 等: "复合还原剂浸出低品位软锰矿", 《无机盐工业》 * |
王雪婷 等: "木薯生物质酸解制取还原糖并用于软锰矿的还原浸出工艺", 《环境工程学报》 * |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108928853A (zh) * | 2018-08-15 | 2018-12-04 | 广西锰华新能源科技发展有限公司 | 一种锰矿浸出渣的综合回收利用方法 |
CN113957483A (zh) * | 2021-11-08 | 2022-01-21 | 田世超 | 用羟基组合液相还原制备电解锰合格液的方法 |
CN114015899A (zh) * | 2021-11-08 | 2022-02-08 | 田世超 | 一种用羟基组合液相还原处理氧化锰矿的方法 |
CN115108588A (zh) * | 2022-07-26 | 2022-09-27 | 贵州金瑞新材料有限责任公司 | 一种氧化锰矿浸出工艺 |
Also Published As
Publication number | Publication date |
---|---|
CN108220595B (zh) | 2019-11-05 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN108220595B (zh) | 利用木薯干粉和甲醛还原浸出氧化锰矿的方法 | |
CN100491549C (zh) | 从碳酸锰矿石中浸取高价锰的方法 | |
CN102534209B (zh) | 一种氧化锰矿的还原浸出方法 | |
CN101886168B (zh) | 一种半氧化锰矿浸出工艺 | |
CN103937973B (zh) | 一种有机-无机复合还原软锰矿的方法 | |
CN102560107A (zh) | 一种还原浸出氧化锰的方法 | |
CN102676803B (zh) | 从钼镍矿中催化氧化浸出钼和镍的资源化利用方法 | |
CN106432368A (zh) | 一种从造纸黑液中高效提取黄腐酸类物质的方法 | |
CN106601385A (zh) | 报废动力电池正极材料的循环利用方法 | |
CN103805774B (zh) | 一种低碳数有机物协同还原软锰矿的方法 | |
CN104120269A (zh) | 钒渣的综合利用方法 | |
CN107502740B (zh) | 一种从软锰矿浸出渣中回收铁资源方法 | |
CN102229548A (zh) | 一种巯基乙酸的生产方法 | |
CN108251663A (zh) | 利用木薯淀粉还原浸出氧化锰矿的方法 | |
CN104261473A (zh) | 一种五氧化二钒的制备方法 | |
CN102660690A (zh) | 从湿法炼锌高浸渣中回收有价金属的方法 | |
CN101260471B (zh) | 一种采用阳极液提取锰渣中可溶性锰的成套清洁生产工艺 | |
CN103526018A (zh) | 贫锰高铁碳酸锰矿生产电解锰的方法 | |
CN110616329B (zh) | 一种含锡废料中锡的回收方法 | |
CN100480404C (zh) | 一种从石煤中氧化转化浸出钒的方法 | |
CN103738928B (zh) | 一种利用超声强化回收电解锰阳极泥中硒的方法 | |
CN104962734A (zh) | 一种资源化利用菠萝皮与电解锰阳极泥的方法 | |
CN105349778A (zh) | 一种磷铁回收黄磷、氧化铁红及贵重金属的清洁生产方法 | |
CN109112299A (zh) | 一种应用于氧化锰矿生物还原浸出的装置及方法 | |
CN104775033A (zh) | 利用废杂铜循环强化提取高纯铜粉的工艺 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant | ||
CP03 | Change of name, title or address |
Address after: 532399 Xialei Town, Daxin County, Chongzuo City, Guangxi Zhuang Autonomous Region Patentee after: Daxin Manganese Mine Branch of Nanfang Manganese Industry Group Co.,Ltd. Address before: 532121 Daxin Manganese Mine, Xialei Town, Daxin County, Chongzuo City, Guangxi Zhuang Autonomous Region Patentee before: DAXIN MANGANESE MINE BRANCH OF CITIC DAMENG MINING INDUSTRIES Ltd. |
|
CP03 | Change of name, title or address | ||
TR01 | Transfer of patent right |
Effective date of registration: 20211029 Address after: 532399 Xialei Town, Daxin County, Chongzuo City, Guangxi Zhuang Autonomous Region Patentee after: Daxin Manganese Mine Branch of Nanfang Manganese Industry Group Co.,Ltd. Patentee after: Nanfang Manganese Industry Group Co.,Ltd. Address before: 532399 Xialei Town, Daxin County, Chongzuo City, Guangxi Zhuang Autonomous Region Patentee before: Daxin Manganese Mine Branch of Nanfang Manganese Industry Group Co.,Ltd. |
|
TR01 | Transfer of patent right |