CN108219575A - A kind of LED curings high-temperature resistant water transfer ink and preparation method thereof - Google Patents
A kind of LED curings high-temperature resistant water transfer ink and preparation method thereof Download PDFInfo
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- CN108219575A CN108219575A CN201711493478.2A CN201711493478A CN108219575A CN 108219575 A CN108219575 A CN 108219575A CN 201711493478 A CN201711493478 A CN 201711493478A CN 108219575 A CN108219575 A CN 108219575A
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- temperature resistant
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- transfer ink
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/101—Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/14—Printing inks based on carbohydrates
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses a kind of LED curing high-temperature resistant water transfer inks and preparation method thereof.It is mainly made of the component of following parts by weight：20~80 parts of heat resistance epoxy novolac based polyurethanes, 20~40 parts of acrylic resin, 5~25 parts of hydroxyethyl methacrylate, 3~15 parts of sodium carboxymethylcellulose, 2~15 parts of photoinitiator, 0~30 part of pigment, 0.5~5 part of surfactant, 0~2 part of aqueous levelling agent.LED provided by the present invention cures water transfer ink, pass through each component, mutual synergistic effect particularly between the components such as heat resistance epoxy novolac based polyurethanes, acrylic resin, hydroxyethyl methacrylate and sodium carboxymethylcellulose, it can make ink high temperature resistant, meet technological temperature requirement, it is bright-colored, for a long time using colour-fast.
Description
Technical field
The invention belongs to ink areas, and in particular to a kind of LED curings high-temperature resistant water transfer ink and preparation method thereof.
Background technology
Water transfer materials refer to the print film for being capable of global transfer picture and text processed in substrate surface, and base material can be plastics
Film or water-transfer printing paper.For this print film as text carrier, its appearance should be a much progress of printing technology,
Because many products are difficult to directly print, and have this carrier, people can will be schemed by ripe printing technology
Text is first imprinted on the carrier easily printed, then picture and text are transferred on stock.Such as with certain altitude, more bulky,
Extraordinary-looking article or the article of area very little can use transfer printing process.For water transfer printing technique, it is fitted list
Answering property is very wide, almost without the product that cannot be transferred.
Water transfer technique is a kind of special trans-printing new technology, and finished product film quality is stablized after processing, and figure line is clearly forced
Very, the pure and fresh gorgeous, strong adhesive force of color and luster.The technology can the irregular position of polychrome chromatography.Water transfer is divided into water gauge transfer and water drapes over one's shoulders
Transfer is covered, the transfer of word and pattern of drawing a portrait mainly is completed in water gauge transfer, shifts word and description pattern by water decomposition
Onto article to be printed, pattern and word can voluntarily be provided by client.Water coating transfer is tended to carry out in entire product surface
Turn over prints, and coating transfer technique carries picture and text using the aqueous film in a kind of dissolve easily in water.It is curved draped also can be
Product surface adds different lines, such as dermatoglyph, wood grain, decorative pattern, emerald line and marble line, while can also keep away the general plate face print of color
The diastema often occurred in spending.It is widely used in ABS, PP, PE, timber, glass, ceramics, carbon fibre, there are coated metal surfaces etc..It is but existing
Some water transfer inks baking-curing generally at 160~170 DEG C, needs some in the ink of hot setting, then easily exists
Situations such as colour fading occurs under hot conditions, is faint in color.
Invention content
The purpose of the present invention is on the basis of existing technology, provide a kind of LED curing high-temperature resistant water transfer ink and its
Preparation method.
The purpose of the present invention can be achieved by the following measures：
A kind of LED cures high-temperature resistant water transfer ink, it is mainly made of the component of following parts by weight：Heat resistance epoxy novolac
20~80 parts of based polyurethanes, 20~40 parts of acrylic resin, 5~25 parts of hydroxyethyl methacrylate, sodium carboxymethylcellulose 3~
15 parts, 2~15 parts of photoinitiator, 0~30 part of pigment, 0.5~5 part of surfactant, 0~2 part of aqueous levelling agent.
The LED curing high-temperature resistant waters transfer ink of the present invention can only be made of said components, also can be in said components
On the basis of increase other and do not influence the other components of this ink main performance.
In a kind of preferred embodiment, LED curing high-temperature resistant water transfer inks are mainly made of the component of following parts by weight：
30~70 parts of heat resistance epoxy novolac based polyurethanes, 20~30 parts of acrylic resin, 5~20 parts of hydroxyethyl methacrylate, carboxylic
3~10 parts of sodium carboxymethylcellulose pyce, 2~15 parts of photoinitiator, 0~30 part of pigment, 0.5~5 part of surfactant, aqueous levelling agent
0.5~2 part.
In another preferred embodiment, LED cures high-temperature resistant water transfer ink mainly by the component system of following parts by weight
Into：40~60 parts of heat resistance epoxy novolac based polyurethanes, 20~25 parts of acrylic resin, 5~15 parts of hydroxyethyl methacrylate,
3~10 parts of sodium carboxymethylcellulose, 2~10 parts of photoinitiator, 5~20 parts of pigment, 0.5~5 part of surfactant, aqueous levelling
0.5~2 part of agent.
The acrylic resin of the present invention is selected from Weifang Fuller new material CFP7550, CFP7250, CFP5450, Chuzhou Golden Bridge
One or more of De Ke new materials Co., Ltd A-201, A-202, A-203, A-204.
The photoinitiator of the present invention is selected from Tianjin English power science and technology PI-184, PI-TPO, Ai Jian cover resin TPO, TPO-L,
380th, one or more of EMK, BASF Irgacure 369, Irgacure 651.
The pigment of the present invention is preferably selected from Ou Lilong（ORION）Goth black 4A, goth black 250, the good SR2377 titanium dioxides in Shandong east,
Triumphant chemical industry everbright fast yellow 2GX is believed in Belgian Ka Peile Red BG4813C, Hangzhou（C.I. P.Y.74）, Belgian Ka Peile PTM
One or more of 0151N pthalocyanine blues.
Surfactant is preferably selected from Laiyang sage nation organosilicon SI-2047 wetting agents, the German peaceful Cognis PE-100 of section,
Anticipate chemical industry ZY-096 for Shanghai Chinese catalpa, 8 wetting agents of Figure 40 advanced in years, one kind in new ten thousand one-tenth of Hefei environmentally friendly science and technology S-711, S-712, S-713
It is or several.
The aqueous levelling agent of the present invention is preferably selected from modest 432 levelling agent of this moral of hamming, and Guangzhou paulownia reaches chemical industry GLP-333, extensively
Open up hundred million trade B306, Bi Ke chemistry BYK-345, new Hua chemical industry XH-333, Guangzhou Zhong Hao Jing high molecular materials Skytech in state
One or more of LA0490, Skytech LA5333.
The present invention a kind of LED curing high-temperature resistant water transfer ink preparation method be：First by heat resistance phenolic and epoxy
After polyurethane, acrylic resin and hydroxyethyl methacrylate mixing, high-speed stirred uniformly disperses, and then adds in carboxymethyl cellulose
Plain sodium, photoinitiator, pigment, surfactant and aqueous levelling agent, continue stirring at low speed dispersion, reuse three-roller into
Row repeatedly grinding, obtains ink of the fineness below 7.5 μm.
In preparation method, it is preferred that the speed of high-speed stirred is 1000~1200 revs/min, and the speed of stirring at low speed is
600~800 revs/min.
LED provided by the present invention cures water transfer ink, passes through each component, the particularly poly- ammonia of heat resistance phenolic and epoxy
Mutual synergistic effect between the components such as ester, acrylic resin, hydroxyethyl methacrylate and sodium carboxymethylcellulose, can make
Ink high temperature resistant meets technological temperature requirement, bright-colored, for a long time using colour-fast.
Specific embodiment
The solution of the present invention is described further with reference to embodiments, but the scope of the invention is not limited to following
Each embodiment.
The weight and performance of the raw material of Examples 1 to 3 are as shown in table 1.
Table 1
The weight and performance of the raw material of comparative example 1~3 are as shown in table 2.
Table 2
The preparation method of each embodiment：First by heat resistance epoxy novolac based polyurethanes, acrylic resin and hydroxyethyl methacrylate second
After ester mixing, dispersion is stirred evenly with 1000~1200 revs/min of rotating speeds, then adds in sodium carboxymethylcellulose, photoinitiator, face
Material, surfactant and aqueous levelling agent continue 600~800 revs/min of stirring at low speed dispersions, reuse three-roller progress
Repeatedly grinding, obtains ink of the fineness below 7.5 μm.
The preparation method of each comparative example is similar with embodiment.
Ink printing method：Diluent adjustment ink viscosity is added, is stirred 10 minutes, then stand 10 minutes；Use 250-
300 mesh grid screen printings, are printed on water-transfer printing paper；Turned on paper with the curing drying of LED machines cold light source by print and water；It is dry
Transfer paper after dry is attached to pattern layer disengaging positive transfer on glass through soaked.Using face oil guard after going on glass, directly
By 220 DEG C to 20 minutes bakings.
The test method of the present invention is as follows：
Ink form and aspect：U.S.'s Ai Seli X-rite color difference meters test.
Ink gloss：German Bi Ke-Jia Te Grossmeters (gloss meter) test.
Ink adhesion：3M adhesive tapes, the test of hundred lattice, GB/T 9286-1998.
Claims (10)
1. a kind of LED cures high-temperature resistant water transfer ink, it is characterised in that it is mainly made of the component of following parts by weight：It is resistance to
Hot 20~80 parts of epoxy novolac based polyurethanes, 20~40 parts of acrylic resin, 5~25 parts of hydroxyethyl methacrylate, carboxylic first
3~15 parts of base sodium cellulosate, 2~15 parts of photoinitiator, 0~30 part of pigment, 0.5~5 part of surfactant, aqueous levelling agent 0
~2 parts.
2. LED according to claim 1 cures high-temperature resistant water transfer ink, it is characterised in that it is mainly by following parts by weight
Several components are made：30~70 parts of heat resistance epoxy novolac based polyurethanes, 20~30 parts of acrylic resin, hydroxyethyl methacrylate second
5~20 parts of ester, 3~10 parts of sodium carboxymethylcellulose, 2~15 parts of photoinitiator, 0~30 part of pigment, surfactant 0.5~5
Part, 0.5~2 part of aqueous levelling agent.
3. LED according to claim 2 cures high-temperature resistant water transfer ink, it is characterised in that it is mainly by following parts by weight
Several components are made：40~60 parts of heat resistance epoxy novolac based polyurethanes, 20~25 parts of acrylic resin, hydroxyethyl methacrylate second
5~15 parts of ester, 3~10 parts of sodium carboxymethylcellulose, 2~10 parts of photoinitiator, 5~20 parts of pigment, surfactant 0.5~5
Part, 0.5~2 part of aqueous levelling agent.
4. LED according to claim 1 cures high-temperature resistant water transfer ink, it is characterised in that the acrylic resin is selected from
Weifang Fuller new material CFP7550, CFP7250, CFP5450, Chuzhou Golden Bridge De Ke new materials Co., Ltd A-201, A-202,
One or more of A-203, A-204.
5. LED according to claim 1 cures high-temperature resistant water transfer ink, it is characterised in that the photoinitiator is selected from day
Jin Yingli science and technology PI-184, PI-TPO, Ai Jian illiteracy resins TPO, TPO-L, 380, EMK, BASF Irgacure 369,
One or more of Irgacure 651.
6. LED according to claim 1 cures high-temperature resistant water transfer ink, it is characterised in that the pigment is selected from Ou Lilong
（ORION）Goth black 4A, goth black 250, the good SR2377 titanium dioxides in Shandong east, Belgian Ka Peile Red BG4813C, Hangzhou letter triumphantization
Work everbright fast yellow 2GX（C.I. P.Y.74）One or more of, Belgian Ka Peile PTM 0151N pthalocyanine blues.
7. LED according to claim 1 cures high-temperature resistant water transfer ink, it is characterised in that the surfactant is selected from
Laiyang sage nation organosilicon SI-2047 wetting agents, the German peaceful Cognis PE-100 of section, Shanghai Chinese catalpa meaning chemical industry ZY-096 step Figure 40 8
One or more of wetting agent, new ten thousand one-tenth of Hefei environmentally friendly science and technology S-711, S-712, S-713.
8. LED according to claim 1 cures high-temperature resistant water transfer ink, it is characterised in that the aqueous levelling agent is selected from
Modest 432 levelling agent of this moral of hamming, Guangzhou paulownia reach chemical industry GLP-333, and hundred million trade B306, Bi Ke chemistry BYK-345 are opened up in Guangzhou, newly
One or more of Hua chemical industry XH-333, Guangzhou Zhong Hao Jing high molecular materials Skytech LA0490, Skytech LA5333.
9. the preparation method of LED curings high-temperature resistant water transfer ink described in claim 1, it is characterised in that first by heat resistance phenol
After aldehyde epoxy based polyurethanes, acrylic resin and hydroxyethyl methacrylate mixing, high-speed stirred uniformly disperses, and then adds in carboxylic
Sodium carboxymethylcellulose pyce, photoinitiator, pigment, surfactant and aqueous levelling agent continue stirring at low speed dispersion, reuse
Three-roller is repeatedly ground, and obtains ink of the fineness below 7.5 μm.
10. the preparation method of LED curings high-temperature resistant water transfer ink according to claim 6, it is characterised in that the height
The speed of speed stirring is 1000~1200 revs/min, and the speed of the stirring at low speed is 600~800 revs/min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711493478.2A CN108219575A (en) | 2017-12-30 | 2017-12-30 | A kind of LED curings high-temperature resistant water transfer ink and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201711493478.2A CN108219575A (en) | 2017-12-30 | 2017-12-30 | A kind of LED curings high-temperature resistant water transfer ink and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109206958A (en) * | 2018-08-27 | 2019-01-15 | 成都韩尚艺术贴花有限公司 | A kind of gloss oil and preparation method thereof for discharging anion |
-
2017
- 2017-12-30 CN CN201711493478.2A patent/CN108219575A/en not_active Withdrawn
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109206958A (en) * | 2018-08-27 | 2019-01-15 | 成都韩尚艺术贴花有限公司 | A kind of gloss oil and preparation method thereof for discharging anion |
| CN109206958B (en) * | 2018-08-27 | 2020-11-13 | 成都韩尚艺术贴花有限公司 | Gloss oil for releasing negative ions |
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Application publication date: 20180629 |