CN108203151A - A kind of wastewater oxidation system with central tube - Google Patents

A kind of wastewater oxidation system with central tube Download PDF

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Publication number
CN108203151A
CN108203151A CN201810099157.2A CN201810099157A CN108203151A CN 108203151 A CN108203151 A CN 108203151A CN 201810099157 A CN201810099157 A CN 201810099157A CN 108203151 A CN108203151 A CN 108203151A
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CN
China
Prior art keywords
wastewater oxidation
central tube
tank
wastewater
oxidation system
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810099157.2A
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Chinese (zh)
Inventor
李林瑛
张国生
陈康
尹伟
徐建华
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Golden Carbon Environment Technology (tianjin) Co Ltd
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Golden Carbon Environment Technology (tianjin) Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
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Priority to CN201810099157.2A priority Critical patent/CN108203151A/en
Publication of CN108203151A publication Critical patent/CN108203151A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/725Treatment of water, waste water, or sewage by oxidation by catalytic oxidation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/722Oxidation by peroxides
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/76Treatment of water, waste water, or sewage by oxidation with halogens or compounds of halogens
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/30Organic compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/30Organic compounds
    • C02F2101/32Hydrocarbons, e.g. oil
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00Apparatus for treatment of water, waste water or sewage
    • C02F2201/002Construction details of the apparatus
    • C02F2201/007Modular design

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Water Treatment By Sorption (AREA)

Abstract

The present invention relates to a kind of wastewater oxidation systems with central tube, wastewater oxidation system includes wastewater oxidation tank, the wastewater oxidation tank from top to bottom includes upper cover, tank body and lower cover, the upper cover setting water inlet and feeding opening, the lower cover sets water outlet, the tank body upper side setting adsorbent entrance, tank body lower part side set displacer mouth, the absorbing treatment device further includes central tube, described central tube one end is connect with feeding opening, the other end is closed and is stretched to wastewater oxidation tank lower part, and the central tube tube wall is from top to bottom uniformly arranged medicine outlet hole.It is proved by the experimental rig of exploitation, oil content can be removed to 40mg/l from oil-containing 10000mg/l;COD can be removed to from 4800mg/l<20mg/l reaches the quality conditions of high-quality water process raw material.

Description

A kind of wastewater oxidation system with central tube
Technical field
The present invention relates to a kind of wastewater oxidation systems with central tube.
Background technology
Oily wastewater is a kind of pollution sources having a large capacity and a wide range.According to relevant information show in the world annual at least 500- 10000000 tons of oils enter water body by all means.The source of oily waste water is very extensive, essentially from ship, oil Work, the industrial enterprises such as steel, coal gas, machinery, also railway transportation, weaving light industry and people's life can all generate big The oily wastewater of amount.
Oily wastewater after initial gross separation, often can not depth remove organic matter in sewage, so conventional processing Method can not meet local wastewater discharge standard (COD≤60 mg/L), to oil refining enterprise cause it is larger use ground pressure, especially It is in oily wastewater containing a large amount of water-soluble organic matter so that conventional processing method can not meet discharge of wastewater mark It is accurate.
Invention content
In order to solve the above technical problem, the present invention provides a kind of wastewater oxidation system with central tube, the waste water Oxidative system includes wastewater oxidation tank, and the wastewater oxidation tank from top to bottom includes upper cover, tank body and lower cover, the upper cover setting Water inlet and feeding opening, the lower cover set water outlet, the tank body upper side setting adsorbent entrance, tank body lower part side If displacer mouth, the absorbing treatment device further includes central tube, and described central tube one end is connect with feeding opening, other end closing And stretch to wastewater oxidation tank lower part, the central tube tube wall is from top to bottom uniformly arranged medicine outlet hole.
As a kind of perferred technical scheme, the wastewater oxidation system further includes oxidating chemicals tank and oxidating chemicals pump, The oxidating chemicals tank is pumped by oxidating chemicals and is connect with the feeding opening of wastewater oxidation tank.
As a kind of perferred technical scheme, the wastewater oxidation system further includes regenerative agent tank and regenerative agent pump, The regenerative agent tank is pumped by regenerative agent and is connect with the feeding opening of wastewater oxidation tank.
As a kind of perferred technical scheme, the pharmacy jar setting oxidant adds in mouth and acid & alkali liquid adds in mouth.
As a kind of perferred technical scheme, the oxidant is hydrogen peroxide acid solution or sodium hypochlorite alkaline solution.
As a kind of perferred technical scheme, filling adsorption material in the wastewater oxidation tank.
As a kind of perferred technical scheme, the sorbing material is polymer powder.
As a kind of perferred technical scheme, the polymer powder is the foamable polymer powder of the filler containing iron oxide, The content of the filler is 0.1 wt %-30 wt %.
It is proved by the experimental rig of exploitation, oil content can be removed to 40mg/l from oil-containing 10000mg/l;COD can be with It is removed to from 4800mg/l<20mg/l reaches the quality conditions of high-quality water process raw material.Using adsorption and oxidation technology, in matrix Under the action of peroxy, sorbing material, catalyst, organic matter effectively degradation and autoxidation can be realized;If it is considered to water treatment agent Filtering, autoxidation function cannot meet processing target requirement, can add acid hydrogen peroxide and realize and potent help oxidation.
The above-mentioned of the application and other features, aspect and advantage is more readily understood with reference to following detailed description.
Description of the drawings
Fig. 1 is a kind of structure diagram of the wastewater oxidation tank of the wastewater oxidation system with central tube.
Fig. 2 is a kind of structure diagram of the wastewater oxidation system with central tube.
Fig. 3 is a kind of another structure diagram of the wastewater oxidation system with central tube.
Wherein, reference numeral is as follows:
Wastewater oxidation tank 1, oxidating chemicals tank 2, oxidating chemicals pump 3, regenerative agent tank 4, regenerative agent pump 5, oxidant add in mouth 21st, acid & alkali liquid adds in mouth 22, upper cover 11, tank body 12, lower cover 13, water inlet 14, feeding opening 15, water outlet 16, adsorbent entrance 17th, agent mouth 18, central tube 19, medicine outlet hole 191 are changed.
Specific embodiment
Purpose, technical scheme and advantage to make the embodiment of the present invention are clearer, below in conjunction with the embodiment of the present invention Attached drawing, the technical solution of the embodiment of the present invention is clearly and completely described.Obviously, described embodiment is this hair Bright part of the embodiment, instead of all the embodiments.Based on described the embodiment of the present invention, ordinary skill All other embodiment that personnel are obtained under the premise of without creative work, shall fall within the protection scope of the present invention.
Unless otherwise defined, technical term or scientific terminology used herein should be in fields of the present invention and have The ordinary meaning that the personage of general technical ability is understood.Used in present patent application specification and claims " the One ", " second " and similar word are not offered as any sequence, quantity or importance, and are used only to distinguish different Component part.Equally, the similar word such as "one" or " one " does not indicate that quantity limits yet, but represents that there are at least one.
A kind of wastewater oxidation system with central tube, wastewater oxidation system include wastewater oxidation tank, and wastewater oxidation tank is by upper It is set to lower including upper cover, tank body and lower cover, upper cover setting water inlet and feeding opening, lower cover setting water outlet, tank body upper side Put adsorbent entrance, tank body lower part side sets displacer mouth, absorbing treatment device further includes central tube, central tube one end with into medicine Mouth connection, the other end are closed and are stretched to wastewater oxidation tank lower part, and central tube tube wall is from top to bottom uniformly arranged medicine outlet hole.
As a kind of preferred embodiment, wastewater oxidation system further includes oxidating chemicals tank and oxidating chemicals pump, oxidation Pharmacy jar is pumped by oxidating chemicals and is connect with the feeding opening of wastewater oxidation tank.
As a kind of preferred embodiment, wastewater oxidation system further includes regenerative agent tank and regenerative agent pump, regeneration Pharmacy jar is pumped by regenerative agent and is connect with the feeding opening of wastewater oxidation tank.
As a kind of preferred embodiment, pharmacy jar setting oxidant adds in mouth and acid & alkali liquid adds in mouth.
As a kind of preferred embodiment, oxidant is hydrogen peroxide acid solution or sodium hypochlorite alkaline solution.
As a kind of preferred embodiment, filling adsorption material in wastewater oxidation tank.
As a kind of preferred embodiment, sorbing material is polymer powder.Available polymer powder includes poly- Ethylene powder, polypropylene powder, ABS powder, Polystyrene powder, acrylic polymer powder, polyurethane powder.
As a kind of preferred embodiment, polymer powder is the foamable polymer powder of the filler containing iron oxide, optional Polymer powder include polyethylene foamed powder, expanded polypropylene powder, foaming ABS powder, expanded polystyrene (EPS) powder, Foamed propylene acid polymer powder, polyurathamc powder.It, will be poly- by milling apparatus after filler and polymer are foamed together It closes object and is ground to powder, control the grain size of powder at 1-1000 microns.The content of filler is 0.1 wt %-30 wt %.
Embodiment 1
As shown in Fig. 2, a kind of wastewater oxidation system with central tube, wastewater oxidation system includes wastewater oxidation tank, wastewater oxidation Tank from top to bottom includes upper cover, tank body and lower cover, and the upper cover setting water inlet and feeding opening, the lower cover set water outlet, The tank body upper side setting adsorbent entrance, tank body lower part side set displacer mouth, and the absorbing treatment device further includes Central tube, described central tube one end are connect with feeding opening, and the other end is closed and stretched to wastewater oxidation tank lower part, the central tube Tube wall is from top to bottom uniformly arranged medicine outlet hole.Oxidant is hydrogen peroxide acid solution.Filling adsorption material in wastewater oxidation tank.It inhales Enclosure material is polymer powder.Polymer powder is containing iron oxide filler 2wt% polyethylene foamed powder, and the grain size of powder exists 100-200 microns.
Embodiment 2
As shown in Fig. 2, wastewater oxidation tank from top to bottom includes upper cover, tank body and lower cover, upper cover setting water inlet and into medicine Mouthful, the lower cover sets water outlet, and the tank body upper side setting adsorbent entrance, tank body lower part side set displacer mouth, The absorbing treatment device further includes central tube, and described central tube one end is connect with feeding opening, and the other end is closed and stretched to useless Water oxidation tank lower part, the central tube tube wall are from top to bottom uniformly arranged medicine outlet hole.Wastewater oxidation system further includes oxidating chemicals Tank and oxidating chemicals pump, oxidating chemicals tank are pumped by oxidating chemicals and are connect with the feeding opening of wastewater oxidation tank.Pharmacy jar sets oxygen Agent adds in mouth and acid & alkali liquid adds in mouth.Oxidant is hydrogen peroxide acid solution.Filling adsorption material in wastewater oxidation tank.Absorption Material is polymer powder.Polymer powder is containing iron oxide filler 5wt% expanded polypropylene powder, and the grain size of powder exists 200-500 microns.
Embodiment 3
As shown in figure 3, wastewater oxidation tank from top to bottom includes upper cover, tank body and lower cover, upper cover setting water inlet and into medicine Mouthful, the lower cover sets water outlet, and the tank body upper side setting adsorbent entrance, tank body lower part side set displacer mouth, The absorbing treatment device further includes central tube, and described central tube one end is connect with feeding opening, and the other end is closed and stretched to useless Water oxidation tank lower part, the central tube tube wall are from top to bottom uniformly arranged medicine outlet hole.Wastewater oxidation system further includes oxidating chemicals Tank and oxidating chemicals pump, oxidating chemicals tank are pumped by oxidating chemicals and are connect with the feeding opening of wastewater oxidation tank.Pharmacy jar sets oxygen Agent adds in mouth and acid & alkali liquid adds in mouth.Wastewater oxidation system further includes regenerative agent tank and regenerative agent pump, regenerative agent tank It is pumped by regenerative agent and is connect with the feeding opening of wastewater oxidation tank.Oxidant is sodium hypochlorite alkaline solution.In wastewater oxidation tank Filling adsorption material.Sorbing material is polymer powder.Polymer powder is contains iron oxide filler 15wt% polyurathamc powder End, the grain size of powder is at 20-90 microns.
It is proved by the experimental rig of exploitation, oil content can be removed to 40mg/l from oil-containing 10000mg/l;COD can be with It is removed to from 4800mg/l<20mg/l reaches the quality conditions of high-quality water process raw material.Without adsorption and oxidation using the present invention Technology(Polymer powder sorbing material, catalyst, hydrogen peroxide), it is example with embodiment 3, is removed from oil-containing 10000mg/l 1000mg/l can be removed to 2000mg/l, COD from 4800mg/l.And adsorption and oxidation technology using the present invention, then from containing Oily 10000mg/l is removed to 20mg/l, and COD can be removed to 20mg/l from 4800mg/l.
Using adsorption and oxidation technology, under the action of peroxy, sorbing material, iron catalyst, it can realize that organic matter is effective Degradation and autoxidation;After oily wastewater is adsorbed by sorbing material by sorbing material, the hole of central tube can be molten by hydrogen peroxide Liquid infiltrates through sorbing material, and under the action of peroxy, sorbing material, iron catalyst, organic matter is decomposed, so as to fulfill efficient Oxidation.If it is considered to water treatment agent filtering, autoxidation function cannot meet processing target requirement, acid hydrogen peroxide can be added It realizes and potent helps oxidation.After adding acid solution, filler can play the oxidation of bigger.
The foregoing is only a preferred embodiment of the present invention, is not intended to limit the scope of the present invention.It is every The equivalent changes and modifications done according to the content of present invention are encompassed by the scope of the claims of the present invention.

Claims (8)

1. a kind of wastewater oxidation system with central tube, which is characterized in that the wastewater oxidation system includes wastewater oxidation tank, institute It states wastewater oxidation tank and from top to bottom includes upper cover, tank body and lower cover, the upper cover setting water inlet and feeding opening, the lower cover are set Water outlet is put, the tank body upper side setting adsorbent entrance, tank body lower part side set displacer mouth, the adsorption treatment dress It puts and further includes central tube, described central tube one end is connect with feeding opening, and the other end is closed and stretched to wastewater oxidation tank lower part, institute It states central tube tube wall and is from top to bottom uniformly arranged medicine outlet hole.
A kind of 2. wastewater oxidation system with central tube according to claim 1, which is characterized in that the wastewater oxidation system System further includes oxidating chemicals tank and oxidating chemicals pump, and the oxidating chemicals tank is by oxidating chemicals pump and wastewater oxidation tank into medicine Mouth connection.
A kind of 3. wastewater oxidation system with central tube according to claim 1, which is characterized in that the wastewater oxidation system System further includes regenerative agent tank and regenerative agent pump, and the regenerative agent tank is by regenerative agent pump and wastewater oxidation tank into medicine Mouth connection.
A kind of 4. wastewater oxidation system with central tube according to claim 1, which is characterized in that the pharmacy jar setting Oxidant adds in mouth and acid & alkali liquid adds in mouth.
5. a kind of wastewater oxidation system with central tube according to claim 4, which is characterized in that the oxidant is double Oxygen water acid solution or sodium hypochlorite alkaline solution.
A kind of 6. wastewater oxidation system with central tube according to claim 1, which is characterized in that the wastewater oxidation tank Interior filling adsorption material.
7. a kind of wastewater oxidation system with central tube according to claim 6, which is characterized in that the sorbing material is Polymer powder.
A kind of 8. wastewater oxidation system with central tube according to claim 7, which is characterized in that the polymer powder Foamable polymer powder for the filler containing iron oxide.
CN201810099157.2A 2018-01-31 2018-01-31 A kind of wastewater oxidation system with central tube Pending CN108203151A (en)

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Application Number Priority Date Filing Date Title
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110790688A (en) * 2019-10-09 2020-02-14 江苏远洋药业股份有限公司 A device for taurine fine work mother liquor purifies

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101555060A (en) * 2009-05-20 2009-10-14 南京工业大学 Supercritical water oxidation reactor
CN203530001U (en) * 2013-11-19 2014-04-09 宁波市恒洁水务发展有限公司 Reactor for activating advanced oxidation by persulfate
CN204162544U (en) * 2014-10-24 2015-02-18 湖南迪亚环境工程有限公司 A kind of equipment of light electrolysis associating Fenton process fracturing wastewater
CN204824306U (en) * 2015-07-17 2015-12-02 北京中凯兴业投资管理有限公司 Difficult degradation organic waste water pretreatment systems and hopcalite canister thereof
CN205061738U (en) * 2015-08-20 2016-03-02 陕西立佳环保工程有限公司 Clarifier is adsorbed with fixed attention to high -efficient mixing
CN205151957U (en) * 2015-11-11 2016-04-13 四川希望环保工程技术有限公司 Heterogeneous fenton reaction ware
CN105585103A (en) * 2016-01-26 2016-05-18 江苏赛欧环保设备有限公司 Oxidizing tank
CN205367992U (en) * 2016-01-26 2016-07-06 博天环境集团股份有限公司 Compound ozone catalytic oxidation reaction tower
CN206810286U (en) * 2017-06-19 2017-12-29 江苏绿和源节能科技有限公司 A kind of oxidation tank
CN208022765U (en) * 2018-01-31 2018-10-30 金碳环境科技(天津)有限公司 A kind of wastewater oxidation system with central tube

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101555060A (en) * 2009-05-20 2009-10-14 南京工业大学 Supercritical water oxidation reactor
CN203530001U (en) * 2013-11-19 2014-04-09 宁波市恒洁水务发展有限公司 Reactor for activating advanced oxidation by persulfate
CN204162544U (en) * 2014-10-24 2015-02-18 湖南迪亚环境工程有限公司 A kind of equipment of light electrolysis associating Fenton process fracturing wastewater
CN204824306U (en) * 2015-07-17 2015-12-02 北京中凯兴业投资管理有限公司 Difficult degradation organic waste water pretreatment systems and hopcalite canister thereof
CN205061738U (en) * 2015-08-20 2016-03-02 陕西立佳环保工程有限公司 Clarifier is adsorbed with fixed attention to high -efficient mixing
CN205151957U (en) * 2015-11-11 2016-04-13 四川希望环保工程技术有限公司 Heterogeneous fenton reaction ware
CN105585103A (en) * 2016-01-26 2016-05-18 江苏赛欧环保设备有限公司 Oxidizing tank
CN205367992U (en) * 2016-01-26 2016-07-06 博天环境集团股份有限公司 Compound ozone catalytic oxidation reaction tower
CN206810286U (en) * 2017-06-19 2017-12-29 江苏绿和源节能科技有限公司 A kind of oxidation tank
CN208022765U (en) * 2018-01-31 2018-10-30 金碳环境科技(天津)有限公司 A kind of wastewater oxidation system with central tube

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110790688A (en) * 2019-10-09 2020-02-14 江苏远洋药业股份有限公司 A device for taurine fine work mother liquor purifies

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Inventor after: Li Linying

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