CN108192255A - Entity plane materiel based on acrylic-styrene copolymerized resin and preparation method thereof - Google Patents
Entity plane materiel based on acrylic-styrene copolymerized resin and preparation method thereof Download PDFInfo
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- CN108192255A CN108192255A CN201711459861.6A CN201711459861A CN108192255A CN 108192255 A CN108192255 A CN 108192255A CN 201711459861 A CN201711459861 A CN 201711459861A CN 108192255 A CN108192255 A CN 108192255A
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- parts
- acrylic
- plane materiel
- styrene
- entity plane
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
- C08J2333/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
- C08J2333/06—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C08J2333/10—Homopolymers or copolymers of methacrylic acid esters
- C08J2333/12—Homopolymers or copolymers of methyl methacrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polymerisation Methods In General (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Graft Or Block Polymers (AREA)
Abstract
The invention discloses a kind of entity plane materiels based on acrylic styrene copolymerized resin and preparation method thereof, wherein entity plane materiel includes 100 parts of acrylic styrene copolymerized resins, 150 400 parts of aluminium hydrate powders, 0.1 5 parts of titanium dioxides, 0.5 15 parts acrylate cross linked dose, 0.1 3 parts of curing agent, wherein, the acrylic styrene copolymerized resin is methyl methacrylate, styrene, polymerization initiator are copolymerized after mixing in proportion.The present invention has opened up entity plane materiel raw material channel, it changes because of the original predicament in short supply brought of single acryl resin, the entity plane materiel chemical property produced using acrylic styrene copolymerized resin is significantly improved, more than bending strength 52Mpa, impact strength 4.8kJ/cm2More than；Styrene material price is only the half of MMA, and cost is substantially reduced.
Description
Technical field
The present invention relates to chemical field, more particularly to a kind of entity plane materiel based on acrylic-styrene copolymerized resin
And preparation method thereof.
Background technology
The production of acrylic entity plane materiel has more than 20 years history, is mixed with acryl resin with filler (aluminium hydroxide),
It adds in crosslinking agent, initiator stirring pulping, be cast in 60 DEG C of polymerisations 3 hours, curing reaction 2 hours after 120 DEG C of drying chambers,
Obtain entity plane materiel.The technique presently, there are the problem of：1st, mechanical property is relatively low, impact strength 3.4kJ/cm2, bending strength
48Mpa；2nd, the primary raw material MMA prices of acryl resin are too high, and entity plane materiel production cost is high.
Invention content
The technical problems to be solved by the invention exactly propose a kind of entity based on acrylic-styrene copolymerized resin
Plane materiel and preparation method thereof, it is of the invention by MMA and two kinds of monomer copolymerizations of styrene so that copolymer resins are given birth to applied to entity plane materiel
Production, performance is better than traditional handicraft, and cost is substantially reduced.
In order to solve the above technical problems, the present invention is achieved by the following scheme：
A kind of entity plane materiel based on acrylic-styrene copolymerized resin includes the raw material of following parts by weight：
Wherein, the acrylic-styrene copolymerized resin includes the raw material of following parts by weight：
100 parts of methyl methacrylate；
1-100 parts of styrene；
0.01-0.5 parts of polymerization initiator.
A kind of entity plane materiel based on acrylic-styrene copolymerized resin includes the raw material of following parts by weight：
Wherein, the acrylic-styrene copolymerized resin includes the raw material of following parts by weight：
100 parts of methyl methacrylate；
20 parts of styrene；
0.12 part of polymerization initiator.
Preferably, the polymerization initiator is benzoyl peroxide.
Preferably, described acrylate cross linked dose is dimethacrylate succinate.
Preferably, the curing agent is perbenzoic acid methyl esters.
A kind of preparation method of the entity plane materiel based on acrylic-styrene copolymerized resin, includes the following steps：
It is prepared by S1, acrylic-styrene copolymerized resin
100 parts of methyl methacrylate and 1-100 parts of styrene are put into reaction kettle, chuck is warming up to 70-80 DEG C,
0.01-0.5 parts of polymerization initiator is added in, in 80-100 DEG C of polymerisation 80-120 minutes, is cooled to 25-40 DEG C, get Ya Ke
Power-styrene copolymerized resin；
It is prepared by S2, entity plane materiel
By 100 parts of acrylic-styrene copolymerized resins and 150-400 parts of aluminium hydrate powders, 0.1-5 parts of titanium dioxides, 0.5-
15 parts acrylate cross linked dose and 0.1-3 parts of curing agent add in mixing kettles and stir evenly, and steel band line is cast in after vacuum defoamation
On, reaction in 18-40 minutes finishes, and process is sized, polishes after, obtains entity plane materiel.
Preferably, in the step S1, acrylic-styrene copolymerized resin preparation process is：By 100 parts of methyl
Methyl acrylate and 20 parts of styrene input reaction kettle, chuck are warming up to 70-80 DEG C, add in 0.12 part of polymerization initiator,
In 80-100 DEG C of polymerisation 80-120 minutes, 25-40 DEG C is cooled to, obtains acrylic-styrene copolymerized resin.
Preferably, in the step S2, entity plane materiel preparation process is：By 100 parts of acrylics-styrene copolymerized tree
It is equal that fat and 200 parts of aluminium hydrate powders, 2 parts of titanium dioxides, 5 parts acrylate cross linked dose and 2 parts of curing agent add in mixing kettle stirring
It is even, it is cast in after vacuum defoamation on steel band line, reaction in 18-40 minutes finishes, and process is sized, polishes after, obtains entity plane materiel.
Preferably, the polymerization initiator is benzoyl peroxide.
Preferably, described acrylate cross linked dose is dimethacrylate succinate.
Preferably, the curing agent is perbenzoic acid methyl esters.
Compared with prior art, the device have the advantages that being：
1st, opened up entity plane materiel raw material channel, change because single acryl resin it is original it is in short supply bring it is tired
Border.
2nd, the entity plane materiel chemical property of acrylic-styrene copolymerized resin production is significantly improved, bending strength 52Mpa
More than, impact strength 4.8kJ/cm2More than.
3rd, styrene material price is only the half of MMA, and cost is substantially reduced.
Specific embodiment
The present invention is got information about for those skilled in the art is allowed to be more clear, the present invention will be made below further
Explanation.
Embodiment 1
A kind of entity plane materiel based on acrylic-styrene copolymerized resin includes the raw material of following parts by weight：
Wherein, the acrylic-styrene copolymerized resin includes the raw material of following parts by weight：
100 parts of methyl methacrylate；
1 part of styrene；
0.001 part of benzoyl peroxide.
Embodiment 2
A kind of entity plane materiel based on acrylic-styrene copolymerized resin includes the raw material of following parts by weight：
Wherein, the acrylic-styrene copolymerized resin includes the raw material of following parts by weight：
100 parts of methyl methacrylate；
20 parts of styrene；
0.12 part of benzoyl peroxide.
Embodiment 3
A kind of entity plane materiel based on acrylic-styrene copolymerized resin includes the raw material of following parts by weight：
Wherein, the acrylic-styrene copolymerized resin includes the raw material of following parts by weight：
100 parts of methyl methacrylate；
100 parts of styrene；
0.5 part of benzoyl peroxide.
The preparation method for the entity plane materiel that embodiment 1-3 is related to, includes the following steps：
It is prepared by S1, acrylic-styrene copolymerized resin
Methyl methacrylate and styrene are first put into reaction kettle, chuck is warming up to 70-80 DEG C, adds in 0.01-0.5 parts
Benzoyl peroxide, in 80-100 DEG C of polymerisation 80-120 minutes, be cooled to 25-40 DEG C, obtain acrylic-styrene copolymerized
Resin；
It is prepared by S2, entity plane materiel
By acrylic-styrene copolymerized resin and aluminium hydrate powder, titanium dioxide, dimethacrylate succinate and mistake
Oxidation methyl benzoate adds in mixing kettle and stirs evenly, and is cast in after vacuum defoamation on steel band line, and reaction in 18-40 minutes finishes,
Process is sized, polishes after, obtains entity plane materiel.
The application that the present invention passes through acrylic-styrene copolymerized resin so that entity plane materiel chemical property is significantly improved,
Bending strength reaches more than 52Mpa, and impact strength reaches 4.8kJ/cm2More than.
The acrylic entity plane materiel that embodiment 2 is prepared is tested, as a result such as following table：
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all essences in the present invention
With within principle, any modification, equivalent replacement, improvement and so on should all be included in the protection scope of the present invention god.
Claims (10)
1. a kind of entity plane materiel based on acrylic-styrene copolymerized resin, which is characterized in that include the original of following parts by weight
Material：
Wherein, the acrylic-styrene copolymerized resin includes the raw material of following parts by weight：
100 parts of methyl methacrylate；
1-100 parts of styrene；
0.01-0.5 parts of polymerization initiator.
2. a kind of entity plane materiel based on acrylic-styrene copolymerized resin, which is characterized in that include the original of following parts by weight
Material：
Wherein, the acrylic-styrene copolymerized resin includes the raw material of following parts by weight：
100 parts of methyl methacrylate；
20 parts of styrene；
0.12 part of polymerization initiator.
3. entity plane materiel according to claim 1 or 2, which is characterized in that the polymerization initiator is benzoyl peroxide.
4. entity plane materiel according to claim 1 or 2, which is characterized in that described acrylate cross linked dose is dimethyl propylene
Olefin(e) acid succinate.
5. entity plane materiel according to claim 1 or 2, which is characterized in that the curing agent is perbenzoic acid methyl esters.
6. a kind of preparation method of the entity plane materiel based on acrylic-styrene copolymerized resin, which is characterized in that including walking as follows
Suddenly：
It is prepared by S1, acrylic-styrene copolymerized resin
100 parts of methyl methacrylate and 1-100 parts of styrene are put into reaction kettle, chuck is warming up to 70-80 DEG C, adds in
0.01-0.5 parts of polymerization initiator in 80-100 DEG C of polymerisation 80-120 minutes, is cooled to 25-40 DEG C, obtains acrylic-benzene
Ethylene copolymer；
It is prepared by S2, entity plane materiel
By 100 parts of acrylic-styrene copolymerized resins and 150-400 parts of aluminium hydrate powders, 0.1-5 parts of titanium dioxides, 0.5-15 parts
Acrylate cross linked dose and 0.1-3 parts of curing agent add in mixing kettles and stir evenly, and are cast in after vacuum defoamation on steel band line,
Reaction in 18-40 minutes finishes, and process is sized, polishes after, obtains entity plane materiel.
7. according to the method described in claim 6, it is characterized in that, in the step S1, acrylic-styrene copolymerized resin system
It is for step：100 parts of methyl methacrylate and 20 parts of styrene are put into reaction kettle, chuck is warming up to 70-80 DEG C, adds
Enter 0.12 part of polymerization initiator, in 80-100 DEG C of polymerisation 80-120 minutes, be cooled to 25-40 DEG C, obtain acrylic-benzene second
Alkene copolymer resins；
In the step S2, entity plane materiel preparation process is：By 100 parts of acrylic-styrene copolymerized resins and 200 parts of hydroxides
Aluminium powder, 2 parts of titanium dioxides, 5 parts acrylate cross linked dose and 2 parts of curing agent add in mixing kettle and stir evenly, and are poured after vacuum defoamation
It notes on steel band line, reaction in 18-40 minutes finishes, and process is sized, polishes after, obtains entity plane materiel.
8. the method described according to claim 6 or 7, which is characterized in that the polymerization initiator is benzoyl peroxide.
9. the method described according to claim 6 or 7, which is characterized in that described acrylate cross linked dose is dimethacrylate
Succinate.
10. the method described according to claim 6 or 7, which is characterized in that the curing agent is perbenzoic acid methyl esters.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711459861.6A CN108192255A (en) | 2017-12-28 | 2017-12-28 | Entity plane materiel based on acrylic-styrene copolymerized resin and preparation method thereof |
| PCT/CN2017/119703 WO2019127316A1 (en) | 2017-12-28 | 2017-12-29 | Acylic-styrene copolymer resin-based solid surfacing material and preparation method therefor |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711459861.6A CN108192255A (en) | 2017-12-28 | 2017-12-28 | Entity plane materiel based on acrylic-styrene copolymerized resin and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108192255A true CN108192255A (en) | 2018-06-22 |
Family
ID=62585004
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711459861.6A Pending CN108192255A (en) | 2017-12-28 | 2017-12-28 | Entity plane materiel based on acrylic-styrene copolymerized resin and preparation method thereof |
Country Status (2)
| Country | Link |
|---|---|
| CN (1) | CN108192255A (en) |
| WO (1) | WO2019127316A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108929402A (en) * | 2018-09-04 | 2018-12-04 | 厦门纬达树脂有限公司 | A kind of solution-type acrylic solution slurry production method |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0863167A1 (en) * | 1997-03-04 | 1998-09-09 | Mitsubishi Gas Chemical Company, Inc. | Process for producing a copolymer |
| CN102181115A (en) * | 2011-02-12 | 2011-09-14 | 台州艾斐建材有限公司 | Polymethyl methacrylate product and preparation method thereof |
| CN104945556A (en) * | 2015-07-14 | 2015-09-30 | 苏州双象光学材料有限公司 | Preparation method of methyl methacrylate-styrene copolymer |
| CN106986578A (en) * | 2017-05-03 | 2017-07-28 | 珠海市盛西源机电设备有限公司 | A kind of acrylic entity plane materiel of artificial marble and preparation method thereof |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101545191B1 (en) * | 2013-11-22 | 2015-08-18 | 엘지엠엠에이 주식회사 | Manufacturing method of acrylic copolymer with excellent chemical resistance and weather resistance |
-
2017
- 2017-12-28 CN CN201711459861.6A patent/CN108192255A/en active Pending
- 2017-12-29 WO PCT/CN2017/119703 patent/WO2019127316A1/en active Application Filing
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0863167A1 (en) * | 1997-03-04 | 1998-09-09 | Mitsubishi Gas Chemical Company, Inc. | Process for producing a copolymer |
| CN102181115A (en) * | 2011-02-12 | 2011-09-14 | 台州艾斐建材有限公司 | Polymethyl methacrylate product and preparation method thereof |
| CN104945556A (en) * | 2015-07-14 | 2015-09-30 | 苏州双象光学材料有限公司 | Preparation method of methyl methacrylate-styrene copolymer |
| CN106986578A (en) * | 2017-05-03 | 2017-07-28 | 珠海市盛西源机电设备有限公司 | A kind of acrylic entity plane materiel of artificial marble and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108929402A (en) * | 2018-09-04 | 2018-12-04 | 厦门纬达树脂有限公司 | A kind of solution-type acrylic solution slurry production method |
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| Publication number | Publication date |
|---|---|
| WO2019127316A1 (en) | 2019-07-04 |
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Application publication date: 20180622 |
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