CN108158035A - A kind of wingceltis skin, sugarcane fiber composite paper filter material and its preparation method and application - Google Patents

A kind of wingceltis skin, sugarcane fiber composite paper filter material and its preparation method and application Download PDF

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Publication number
CN108158035A
CN108158035A CN201810027287.5A CN201810027287A CN108158035A CN 108158035 A CN108158035 A CN 108158035A CN 201810027287 A CN201810027287 A CN 201810027287A CN 108158035 A CN108158035 A CN 108158035A
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China
Prior art keywords
preparation
filter material
paper
paper filter
wingceltis
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CN201810027287.5A
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CN108158035B (en
Inventor
殷沛沛
董高峰
和智君
高锐
王保兴
马迅
宋鹏飞
余贺龙
唐丽
杨威
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China Tobacco Yunnan Industrial Co Ltd
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China Tobacco Yunnan Industrial Co Ltd
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    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/02Manufacture of tobacco smoke filters
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/06Use of materials for tobacco smoke filters
    • A24D3/08Use of materials for tobacco smoke filters of organic materials as carrier or major constituent
    • A24D3/10Use of materials for tobacco smoke filters of organic materials as carrier or major constituent of cellulose or cellulose derivatives
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/06Use of materials for tobacco smoke filters
    • A24D3/14Use of materials for tobacco smoke filters of organic materials as additive

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Paper (AREA)

Abstract

The present invention relates to a kind of wingceltis skins, sugarcane fiber composite paper filter material and its preparation method and application, which includes the following steps:Step(1), paper substrate preparation;Step(2), coating fluid preparation;Step(3), paper filter material preparation.The present invention is reasonably combined by wingceltis skin long fibre and bagasse staple fiber, tensile strength and the preferable paper substrate of pliability are obtained, the dark plum and licorice for the invention paper substrate are developed simultaneously, and aesthetic quality caused by solving the problems, such as traditionally on paper filter material reduces.For that can assign cigarette smoke sweetness note after cigarette filter rod, wooden miscellaneous gas, irritation and dry sensation are declined the Novel plant fiber composite paper filter material of the present invention, and residual is smaller, and pleasant impression is sour-sweet.

Description

A kind of wingceltis skin, sugarcane fiber composite paper filter material and its preparation method and application
Technical field
The present invention relates to a kind of composite paper filter material, especially wingceltis skin, sugarcane fiber composite paper filter materials, further relate to its system Preparation Method and application belong to cigarette filter rod field of new materials.
Background technology
Cigarette filter is the main cigarette supplementary of tobacco business, the selection of cigarette filter rod material to the suction quality of cigarette and Tar reduction has significant impact.Compared with the cellulose acetate filter rod being commonly used, paper filter stick is in tar reduction, cost and environmental protection It is upper that there is apparent advantage, but there are flue gas is dry, irritation is big, there have to be apparent wooden when cigarette is aspirated for paper filter stick cigarette The shortcomings of gas, bitter pleasant impression, is difficult to it commonly used in cigarette.The research report being modified both at home and abroad about paper filter stick at present Still using pure wood pulp cellulose paper or bamboo pulp fiber paper as carrier, the defects of paper filter stick, does not obtain the improvement of essence in road.Therefore, it seeks Asking and developing Novel plant fiber material has become one of new tool for improving paper filter stick quality.
Wingceltis, alias wingceltis skin tree, scaling elm, wing Piao, belongs to Ulmaceae wingceltis category deciduous tree, is the distinctive fiber tree in China Kind.The bast fiber (abbreviation wingceltis skin) of wingceltis limb be manufacture rice paper primary raw material, the rice paper manufactured with Barks of Pteroceltis Tatarinowii, Have the characteristics that small strong adsorption, deformation, long lifespan, anti-aging, insect prevention keep away moth, paper is made to reach thin, soft, light, tough, thin, white Peculiar artistic effect.The holocellulose content of wingceltis skin is 61.43%, content of lignin 9.03%, content of ashes 5.07%, From the point of view of its chemical composition, the content of lignin of wingceltis skin is relatively low, easy slurrying, but pulping yield is than relatively low, calcium carbonate in wingceltis skin Content is high, is conducive to enhance the ink wetting capability of rice paper, the cell wall thickness of wingceltis hide fiber, microfibril is more, and gap therebetween is also more, makes a surname The absorbency of paper is fine, and the average length of wingceltis hide fiber is 2.95 mm, and expansion is preferable, and mean breadth is 10.99 μm, length and width It is big compared with general softwood fiber than being 268(Economic forest is studied, 2007,25 (4):28-33).
In view of the material property of wingceltis hide fiber, attempt itself and compound rear prepare of sugarcane fiber being used for papery cigarette filter stick Paper filter material, not yet occur pertinent literature and report at present.
Invention content
To solve the above-mentioned problems, the invention reside in the preparation sides for providing a kind of wingceltis skin, sugarcane fiber composite paper filter material Application of the composite paper filter material that method and this method obtain in papery cigarette filter stick or composite filter.
The present invention mixes wingceltis hide fiber and sugarcane fiber match after manufacture paper with pulp into paper filter material paper substrate, paper substrate is carried through dark plum and Radix Glycyrrhizae Take liquid coating, it is dry after wingceltis skin, sugarcane fiber composite paper filter material is made, common paper filter stick can be improved and inhale that taste is poor to be lacked It falls into.
The purpose of the present invention is realized especially by following technical scheme:
The preparation method of a kind of wingceltis skin, sugarcane fiber composite paper filter material, is made by the steps:
Step(1), paper substrate preparation:Commercially available wingceltis leather board and bagasse paddle board are taken according to dry weight(6-9):(1-4)Into Row is mixed and is matched, through hydraulic pulping, discongest after with PFI fiberizers carries out defibrination, slurry concentration is mass fraction 5-9%, control beating degree In 35-42 oSR, molding of manufacturing paper with pulp on sheet forming machine after conven-tional adjuvants is added in the slurry, and page is spare after drying;
Step(2), coating fluid preparation:Dark plum and Radix Glycyrrhizae are taken according to mass ratio 3:7-7:Heat is carried out after 3 mixing are broken with water to return Stream extracts to obtain extracting solution, and solid-liquid ratio during extraction is 1:25-1:35, Extracting temperature is 60-70 DEG C, time 1.5-3h;It will carry Liquid is taken to carry out being concentrated under reduced pressure into the 1/4 of original volume after filtering, obtains concentrate, is then added in and concentrate isometric 95% Ethyl alcohol carries out alcohol precipitation, and supernatant liquor is taken after centrifugation as coating fluid;
Step(3), paper filter material preparation:By step(2)The coating solution of preparation is in step(1)It is dried after on the paper substrate of preparation Dry, wherein additive amount of the coating fluid on paper substrate is 0.3%-0.8%.
When the present invention is not added with any extracting solution, fresh and sweet note is had, reduces wooden miscellaneous gas, but it is had on aesthetic quality His defect, the present invention is innovative to be developed dark plum and licorice extract and is coated on the compound paper substrate of wingceltis skin, sugarcane fiber, should Composite paper filter material can reduce the stimulation of flue gas, while increase the moisture feeling of flue gas after being used for filter stick, improve the comfort in oral cavity And the sour-sweet sense of pleasant impression.
Wingceltis skin long fibre and bagasse staple fiber are interweaved so that and the institutional framework prepared inside paper substrate is loose porous, The tensile strength and pliability of paper substrate are superior to paper substrate prepared by conventional wood pulp cellulose, and flue gas can be reduced after being used for cigarette filter rod Tar.In terms of aesthetic quality, after paper substrate is coated with dark plum and licorice extract, the integrated sensory of composite paper filter material is improved Quality.
Further, step(1)In, control quantification of 37 ± 1g/m of page2, thickness is 0.12 ± 0.02 mm.
Further, step(2)In, it carries out being concentrated under reduced pressure into the 1/4 of original volume after extracting solution filtering.
It is of the present invention to use wingceltis skin made from above-mentioned preparation method, sugarcane fiber Compound filtering material.
Above-mentioned wingceltis skin of the present invention, sugarcane fiber composite paper filter material are in papery cigarette filter stick or composite filter Application.
Compared with prior art, the advantage of the invention is that:
(1), by wingceltis skin long fibre and the intertexture of bagasse staple fiber, the tensile strength and pliability of paper substrate are superior to conventional wood pulp Paper substrate prepared by fiber, for that can reduce tarry matters in smoke after cigarette filter rod, a kind of Novel plant fiber is provided for paper filter material Material.
(2), the present invention develop for the dark plum and licorice of the invention composite paper filter material paper substrate, solve biography The problem of flue gas caused by paper filter material of uniting is dry, stimulation is larger, texture declines, pleasant impression is bitter.
(3), the present invention composite paper filter material fresh and sweet note can be brought when cigarette is aspirated for cigarette filter rod, it is wooden miscellaneous Gas, irritation and dry sensation are declined, and fragrance is clear, fine and smooth, and moisture feeling is preferable, and residual is smaller, and pleasant impression is sour-sweet.
Specific embodiment
The present invention is clearly and completely described with reference to the technical solution in embodiment, it is clear that described reality It is only part of the embodiment of the present invention to apply example, instead of all the embodiments.Those skilled in the art are not paying creation Property labour under the premise of all other embodiments obtained, shall fall within the protection scope of the present invention.
Embodiment 1
The wingceltis skin of the present embodiment, the preparation method of sugarcane fiber composite paper filter material, are made by the steps:
(1)The preparation of paper substrate:Commercially available wingceltis leather board and bagasse paddle board are taken according to the 6 of dry weight:4 mix matching, through waterpower Pulping with PFI fiberizers carries out defibrination after discongesting, and slurry concentration is mass fraction 5%, and beating degree is 35 oSR, is added in the slurry Add molding of manufacturing paper with pulp on sheet forming machine after conven-tional adjuvants, page is spare after drying.Control quantification of 37 ± 1 g/ of page M2, thickness are 0.12 ± 0.02 mm;
(2)The preparation of coating fluid:Dark plum and Radix Glycyrrhizae are taken according to mass ratio 7:Carrying out circumfluence distillation with water after 3 mixing are broken must carry Take liquid, solid-liquid ratio during extraction(w/v)It is 1:30, Extracting temperature is 65 DEG C, and the time is 2 h.Subtract after extracting solution is filtered Pressure is concentrated into the 1/4 of original volume, and then the ethyl alcohol of isometric addition 95% carries out alcohol precipitation, and supernatant liquor is taken to be used as after centrifugation and is applied Cloth liquid;
(3)The preparation of paper filter material:By step(2)The coating solution of preparation is in step(1)It is dried after on the paper substrate of preparation, Additive amount of the middle coating fluid on paper substrate is 0.3%.
By obtained paper filter material, routinely papery cigarette filter stick or composite filter is made in technique.
Embodiment 2
The wingceltis skin of the present embodiment, the preparation method of sugarcane fiber composite paper filter material, are made by the steps:
(1)The preparation of paper substrate:Commercially available wingceltis leather board and bagasse paddle board are taken according to the 9 of dry weight:1 mix matching, through waterpower Pulping with PFI fiberizers carries out defibrination after discongesting, and slurry concentration is mass fraction 8%, and beating degree is 38 oSR, is added in the slurry Add molding of manufacturing paper with pulp on sheet forming machine after conven-tional adjuvants, page is spare after drying.Control quantification of 37 ± 1g/ of page M2, thickness are 0.12 ± 0.02mm;
(2)The preparation of coating fluid:Dark plum and Radix Glycyrrhizae are taken according to mass ratio 3:Carrying out circumfluence distillation with water after 7 mixing are broken must carry Take liquid, solid-liquid ratio during extraction(w/v)It is 1:25, Extracting temperature is 60 DEG C, and the time is 3 h.Subtract after extracting solution is filtered Pressure is concentrated into the 1/4 of original volume, and then the ethyl alcohol of isometric addition 95% carries out alcohol precipitation, and supernatant liquor is taken to be used as after centrifugation and is applied Cloth liquid;
(3)The preparation of paper filter material:By step(2)The coating solution of preparation is in step(1)It is dried after on the paper substrate of preparation, Additive amount of the middle coating fluid on paper substrate is 0.5%.
By obtained paper filter material, routinely papery cigarette filter stick or composite filter is made in technique.
Embodiment 3
The wingceltis skin of the present embodiment, the preparation method of sugarcane fiber composite paper filter material, are made by the steps:
(1)The preparation of paper substrate:Commercially available wingceltis leather board and bagasse paddle board are taken according to the 8 of dry weight:2 mix matching, through waterpower Pulping with PFI fiberizers carries out defibrination after discongesting, and slurry concentration is mass fraction 9%, and beating degree is 42 oSR, is added in the slurry Add molding of manufacturing paper with pulp on sheet forming machine after conven-tional adjuvants, page is spare after drying.Control quantification of 37 ± 1 g/ of page M2, thickness are 0.12 ± 0.02 mm;
(2)The preparation of coating fluid:Dark plum and Radix Glycyrrhizae are taken according to mass ratio 4:Carrying out circumfluence distillation with water after 6 mixing are broken must carry Take liquid, solid-liquid ratio during extraction(w/v)It is 1:35, Extracting temperature is 60 DEG C, and the time is 1.5 h.It is carried out after extracting solution is filtered The 1/4 of original volume is concentrated under reduced pressure into, then the ethyl alcohol of isometric addition 95% carries out alcohol precipitation, and supernatant liquor conduct is taken after centrifugation Coating fluid;
(3)The preparation of paper filter material:By step(2)The coating solution of preparation is in step(1)It is dried after on the paper substrate of preparation, Additive amount of the middle coating fluid on paper substrate is controlled 0.8%.
By obtained paper filter material, routinely papery cigarette filter stick or composite filter is made in technique.
By wingceltis skin prepared by embodiment 1-3, sugarcane fiber composite paper filter material with compareing wood pulp and bamboo pulp fiber paper filter material point Not Qu Yang after carry out the detection of tensile strength and pliability, use《The measure of paper and cardboard tensile strength》(GB/T 12914- 2008)With《The measure of paper pliability》(GB/T 8942-2016)Standard method carries out, and the results are shown in Table 1.
As it can be seen from table 1 the tensile strength and pliability of the wingceltis skin of the invention prepared, sugarcane fiber composite paper filter material It is superior to traditional wood pulp and bamboo pulp fiber paper filter material.
The tensile strength of 1 paper filter material of table and pliability testing result
Wingceltis skin prepared by examples detailed above 1-3, sugarcane fiber composite paper filter material are rolled using paper filter stick conventional molding processes Into paper filter stick, be then combined into composite filter and cigarette sample with vinegar fibre filter stick, using traditional wood pulp cellulose paper filter stick as Control carries out comparative evaluation's analysis to the conventional fume indication of cigarette sample and aesthetic quality, wherein the inspection of conventional fume indication Survey according to GB/T19609-2004, GB/T23355-2009, GB/T23203.1-2008, GB/T23356-2009 standard method into Row.Sensory quality assessment is carried out using the method that comparison is secretly commented.As a result as shown in Table 2-4.
2 cigarette sample of table describes
3 cigarette sample flue gas conventional index comparative analysis of table
4 cigarette sample aesthetic quality's comparative evaluation's result of table
By the conventional fume indication testing result of the cigarette sample of table 3 it is found that wingceltis skin using the present invention, sugarcane fiber extrusion coating paper Every fume indication of the cigarette sample of filter material is declined, with the cigarette sample phase using wood pulp cellulose paper filter material Than the fall of tar is respectively 3.36%, 1.94% and 5.69%.
From the point of view of the sensory quality assessment result of table 4, in all three groups of cigarette samples, wingceltis skin of the present invention, sugarcane fiber The aesthetic quality of composite paper filter material cigarette sample is all remarkably higher than the cigarette sample using wood pulp cellulose paper filter material, with wood pulp Fiber paper filter material is compared, and wingceltis skin of the invention, sugarcane fiber composite paper filter material can assign cigarette smoke when cigarette is aspirated Fresh and sweet note, wooden miscellaneous gas, irritation and dry sensation are declined, and fragrance is clear, fine and smooth, and moisture feeling is preferable, and residual is smaller, remaining Sweet and sour.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all essences in the present invention With within principle, any modification, equivalent replacement, improvement and so on should all be included in the protection scope of the present invention god.

Claims (5)

1. the preparation method of a kind of wingceltis skin, sugarcane fiber composite paper filter material, which is characterized in that be made by the steps:
Step(1), paper substrate preparation:Commercially available wingceltis leather board and bagasse paddle board are taken according to dry weight(6-9):(1-4)Into Row is mixed and is matched, through hydraulic pulping, discongest after with PFI fiberizers carries out defibrination, slurry concentration is mass fraction 5-9%, control beating degree In 35-42 oSR, molding of manufacturing paper with pulp on sheet forming machine after conven-tional adjuvants is added in the slurry, and page is spare after drying;
Step(2), coating fluid preparation:Dark plum and Radix Glycyrrhizae are taken according to mass ratio 3:7-7:Heat is carried out after 3 mixing are broken with water to return Stream extracts to obtain extracting solution, and solid-liquid ratio during extraction is 1:25-1:35, Extracting temperature is 60-70 DEG C, time 1.5-3h;It will carry Liquid is taken to carry out being concentrated under reduced pressure to give concentrate after filtering, then adds in and carries out alcohol precipitation, centrifugation with the ethyl alcohol of concentrate isometric 95% After take supernatant liquor as coating fluid;
Step(3), paper filter material preparation:By step(2)The coating solution of preparation is in step(1)It is dried after on the paper substrate of preparation Dry, wherein additive amount of the coating fluid on paper substrate is 0.3%-0.8%.
2. preparation method according to claim 1, it is characterised in that:Step(1)In, control quantification of the 37 ± 1 of page g/m2, thickness is 0.12 ± 0.02 mm.
3. preparation method according to claim 1, it is characterised in that:Step(2)In, after extracting solution filtering depressurize dense It is reduced to the 1/4 of original volume.
4. use composite paper filter material made from the preparation method described in one of claim 1-3.
5. the answering in papery cigarette filter stick or composite filter of the wingceltis skin, sugarcane fiber composite paper filter material described in claim 4 With.
CN201810027287.5A 2018-01-11 2018-01-11 Sanders and bagasse fiber composite paper filter material and preparation method and application thereof Active CN108158035B (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109998156A (en) * 2019-04-19 2019-07-12 云南中烟工业有限责任公司 A kind of paper base gel thread and the cigarette comprising the paper base gel thread
CN113445365A (en) * 2020-03-26 2021-09-28 杭州特种纸业有限公司 Quantitative filter paper and preparation method thereof

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CN102326865A (en) * 2011-07-02 2012-01-25 云南瑞升烟草技术(集团)有限公司 Paper filter material containing polyester fibers for cigarette filter tip and preparation method thereof
CN102733248A (en) * 2012-07-11 2012-10-17 安徽中烟工业有限责任公司 Method used for lowering release amounts of harmful components in main stream smoke and applied to cigarette paper containing rice paper pulp fibers
CN104172472A (en) * 2014-07-31 2014-12-03 云南中烟工业有限责任公司 Paper filter stick of bagasse fiber cigarette
CN106281690A (en) * 2016-09-09 2017-01-04 湖北中烟工业有限责任公司 A kind of flavoring essence improving bamboo pulp Chip Quality and application thereof
CN106307605A (en) * 2016-08-26 2017-01-11 湖南珠峰科技有限公司 Cigarette essence capable of improving cigarette flavor and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102326865A (en) * 2011-07-02 2012-01-25 云南瑞升烟草技术(集团)有限公司 Paper filter material containing polyester fibers for cigarette filter tip and preparation method thereof
CN102733248A (en) * 2012-07-11 2012-10-17 安徽中烟工业有限责任公司 Method used for lowering release amounts of harmful components in main stream smoke and applied to cigarette paper containing rice paper pulp fibers
CN104172472A (en) * 2014-07-31 2014-12-03 云南中烟工业有限责任公司 Paper filter stick of bagasse fiber cigarette
CN106307605A (en) * 2016-08-26 2017-01-11 湖南珠峰科技有限公司 Cigarette essence capable of improving cigarette flavor and preparation method thereof
CN106281690A (en) * 2016-09-09 2017-01-04 湖北中烟工业有限责任公司 A kind of flavoring essence improving bamboo pulp Chip Quality and application thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109998156A (en) * 2019-04-19 2019-07-12 云南中烟工业有限责任公司 A kind of paper base gel thread and the cigarette comprising the paper base gel thread
CN113445365A (en) * 2020-03-26 2021-09-28 杭州特种纸业有限公司 Quantitative filter paper and preparation method thereof
CN113445365B (en) * 2020-03-26 2023-12-12 杭州特种纸业有限公司 Quantitative filter paper and preparation method thereof

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