CN108152205A - Pincers hold device in a kind of Atomic Fluorescence Spectrometer injector - Google Patents
Pincers hold device in a kind of Atomic Fluorescence Spectrometer injector Download PDFInfo
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- CN108152205A CN108152205A CN201711444355.XA CN201711444355A CN108152205A CN 108152205 A CN108152205 A CN 108152205A CN 201711444355 A CN201711444355 A CN 201711444355A CN 108152205 A CN108152205 A CN 108152205A
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/01—Arrangements or apparatus for facilitating the optical investigation
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/62—Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light
- G01N21/63—Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light optically excited
- G01N21/64—Fluorescence; Phosphorescence
- G01N21/6402—Atomic fluorescence; Laser induced fluorescence
- G01N21/6404—Atomic fluorescence
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Abstract
The invention discloses pincers in a kind of Atomic Fluorescence Spectrometer injector to hold device, including：Babinet, left and right drive gear, left and right position indicator, alarm, motor, front and rear driving device, front and rear position indicator, pincers hold device；Left and right drive gear is equipped in box house；Babinet top is equipped with left and right position indicator, alarm, motor, front and rear driving device, front and rear position indicator, wherein, left and right position indicator, front and rear position indicator are responsible for the positioning calibration to sample, motor holds the mobile around of device for pincers and provides power, and front and rear driving device is connect with being moved forward and backward driving wheel；The pincers hold the side that device is located at babinet；Alarm is connect with controller electric wire；Pincers hold device in a kind of Atomic Fluorescence Spectrometer injector of the present invention, and device clamping is firm, operates steadily, rotating speed is adjustable, improves the safety in whole work efficiency and operation process.
Description
Technical field
The invention belongs to instrument and equipment fields, and in particular to pincers hold device in a kind of Atomic Fluorescence Spectrometer injector.
Background technology
At present, due to laboratory sample crawl, Sample location it is convenient, fast, become important in analytical instrument system
Component part examines detection field so as to be widely used with food, health, medicine, chemical industry etc., in the field of inspection, needs big
Amount is accurately captured sample, but during sample is sampled, due to no suitably positioning, position restrainer
Structure, often occur sample transmission it is crooked, cause not capturing, Shi Xia roads detection process cannot normally to sample carry out
Analysis.At present, for existing sample grabbing device in the transmit process of sample, sample grasping mechanism cannot be according to the width of sample
Adjustment rapidly and efficiently is carried out, leads to that sample cannot be limited well, deviation occurs in crawl, needs laboratory technician into pedestrian
Work adjusts, and influences the analysis efficiency of sample, greatly increases the labor intensity of laboratory technician.Available sample grabbing device branch simultaneously
Frame is not affixed on bottom surface, is caused to generate displacement during sample crawl, is influenced the analysis of sample late detection.
Invention content
In order to solve the above technical problem, the present invention provides pincers in a kind of Atomic Fluorescence Spectrometer injector to hold device, wraps
It includes：Babinet 1, left and right drive gear 2, left and right position indicator 3, alarm 4, motor 5, front and rear driving device 6, front and rear position indicator 7, pincers
Hold device 8；It is characterized in that, it is internally provided with left and right drive gear 2 in babinet 1；1 top of babinet is equipped with left and right position indicator 3, alarm
Device 4, motor 5, front and rear driving device 6, front and rear position indicator 7, wherein, left and right position indicator 3, front and rear position indicator 7 are responsible for sample
Positioning calibration, motor 5 hold the mobile around of device 8 for pincers and provide power, and front and rear driving device 6 drives with being moved forward and backward
Take turns 8-5 connections；The pincers hold the side that device 8 is located at babinet 1；Alarm 4 is connect with controller electric wire.
Further, the pincers hold device 8, including：Move left and right device 8-1, shear arm 8-2, jaw 8-3, front and rear shifting
The dynamic 8-4 that cranks arm, is moved forward and backward driving wheel 8-5, moves left and right the 8-6 that cranks arm, jaw opening angle driving wheel 8-7, and clip opens driving
Arm 8-8 is moved forward and backward slideway 8-9, anti-skidding bed course 8-10；
It is moved forward and backward slideway 8-9 and holds 8 lower rearward side of device positioned at pincers, be moved forward and backward slideway 8-9 and be equipped with two one slide rails, be moved forward and backward
Slideway 8-9 limiting pliers are held device 8 and are slid back and forth in horizontal plane, are moved forward and backward slideway 8-9 and move left and right the folder between device 8-1
Angle is 90 degree；
Jaw 8-3 be located at pincers hold 8 forepart of device, shear arm 8-2 front end, jaw 8-3 laciniations are internally provided with non-slip mat
Layer 8-10；
It moves left and right device 8-1 to hold at left and right sides of 8 lower part of device positioned at pincers, moves left and right device 8-1 equipped with two one slide rails, left and right
Mobile device 8-1 limiting pliers hold device 8 and horizontally slip in horizontal plane；It moves left and right device 8-1 tops and is equipped with and move left and right and crank arm
8-6, the lower part of one end are connect with left and right drive gear 2, and are passed through sliding block and be slidably connected with moving left and right device 8-1；
Jaw opening angle driving wheel 8-7 is located at clip and opens actuating arm 8-8 tops, and jaw opening angle driving wheel 8-7 passes through gear
Actuating arm 8-8 is opened with clip and engages connection, and jaw opening angle driving wheel 8-7 drives clip to open actuating arm 8-8 rotations；
The other end that clip opens actuating arm 8-8 is hinged with shear arm 8-2, and rotation axis is equipped in the middle part of shear arm 8-2, and clip is opened
Actuating arm 8-8 drives shear arm 8-2 to be rotated around rotation axis, realizes unlatching and the closure of jaw 8-3；
It is moved forward and backward driving wheel 8-5 and is located at the side that pincers hold device 8, be moved forward and backward driving wheel 8-5 and the back-and-forth motion 8-4 that cranks arm and nibble
Connection is closed, the other end for being moved forward and backward the 8-4 that cranks arm is hinged by pin and shear arm 8-2, and back-and-forth motion driving wheel 8-5 passes through preceding
Mobile 8-4 driving pincers of cranking arm are held device 8 and are moved forward and backward afterwards.
Further, the device 8-1 that moves left and right includes：Slide bar 8-1-1, cartridge type sliding slot 8-1-2, damping unit 8-1-
3；Pincers hold device 8 and are located at slide bar 8-1-1 tops, and one end and the pincers of slide bar 8-1-1 are held device 8 and connect, another end caps of slide bar 8-1-1
It is connected on inside cartridge type sliding slot 8-1-2, the two is slidably connected；Damping unit 8-1-3 is internally provided on the right side of cartridge type sliding slot 8-1-2,
The right end of damping unit 8-1-3 is connect with cartridge type sliding slot 8-1-2 right ends.
Further, the damping unit 8-1-3 includes：Buffer board 8-1-3-1, retarding spring 8-1-3-2, retaining plate 8-
1-3-3, guiding bar 8-1-3-4, oil cylinder column 8-1-3-5, heat-dissipating pipe 8-1-3-6, oil cylinder set 8-1-3-7, oil filler point 8-1-3-8,
Generator 8-1-3-9, rack 8-1-3-10, baffle 8-1-3-11；
The buffer board 8-1-3-1 is located at damping unit 8-1-3 left ends, buffer board 8-1-3-1 rectangle structures, four, right side
Vertex is fixedly connected with one end of guiding bar 8-1-3-4, is received on the left of buffer board 8-1-3-1 and is rushed from what slide bar 8-1-1 was moved
Hit power；
The other end of guiding bar 8-1-3-4 is slidably socketed with the baffle 8-1-3-11 on the left of oil cylinder column 8-1-3-5, the guiding bar
Sliding sleeve is connected to retarding spring 8-1-3-2, retaining plate 8-1-3-3, retaining plate 8-1-3-3 successively from left to right in the middle part of 8-1-3-4
One end is slidably connected with guiding bar 8-1-3-4, and the other end is fixed；
The cylindric solid construction of the oil cylinder column 8-1-3-5, any surface finish are equipped with baffle 8-1-3- on the left of oil cylinder column 8-1-3-5
11, right side is slidably socketed with oil cylinder set 8-1-3-7；
Oil cylinder covers 8-1-3-7 cylindrical structures, and right side is closed, full of cylinder oil inside oil cylinder set 8-1-3-7, covers 8-1-3- in oil cylinder
7 tops are equipped with oil filler point 8-1-3-8, and oil cylinder set 8-1-3-7 casing walls are internally provided with heat-dissipating pipe 8-1-3-6；
Heat-dissipating pipe 8-1-3-6 is red copper hollow tube, and snakelike helical design, inside is full of freon, one end of heat-dissipating pipe 8-1-3-6
It is connected with external refrigeration compressor, heat-dissipating pipe 8-1-3-6 covers 8-1-3-7 coolings for oil cylinder；
Rack 8-1-3-10, rack 8-1-3-10 left ends and buffering are equipped between buffer board 8-1-3-1 and baffle 8-1-3-11
Plate 8-1-3-1 is fixedly connected, and rack 8-1-3-10 right ends pass through baffle 8-1-3-11, are slidably connected with baffle 8-1-3-11；Tooth
8-1-3-10 tops are connect by meshing gear with generator 8-1-3-9, and the kinetic energy that rack 8-1-3-10 movements generate passes through
Generator 8-1-3-9 is converted to electric energy and exports outward.
Further, the anti-skidding bed course 8-10 is molded by high molecular material pressing mold, the constituent of anti-skidding bed course 8-10
It is as follows with manufacturing process：
First, anti-skidding bed course 8-10 constituents：
It counts in parts by weight, softens 261.0~486.9 parts of pure water, acrylamide/2- acrylamide-2-methylpro panesulfonic acids/first
53.1~95.1 parts of base acrylic ternary copolymer, two-(2- ethylhexyls) 56.7~165.1 parts of sodium sulfosuccinates, bis- (three
Methyl fluoride sulfonyl) 52.5~69.7 parts of imide li, 1- amino -9,10- dihydros -4- [[4- [[methyl [(4- tolyls) sulphurs
Acyl group] amino] methyl] phenyl] amino] -55.2~112.1 parts of 9,10- titanium dioxide anthracene -2- sulfonic acid, oxygen] propyl two-methyl silicon
58.8~119.0 parts of oxygen alkane and polysiloxanes, 60.9~115.4 parts of osmium nanoparticle, 1- amino -4- [4- (2- chloro-acetyl chlorides
Base) phenylamino] -53.9~95.3 parts of 9,10- dihydro -9,10- dioxo anthracene -2- sulfonate sodiums, N- (1,1- dimethyl ethyl) -
55.4~95.5 parts of 2-[4-morpholinodithio sulfenamide, 2- [(bromo- 9,10- dihydros -9, the 10- dioxo -1- anthryls of 4- amino -3-)
Amino] 55.5~78.8 parts of -5- toluenesulfonic acids mono-sodium salt, N- [5- [two [2- (1- oxygen propoxyl group) ethyl] amino] -4- methoxies
Base -2- [(5- nitro -2- thiazolyls) azo] phenyl] 44.2~80.3 parts of acetamide, N- methyl -3,4,5,6- tetrachloro phosphorus benzene two
43.8~86.4 parts of carboximide, 3,5- 52.1~97.5 parts of dimethoxy-ps, the chloro- 3- of 4- (4,5- dihydro -3- methyl -5-
Oxo -1H- pyrazol-1-yls) 62.4~106.5 parts of-benzene sulfonic acid, mass concentration is the sulfuric acid 12 of 52.4ppm~319.4ppm
85.1~139.1 parts of Arrcostab；
2nd, the manufacturing process of anti-skidding bed course 8-10, comprises the steps of：
1st step：In stirred-tank reactor, softening pure water and acrylamide/2- acrylamido -2- methyl-prop sulphurs are added in
Acid/metering system acid ter-polymer starts the blender in stirred-tank reactor, and setting speed is 54rpm~100rpm,
Start the light oil heater in stirred-tank reactor, temperature is made to rise to 69.0 DEG C~70.9 DEG C, add in two-(2- ethylhexyls)
Sodium sulfosuccinate stirs evenly, and carries out reaction 46.1~57.1 minutes, adds in bis- (trifluoromethyl sulfonyl) imide lis, leads to
Inbound traffics are 45.153m3/ min~86.308m3The ammonia of/min 0.54~0.119 hour；Later in stirred-tank reactor
Add in 1- amino -9,10- dihydros -4- [[4- [[methyl [(4- tolyls) sulfonyl] amino] methyl] phenyl] amino] -9,10-
Titanium dioxide anthracene -2- sulfonic acid, the light oil heater being again started up in stirred-tank reactor make temperature rise to 86.7 DEG C~119.1
DEG C, 46.5~57.7 minutes are kept the temperature, adds in oxygen] two-methylsiloxane of propyl and polysiloxanes, it adjusts in stirred-tank reactor
The pH value of solution is 4.8~8.9, keeps the temperature 46.2~286.1 minutes；
2nd step：Separately take osmium nanoparticle, by osmium nanoparticle power for ultrasonication 0.52 under 5.86KW~11.3KW~
0.119 hour；Osmium nanoparticle is added in another stirred-tank reactor, addition mass concentration for 56.3ppm~
1- amino -4- [4- (2- chloro acetylaminos) phenylamino] -9,10- dihydro -9,10- dioxo anthracene -2- sodium sulfonates of 286.4ppm
Salt disperse osmium nanoparticle, start stirred-tank reactor in light oil heater, make solution temperature 4.85 × 10 DEG C~
Between 8.95 × 10 DEG C, start the blender in stirred-tank reactor, and with 4.8 × 102Rpm~8.9 × 102The speed of rpm
Stirring, adjustment pH value is between 4.8~8.9, insulated and stirred 5.86 × 10-1~11.3 × 10-1Hour；It is quiet to stop reaction later
It puts 5.86 × 10~11.3 × 10 minutes, removes impurity；It is sub- that suspension is added in into N- (1,1- dimethyl ethyls) -2-[4-morpholinodithio
Sulfonamide, adjustment pH value form sediment and are eluted with softening pure water, by centrifuge in rotating speed 4.647 between 1.2~2.3
×103Rpm~9.475 × 103Solid content is obtained under rpm, 2.651 × 102DEG C~3.589 × 102It is dry at a temperature of DEG C, it grinds
0.647 × 10 is crossed after mill3~1.475 × 103Mesh sieves, spare；
3rd step：Separately take 2- [(the bromo- 9,10- dihydros -9,10- dioxos -1- anthryls of 4- amino -3-) amino] -5- toluenesulfonic acids
Osmium nanoparticle after mono-sodium salt and the processing of the 2nd step, is irradiated after mixing using the back reflection of low-angle alpha ray, the low-angle alpha ray back of the body
The energy for penetrating irradiation is 43.231MeV~71.891MeV, dosage is 91.90kGy~131.915kGy, irradiation time 55.8
~80.4 minutes, obtain character change 2- [(bromo- 9,10- dihydros -9, the 10- dioxo -1- anthryls of 4- amino -3-) amino] -
5- toluenesulfonic acids mono-sodium salt and osmium nanoparticle mixture；By 2- [(the bromo- 9,10- dihydros -9,10- dioxos of 4- amino -3- -
1- anthryls) amino] -5- toluenesulfonic acids mono-sodium salt and osmium nanoparticle mixture be placed in another stirred-tank reactor, open
Light oil heater in dynamic stirred-tank reactor, 54.1 DEG C~100.5 DEG C of set temperature start in stirred-tank reactor
Blender, rotating speed are 46rpm~441rpm, and pH is adjusted between 4.8~8.9, are dehydrated 55.4~69.5 minutes, spare；
4th step：2- [(the bromo- 9,10- dihydros -9,10- dioxos -1- anthracenes of 4- amino -3- that the character that 3rd step is obtained changes
Base) amino] -5- toluenesulfonic acids mono-sodium salt and osmium nanoparticle mixture, mass concentration is added to as 56.4ppm~286.4ppm
N- [5- [two [2- (1- oxygen propoxyl group) ethyl] amino] -4- methoxyl groups -2- [(5- nitro -2- thiazolyls) azo] phenyl] second
In amide, cocurrent is added in the stirred-tank reactor of the 1st step, and flow acceleration is 191mL/min~919mL/min；Startup is stirred
Still reaction mechanical stirrer is mixed, setting speed is 60rpm~100rpm；Stirring 4.8~8.9 minutes；N- methyl -3,4 are added,
5,6- tetrachloro phosphorus phthalimide start the light oil heater in stirred-tank reactor, are warming up to 90.1 DEG C~127.1
DEG C, pH is adjusted between 4.8~8.9, is passed through ammonia ventilatory capacity as 45.665m3/ min~86.666m3/ min, heat preservation are stood
80.0~110.9 minutes；Stirred-tank reactor blender is again started up, rotating speed is 55rpm~100rpm, adds in 3,5- diformazans
Oxygroup toluene, and pH is adjusted between 4.8~8.9, heat preservation stands 79.1~119.1 minutes；
5th step：Start the blender in stirred-tank reactor, setting speed is 52rpm~119rpm, and it is anti-to start stirring autoclave
The light oil heater in device is answered, sets temperature in stirred-tank reactor as 1.770 × 102DEG C~2.777 × 102DEG C, it adds in
The chloro- 3- of 4- (4,5- dihydro -3- methyl -5- oxo -1H- pyrazol-1-yls)-benzene sulfonic acid reacts 46.7~57.1 minutes；Later plus
Enter lauryl sulfate, start the light oil heater in stirred-tank reactor, set the temperature in stirred-tank reactor
Be 130.5 DEG C~186.7 DEG C, pH is adjusted between 4.8~8.9, pressure be 0.52MPa~0.53MPa, the reaction time 0.4
~0.9 hour；It is depressurized to 0MPa later, is cooled to 54.52 DEG C~59.52 DEG C dischargings to get to anti-skidding bed course 8-10；
The grain size of the osmium nanoparticle is 60.9 μm~70.1 μm.
Pincers hold device in a kind of Atomic Fluorescence Spectrometer injector disclosed by the invention, the advantage is that：
(1) device clamping is firm, operates steadily, rotating speed is adjustable, improves the peace in whole work efficiency and operation process
Quan Xing；
(2) device avoids operating personnel's hand operation, improves processing safety using automatically controlling.
Description of the drawings
Fig. 1 is that pincers hold apparatus structure schematic diagram in a kind of heretofore described Atomic Fluorescence Spectrometer injector.
Fig. 2 is that heretofore described pincers hold apparatus structure schematic diagram.
Fig. 3 is heretofore described to move left and right apparatus structure schematic diagram.
Fig. 4 is that heretofore described pincers hold apparatus structure schematic diagram.
In figure 1 above~Fig. 4, babinet 1, left and right drive gear 2, left and right position indicator 3, alarm 4, motor 5, front and rear driving
Device 6, front and rear position indicator 7, pincers hold device 8, move left and right device 8-1, slide bar 8-1-1, cartridge type sliding slot 8-1-2, damping unit
8-1-3, buffer board 8-1-3-1, retarding spring 8-1-3-2, retaining plate 8-1-3-3, guiding bar 8-1-3-4, oil cylinder column 8-1-3-
5, heat-dissipating pipe 8-1-3-6, oil cylinder set 8-1-3-7, oil filler point 8-1-3-8, generator 8-1-3-9, rack 8-1-3-10, baffle 8-
1-3-11, shear arm 8-2, jaw 8-3 are moved forward and backward the 8-4 that cranks arm, and are moved forward and backward driving wheel 8-5, move left and right the 8-6 that cranks arm, and clamp
Mouth opening angle driving wheel 8-7, clip open actuating arm 8-8, are moved forward and backward slideway 8-9, anti-skidding bed course 8-10.
Specific embodiment
Device is held into traveling one to pincers in a kind of Atomic Fluorescence Spectrometer injector provided by the invention below in conjunction with the accompanying drawings
Walk explanation.
As shown in Figure 1, it is that pincers hold apparatus structure signal in a kind of heretofore described Atomic Fluorescence Spectrometer injector
Figure.It is seen in fig. 1, that including：Babinet 1, left and right drive gear 2, left and right position indicator 3, alarm 4, motor 5, front and rear driving dress
6 are put, front and rear position indicator 7, pincers hold device 8；It is characterized in that, it is internally provided with left and right drive gear 2 in babinet 1；1 top of babinet is set
There are left and right position indicator 3, alarm 4, motor 5, front and rear driving device 6, front and rear position indicator 7, wherein, it is left and right position indicator 3, front and rear fixed
The positioning that position instrument 7 is responsible for sample is calibrated, and motor 5 holds the mobile around of device 8 for pincers and provides power, front and rear driving dress
It puts 6 and is connect with being moved forward and backward driving wheel 8-5；The pincers hold the side that device 8 is located at babinet 1；Alarm 4 connects with controller electric wire
It connects.
As shown in Fig. 2, it is that heretofore described pincers hold apparatus structure schematic diagram.As seen from Figure 2, pincers hold device 8, wrap
It includes：Device 8-1, shear arm 8-2, jaw 8-3 are moved left and right, is moved forward and backward the 8-4 that cranks arm, is moved forward and backward driving wheel 8-5, left and right is moved
The dynamic 8-6 that cranks arm, jaw opening angle driving wheel 8-7, clip open actuating arm 8-8, are moved forward and backward slideway 8-9, anti-skidding bed course 8-10；
It is moved forward and backward slideway 8-9 and holds 8 lower rearward side of device positioned at pincers, be moved forward and backward slideway 8-9 and be equipped with two one slide rails, be moved forward and backward
Slideway 8-9 limiting pliers are held device 8 and are slid back and forth in horizontal plane, are moved forward and backward slideway 8-9 and move left and right the folder between device 8-1
Angle is 90 degree；
Jaw 8-3 be located at pincers hold 8 forepart of device, shear arm 8-2 front end, jaw 8-3 laciniations are internally provided with non-slip mat
Layer 8-10；
It moves left and right device 8-1 to hold at left and right sides of 8 lower part of device positioned at pincers, moves left and right device 8-1 equipped with two one slide rails, left and right
Mobile device 8-1 limiting pliers hold device 8 and horizontally slip in horizontal plane；It moves left and right device 8-1 tops and is equipped with and move left and right and crank arm
8-6, the lower part of one end are connect with left and right drive gear 2, and are passed through sliding block and be slidably connected with moving left and right device 8-1；
Jaw opening angle driving wheel 8-7 is located at clip and opens actuating arm 8-8 tops, and jaw opening angle driving wheel 8-7 passes through gear
Actuating arm 8-8 is opened with clip and engages connection, and jaw opening angle driving wheel 8-7 drives clip to open actuating arm 8-8 rotations；
The other end that clip opens actuating arm 8-8 is hinged with shear arm 8-2, and rotation axis is equipped in the middle part of shear arm 8-2, and clip is opened
Actuating arm 8-8 drives shear arm 8-2 to be rotated around rotation axis, realizes unlatching and the closure of jaw 8-3；
It is moved forward and backward driving wheel 8-5 and is located at the side that pincers hold device 8, be moved forward and backward driving wheel 8-5 and the back-and-forth motion 8-4 that cranks arm and nibble
Connection is closed, the other end for being moved forward and backward the 8-4 that cranks arm is hinged by pin and shear arm 8-2, and back-and-forth motion driving wheel 8-5 passes through preceding
Mobile 8-4 driving pincers of cranking arm are held device 8 and are moved forward and backward afterwards.
It is the embodiment of the manufacturing process of anti-skidding bed course 8-10 of the present invention below.
Embodiment 1
Anti-skidding bed course 8-10 of the present invention is prepared, and count in parts by weight according to following steps：
1st step：In stirred-tank reactor, 261.0 parts of softening pure water and acrylamide/2- acrylamido -2- first are added in
Base propane sulfonic acid/53.1 parts of metering system acid ter-polymer, starts the blender in stirred-tank reactor, and setting speed is
54rpm starts the light oil heater in stirred-tank reactor, and temperature is made to rise to 69.0 DEG C, adds in two-(2- ethylhexyls) sulphurs
56.7 parts of base sodium succinate stirs evenly, and carries out reaction 46.1 minutes, adds in bis- (trifluoromethyl sulfonyl) imide lis 52.5
Part, flow is passed through as 45.153m3The ammonia of/min 0.54 hour；1- amino -9 are added in stirred-tank reactor later,
10- dihydros -4- [[4- [[methyl [(4- tolyls) sulfonyl] amino] methyl] phenyl] amino] -9,10- titanium dioxide anthracene -2- sulphurs
55.2 parts of acid, the light oil heater being again started up in stirred-tank reactor make temperature rise to 86.7 DEG C, keep the temperature 46.5 minutes,
Add in oxygen] 58.8 parts of two-methylsiloxane of propyl and polysiloxanes, the pH value for adjusting solution in stirred-tank reactor is 4.8,
Heat preservation 46.2 minutes；
2nd step：60.9 parts of osmium nanoparticle separately is taken, osmium nanoparticle is small for ultrasonication 0.52 under 5.86KW in power
When；Osmium nanoparticle is added in another stirred-tank reactor, adds in the 1- amino -4- that mass concentration is 56.3ppm
53.9 parts of dispersion osmium nanometers of [4- (2- chloro acetylaminos) phenylamino] -9,10- dihydro -9,10- dioxo anthracene -2- sulfonate sodiums are micro-
Grain starts the light oil heater in stirred-tank reactor, makes solution temperature at 4.85 × 10 DEG C, starts stirred-tank reactor
In blender, and stirred with the speed of 4.8 × 10rpm, adjustment pH value is 4.8, insulated and stirred 5.86 × 10-1Hour；Later
Stop reaction and stand 5.86 × 10 minutes, remove impurity；It is sub- that suspension is added in into N- (1,1- dimethyl ethyls) -2-[4-morpholinodithio
55.4 parts of sulfonamide, adjustment pH value form sediment and are eluted with softening pure water 1.2, by centrifuge rotating speed 4.647 ×
103Solid content is obtained under rpm, 2.651 × 102It is dry at a temperature of DEG C, 0.647 × 10 is crossed after grinding3Mesh sieves, spare；
3rd step：Separately take 2- [(the bromo- 9,10- dihydros -9,10- dioxos -1- anthryls of 4- amino -3-) amino] -5- toluenesulfonic acids
Osmium nanoparticle after 55.5 parts of mono-sodium salt and the processing of the 2nd step, is irradiated, low-angle α using the back reflection of low-angle alpha ray after mixing
Ray back reflection irradiation energy be 43.231MeV dosage be 91.90kGy, irradiation time is 55.8 minutes, obtain character change
2- [(the bromo- 9,10- dihydros -9,10- dioxos -1- anthryls of 4- amino -3-) amino] -5- toluenesulfonic acids mono-sodium salts and osmium nanometer
Particle mixture；By 2- [(the bromo- 9,10- dihydros -9,10- dioxos -1- anthryls of 4- amino -3-) amino] -5- toluenesulfonic acids
Mono-sodium salt and osmium nanoparticle mixture are placed in another stirred-tank reactor, and the light oil started in stirred-tank reactor adds
Hot device, 54.1 DEG C of set temperature start the blender in stirred-tank reactor, and rotating speed 46rpm, pH are adjusted to 4.8, dehydration
It is 55.4 minutes, spare；
4th step：2- [(the bromo- 9,10- dihydros -9,10- dioxos -1- anthracenes of 4- amino -3- that the character that 3rd step is obtained changes
Base) amino] -5- toluenesulfonic acids mono-sodium salt and osmium nanoparticle mixture, add to the N- [5- [two that mass concentration is 56.4ppm
[2- (1- oxygen propoxyl group) ethyl] amino] -4- methoxyl groups -2- [(5- nitro -2- thiazolyls) azo] phenyl] 44.2 parts of acetamide
In, cocurrent is added in the stirred-tank reactor of the 1st step, flow acceleration 191mL/min；Start stirred-tank reactor stirring
Machine, setting speed 60rpm；Stirring 4.8 minutes；Add N- methyl -3,4,5,6- 43.8 parts of tetrachloro phosphorus phthalimide,
Start the light oil heater in stirred-tank reactor, be warming up to 90.1 DEG C, pH is adjusted to 4.8, is passed through ammonia ventilatory capacity and is
45.665m3/ min, heat preservation stand 80.0 minutes；Stirred-tank reactor blender is again started up, rotating speed 55rpm adds in 3,
52.1 parts of 5- dimethoxy-ps, and pH is caused to be adjusted to 4.8, heat preservation stands 79.1 minutes；
5th step：Start the blender in stirred-tank reactor, setting speed 52rpm starts in stirred-tank reactor
Light oil heater sets temperature in stirred-tank reactor as 1.770 × 102DEG C, add in 4- chloro- 3- (4,5- dihydro -3- first
Base -5- oxo -1H- pyrazol-1-yls) 62.4 parts of-benzene sulfonic acid, reacts 46.7 minutes；It is 52.4ppm sulphur to add in mass concentration later
Sour 85.1 parts of dodecyl ester starts the light oil heater in stirred-tank reactor, sets the temperature in stirred-tank reactor
It is 130.5 DEG C to spend, and pH is adjusted to 4.8, and pressure 0.52MPa, the reaction time is 0.4 hour；It is depressurized to 0MPa later, is cooled to
54.52 DEG C of dischargings are to get to anti-skidding bed course 8-10.
The grain size of wherein described osmium nanoparticle is 60.9 μm.
Embodiment 2
Anti-skidding bed course 8-10 of the present invention is manufactured, and count in parts by weight according to following steps：
1st step：In stirred-tank reactor, 486.9 parts of softening pure water and acrylamide/2- acrylamido -2- first are added in
Base propane sulfonic acid/95.1 parts of metering system acid ter-polymer, starts the blender in stirred-tank reactor, and setting speed is
100rpm starts the light oil heater in stirred-tank reactor, and temperature is made to rise to 70.9 DEG C, adds in two-(2- ethylhexyls)
165.1 parts of sodium sulfosuccinate stirs evenly, and carries out reaction 57.1 minutes, adds in bis- (trifluoromethyl sulfonyl) imide lis
69.7 parts, flow is passed through as 86.308m3The ammonia of/min 0.119 hour；1- ammonia is added in stirred-tank reactor later
Base -9,10- dihydros -4- [[4- [[methyl [(4- tolyls) sulfonyl] amino] methyl] phenyl] amino] -9,10- titanium dioxides
112.1 parts of anthracene -2- sulfonic acid, the light oil heater being again started up in stirred-tank reactor make temperature rise to 119.1 DEG C, heat preservation
57.7 minutes, add in oxygen] 119.0 parts of two-methylsiloxane of propyl and polysiloxanes, adjust solution in stirred-tank reactor
PH value is 8.9, keeps the temperature 286.1 minutes；
2nd step：115.4 parts of osmium nanoparticle separately is taken, osmium nanoparticle is small for ultrasonication 0.119 under 11.3KW in power
When；Osmium nanoparticle is added in another stirred-tank reactor, adds in the 1- amino -4- that mass concentration is 286.4ppm
95.3 parts of dispersion osmium nanometers of [4- (2- chloro acetylaminos) phenylamino] -9,10- dihydro -9,10- dioxo anthracene -2- sulfonate sodiums are micro-
Grain starts the light oil heater in stirred-tank reactor, makes solution temperature at 8.95 × 10 DEG C, starts stirred-tank reactor
In blender, and stirred with the speed of 8.9 × 10rpm, adjustment pH value is 8.9, insulated and stirred 11.3 × 10-1Hour；Later
Stop reaction and stand 11.3 × 10 minutes, remove impurity；It is sub- that suspension is added in into N- (1,1- dimethyl ethyls) -2-[4-morpholinodithio
95.5 parts of sulfonamide, adjustment pH value form sediment and are eluted with softening pure water 2.3, by centrifuge rotating speed 9.475 ×
103Solid content is obtained under rpm, 3.589 × 102It is dry at a temperature of DEG C, 1.475 × 10 are crossed after grinding3Mesh sieves, spare；
3rd step：Separately take 2- [(the bromo- 9,10- dihydros -9,10- dioxos -1- anthryls of 4- amino -3-) amino] -5- toluenesulfonic acids
Osmium nanoparticle after 78.8 parts of mono-sodium salt and the processing of the 2nd step, is irradiated, low-angle α using the back reflection of low-angle alpha ray after mixing
The energy of ray back reflection irradiation is 71.891MeV, dosage 131.915kGy, irradiation time are 80.4 minutes, obtains character and changes
2- [(the bromo- 9,10- dihydros -9,10- dioxos -1- anthryls of 4- amino -3-) the amino] -5- toluenesulfonic acids mono-sodium salts and osmium of change
Nanoparticle mixture；By 2- [(the bromo- 9,10- dihydros -9,10- dioxos -1- anthryls of 4- amino -3-) amino] -5- methylbenzenes
Sulfonic acid monosodium salt and osmium nanoparticle mixture are placed in another stirred-tank reactor, are started light in stirred-tank reactor
Oil heater, 100.5 DEG C of set temperature start the blender in stirred-tank reactor, and rotating speed 441rpm, pH are adjusted to
8.9, it is dehydrated 69.5 minutes, it is spare；
4th step：2- [(the bromo- 9,10- dihydros -9,10- dioxos -1- anthracenes of 4- amino -3- that the character that 3rd step is obtained changes
Base) amino] -5- toluenesulfonic acids mono-sodium salt and osmium nanoparticle mixture, add to the N- [5- that mass concentration is 286.4ppm
[two [2- (1- oxygen propoxyl group) ethyl] amino] -4- methoxyl groups -2- [(5- nitro -2- thiazolyls) azo] phenyl] acetamide
In 80.3 parts, cocurrent is added in the stirred-tank reactor of the 1st step, flow acceleration 919mL/min；Start stirring still reaction
Mechanical stirrer, setting speed 100rpm；Stirring 8.9 minutes；Add N- methyl -3,4,5,6- tetrachloro phosphorus phthalimide
86.4 parts, start the light oil heater in stirred-tank reactor, be warming up to 127.1 DEG C, pH is adjusted to 8.9, is passed through ammonia and leads to
Tolerance is 86.666m3/ min, heat preservation stand 110.9 minutes；Stirred-tank reactor blender is again started up, rotating speed is
100rpm adds in 97.5 parts of 3,5- dimethoxy-ps, and pH is caused to be adjusted to 8.9, and heat preservation stands 119.1 minutes；
5th step：Start the blender in stirred-tank reactor, setting speed 119rpm starts in stirred-tank reactor
Light oil heater, set temperature in stirred-tank reactor as 2.777 × 102DEG C, add in the chloro- 3- of 4- (4,5- dihydro -3-
Methyl -5- oxo -1H- pyrazol-1-yls) 106.5 parts of-benzene sulfonic acid, reacts 57.1 minutes；Adding in mass concentration later is
139.1 parts of 319.4ppm lauryl sulfates, start the light oil heater in stirred-tank reactor, and setting stirring autoclave is anti-
It is 186.7 DEG C to answer the temperature in device, and pH is adjusted to 8.9, and pressure 0.53MPa, the reaction time is 0.9 hour；It is depressurized to later
0MPa is cooled to 59.52 DEG C of dischargings to get to anti-skidding bed course 8-10.
The grain size of wherein described osmium nanoparticle is 70.1 μm.
Embodiment 3
Anti-skidding bed course 8-10 of the present invention is manufactured, and count in parts by weight according to following steps：
1st step：In stirred-tank reactor, 261.90 parts of softening pure water and acrylamide/2- acrylamido -2- first are added in
Base propane sulfonic acid/53.91 parts of metering system acid ter-polymer, starts the blender in stirred-tank reactor, and setting speed is
54rpm starts the light oil heater in stirred-tank reactor, and temperature is made to rise to 69.9 DEG C, adds in two-(2- ethylhexyls) sulphurs
56.97 parts of base sodium succinate stirs evenly, and carries out reaction 46.9 minutes, adds in bis- (trifluoromethyl sulfonyl) imide lis
52.95 parts, flow is passed through as 45.9153m3The ammonia of/min 0.549 hour；1- ammonia is added in stirred-tank reactor later
Base -9,10- dihydros -4- [[4- [[methyl [(4- tolyls) sulfonyl] amino] methyl] phenyl] amino] -9,10- titanium dioxides
55.92 parts of anthracene -2- sulfonic acid, the light oil heater being again started up in stirred-tank reactor make temperature rise to 86.9 DEG C, heat preservation
46.9 minutes, add in oxygen] 58.98 parts of two-methylsiloxane of propyl and polysiloxanes, adjust solution in stirred-tank reactor
PH value is 4.89, keeps the temperature 46.9 minutes；
2nd step：60.99 parts of osmium nanoparticle separately is taken, in power is ultrasonication 0.529 under 5.869KW by osmium nanoparticle
Hour；Osmium nanoparticle is added in another stirred-tank reactor, the 1- amino that addition mass concentration is 56.9ppm-
53.99 parts of dispersion osmiums of 4- [4- (2- chloro acetylaminos) phenylamino] -9,10- dihydro -9,10- dioxo anthracene -2- sulfonate sodiums are received
Rice particle, starts the light oil heater in stirred-tank reactor, makes solution temperature at 4.89 × 10 DEG C, and it is anti-to start stirring autoclave
It answers the blender in device, and is stirred with the speed of 4.8 × 10rpm, adjustment pH value is 4.89, insulated and stirred 5.869 × 10-1It is small
When；Stop reaction later and stand 5.869 × 10 minutes, remove impurity；Suspension is added in into N- (1,1- dimethyl ethyls) -2- benzene
And 55.94 parts of thiazole sulfenamide, adjustment pH value form sediment and are eluted with softening pure water, by centrifuge in rotating speed 1.9
4.9×103Solid content is obtained under rpm, 2.9 × 102It is dry at a temperature of DEG C, 8.9 × 10 are crossed after grinding3Mesh sieves, spare；
3rd step：Separately take 2- [(the bromo- 9,10- dihydros -9,10- dioxos -1- anthryls of 4- amino -3-) amino] -5- toluenesulfonic acids
Osmium nanoparticle after 55.95 parts of mono-sodium salt and the processing of the 2nd step, is irradiated, low-angle using the back reflection of low-angle alpha ray after mixing
The energy of alpha ray back reflection irradiation is 43.9231MeV, dosage 91.990kGy, irradiation time are 55.9 minutes, obtains character and changes
2- [(the bromo- 9,10- dihydros -9,10- dioxos -1- anthryls of 4- amino -3-) the amino] -5- toluenesulfonic acids mono-sodium salts and osmium of change
Nanoparticle mixture；By 2- [(the bromo- 9,10- dihydros -9,10- dioxos -1- anthryls of 4- amino -3-) amino] -5- methylbenzenes
Sulfonic acid monosodium salt and osmium nanoparticle mixture are placed in another stirred-tank reactor, are started light in stirred-tank reactor
Oil heater, 54.9 DEG C of set temperature start the blender in stirred-tank reactor, and rotating speed 46.9rpm, pH are adjusted to
4.89, it is dehydrated 55.9 minutes, it is spare；
4th step：2- [(the bromo- 9,10- dihydros -9,10- dioxos -1- anthracenes of 4- amino -3- that the character that 3rd step is obtained changes
Base) amino] -5- toluenesulfonic acids mono-sodium salt and osmium nanoparticle mixture, add to the N- [5- [two that mass concentration is 56.9ppm
[2- (1- oxygen propoxyl group) ethyl] amino] -4- methoxyl groups -2- [(5- nitro -2- thiazolyls) azo] phenyl] acetamide 44.92
In part, cocurrent is added in the stirred-tank reactor of the 1st step, flow acceleration 191.9mL/min；Start stirred-tank reactor
Blender, setting speed 60rpm；Stirring 4.89 minutes；Add N- methyl -3,4,5,6- tetrachloro phosphorus phthalimide
43.98 parts, start the light oil heater in stirred-tank reactor, be warming up to 90.9 DEG C, pH is adjusted to 4.89, is passed through ammonia and leads to
Tolerance is 45.9665m3/ min, heat preservation stand 80.9 minutes；Stirred-tank reactor blender is again started up, rotating speed is
55rpm adds in 52.91 parts of 3,5- dimethoxy-ps, and pH is caused to be adjusted to 4.89, and heat preservation stands 79.9 minutes；
5th step：Start the blender in stirred-tank reactor, setting speed 52rpm starts in stirred-tank reactor
Light oil heater sets temperature in stirred-tank reactor as 1.7709 × 102DEG C, add in the chloro- 3- of 4- (4,5- dihydro -3-
Methyl -5- oxo -1H- pyrazol-1-yls) 62.94 parts of-benzene sulfonic acid, reacts 46.9 minutes；Adding in mass concentration later is
85.91 parts of 52.94ppm lauryl sulfates, start the light oil heater in stirred-tank reactor, and setting stirring autoclave is anti-
It is 130.9 DEG C to answer the temperature in device, and pH is adjusted to 4.89, and pressure 0.529MPa, the reaction time is 0.49 hour；It is depressured later
To 0MPa, 54.529 DEG C of dischargings are cooled to get to anti-skidding bed course 8-10.
The grain size of wherein described osmium nanoparticle is 60.9 μm.
Reference examples
Reference examples are the anti-skidding bed course of certain commercially available brand.
Embodiment 4
Anti-skidding bed course described in the anti-skidding bed course 8-10 and reference examples that Examples 1 to 3 is prepared carries out using effect comparison.
The two wearing coefficient, anti-aging strength enhancing rate, clamping coefficient of stabilization, clamp pressure are counted, the results are shown in Table 1.From
Table 1 is as it can be seen that anti-skidding bed course 8-10 of the present invention, wearing coefficient, anti-aging strength enhancing rate, clamping coefficient of stabilization, clamping
Pressure index is superior to the product of prior art production.
Claims (5)
1. pincers hold device in a kind of Atomic Fluorescence Spectrometer injector, including：Babinet (1), left and right drive gear (2), left and right are fixed
Position instrument (3), alarm (4), motor (5), front and rear driving device (6), front and rear position indicator (7), pincers hold device (8)；Its feature exists
In being internally provided with left and right drive gear (2) in babinet (1)；Babinet (1) top is equipped with left and right position indicator (3), alarm (4), electricity
Machine (5), front and rear driving device (6), front and rear position indicator (7), wherein, left and right position indicator (3), front and rear position indicator (7) are responsible for sample
The positioning calibration of product, motor (5) hold the mobile around of device (8) for pincers and provide power, and front and rear driving device (6) is with before
After move driving wheel (8-5) connection；The pincers hold device (8) positioned at the side of babinet (1)；Alarm (4) and controller electric wire
Connection.
2. pincers hold device in a kind of Atomic Fluorescence Spectrometer injector according to claim 1, which is characterized in that the pincers
Device (8) is held, including：Device (8-1) is moved left and right, shear arm (8-2), jaw (8-3), back-and-forth motion is cranked arm (8-4), front and rear
Mobile driving wheel (8-5), moves left and right crank arm (8-6), jaw opening angle driving wheel (8-7), and clip opens actuating arm (8-8),
It is moved forward and backward slideway (8-9), anti-skidding bed course (8-10)；
It using jaw (8-3) direction as front, is then moved forward and backward slideway (8-9) and holds device (8) lower rearward side positioned at pincers, be moved forward and backward
Slideway (8-9) is held device (8) and is slid back and forth in horizontal plane equipped with two one slide rails, back-and-forth motion slideway (8-9) limiting pliers, front and rear shifting
Sliding way (8-9) and the angle moved left and right between device (8-1) are 90 degree；
Jaw (8-3) positioned at pincers hold device (8) forepart, shear arm (8-2) front end, jaw (8-3) laciniation, inside is set
There is anti-skidding bed course (8-10)；
It moves left and right device (8-1) to hold at left and right sides of device (8) lower part positioned at pincers, moves left and right device (8-1) equipped with two cunnings
Rail, moves left and right device (8-1) limiting pliers and holds device (8) and horizontally slip in horizontal plane；Device (8-1) top is moved left and right to be equipped with
It moves left and right crank arm (8-6), the lower part of one end is connect with left and right drive gear (2), and is passed through sliding block and moved left and right device
(8-1) is slidably connected；
Jaw opening angle driving wheel (8-7) opens actuating arm (8-8) top positioned at clip, and jaw opening angle driving wheel (8-7) is logical
It crosses gear and connection is engaged with clip unlatching actuating arm (8-8), jaw opening angle driving wheel (8-7) drives clip to open actuating arm
(8-8) rotates；
The other end that clip opens actuating arm (8-8) is hinged with shear arm (8-2), and rotation axis is equipped in the middle part of shear arm (8-2), is cut
Mouth opens actuating arm (8-8) and shear arm (8-2) is driven to be rotated around rotation axis, realizes unlatching and the closure of jaw (8-3)；It is front and rear
Mobile driving wheel (8-5) holds the side of device (8) positioned at pincers, be moved forward and backward driving wheel (8-5) and back-and-forth motion crank arm (8-4) nibble
Close connection, be moved forward and backward crank arm (8-4) the other end it is hinged by pin and shear arm (8-2), be moved forward and backward driving wheel (8-5)
Device (8) back-and-forth motion is held by being moved forward and backward (8-4) driving pincers of cranking arm.
3. pincers hold device in a kind of Atomic Fluorescence Spectrometer injector according to claim 2, which is characterized in that the left side
Device (8-1) is moved right to include：Slide bar (8-1-1), cartridge type sliding slot (8-1-2), damping unit (8-1-3)；Pincers hold device (8) position
In slide bar (8-1-1) top, one end and the pincers of slide bar (8-1-1) are held device (8) and are connect, and slide bar (8-1-1) other end is socketed in
Cartridge type sliding slot (8-1-2) is internal, and the two is slidably connected；Damping unit (8-1- is internally provided on the right side of cartridge type sliding slot (8-1-2)
3), the right end of damping unit (8-1-3) is connect with cartridge type sliding slot (8-1-2) right end.
4. pincers hold device in a kind of Atomic Fluorescence Spectrometer injector according to claim 3, which is characterized in that the resistance
Buddhist nun's device (8-1-3) includes：Buffer board (8-1-3-1), retarding spring (8-1-3-2), retaining plate (8-1-3-3), guiding bar (8-
1-3-4), oil cylinder column (8-1-3-5), heat-dissipating pipe (8-1-3-6), oil cylinder set (8-1-3-7), oil filler point (8-1-3-8), generator
(8-1-3-9), rack (8-1-3-10), baffle (8-1-3-11)；
The buffer board (8-1-3-1) is positioned at damping unit (8-1-3) left end, buffer board (8-1-3-1) rectangle structure, the right side
The vertex of side four is fixedly connected with one end of guiding bar (8-1-3-4), is received on the left of buffer board (8-1-3-1) from slide bar (8-
1-1) the impact force of movement；
The other end of guiding bar (8-1-3-4) is slidably socketed with the baffle (8-1-3-11) on the left of oil cylinder column (8-1-3-5), described
Sliding sleeve is connected to retarding spring (8-1-3-2), retaining plate (8-1-3-3) successively from left to right in the middle part of guiding bar (8-1-3-4), only
It moves back plate (8-1-3-3) one end to be slidably connected with guiding bar (8-1-3-4), the other end is fixed；
The cylindric solid construction of the oil cylinder column (8-1-3-5), any surface finish are equipped with baffle (8- on the left of oil cylinder column (8-1-3-5)
1-3-11), right side is slidably socketed with oil cylinder set (8-1-3-7)；
Oil cylinder set (8-1-3-7) cylindrical structure, right side is closed, full of cylinder oil inside oil cylinder set (8-1-3-7), in oil cylinder set
(8-1-3-7) top is equipped with oil filler point (8-1-3-8), and oil cylinder set (8-1-3-7) casing wall is internally provided with heat-dissipating pipe (8-1-3-6)；
Heat-dissipating pipe (8-1-3-6) is red copper hollow tube, and snakelike helical design is internal to be full of freon, heat-dissipating pipe (8-1-3-6)
One end is connected with external refrigeration compressor, and heat-dissipating pipe (8-1-3-6) cools down for oil cylinder set (8-1-3-7)；
Rack (8-1-3-10) is equipped between buffer board (8-1-3-1) and baffle (8-1-3-11), rack (8-1-3-10) is left
End is fixedly connected with buffer board (8-1-3-1), and rack (8-1-3-10) right end passes through baffle (8-1-3-11), with baffle (8-1-
3-11) it is slidably connected；Rack (8-1-3-10) top is connect by meshing gear with generator (8-1-3-9), rack (8-1-3-
10) the mobile kinetic energy generated is converted to electric energy by generator (8-1-3-9) and exports outward.
5. pincers hold device in a kind of Atomic Fluorescence Spectrometer injector according to claim 4, which is characterized in that described anti-
Skidding layer (8-10) is molded by high molecular material pressing mold, and the constituent and manufacturing process of anti-skidding bed course (8-10) are as follows：
First, anti-skidding bed course (8-10) constituent：
It counts in parts by weight, softens 261.0~486.9 parts of pure water, acrylamide/2- acrylamide-2-methylpro panesulfonic acids/first
53.1~95.1 parts of base acrylic ternary copolymer, two-(2- ethylhexyls) 56.7~165.1 parts of sodium sulfosuccinates, bis- (three
Methyl fluoride sulfonyl) 52.5~69.7 parts of imide li, 1- amino -9,10- dihydros -4- [[4- [[methyl [(4- tolyls) sulphurs
Acyl group] amino] methyl] phenyl] amino] -55.2~112.1 parts of 9,10- titanium dioxide anthracene -2- sulfonic acid, oxygen] propyl two-methyl silicon
58.8~119.0 parts of oxygen alkane and polysiloxanes, 60.9~115.4 parts of osmium nanoparticle, 1- amino -4- [4- (2- chloro-acetyl chlorides
Base) phenylamino] -53.9~95.3 parts of 9,10- dihydro -9,10- dioxo anthracene -2- sulfonate sodiums, N- (1,1- dimethyl ethyl) -
55.4~95.5 parts of 2-[4-morpholinodithio sulfenamide, 2- [(bromo- 9,10- dihydros -9, the 10- dioxo -1- anthryls of 4- amino -3-)
Amino] 55.5~78.8 parts of -5- toluenesulfonic acids mono-sodium salt, N- [5- [two [2- (1- oxygen propoxyl group) ethyl] amino] -4- methoxies
Base -2- [(5- nitro -2- thiazolyls) azo] phenyl] 44.2~80.3 parts of acetamide, N- methyl -3,4,5,6- tetrachloro phosphorus benzene two
43.8~86.4 parts of carboximide, 3,5- 52.1~97.5 parts of dimethoxy-ps, the chloro- 3- of 4- (4,5- dihydro -3- methyl -5-
Oxo -1H- pyrazol-1-yls) 62.4~106.5 parts of-benzene sulfonic acid, mass concentration is the sulfuric acid 12 of 52.4ppm~319.4ppm
85.1~139.1 parts of Arrcostab；
2nd, the manufacturing process of anti-skidding bed course (8-10), comprises the steps of：
1st step：In stirred-tank reactor, softening pure water and acrylamide/2- acrylamido -2- methyl-prop sulphurs are added in
Acid/metering system acid ter-polymer starts the blender in stirred-tank reactor, and setting speed is 54rpm~100rpm,
Start the light oil heater in stirred-tank reactor, temperature is made to rise to 69.0 DEG C~70.9 DEG C, add in two-(2- ethylhexyls)
Sodium sulfosuccinate stirs evenly, and carries out reaction 46.1~57.1 minutes, adds in bis- (trifluoromethyl sulfonyl) imide lis, leads to
Inbound traffics are 45.153m3/ min~86.308m3The ammonia of/min 0.54~0.119 hour；Later in stirred-tank reactor
Add in 1- amino -9,10- dihydros -4- [[4- [[methyl [(4- tolyls) sulfonyl] amino] methyl] phenyl] amino] -9,10-
Titanium dioxide anthracene -2- sulfonic acid, the light oil heater being again started up in stirred-tank reactor make temperature rise to 86.7 DEG C~119.1
DEG C, 46.5~57.7 minutes are kept the temperature, adds in oxygen] two-methylsiloxane of propyl and polysiloxanes, it adjusts in stirred-tank reactor
The pH value of solution is 4.8~8.9, keeps the temperature 46.2~286.1 minutes；
2nd step：Separately take osmium nanoparticle, by osmium nanoparticle power for ultrasonication 0.52 under 5.86KW~11.3KW~
0.119 hour；Osmium nanoparticle is added in another stirred-tank reactor, addition mass concentration for 56.3ppm~
1- amino -4- [4- (2- chloro acetylaminos) phenylamino] -9,10- dihydro -9,10- dioxo anthracene -2- sodium sulfonates of 286.4ppm
Salt disperse osmium nanoparticle, start stirred-tank reactor in light oil heater, make solution temperature 4.85 × 10 DEG C~
Between 8.95 × 10 DEG C, start the blender in stirred-tank reactor, and with 4.8 × 102Rpm~8.9 × 102The speed of rpm
Stirring, adjustment pH value is between 4.8~8.9, insulated and stirred 5.86 × 10-1~11.3 × 10-1Hour；It is quiet to stop reaction later
It puts 5.86 × 10~11.3 × 10 minutes, removes impurity；It is sub- that suspension is added in into N- (1,1- dimethyl ethyls) -2-[4-morpholinodithio
Sulfonamide, adjustment pH value form sediment and are eluted with softening pure water, by centrifuge in rotating speed 4.647 between 1.2~2.3
×103Rpm~9.475 × 103Solid content is obtained under rpm, 2.651 × 102DEG C~3.589 × 102It is dry at a temperature of DEG C, it grinds
0.647 × 10 is crossed after mill3~1.475 × 103Mesh sieves, spare；
3rd step：Separately take 2- [(the bromo- 9,10- dihydros -9,10- dioxos -1- anthryls of 4- amino -3-) amino] -5- toluenesulfonic acids
Osmium nanoparticle after mono-sodium salt and the processing of the 2nd step, is irradiated after mixing using the back reflection of low-angle alpha ray, the low-angle alpha ray back of the body
The energy for penetrating irradiation is 43.231MeV~71.891MeV, dosage is 91.90kGy~131.915kGy, irradiation time 55.8
~80.4 minutes, obtain character change 2- [(bromo- 9,10- dihydros -9, the 10- dioxo -1- anthryls of 4- amino -3-) amino] -
5- toluenesulfonic acids mono-sodium salt and osmium nanoparticle mixture；By 2- [(the bromo- 9,10- dihydros -9,10- dioxos of 4- amino -3- -
1- anthryls) amino] -5- toluenesulfonic acids mono-sodium salt and osmium nanoparticle mixture be placed in another stirred-tank reactor, open
Light oil heater in dynamic stirred-tank reactor, 54.1 DEG C~100.5 DEG C of set temperature start in stirred-tank reactor
Blender, rotating speed are 46rpm~441rpm, and pH is adjusted between 4.8~8.9, are dehydrated 55.4~69.5 minutes, spare；
4th step：2- [(the bromo- 9,10- dihydros -9,10- dioxos -1- anthracenes of 4- amino -3- that the character that 3rd step is obtained changes
Base) amino] -5- toluenesulfonic acids mono-sodium salt and osmium nanoparticle mixture, mass concentration is added to as 56.4ppm~286.4ppm
N- [5- [two [2- (1- oxygen propoxyl group) ethyl] amino] -4- methoxyl groups -2- [(5- nitro -2- thiazolyls) azo] phenyl] second
In amide, cocurrent is added in the stirred-tank reactor of the 1st step, and flow acceleration is 191mL/min~919mL/min；Startup is stirred
Still reaction mechanical stirrer is mixed, setting speed is 60rpm~100rpm；Stirring 4.8~8.9 minutes；N- methyl -3,4 are added,
5,6- tetrachloro phosphorus phthalimide start the light oil heater in stirred-tank reactor, are warming up to 90.1 DEG C~127.1
DEG C, pH is adjusted between 4.8~8.9, is passed through ammonia ventilatory capacity as 45.665m3/ min~86.666m3/ min, heat preservation are stood
80.0~110.9 minutes；Stirred-tank reactor blender is again started up, rotating speed is 55rpm~100rpm, adds in 3,5- diformazans
Oxygroup toluene, and pH is adjusted between 4.8~8.9, heat preservation stands 79.1~119.1 minutes；
5th step：Start the blender in stirred-tank reactor, setting speed is 52rpm~119rpm, and it is anti-to start stirring autoclave
The light oil heater in device is answered, sets temperature in stirred-tank reactor as 1.770 × 102DEG C~2.777 × 102DEG C, it adds in
The chloro- 3- of 4- (4,5- dihydro -3- methyl -5- oxo -1H- pyrazol-1-yls)-benzene sulfonic acid reacts 46.7~57.1 minutes；Later plus
Enter lauryl sulfate, start the light oil heater in stirred-tank reactor, set the temperature in stirred-tank reactor
Be 130.5 DEG C~186.7 DEG C, pH is adjusted between 4.8~8.9, pressure be 0.52MPa~0.53MPa, the reaction time 0.4
~0.9 hour；It is depressurized to 0MPa later, is cooled to 54.52 DEG C~59.52 DEG C dischargings to get to anti-skidding bed course (8-10)；
The grain size of the osmium nanoparticle is 60.9 μm~70.1 μm.
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Citations (6)
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|---|---|---|---|---|
| JPH0943037A (en) * | 1995-07-26 | 1997-02-14 | Yokohama Rubber Co Ltd:The | Metering apparatus |
| JP2001310285A (en) * | 2000-04-26 | 2001-11-06 | Aloka Co Ltd | Tube carrying device |
| JP2004502181A (en) * | 2000-06-29 | 2004-01-22 | ピーイー コーポレイション （エヌワイ） | Apparatus and method for transporting sample well tray |
| CN203471786U (en) * | 2013-09-10 | 2014-03-12 | 博奥赛斯（天津）生物科技有限公司 | Mechanical gripper of chemical luminescence immunity analyzer |
| CN203557377U (en) * | 2013-11-26 | 2014-04-23 | 四川峨胜水泥集团股份有限公司 | Mechanical arm for sampling for testing |
| CN105252531A (en) * | 2015-11-26 | 2016-01-20 | 哈尔滨工业大学 | Paw for double-position grabbing |
-
2017
- 2017-12-27 CN CN201711444355.XA patent/CN108152205B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0943037A (en) * | 1995-07-26 | 1997-02-14 | Yokohama Rubber Co Ltd:The | Metering apparatus |
| JP2001310285A (en) * | 2000-04-26 | 2001-11-06 | Aloka Co Ltd | Tube carrying device |
| JP2004502181A (en) * | 2000-06-29 | 2004-01-22 | ピーイー コーポレイション （エヌワイ） | Apparatus and method for transporting sample well tray |
| CN203471786U (en) * | 2013-09-10 | 2014-03-12 | 博奥赛斯（天津）生物科技有限公司 | Mechanical gripper of chemical luminescence immunity analyzer |
| CN203557377U (en) * | 2013-11-26 | 2014-04-23 | 四川峨胜水泥集团股份有限公司 | Mechanical arm for sampling for testing |
| CN105252531A (en) * | 2015-11-26 | 2016-01-20 | 哈尔滨工业大学 | Paw for double-position grabbing |
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