CN108117265A - A kind of radiation-screening tempered glass and its manufacturing method - Google Patents
A kind of radiation-screening tempered glass and its manufacturing method Download PDFInfo
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- CN108117265A CN108117265A CN201711455047.7A CN201711455047A CN108117265A CN 108117265 A CN108117265 A CN 108117265A CN 201711455047 A CN201711455047 A CN 201711455047A CN 108117265 A CN108117265 A CN 108117265A
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C14/00—Glass compositions containing a non-glass component, e.g. compositions containing fibres, filaments, whiskers, platelets, or the like, dispersed in a glass matrix
- C03C14/002—Glass compositions containing a non-glass component, e.g. compositions containing fibres, filaments, whiskers, platelets, or the like, dispersed in a glass matrix the non-glass component being in the form of fibres, filaments, yarns, felts or woven material
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B13/00—Rolling molten glass, i.e. where the molten glass is shaped by rolling
- C03B13/01—Rolling profiled glass articles, e.g. with I, L, T cross-sectional profiles
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B27/00—Tempering or quenching glass products
- C03B27/04—Tempering or quenching glass products using gas
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3636—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer one layer at least containing silicon, hydrogenated silicon or a silicide
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3644—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the metal being silver
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3649—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer made of metals other than silver
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/10—Deposition methods
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Ceramic Engineering (AREA)
- Dispersion Chemistry (AREA)
- Glass Compositions (AREA)
Abstract
The invention discloses a kind of radiation-screening tempered glass and its manufacturing method, which includes 85 parts 90 parts of silica, 8 parts 10 parts of 2 parts 3 parts of 10 parts 15 parts of 5 parts 8 parts of oxidation tungsten filament, sodium oxide molybdena, aluminium oxide, the calcium oxide of diameter 0.1mm by weight;This liposome surface also deposits the 4 layers of silver-colored sial composite deposition film that have three layers, then physical toughened to be made by using pyrolytic deposition surface coating after iron-free material vacuum melting.Radiation-screening tempered glass itself the anti-shielding ability of the present invention is strong, good toughness, translucency are good, shock resistance is good, not easy to change.
Description
Technical field
The present invention relates to glassware field more particularly to a kind of radiation-screening tempered glass and its manufacturing methods.
Background technology
Tempered glass, i.e. surface have the glass of compression, can be obtained in routine techniques by physical method or chemical method
, glass bears to offset skin stress first during external force, and so as to improve bearing capacity, reinforcing glass itself anti-wind pressure is trembled with fear
Heat, impact etc..No sharp side, security are preferable when these glass rupture.
But it is with the development of the times, much higher and higher using requirement of the field to tempered glass, pursue quality of the life
People had not only required the translucent effect of glass, but also required stabilization non-discolouring, while there is also a need for glass and have certain radioresistance energy
Power, but tempered glass of the prior art, are limited to the prior art and conventional production process, the light transmittance of non-browning glass and steady
Qualitative very poor (easy to change), translucency are then inversely proportional (conflict index, it is difficult to coexist) with capability of resistance to radiation, stablize constant
The glass of color does not possess the characteristics of radioresistance and good translucency again.
Therefore, a kind of itself anti-shielding ability of urgent need is strong on the market, good toughness, translucency are good, shock resistance is good, are not easy
The radiation-screening tempered glass and its manufacturing method of discoloration.
The content of the invention
In view of the above defects of the prior art, the present invention is intended to provide itself a kind of anti-shielding ability is strong, toughness
The radiation-screening tempered glass good, translucency is good, shock resistance is good, not easy to change and its manufacturing method.
To achieve these goals, the present invention uses following technical scheme:A kind of manufacturer of radiation-screening tempered glass
Method comprises the following steps:
1) prepare before production
1. glass raw material prepares:Prepare 85 parts -90 parts of silica, the oxidation tungsten filament 5 of diameter 0.1mm by weight
- 8 parts of part, 10 parts -15 parts of sodium oxide molybdena, 2 parts -3 parts of aluminium oxide, 8 parts -10 parts of calcium oxide;
2. surface modifying material prepares:Enough fine silver, enough fine aluminiums, enough pure silicons;
2) this plastid of glass is fired and surface is modified
1. by with 1) in the step silica, sodium oxide molybdena, aluminium oxide, the calcium oxide that 1. prepare be uniformly mixed, mixed
Object;
2. 1. mixture that step is obtained is placed in vacuum electric heating treatment furnace, after 1250 DEG C -1300 DEG C are warming up in stove
It is stirred with the rate of 60rpm-80rpm, molten bath liquid is obtained after stirring;
3. step in 1) is 1. prepared tungsten oxide silk spinning is made into the layer net that smooth vertical and horizontal and aperture is length of side 2mm square holes, with
3mm is equidistantly laid in a mold for interlamellar spacing, and the molten bath liquid for then 2. obtaining step is cast in vacuum environment into mold,
Obtain glass this plastid fluid;
4. by this plastid of glass fluid in mold under vacuum conditions with the calendering rate of 10%/h-12%/h, 25%
Total calendering deflection carry out roll-in calendering process, until obtaining the rolled glass fluid for meeting design size;
5. silver, silicon, aluminium are sequentially deposited at by flow surface, and repeated deposition, single-layer metal using high temperature pyrolysis sedimentation
1 μm -1.5 μm of deposition thickness, with include silver, silicon, aluminium film composite film be calculated as 1 tunic, until obtaining 3 layers of -4 layers of silver-colored silicon
Aluminium composite deposition film;
3) this plastid of glass tempering
1. this plastid of glass that flow-like is filled in mold is gas-cooled under the nitrogen of 5bar-6bar, i.e., needed for acquisition
Radiation-screening tempered glass.
The radiation-screening tempered glass manufactured using the above method, this plastid composition include titanium dioxide by weight
2 parts -3 parts of 10 parts -15 parts of 5 parts -8 parts of oxidation tungsten filament, sodium oxide molybdena, aluminium oxide, the calcium oxide 8 of 85 parts -90 parts of silicon, diameter 0.1mm
- 10 parts of part;This liposome surface also deposits -4 layers of silver-colored sial composite deposition film that have three layers.
Compared with the prior art, the present invention has the following advantages as a result of said program:(1) using iron-free
Raw material, greatly reduce the present invention glass raw material in irony content, according to correlative study, the smaller glass of iron content it is saturating
Light rate is better, and glass of the invention is compounded with light transmittance still up to 92% in the case of oxidation tungsten filament and surface coating, greatly
Ground is better than the non-browning glass of the prior art, simultaneously because still fully belonging to unorganic glass, intensity and wearability are also far above
(non-browning glass in routine techniques is broadly divided into organic glass:1. common non-browning glass generally uses nickel alloy silk screen skill
Art, shield effectiveness is good, but light transmittance is low, has an impact to vision;2nd, high lead optical glass mainly adds in glass composition
The higher oxide of atomic number, wherein predominantly PbO, such glass has preferable shielding property, but it is steady to there is chemistry
It is qualitative poor, glass itself radiation resistance difference it is easy to change the problems such as;3. radiation protection organic glass, such glass uses methyl mostly
Methyl acrylate glass, and introduce the metallic elements such as lead, barium, samarium wherein and realize its shielding property.Its shortcoming mainly has
Machine strength of glass hardness is low, and scratch-resistant poor performance, alpha ray shield scope is also than relatively limited etc.).(2) present invention is also in glass matrix
It adds and compares thinner more loose oxidation tungsten silk screen with the prior art, what it is different from nickel alloy is molecular weight due to tungsten in itself
Larger, radiation-proof effect is more preferable, simultaneously because first layer radiation proof function of the present invention is realized by surface deposition film, metal
The effect of oxide silk is light intensity (the shorter light wave of the wavelength such as ultraviolet light for absorbing harmful radiation and being further reduced high-energy radiation
Deng), the light of injection is made not hinder eye, Low emissivity energy in the case that distortionless softer.(3) it is different from routine techniques
Surface coating is realized using magnetron sputtering after glass shaping, but directly on surface after glass obtains specular surface by roll-in
Progress is compound in the form of hot high activity free metal, is substantially better than post-production with reference to power and has simplified process, saved energy
Source simultaneously because being done directly pouring, roll-in and surface deposition in vacuum environment, largely eliminates bubble generation
Possibility so that the glass integrality of acquisition is more preferable, post-processing is less, and since all meltings and surface deposition are heating
It is completed under state, therefore can tempering only be realized by physics mode, on the one hand make film layer combined strength bination higher, surface pressure should
Power it is stronger (about 450MPa, mainly due to except quenching quickly cooling stress outside also have due to calendering generation uniform residual stress,
The bearing stress layer for making the present invention is deeper stronger), on the other hand due to there is no applied chemistry mode (such as Li ion exchanges), more
Beneficial to environmental protection, (environmental pollution caused by present National Industrial has strict requirements, therefore this advantage of the present invention makes it more
Suitable for modern industrial production).
Specific embodiment
Embodiment 1:
A kind of radiation-screening tempered glass, this plastid composition include silica 85Kg, diameter by weight
Oxidation tungsten filament 8Kg, sodium oxide molybdena 15Kg, aluminium oxide 3Kg, the calcium oxide 10Kg of 0.1mm;This liposome surface also deposits the silver that haves three layers
Sial composite deposition film.
The manufacturing method of above-mentioned radiation-screening tempered glass, comprises the following steps:
1) prepare before production
1. glass raw material prepares:Prepare silica 85Kg, the oxidation tungsten filament 8Kg of diameter 0.1mm, oxidation by weight
Sodium 15Kg, aluminium oxide 3Kg, calcium oxide 10Kg;
2. surface modifying material prepares:Enough fine silver, enough fine aluminiums, enough pure silicons;
2) this plastid of glass is fired and surface is modified
1. by with 1) in the step silica, sodium oxide molybdena, aluminium oxide, the calcium oxide that 1. prepare be uniformly mixed, mixed
Object;
2. 1. mixture that step is obtained is placed in vacuum electric heating treatment furnace, it is warming up in stove after 1250 DEG C with 60rpm
Rate stirring, after stirring obtain molten bath liquid;
3. step in 1) is 1. prepared tungsten oxide silk spinning is made into the layer net that smooth vertical and horizontal and aperture is length of side 2mm square holes, with
3mm is equidistantly laid in a mold for interlamellar spacing, and the molten bath liquid for then 2. obtaining step is cast in vacuum environment into mold,
Obtain glass this plastid fluid;
4. by this plastid of glass fluid in mold under vacuum conditions with the calendering rate of 10%/h, 25% total calendering
Deflection carries out roll-in calendering process, until obtaining the rolled glass fluid for meeting design size;
5. silver, silicon, aluminium are sequentially deposited at by flow surface, and repeated deposition, single-layer metal using high temperature pyrolysis sedimentation
1 μm -1.5 μm of deposition thickness, with include silver, silicon, aluminium film composite film be calculated as 1 tunic, answered until obtaining 3 layers of silver-colored sial
Close deposition film;
3) this plastid of glass tempering
1. this plastid of glass that flow-like is filled in mold is gas-cooled under the nitrogen of 5bar, that is, obtain required shielding spoke
Penetrate tempered glass.
According to the radiation-screening tempered glass light transmittance that the present embodiment produces up to the 90%, harmful radiation of abatement 87%
(using simple glass radiation transmission amount as radix, the only remaining harmful radiation of residue 13%), 93% ultraviolet light of abatement, bearing stress
430MPa。
Embodiment 2:
A kind of radiation-screening tempered glass, this plastid composition include silica 90Kg, diameter by weight
Oxidation tungsten filament 5Kg, sodium oxide molybdena 10Kg, aluminium oxide 2Kg, the calcium oxide 8Kg of 0.1mm;This liposome surface has also deposited 4 layers of silver-colored silicon
Aluminium composite deposition film.
The manufacturing method of above-mentioned radiation-screening tempered glass, comprises the following steps:
1) prepare before production
1. glass raw material prepares:Prepare silica 90Kg, the oxidation tungsten filament 5Kg of diameter 0.1mm, oxidation by weight
Sodium 10Kg, aluminium oxide 2Kg, calcium oxide 8Kg;
2. surface modifying material prepares:Enough fine silver, enough fine aluminiums, enough pure silicons;
2) this plastid of glass is fired and surface is modified
1. by with 1) in the step silica, sodium oxide molybdena, aluminium oxide, the calcium oxide that 1. prepare be uniformly mixed, mixed
Object;
2. 1. mixture that step is obtained is placed in vacuum electric heating treatment furnace, it is warming up in stove after 1300 DEG C with 80rpm
Rate stirring, after stirring obtain molten bath liquid;
3. step in 1) is 1. prepared tungsten oxide silk spinning is made into the layer net that smooth vertical and horizontal and aperture is length of side 2mm square holes, with
3mm is equidistantly laid in a mold for interlamellar spacing, and the molten bath liquid for then 2. obtaining step is cast in vacuum environment into mold,
Obtain glass this plastid fluid;
4. by this plastid of glass fluid in mold under vacuum conditions with the calendering rate of 12%/h, 25% total calendering
Deflection carries out roll-in calendering process, until obtaining the rolled glass fluid for meeting design size;
5. silver, silicon, aluminium are sequentially deposited at by flow surface, and repeated deposition, single-layer metal using high temperature pyrolysis sedimentation
1 μm -1.5 μm of deposition thickness, with include silver, silicon, aluminium film composite film be calculated as 1 tunic, answered until obtaining 4 layers of silver-colored sial
Close deposition film;
3) this plastid of glass tempering
1. this plastid of glass that flow-like is filled in mold is gas-cooled under the nitrogen of 6bar, that is, obtain required shielding spoke
Penetrate tempered glass.
According to the radiation-screening tempered glass light transmittance that the present embodiment produces up to the 92%, harmful radiation of abatement 85%
(using simple glass radiation transmission amount as radix, the only remaining harmful radiation of residue 15%), 90% ultraviolet light of abatement, bearing stress
450MPa。
The foregoing description of the disclosed embodiments, only for professional and technical personnel in the field is enable to realize or use this
Invention.A variety of modifications of these embodiments will be apparent for those skilled in the art, institute herein
The General Principle of definition can be realized in other embodiments without departing from the spirit or scope of the present invention.Therefore,
The present invention is not intended to be limited to the embodiments shown herein, and is to fit to special with principles disclosed herein and novelty
The consistent most wide scope of point.
Claims (2)
1. a kind of manufacturing method of radiation-screening tempered glass, it is characterised in that comprise the following steps:
1) prepare before production
1. glass raw material prepares:Prepare 5 part -8 of the oxidation tungsten filament of 85 parts -90 parts of silica, diameter 0.1mm by weight
Part, 10 parts -15 parts of sodium oxide molybdena, 2 parts -3 parts of aluminium oxide, 8 parts -10 parts of calcium oxide;
2. surface modifying material prepares:Enough fine silver, enough fine aluminiums, enough pure silicons;
2) this plastid of glass is fired and surface is modified
1. by with 1) in the step silica, sodium oxide molybdena, aluminium oxide, the calcium oxide that 1. prepare be uniformly mixed, obtain mixture;
2. 1. mixture that step is obtained is placed in vacuum electric heating treatment furnace, be warming up in stove after 1250 DEG C -1300 DEG C with
The rate stirring of 60rpm-80rpm, obtains molten bath liquid after stirring;
3. step in 1) is 1. prepared tungsten oxide silk spinning is made into the layer net that smooth vertical and horizontal and aperture is length of side 2mm square holes, using 3mm as
Interlamellar spacing is equidistantly laid in a mold, and the molten bath liquid for then 2. obtaining step is cast in vacuum environment into mold, is obtained
Glass this plastid fluid;
4. by this plastid of glass fluid in mold under vacuum conditions with the calendering rate of 10%/h-12%/h, 25% it is total
Roll deflection and carry out roll-in calendering process, until obtaining the rolled glass fluid for meeting design size;
5. silver, silicon, aluminium are sequentially deposited at flow surface, and repeated deposition using high temperature pyrolysis sedimentation, single-layer metal sinks
Product 1 μm -1.5 μm of thickness, with include silver, silicon, aluminium film composite film be calculated as 1 tunic, until obtain 3 layers -4 layers silver sial answer
Close deposition film;
3) this plastid of glass tempering
1. this plastid of glass that flow-like is filled in mold is gas-cooled under the nitrogen of 5bar-6bar, that is, obtain required shielding
Radiation toughened glass.
2. a kind of radiation-screening tempered glass manufactured using claim 1 the method, it is characterised in that:Its this plastid composition
Including by weight 85 parts -90 parts of silica, 10 parts -15 parts of 5 parts -8 parts of oxidation tungsten filament, the sodium oxide molybdena of diameter 0.1mm,
2 parts -3 parts of aluminium oxide, 8 parts -10 parts of calcium oxide;This liposome surface also deposits -4 layers of silver-colored sial composite deposition film that have three layers.
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CN201711455047.7A CN108117265A (en) | 2017-12-28 | 2017-12-28 | A kind of radiation-screening tempered glass and its manufacturing method |
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CN103387342A (en) * | 2013-08-05 | 2013-11-13 | 常熟市卓诚玻璃制品贸易有限公司 | One-way visible glass |
CN103641326A (en) * | 2013-11-22 | 2014-03-19 | 张亚峰 | Anti-radiation glass |
CN104234592A (en) * | 2014-09-03 | 2014-12-24 | 张玉芬 | Heat absorption wired glass |
CN105293933A (en) * | 2015-11-02 | 2016-02-03 | 北京航玻新材料技术有限公司 | Corrugated microcrystalline glass and preparation method thereof |
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Title |
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