CN108117265A - A kind of radiation-screening tempered glass and its manufacturing method - Google Patents

A kind of radiation-screening tempered glass and its manufacturing method Download PDF

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Publication number
CN108117265A
CN108117265A CN201711455047.7A CN201711455047A CN108117265A CN 108117265 A CN108117265 A CN 108117265A CN 201711455047 A CN201711455047 A CN 201711455047A CN 108117265 A CN108117265 A CN 108117265A
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Prior art keywords
parts
glass
radiation
plastid
silver
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CN201711455047.7A
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Chinese (zh)
Inventor
孙惠丽
黄佳钰
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Ningbo Chenxin Li Energy Co Ltd
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Ningbo Chenxin Li Energy Co Ltd
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Priority to CN201711455047.7A priority Critical patent/CN108117265A/en
Publication of CN108117265A publication Critical patent/CN108117265A/en
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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C14/00Glass compositions containing a non-glass component, e.g. compositions containing fibres, filaments, whiskers, platelets, or the like, dispersed in a glass matrix
    • C03C14/002Glass compositions containing a non-glass component, e.g. compositions containing fibres, filaments, whiskers, platelets, or the like, dispersed in a glass matrix the non-glass component being in the form of fibres, filaments, yarns, felts or woven material
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B13/00Rolling molten glass, i.e. where the molten glass is shaped by rolling
    • C03B13/01Rolling profiled glass articles, e.g. with I, L, T cross-sectional profiles
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B27/00Tempering or quenching glass products
    • C03B27/04Tempering or quenching glass products using gas
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C1/00Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • C03C17/3602Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
    • C03C17/3636Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer one layer at least containing silicon, hydrogenated silicon or a silicide
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • C03C17/3602Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
    • C03C17/3644Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the metal being silver
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • C03C17/3602Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
    • C03C17/3649Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer made of metals other than silver
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2218/00Methods for coating glass
    • C03C2218/10Deposition methods

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Glass Compositions (AREA)

Abstract

The invention discloses a kind of radiation-screening tempered glass and its manufacturing method, which includes 85 parts 90 parts of silica, 8 parts 10 parts of 2 parts 3 parts of 10 parts 15 parts of 5 parts 8 parts of oxidation tungsten filament, sodium oxide molybdena, aluminium oxide, the calcium oxide of diameter 0.1mm by weight;This liposome surface also deposits the 4 layers of silver-colored sial composite deposition film that have three layers, then physical toughened to be made by using pyrolytic deposition surface coating after iron-free material vacuum melting.Radiation-screening tempered glass itself the anti-shielding ability of the present invention is strong, good toughness, translucency are good, shock resistance is good, not easy to change.

Description

A kind of radiation-screening tempered glass and its manufacturing method
Technical field
The present invention relates to glassware field more particularly to a kind of radiation-screening tempered glass and its manufacturing methods.
Background technology
Tempered glass, i.e. surface have the glass of compression, can be obtained in routine techniques by physical method or chemical method , glass bears to offset skin stress first during external force, and so as to improve bearing capacity, reinforcing glass itself anti-wind pressure is trembled with fear Heat, impact etc..No sharp side, security are preferable when these glass rupture.
But it is with the development of the times, much higher and higher using requirement of the field to tempered glass, pursue quality of the life People had not only required the translucent effect of glass, but also required stabilization non-discolouring, while there is also a need for glass and have certain radioresistance energy Power, but tempered glass of the prior art, are limited to the prior art and conventional production process, the light transmittance of non-browning glass and steady Qualitative very poor (easy to change), translucency are then inversely proportional (conflict index, it is difficult to coexist) with capability of resistance to radiation, stablize constant The glass of color does not possess the characteristics of radioresistance and good translucency again.
Therefore, a kind of itself anti-shielding ability of urgent need is strong on the market, good toughness, translucency are good, shock resistance is good, are not easy The radiation-screening tempered glass and its manufacturing method of discoloration.
The content of the invention
In view of the above defects of the prior art, the present invention is intended to provide itself a kind of anti-shielding ability is strong, toughness The radiation-screening tempered glass good, translucency is good, shock resistance is good, not easy to change and its manufacturing method.
To achieve these goals, the present invention uses following technical scheme:A kind of manufacturer of radiation-screening tempered glass Method comprises the following steps:
1) prepare before production
1. glass raw material prepares:Prepare 85 parts -90 parts of silica, the oxidation tungsten filament 5 of diameter 0.1mm by weight - 8 parts of part, 10 parts -15 parts of sodium oxide molybdena, 2 parts -3 parts of aluminium oxide, 8 parts -10 parts of calcium oxide;
2. surface modifying material prepares:Enough fine silver, enough fine aluminiums, enough pure silicons;
2) this plastid of glass is fired and surface is modified
1. by with 1) in the step silica, sodium oxide molybdena, aluminium oxide, the calcium oxide that 1. prepare be uniformly mixed, mixed Object;
2. 1. mixture that step is obtained is placed in vacuum electric heating treatment furnace, after 1250 DEG C -1300 DEG C are warming up in stove It is stirred with the rate of 60rpm-80rpm, molten bath liquid is obtained after stirring;
3. step in 1) is 1. prepared tungsten oxide silk spinning is made into the layer net that smooth vertical and horizontal and aperture is length of side 2mm square holes, with 3mm is equidistantly laid in a mold for interlamellar spacing, and the molten bath liquid for then 2. obtaining step is cast in vacuum environment into mold, Obtain glass this plastid fluid;
4. by this plastid of glass fluid in mold under vacuum conditions with the calendering rate of 10%/h-12%/h, 25% Total calendering deflection carry out roll-in calendering process, until obtaining the rolled glass fluid for meeting design size;
5. silver, silicon, aluminium are sequentially deposited at by flow surface, and repeated deposition, single-layer metal using high temperature pyrolysis sedimentation 1 μm -1.5 μm of deposition thickness, with include silver, silicon, aluminium film composite film be calculated as 1 tunic, until obtaining 3 layers of -4 layers of silver-colored silicon Aluminium composite deposition film;
3) this plastid of glass tempering
1. this plastid of glass that flow-like is filled in mold is gas-cooled under the nitrogen of 5bar-6bar, i.e., needed for acquisition Radiation-screening tempered glass.
The radiation-screening tempered glass manufactured using the above method, this plastid composition include titanium dioxide by weight 2 parts -3 parts of 10 parts -15 parts of 5 parts -8 parts of oxidation tungsten filament, sodium oxide molybdena, aluminium oxide, the calcium oxide 8 of 85 parts -90 parts of silicon, diameter 0.1mm - 10 parts of part;This liposome surface also deposits -4 layers of silver-colored sial composite deposition film that have three layers.
Compared with the prior art, the present invention has the following advantages as a result of said program:(1) using iron-free Raw material, greatly reduce the present invention glass raw material in irony content, according to correlative study, the smaller glass of iron content it is saturating Light rate is better, and glass of the invention is compounded with light transmittance still up to 92% in the case of oxidation tungsten filament and surface coating, greatly Ground is better than the non-browning glass of the prior art, simultaneously because still fully belonging to unorganic glass, intensity and wearability are also far above (non-browning glass in routine techniques is broadly divided into organic glass:1. common non-browning glass generally uses nickel alloy silk screen skill Art, shield effectiveness is good, but light transmittance is low, has an impact to vision;2nd, high lead optical glass mainly adds in glass composition The higher oxide of atomic number, wherein predominantly PbO, such glass has preferable shielding property, but it is steady to there is chemistry It is qualitative poor, glass itself radiation resistance difference it is easy to change the problems such as;3. radiation protection organic glass, such glass uses methyl mostly Methyl acrylate glass, and introduce the metallic elements such as lead, barium, samarium wherein and realize its shielding property.Its shortcoming mainly has Machine strength of glass hardness is low, and scratch-resistant poor performance, alpha ray shield scope is also than relatively limited etc.).(2) present invention is also in glass matrix It adds and compares thinner more loose oxidation tungsten silk screen with the prior art, what it is different from nickel alloy is molecular weight due to tungsten in itself Larger, radiation-proof effect is more preferable, simultaneously because first layer radiation proof function of the present invention is realized by surface deposition film, metal The effect of oxide silk is light intensity (the shorter light wave of the wavelength such as ultraviolet light for absorbing harmful radiation and being further reduced high-energy radiation Deng), the light of injection is made not hinder eye, Low emissivity energy in the case that distortionless softer.(3) it is different from routine techniques Surface coating is realized using magnetron sputtering after glass shaping, but directly on surface after glass obtains specular surface by roll-in Progress is compound in the form of hot high activity free metal, is substantially better than post-production with reference to power and has simplified process, saved energy Source simultaneously because being done directly pouring, roll-in and surface deposition in vacuum environment, largely eliminates bubble generation Possibility so that the glass integrality of acquisition is more preferable, post-processing is less, and since all meltings and surface deposition are heating It is completed under state, therefore can tempering only be realized by physics mode, on the one hand make film layer combined strength bination higher, surface pressure should Power it is stronger (about 450MPa, mainly due to except quenching quickly cooling stress outside also have due to calendering generation uniform residual stress, The bearing stress layer for making the present invention is deeper stronger), on the other hand due to there is no applied chemistry mode (such as Li ion exchanges), more Beneficial to environmental protection, (environmental pollution caused by present National Industrial has strict requirements, therefore this advantage of the present invention makes it more Suitable for modern industrial production).
Specific embodiment
Embodiment 1:
A kind of radiation-screening tempered glass, this plastid composition include silica 85Kg, diameter by weight Oxidation tungsten filament 8Kg, sodium oxide molybdena 15Kg, aluminium oxide 3Kg, the calcium oxide 10Kg of 0.1mm;This liposome surface also deposits the silver that haves three layers Sial composite deposition film.
The manufacturing method of above-mentioned radiation-screening tempered glass, comprises the following steps:
1) prepare before production
1. glass raw material prepares:Prepare silica 85Kg, the oxidation tungsten filament 8Kg of diameter 0.1mm, oxidation by weight Sodium 15Kg, aluminium oxide 3Kg, calcium oxide 10Kg;
2. surface modifying material prepares:Enough fine silver, enough fine aluminiums, enough pure silicons;
2) this plastid of glass is fired and surface is modified
1. by with 1) in the step silica, sodium oxide molybdena, aluminium oxide, the calcium oxide that 1. prepare be uniformly mixed, mixed Object;
2. 1. mixture that step is obtained is placed in vacuum electric heating treatment furnace, it is warming up in stove after 1250 DEG C with 60rpm Rate stirring, after stirring obtain molten bath liquid;
3. step in 1) is 1. prepared tungsten oxide silk spinning is made into the layer net that smooth vertical and horizontal and aperture is length of side 2mm square holes, with 3mm is equidistantly laid in a mold for interlamellar spacing, and the molten bath liquid for then 2. obtaining step is cast in vacuum environment into mold, Obtain glass this plastid fluid;
4. by this plastid of glass fluid in mold under vacuum conditions with the calendering rate of 10%/h, 25% total calendering Deflection carries out roll-in calendering process, until obtaining the rolled glass fluid for meeting design size;
5. silver, silicon, aluminium are sequentially deposited at by flow surface, and repeated deposition, single-layer metal using high temperature pyrolysis sedimentation 1 μm -1.5 μm of deposition thickness, with include silver, silicon, aluminium film composite film be calculated as 1 tunic, answered until obtaining 3 layers of silver-colored sial Close deposition film;
3) this plastid of glass tempering
1. this plastid of glass that flow-like is filled in mold is gas-cooled under the nitrogen of 5bar, that is, obtain required shielding spoke Penetrate tempered glass.
According to the radiation-screening tempered glass light transmittance that the present embodiment produces up to the 90%, harmful radiation of abatement 87% (using simple glass radiation transmission amount as radix, the only remaining harmful radiation of residue 13%), 93% ultraviolet light of abatement, bearing stress 430MPa。
Embodiment 2:
A kind of radiation-screening tempered glass, this plastid composition include silica 90Kg, diameter by weight Oxidation tungsten filament 5Kg, sodium oxide molybdena 10Kg, aluminium oxide 2Kg, the calcium oxide 8Kg of 0.1mm;This liposome surface has also deposited 4 layers of silver-colored silicon Aluminium composite deposition film.
The manufacturing method of above-mentioned radiation-screening tempered glass, comprises the following steps:
1) prepare before production
1. glass raw material prepares:Prepare silica 90Kg, the oxidation tungsten filament 5Kg of diameter 0.1mm, oxidation by weight Sodium 10Kg, aluminium oxide 2Kg, calcium oxide 8Kg;
2. surface modifying material prepares:Enough fine silver, enough fine aluminiums, enough pure silicons;
2) this plastid of glass is fired and surface is modified
1. by with 1) in the step silica, sodium oxide molybdena, aluminium oxide, the calcium oxide that 1. prepare be uniformly mixed, mixed Object;
2. 1. mixture that step is obtained is placed in vacuum electric heating treatment furnace, it is warming up in stove after 1300 DEG C with 80rpm Rate stirring, after stirring obtain molten bath liquid;
3. step in 1) is 1. prepared tungsten oxide silk spinning is made into the layer net that smooth vertical and horizontal and aperture is length of side 2mm square holes, with 3mm is equidistantly laid in a mold for interlamellar spacing, and the molten bath liquid for then 2. obtaining step is cast in vacuum environment into mold, Obtain glass this plastid fluid;
4. by this plastid of glass fluid in mold under vacuum conditions with the calendering rate of 12%/h, 25% total calendering Deflection carries out roll-in calendering process, until obtaining the rolled glass fluid for meeting design size;
5. silver, silicon, aluminium are sequentially deposited at by flow surface, and repeated deposition, single-layer metal using high temperature pyrolysis sedimentation 1 μm -1.5 μm of deposition thickness, with include silver, silicon, aluminium film composite film be calculated as 1 tunic, answered until obtaining 4 layers of silver-colored sial Close deposition film;
3) this plastid of glass tempering
1. this plastid of glass that flow-like is filled in mold is gas-cooled under the nitrogen of 6bar, that is, obtain required shielding spoke Penetrate tempered glass.
According to the radiation-screening tempered glass light transmittance that the present embodiment produces up to the 92%, harmful radiation of abatement 85% (using simple glass radiation transmission amount as radix, the only remaining harmful radiation of residue 15%), 90% ultraviolet light of abatement, bearing stress 450MPa。
The foregoing description of the disclosed embodiments, only for professional and technical personnel in the field is enable to realize or use this Invention.A variety of modifications of these embodiments will be apparent for those skilled in the art, institute herein The General Principle of definition can be realized in other embodiments without departing from the spirit or scope of the present invention.Therefore, The present invention is not intended to be limited to the embodiments shown herein, and is to fit to special with principles disclosed herein and novelty The consistent most wide scope of point.

Claims (2)

1. a kind of manufacturing method of radiation-screening tempered glass, it is characterised in that comprise the following steps:
1) prepare before production
1. glass raw material prepares:Prepare 5 part -8 of the oxidation tungsten filament of 85 parts -90 parts of silica, diameter 0.1mm by weight Part, 10 parts -15 parts of sodium oxide molybdena, 2 parts -3 parts of aluminium oxide, 8 parts -10 parts of calcium oxide;
2. surface modifying material prepares:Enough fine silver, enough fine aluminiums, enough pure silicons;
2) this plastid of glass is fired and surface is modified
1. by with 1) in the step silica, sodium oxide molybdena, aluminium oxide, the calcium oxide that 1. prepare be uniformly mixed, obtain mixture;
2. 1. mixture that step is obtained is placed in vacuum electric heating treatment furnace, be warming up in stove after 1250 DEG C -1300 DEG C with The rate stirring of 60rpm-80rpm, obtains molten bath liquid after stirring;
3. step in 1) is 1. prepared tungsten oxide silk spinning is made into the layer net that smooth vertical and horizontal and aperture is length of side 2mm square holes, using 3mm as Interlamellar spacing is equidistantly laid in a mold, and the molten bath liquid for then 2. obtaining step is cast in vacuum environment into mold, is obtained Glass this plastid fluid;
4. by this plastid of glass fluid in mold under vacuum conditions with the calendering rate of 10%/h-12%/h, 25% it is total Roll deflection and carry out roll-in calendering process, until obtaining the rolled glass fluid for meeting design size;
5. silver, silicon, aluminium are sequentially deposited at flow surface, and repeated deposition using high temperature pyrolysis sedimentation, single-layer metal sinks Product 1 μm -1.5 μm of thickness, with include silver, silicon, aluminium film composite film be calculated as 1 tunic, until obtain 3 layers -4 layers silver sial answer Close deposition film;
3) this plastid of glass tempering
1. this plastid of glass that flow-like is filled in mold is gas-cooled under the nitrogen of 5bar-6bar, that is, obtain required shielding Radiation toughened glass.
2. a kind of radiation-screening tempered glass manufactured using claim 1 the method, it is characterised in that:Its this plastid composition Including by weight 85 parts -90 parts of silica, 10 parts -15 parts of 5 parts -8 parts of oxidation tungsten filament, the sodium oxide molybdena of diameter 0.1mm, 2 parts -3 parts of aluminium oxide, 8 parts -10 parts of calcium oxide;This liposome surface also deposits -4 layers of silver-colored sial composite deposition film that have three layers.
CN201711455047.7A 2017-12-28 2017-12-28 A kind of radiation-screening tempered glass and its manufacturing method Pending CN108117265A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711455047.7A CN108117265A (en) 2017-12-28 2017-12-28 A kind of radiation-screening tempered glass and its manufacturing method

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Application Number Priority Date Filing Date Title
CN201711455047.7A CN108117265A (en) 2017-12-28 2017-12-28 A kind of radiation-screening tempered glass and its manufacturing method

Publications (1)

Publication Number Publication Date
CN108117265A true CN108117265A (en) 2018-06-05

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Publication number Priority date Publication date Assignee Title
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CN102219376A (en) * 2011-04-16 2011-10-19 浙江晶兴太阳能科技有限公司 Preparation method of solar ultrawhite ultrathin glass and product thereof
CN102557479A (en) * 2011-12-26 2012-07-11 李德杰 Non-reciprocal type sun-shade low-radiation glass
CN103387342A (en) * 2013-08-05 2013-11-13 常熟市卓诚玻璃制品贸易有限公司 One-way visible glass
CN103641326A (en) * 2013-11-22 2014-03-19 张亚峰 Anti-radiation glass
CN104234592A (en) * 2014-09-03 2014-12-24 张玉芬 Heat absorption wired glass
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EP2303791A1 (en) * 2008-06-25 2011-04-06 Centre Luxembourgeois de Recherches pour le Verre et la Céramique S.A. ( C.R.V.C.) Coated article with low-e coating including zirconium oxide and/or zirconium silicon oxynitride and methods of making same
CN102219376A (en) * 2011-04-16 2011-10-19 浙江晶兴太阳能科技有限公司 Preparation method of solar ultrawhite ultrathin glass and product thereof
CN102557479A (en) * 2011-12-26 2012-07-11 李德杰 Non-reciprocal type sun-shade low-radiation glass
CN103387342A (en) * 2013-08-05 2013-11-13 常熟市卓诚玻璃制品贸易有限公司 One-way visible glass
CN103641326A (en) * 2013-11-22 2014-03-19 张亚峰 Anti-radiation glass
CN104234592A (en) * 2014-09-03 2014-12-24 张玉芬 Heat absorption wired glass
CN105293933A (en) * 2015-11-02 2016-02-03 北京航玻新材料技术有限公司 Corrugated microcrystalline glass and preparation method thereof

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* Cited by examiner, † Cited by third party
Title
蒋晓辉: "《最新新型工程材料生产新技术应用与新产品开发研制及行业技术标准实用大全 10 材料分析测试卷》", 30 November 2004, 学苑音像出版社 *
陈景华: "《无机非金属材料热工过程及设备》", 30 April 2015, 华东理工大学出版社 *
隋良志等: "《建筑与装饰材料》", 30 September 2008, 天津大学出版社 *

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