CN108101701A - A kind of special water-soluble powder fertilizer of humic acid type sweet cherry and its production technology - Google Patents
A kind of special water-soluble powder fertilizer of humic acid type sweet cherry and its production technology Download PDFInfo
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- CN108101701A CN108101701A CN201711400938.2A CN201711400938A CN108101701A CN 108101701 A CN108101701 A CN 108101701A CN 201711400938 A CN201711400938 A CN 201711400938A CN 108101701 A CN108101701 A CN 108101701A
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B7/00—Fertilisers based essentially on alkali or ammonium orthophosphates
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/80—Soil conditioners
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Abstract
The present invention provides a kind of special water-soluble powder fertilizer of humic acid type sweet cherry, belongs to agrochemical technical field.The water-soluble fertilizer powder includes following component：Urea, ammonium polyphosphate, potassium dihydrogen phosphate, potassium sulfate, humic acid potassium, calcium nitrate, magnesium sulfate, ferrous sulfate, copper sulphate, zinc sulfate, sodium tetraborate, manganese sulfate, ammonium molybdate, ethylenediamine disuccinic acid, compound amino acid, citric acid, growth regulator and carboxymethyl cellulose scion grafting N N-isopropylacrylamide copolymers, wherein, growth regulator is indolebutyric acid, gibberellin, diethyl aminoethyl hexanoate and the basic element of cell division in mass ratio 0.8 1.2:1.6‑2:1:2.5 3 combination.The water-soluble fertilizer simple production process, it is of low cost.Growth characteristic of the formula based on sweet cherry is designed, and covers various nutritional ingredients necessary to sweet cherry growth, product fertilizer efficiency is high, good water solubility.Institute's cultivating plants healthy seedlings, leaf dark green, disease-resistant, resistance enhancing, fruit is beautiful in colour, the nature that gives off a strong fragrance, sweet and sour taste, and storage property is splendid.
Description
Technical field
The present invention relates to agrochemical technical field, specifically a kind of special water-soluble powder fertilizer of humic acid type sweet cherry
Material and its production technology.
Background technology
Sweet cherry also known as large cherry, fruit is rounded to heart-shaped, and 6.9 g of mean fruit weight, big fruit weighs 7.9 g.Sweet tea cherry
Peach is in cerise, beautiful in colour, and the small meat of core is thick, belongs to meat type, sweet and sour taste, edible rate is up to more than 95%, deeply by vast consumption
Person's likes.Sweet cherry fruit contains abundant nutriment, and protein content comes out at the top in various fruit, vitamin
Content is apple, three times of pears, has high nutritive value.Modern medicine study finds, sweet cherry also has adjust in beneficial spleen,
Regulating qi and activating blood, soothing the liver such as are reduced phlegm and internal heat at the health-care efficacies, are a kind of health fruits promoted longevity, are referred to as " vitamin pill " by expert.
At present, people usually apply organic chemical fertilizer or animal wastes, however these fertilizer institutes when carrying out sweet cherry cultivation
Low containing nutritional ingredient, utilization rate of fertilizer is low, much can not meet demand of the sweet cherry to nutritional ingredient.When being applied fertilizer, greatly
Amount is using nitrogenous fertilizer, potash fertilizer wretched insufficiency, is easy to cause that bud differentiation is of poor quality, and freeze proof disease resistance is low, and percentage of fertile fruit is low；It is and logical
Often only pay attention to three kinds of nutrients of N P and K, the secondary and micro-element fertilizers such as calcium, magnesium, zinc paid attention to not enough, to be easy to cause various nutritional deficiency diseases,
Coloring evening and it is uneven with fruit mass color is poor, and dehiscent fruit is serious.Rubus suavissimus S.Lee is shallow and blade is big, and main root is undeveloped, and leaf transpiration is made
With vigorous, Stoma of Leaves closing, make cultivated plant blade face Huang, growth slowly, the sweet cherry born is smaller, light-weight, disease-resistant
Force difference is susceptible to suffer from leaf spot, and fruit drop rate is high, and fruits nutrition deficiency, mouthfeel is bad, is easily attacked by various pest and disease damages.
As what ecological agriculture construction, pollution-less agriculture produced widelys popularize, humic acid fertilizer receives high praise.Humic acid is
The polymer organic matter that animals and plants remains are generated through microorganism decomposition conversion, containing a variety of main natural nutrition members needed for plant
Element, can enhance photosynthesis, and strong plant promotes plant yield-increasing and reduces its natural color, smell and taste.Humic acid can promote soil group
Burl is configured to, and enhances soil permeability, and retain water and nutrients significant effect can increase plant drought, cold-resistant, disease resistance ability.It is rotten
Phytic acid is also equipped with chelation, helps to improve the utilization rate of trace element, can promote healthy seedlings, promotes plant early raw fast
Length, leaf dark green, Accelerate bloom, flower and fruit protecting and the fissional effect of promotion, can improve crop and fruit and expand, make fruit product
Matter improves.
The content of the invention
The technical assignment of the present invention is in view of the deficiencies of the prior art, it is balanced comprehensively to provide a kind of fertilizer efficiency height, nutritional ingredient
The special water-soluble powder fertilizer of humic acid type sweet cherry and its production technology, by the fertilizer of the application present invention, sweet cherry it is anti-
Inverse property and fruit output significantly increase, and fruit rate of grade significantly improves.
The technical solution adopted by the present invention to solve the technical problems is：
1st, the present invention provides a kind of special water-soluble powder fertilizer of humic acid type sweet cherry, using the water-soluble powder fertilizer total composition as
100 mass parts calculate, and raw material composition and each component mass fraction are as follows in formula：10-15 parts of urea, 5-8 parts of ammonium polyphosphate,
4-9 parts of potassium dihydrogen phosphate, 5-7 parts of potassium sulfate, 7-10 parts of humic acid potassium, 4-6 parts of calcium nitrate, 3-4 parts of magnesium sulfate, ferrous sulfate
2.5-5 parts, 3-6 parts of copper sulphate, 7-15 parts of zinc sulfate, 3-5 parts of sodium tetraborate, 2.5-5 parts of manganese sulfate, 3-5 parts of ammonium molybdate, second two
5-8 parts of amine disuccinic acid, 3-6 parts of compound amino acid, 6-10 parts of citric acid, 1-3 parts of growth regulator and carboxymethyl cellulose branch
Connect -3 parts of n-isopropyl acrylamide copolymer 1, wherein, wherein, growth regulator for indolebutyric acid, gibberellin, diethyl aminoethyl hexanoate and
Basic element of cell division 0.8-1.2 in mass ratio:1.6-2:1:The combination of 2.5-3.
Preferably, calculated using the water-soluble powder fertilizer total composition as 100 mass parts, raw material composition and each component in formula
Mass fraction is as follows：10-13 parts of urea, 5-8 parts of ammonium polyphosphate, 4-6 parts of potassium dihydrogen phosphate, 5-6 parts of potassium sulfate, humic acid potassium 7-
9 parts, 4-5 parts of calcium nitrate, 3-4 parts of magnesium sulfate, 2.5-5 parts of ferrous sulfate, 4-6 parts of copper sulphate, 10-15 parts of zinc sulfate, tetraboric acid
3-5 parts of sodium, 2.5-3 parts of manganese sulfate, 4-5 parts of ammonium molybdate, 5-8 parts of ethylenediamine disuccinic acid, 3-6 parts of compound amino acid, citric acid
- 2 parts of 6-9 parts, 2-3 parts of growth regulator and carboxymethyl cellulose scion grafting n-isopropyl acrylamide copolymer 1, wherein, growth
Conditioning agent is indolebutyric acid, gibberellin, diethyl aminoethyl hexanoate and the basic element of cell division in mass ratio 1:2:1:3 combination.
The polymerization degree n of the ammonium polyphosphate is 10-20.
The compound amino acid is that compound amino acid is amino acid prepared by hydrolysate of soybean protein extraction.
2nd, the present invention also provides a kind of production technology of the special water-soluble powder fertilizer of humic acid type sweet cherry, including following work
Skill step：
1）It weighs：Good each raw material components are weighed according to proportioning specified in formula；
2）Chelatropic reaction：Suitable quantity of water is added in a kettle, is heated to 75-80 DEG C, by ammonium polyphosphate, humic acid potassium, ethylenediamine
Disuccinic acid, compound amino acid, citric acid are added to stirring in reaction kettle and, to dissolving, prepare containing the water-soluble of association complex
Liquid, according to the amount of every 100 mL water dissolutions 4-6 kg association complexes, by magnesium sulfate, calcium nitrate, ferrous sulfate, copper sulphate, sulphur
Sour zinc, sodium tetraborate, manganese sulfate and ammonium molybdate are added sequentially in reaction kettle, carry out chelatropic reaction, and it is 30- to control the reaction time
45 minutes, after chelatropic reaction, dehydration and drying removed moisture, and Chelating state calcium, Chelating state magnesium, chelated ferrous iron, Chelating state is made
Copper, Chelating state zinc, Chelating state boron, Chelating state manganese and Chelating state molybdenum；
3）Broken, screening：Using grinder respectively Chelating state calcium, Chelating state magnesium, chelated ferrous iron, Chelating state copper, Chelating state zinc,
Chelating state boron, Chelating state manganese and Chelating state molybdenum and other raw material components are ground into little particle respectively, cross 50-100 mesh sieves, spare；
4）It is mixed：By Chelating state calcium broken, after sieving, Chelating state magnesium, chelated ferrous iron, Chelating state copper, Chelating state zinc, chela
It closes state boron, Chelating state manganese and Chelating state molybdenum and other raw material components is added sequentially in fertilizer mixing stirrer, mix at room temperature
Stirring 30-60 minutes is closed, stirs evenly each raw material components to get the special water-soluble powder fertilizer of the humic acid type sweet cherry.
The present invention a kind of special water-soluble powder fertilizer of humic acid type sweet cherry and its production technology compared with prior art,
Generated advantageous effect is,
1st, the fertilizer product good water solubility that the present invention is produced, nutritional ingredient is balanced, and each group distribution ratio is scientific and reasonable, the formula base
It is designed in the growth characteristic of sweet cherry, covers a great number of elements nitrogen, phosphorus, potassium necessary to sweet cherry growth, middle amount member
Plain calcium, magnesium and trace elements iron, copper, zinc, boron, manganese, molybdenum, technical target of the product are as follows：Nitrogen+phosphorus pentoxide+potassium oxide >=
20.0%, humic acid >=4.0%；
2nd, can be absorbed added with fulvo acid potassium, contained bioactivity humic acid functional group in the fertilizer product invented
Potassium ion is stored, there is Resistance to microbes stronger absorption, exchange, complexing and sequestering power, fertilizer efficiency to be utilized than common potash fertilizer
Rate improves 87-95%；It can improve soil, and the generation of soil compaction phenomenon is reduced or avoided；It can also balance the growth hair of plant
It educates, promotes plant metabolism and photosynthesis, hence it is evident that promote the growth of plant, improve the nutritive value of sweet cherry, reach increasing
The effect of production, the sweet cherry cultivated is beautiful in colour, the nature that gives off a strong fragrance, sweet and sour taste, and storage property is splendid；
3rd, carboxymethyl cellulose scion grafting n-isopropyl acrylamide copolymer and macromolecular are added in the fertilizer product invented
Ammonium polyphosphate can be combined with soil colloid, increase the chance contacted with Soil Microorganism, be carried for the sorption enhanced of nutritional ingredient
For favourable conditions：Urea component as involved in for formula, research show that urea can not directly be absorbed by plant,
Must be by the effect of Soil Microorganism, being converted into after ammonium nitrogen can just be utilized, and be designed with using above-mentioned formula beneficial to soil
Earth colloid adsorbs urea, and is ammonium carbonate or ammonium bicarbonate by its decomposition and inversion under microbial action, is provided for crop useful
Nutriment；
4th, it is the special water-soluble powder fertilizer of the humic acid type sweet cherry is soluble in water, it is applied as punching fertilising application or foliar fertilizer
With using the sweet cherry plant healthy seedlings after fertilizer product of the present invention, leaf dark green, percentage of fertile fruit improves 15-20%, and plant resists
Disease, resistance enhancing, fruit output improve 18-27%.
Specific embodiment
With reference to embodiment to the present invention a kind of special water-soluble powder fertilizer of humic acid type sweet cherry and its
Production technology is described in detail below.
Carboxymethyl cellulose scion grafting n-isopropyl acrylamide copolymer of the present invention with carboxymethyl cellulose and
N-isopropyl acrylamide is material in mass ratio 4：1 is polymerized, and specific preparation method is as follows：
4 g carboxymethyl celluloses are dissolved in 200 mL deionized waters at normal pressure, 60 DEG C, are stirred under nitrogen protection to complete
After fully dissolved, 1 g n-isopropyl acrylamide is added in, is stirred under 40 DEG C of water bath conditions complete to n-isopropyl acrylamide
Dissolve and with carboxymethyl cellulose after mixing, the sodium hydrate aqueous solution for adding in mass concentration 4% is adjusted to pH value 8, so
After sequentially add 0.02 g of crosslinking agent N, N- methylene-bisacrylamide, 0.01 g of initiator benzoyl peroxide is crosslinked
Polymerisation, control the reaction time for 9 it is small when, be cooled to room temperature, obtain thick graft copolymer.Into the thick graft copolymer of gained
Add in ethyl alcohol and carry out precipitation separation, extracted with acetone in apparatus,Soxhlet's 10 it is small when after, 20 are freeze-dried under the conditions of -30 DEG C
Hour to obtain the final product.
Embodiment one
A kind of special water-soluble powder fertilizer of humic acid type sweet cherry, raw material composition and each component mass fraction are as follows in being formulated：
15 parts of urea, 5 parts of ammonium polyphosphate（Polymerization degree n=10）, 4 parts of potassium dihydrogen phosphate, 5 parts of potassium sulfate, 8 parts of humic acid potassium, calcium nitrate 4
Part, 3 parts of magnesium sulfate, 3 parts of ferrous sulfate, 5 parts of copper sulphate, 9 parts of zinc sulfate, 4 parts of sodium tetraborate, 5 parts of manganese sulfate, 4 parts of ammonium molybdate,
8 parts of ethylenediamine disuccinic acid, 6 parts of compound amino acid, 10 parts of citric acid, 0.13 part of indolebutyric acid, 0.27 part of gibberellin, diethyl aminoethyl hexanoate
0.17 part, 0.43 part of the basic element of cell division and carboxymethyl cellulose scion grafting n-isopropyl acrylamide copolymer 1 part, wherein, it is compound
Amino acid is that compound amino acid is amino acid prepared by hydrolysate of soybean protein extraction.
A kind of production technology of the special water-soluble powder fertilizer of humic acid type sweet cherry, comprises the technical steps that：
1）It weighs：Good each raw material components are weighed according to proportioning specified in formula；
2）Chelatropic reaction：Suitable quantity of water is added in a kettle, is heated to 75 DEG C, by ammonium polyphosphate, humic acid potassium, two amber of ethylenediamine
Amber acid, compound amino acid, citric acid are added to stirring in reaction kettle and, to dissolving, prepare the aqueous solution containing association complex, press
According to the amount of every 100 mL water dissolutions, 4 kg association complexes, by magnesium sulfate, calcium nitrate, ferrous sulfate, copper sulphate, zinc sulfate, four
Boratex, manganese sulfate and ammonium molybdate are added sequentially in reaction kettle, carry out chelatropic reaction, and it is 30 minutes to control the reaction time, chela
It closes after reaction, dehydration and drying removes moisture, and Chelating state calcium, Chelating state magnesium, chelated ferrous iron, Chelating state copper, Chelating state is made
Zinc, Chelating state boron, Chelating state manganese and Chelating state molybdenum；
3）Broken, screening：Using grinder respectively Chelating state calcium, Chelating state magnesium, chelated ferrous iron, Chelating state copper, Chelating state zinc,
Chelating state boron, Chelating state manganese and Chelating state molybdenum and other raw material components are ground into little particle respectively, cross 50 mesh sieves, spare；
4）It is mixed：By Chelating state calcium broken, after sieving, Chelating state magnesium, chelated ferrous iron, Chelating state copper, Chelating state zinc, chela
It closes state boron, Chelating state manganese and Chelating state molybdenum and other raw material components is added sequentially in fertilizer mixing stirrer, mix at room temperature
Stirring 30 minutes is closed, stirs evenly each raw material components to get the special water-soluble powder fertilizer of the humic acid type sweet cherry.
Embodiment two
A kind of special water-soluble powder fertilizer of humic acid type sweet cherry, raw material composition and each component mass fraction are as follows in being formulated：
10 parts of urea, 8 parts of ammonium polyphosphate（Polymerization degree n=15）, 6 parts of potassium dihydrogen phosphate, 6 parts of potassium sulfate, 7 parts of humic acid potassium, calcium nitrate 5
Part, 54 parts of magnesium sulfate, 2.5 parts of ferrous sulfate, 6 parts of copper sulphate, 15 parts of zinc sulfate, 5 parts of sodium tetraborate, 2.5 parts of manganese sulfate, molybdic acid
4 parts of ammonium, 5 parts of ethylenediamine disuccinic acid, 3 parts of compound amino acid, 6 parts of citric acid, 0.43 part of indolebutyric acid, 0.85 part of gibberellin,
0.43 part of diethyl aminoethyl hexanoate, 1.29 parts of the basic element of cell division, 2 parts of carboxymethyl cellulose scion grafting n-isopropyl acrylamide copolymer, wherein,
Compound amino acid is that compound amino acid is amino acid prepared by hydrolysate of soybean protein extraction.
A kind of production technology of the special water-soluble powder fertilizer of humic acid type sweet cherry, comprises the technical steps that：
1）It weighs：Good each raw material components are weighed according to proportioning specified in formula；
2）Chelatropic reaction：Suitable quantity of water is added in a kettle, is heated to 78 DEG C, by ammonium polyphosphate, humic acid potassium, two amber of ethylenediamine
Amber acid, compound amino acid, citric acid are added to stirring in reaction kettle and, to dissolving, prepare the aqueous solution containing association complex, press
According to the amount of every 100 mL water dissolutions, 5 kg association complexes, by magnesium sulfate, calcium nitrate, ferrous sulfate, copper sulphate, zinc sulfate, four
Boratex, manganese sulfate and ammonium molybdate are added sequentially in reaction kettle, carry out chelatropic reaction, and it is 40 minutes to control the reaction time, chela
It closes after reaction, dehydration and drying removes moisture, and Chelating state calcium, Chelating state magnesium, chelated ferrous iron, Chelating state copper, Chelating state is made
Zinc, Chelating state boron, Chelating state manganese and Chelating state molybdenum；
3）Broken, screening：Using grinder respectively Chelating state calcium, Chelating state magnesium, chelated ferrous iron, Chelating state copper, Chelating state zinc,
Chelating state boron, Chelating state manganese and Chelating state molybdenum and other raw material components are ground into little particle respectively, cross 80 mesh sieves, spare；
4）It is mixed：By Chelating state calcium broken, after sieving, Chelating state magnesium, chelated ferrous iron, Chelating state copper, Chelating state zinc, chela
It closes state boron, Chelating state manganese and Chelating state molybdenum and other raw material components is added sequentially in fertilizer mixing stirrer, mix at room temperature
Stirring 45 minutes is closed, stirs evenly each raw material components to get the special water-soluble powder fertilizer of the humic acid type sweet cherry.
Embodiment three
A kind of special water-soluble powder fertilizer of humic acid type sweet cherry, raw material composition and each component mass fraction are as follows in being formulated：
12 parts of urea, 6 parts of ammonium polyphosphate（Polymerization degree n=20）, 9 parts of potassium dihydrogen phosphate, 7 parts of potassium sulfate, 10 parts of humic acid potassium, calcium nitrate 6
Part, 3.5 parts of magnesium sulfate, 4 parts of ferrous sulfate, 3 parts of copper sulphate, 7 parts of zinc sulfate, 4 parts of sodium tetraborate, 2.5 parts of manganese sulfate, ammonium molybdate
3 parts, 6 parts of ethylenediamine disuccinic acid, 4 parts of compound amino acid, 8 parts of citric acid, 0.35 part of indolebutyric acid, 0.47 part of gibberellin, amine
0.30 part of fresh ester and 3 parts of 0.88 part of the basic element of cell division and carboxymethyl cellulose scion grafting n-isopropyl acrylamide copolymer, wherein,
Compound amino acid is that compound amino acid is amino acid prepared by hydrolysate of soybean protein extraction.
A kind of production technology of the special water-soluble powder fertilizer of humic acid type sweet cherry, comprises the technical steps that：
1）It weighs：Good each raw material components are weighed according to proportioning specified in formula；
2）Chelatropic reaction：Suitable quantity of water is added in a kettle, is heated to 80 DEG C, by ammonium polyphosphate, humic acid potassium, two amber of ethylenediamine
Amber acid, compound amino acid, citric acid are added to stirring in reaction kettle and, to dissolving, prepare the aqueous solution containing association complex, press
According to the amount of every 100 mL water dissolutions, 6 kg association complexes, by magnesium sulfate, calcium nitrate, ferrous sulfate, copper sulphate, zinc sulfate, four
Boratex, manganese sulfate and ammonium molybdate are added sequentially in reaction kettle, carry out chelatropic reaction, and it is 45 minutes to control the reaction time, chela
It closes after reaction, dehydration and drying removes moisture, and Chelating state calcium, Chelating state magnesium, chelated ferrous iron, Chelating state copper, Chelating state is made
Zinc, Chelating state boron, Chelating state manganese and Chelating state molybdenum；
3）Broken, screening：Using grinder respectively Chelating state calcium, Chelating state magnesium, chelated ferrous iron, Chelating state copper, Chelating state zinc,
Chelating state boron, Chelating state manganese and Chelating state molybdenum and other raw material components are ground into little particle respectively, cross 100 mesh sieves, spare；
4）It is mixed：By Chelating state calcium broken, after sieving, Chelating state magnesium, chelated ferrous iron, Chelating state copper, Chelating state zinc, chela
It closes state boron, Chelating state manganese and Chelating state molybdenum and other raw material components is added sequentially in fertilizer mixing stirrer, mix at room temperature
Stirring 60 minutes is closed, stirs evenly each raw material components to get the special water-soluble powder fertilizer of the humic acid type sweet cherry.
Example IV
A kind of special water-soluble powder fertilizer of humic acid type sweet cherry, raw material composition and each component mass fraction are as follows in being formulated：
13 parts of urea, 7 parts of ammonium polyphosphate（Polymerization degree n=10）, 5 parts of potassium dihydrogen phosphate, 6 parts of potassium sulfate, 9 parts of humic acid potassium, calcium nitrate 4
Part, 3 parts of magnesium sulfate, 5 parts of ferrous sulfate, 4 parts of copper sulphate, 10 parts of zinc sulfate, 3 parts of sodium tetraborate, 3 parts of manganese sulfate, ammonium molybdate 5
Part, 7 parts of ethylenediamine disuccinic acid, 5 parts of compound amino acid, 7 parts of citric acid, 0.29 part of indolebutyric acid, 0.57 part of gibberellin, amine are fresh
2 parts of 0.29 part of ester, 0.85 part of the basic element of cell division and carboxymethyl cellulose scion grafting n-isopropyl acrylamide copolymer, wherein, it is multiple
It is that compound amino acid is amino acid prepared by hydrolysate of soybean protein extraction to close amino acid.
A kind of production technology of the special water-soluble powder fertilizer of humic acid type sweet cherry, comprises the technical steps that：
1）It weighs：Good each raw material components are weighed according to proportioning specified in formula；
2）Chelatropic reaction：Suitable quantity of water is added in a kettle, is heated to 75 DEG C, by ammonium polyphosphate, humic acid potassium, two amber of ethylenediamine
Amber acid, compound amino acid, citric acid are added to stirring in reaction kettle and, to dissolving, prepare the aqueous solution containing association complex, press
According to the amount of every 100 mL water dissolutions, 5 kg association complexes, by magnesium sulfate, calcium nitrate, ferrous sulfate, copper sulphate, zinc sulfate, four
Boratex, manganese sulfate and ammonium molybdate are added sequentially in reaction kettle, carry out chelatropic reaction, and it is 45 minutes to control the reaction time, chela
It closes after reaction, dehydration and drying removes moisture, and Chelating state calcium, Chelating state magnesium, chelated ferrous iron, Chelating state copper, Chelating state is made
Zinc, Chelating state boron, Chelating state manganese and Chelating state molybdenum；
3）Broken, screening：Using grinder respectively Chelating state calcium, Chelating state magnesium, chelated ferrous iron, Chelating state copper, Chelating state zinc,
Chelating state boron, Chelating state manganese and Chelating state molybdenum and other raw material components are ground into little particle respectively, cross 80 mesh sieves, spare；
4）It is mixed：By Chelating state calcium broken, after sieving, Chelating state magnesium, chelated ferrous iron, Chelating state copper, Chelating state zinc, chela
It closes state boron, Chelating state manganese and Chelating state molybdenum and other raw material components is added sequentially in fertilizer mixing stirrer, mix at room temperature
Stirring 50 minutes is closed, stirs evenly each raw material components to get the special water-soluble powder fertilizer of the humic acid type sweet cherry.
Embodiment five
A kind of special water-soluble powder fertilizer of humic acid type sweet cherry, raw material composition and each component mass fraction are as follows in being formulated：
11 parts of urea, 5 parts of ammonium polyphosphate（Polymerization degree n=20）, 4 parts of potassium dihydrogen phosphate, 5 parts of potassium sulfate, 8 parts of humic acid potassium, calcium nitrate 5
Part, 4 parts of magnesium sulfate, 4 parts of ferrous sulfate, 5 parts of copper sulphate, 12 parts of zinc sulfate, 3 parts of sodium tetraborate, 3 parts of manganese sulfate, ammonium molybdate 5
Part, 8 parts of ethylenediamine disuccinic acid, 6 parts of compound amino acid, 9 parts of citric acid, 0.29 part of indolebutyric acid, 0.57 part of gibberellin, amine are fresh
0.29 part of ester, 0.85 part of the basic element of cell division and carboxymethyl cellulose scion grafting n-isopropyl acrylamide copolymer 1 part, wherein, it is multiple
It is that compound amino acid is amino acid prepared by hydrolysate of soybean protein extraction to close amino acid.
A kind of production technology of the special water-soluble powder fertilizer of humic acid type sweet cherry, comprises the technical steps that：
1）It weighs：Good each raw material components are weighed according to proportioning specified in formula；
2）Chelatropic reaction：Suitable quantity of water is added in a kettle, is heated to 76 DEG C, by ammonium polyphosphate, humic acid potassium, two amber of ethylenediamine
Amber acid, compound amino acid, citric acid are added to stirring in reaction kettle and, to dissolving, prepare the aqueous solution containing association complex, press
According to the amount of every 100 mL water dissolutions, 5 kg association complexes, by magnesium sulfate, calcium nitrate, ferrous sulfate, copper sulphate, zinc sulfate, four
Boratex, manganese sulfate and ammonium molybdate are added sequentially in reaction kettle, carry out chelatropic reaction, and it is 30 minutes to control the reaction time, chela
It closes after reaction, dehydration and drying removes moisture, and Chelating state calcium, Chelating state magnesium, chelated ferrous iron, Chelating state copper, Chelating state is made
Zinc, Chelating state boron, Chelating state manganese and Chelating state molybdenum；
3）Broken, screening：Using grinder respectively Chelating state calcium, Chelating state magnesium, chelated ferrous iron, Chelating state copper, Chelating state zinc,
Chelating state boron, Chelating state manganese and Chelating state molybdenum and other raw material components are ground into little particle respectively, cross 80 mesh sieves, spare；
4）It is mixed：By Chelating state calcium broken, after sieving, Chelating state magnesium, chelated ferrous iron, Chelating state copper, Chelating state zinc, chela
It closes state boron, Chelating state manganese and Chelating state molybdenum and other raw material components is added sequentially in fertilizer mixing stirrer, mix at room temperature
Stirring 60 minutes is closed, stirs evenly each raw material components to get the special water-soluble powder fertilizer of the humic acid type sweet cherry.
Claims (6)
1. a kind of special water-soluble powder fertilizer of humic acid type sweet cherry, which is characterized in that using the water-soluble powder fertilizer total composition as
100 mass parts calculate, and raw material composition and each component mass fraction are as follows in formula：10-15 parts of urea, 5-8 parts of ammonium polyphosphate,
4-9 parts of potassium dihydrogen phosphate, 5-7 parts of potassium sulfate, 7-10 parts of humic acid potassium, 4-6 parts of calcium nitrate, 3-4 parts of magnesium sulfate, ferrous sulfate
2.5-5 parts, 3-6 parts of copper sulphate, 7-15 parts of zinc sulfate, 3-5 parts of sodium tetraborate, 2.5-5 parts of manganese sulfate, 3-5 parts of ammonium molybdate, second two
5-8 parts of amine disuccinic acid, 3-6 parts of compound amino acid, 6-10 parts of citric acid, 1-3 parts of growth regulator and carboxymethyl cellulose branch
- 3 parts of n-isopropyl acrylamide copolymer 1 is connect, wherein, growth regulator is indolebutyric acid, gibberellin, diethyl aminoethyl hexanoate and cell point
Split element 0.8-1.2 in mass ratio:1.6-2:1:The combination of 2.5-3.
2. the special water-soluble powder fertilizer of a kind of humic acid type sweet cherry according to claim 1, which is characterized in that with the water
Molten powder fertilizer total composition calculates for 100 mass parts, and raw material composition and each component mass fraction are as follows in formula：Urea 10-
13 parts, 5-8 parts of ammonium polyphosphate, 4-6 parts of potassium dihydrogen phosphate, 5-6 parts of potassium sulfate, 7-9 parts of humic acid potassium, 4-5 parts of calcium nitrate, sulfuric acid
3-4 parts of magnesium, 2.5-5 parts of ferrous sulfate, 4-6 parts of copper sulphate, 10-15 parts of zinc sulfate, 3-5 parts of sodium tetraborate, manganese sulfate 2.5-3
Part, 4-5 parts of ammonium molybdate, 5-8 parts of ethylenediamine disuccinic acid, 3-6 parts of compound amino acid, 6-9 parts of citric acid, growth regulator 2-3
Part and -2 parts of carboxymethyl cellulose scion grafting n-isopropyl acrylamide copolymer 1, wherein, growth regulator is indolebutyric acid, red
Mycin, diethyl aminoethyl hexanoate and the basic element of cell division in mass ratio 1:2:1:3 combination.
A kind of 3. special water-soluble powder fertilizer of humic acid type sweet cherry according to claim 1 or 2, which is characterized in that institute
Carboxymethyl cellulose scion grafting n-isopropyl acrylamide copolymer is stated using carboxymethyl cellulose and n-isopropyl acrylamide as material
Material in mass ratio 1:4 are polymerized, and specific preparation method is as follows：
Carboxymethyl cellulose is dissolved in deionized water at normal pressure, 60 DEG C, is stirred under nitrogen protection to being completely dissolved, matched somebody with somebody
It is set to the carboxymethyl cellulose aqueous solution of mass concentration 1%；N-isopropyl acrylamide is added in, is stirred under 40 DEG C of water bath conditions
Be completely dissolved to n-isopropyl acrylamide and with carboxymethyl cellulose after mixing, add in sodium hydroxide adjust to pH value 8,
Then crosslinking agent N, N- methylene-bisacrylamide, initiator benzoyl peroxide progress cross-linking polymerization are sequentially added,
Control the reaction time for 9 it is small when, be cooled to room temperature, obtain thick graft copolymer；Ethyl alcohol is added in into the thick graft copolymer of gained
Carry out precipitation separation, and using acetone extract in apparatus,Soxhlet's 10 it is small when after, be freeze-dried under the conditions of -30 DEG C 20 it is small when
To obtain the final product；Wherein, crosslinking agent N, N- methylene-bisacrylamide addition are the 2% of n-isopropyl acrylamide quality, initiator
Benzoyl peroxide addition is the 1% of n-isopropyl acrylamide quality.
A kind of 4. special water-soluble powder fertilizer of humic acid type sweet cherry according to claim 1 or 2, which is characterized in that institute
The polymerization degree n for stating ammonium polyphosphate is 10-20.
A kind of 5. special water-soluble powder fertilizer of humic acid type sweet cherry according to claim 1 or 2, which is characterized in that institute
State the amino acid that compound amino acid is prepared for hydrolysate of soybean protein extraction.
6. a kind of production technology of the special water-soluble powder fertilizer of humic acid type sweet cherry, which is characterized in that walked including following technique
Suddenly：
1）It weighs：Good each raw material components are weighed according to proportioning specified in formula；
2）Chelatropic reaction：Suitable quantity of water is added in a kettle, is heated to 75-80 DEG C, by ammonium polyphosphate, humic acid potassium, ethylenediamine
Disuccinic acid, compound amino acid, citric acid are added to stirring in reaction kettle and, to dissolving, prepare containing the water-soluble of association complex
Liquid, according to the amount of every 100 mL water dissolutions 4-6 kg association complexes, by magnesium sulfate, calcium nitrate, ferrous sulfate, copper sulphate, sulphur
Sour zinc, sodium tetraborate, manganese sulfate and ammonium molybdate are added sequentially in reaction kettle, carry out chelatropic reaction, and it is 30- to control the reaction time
45 minutes, after chelatropic reaction, dehydration and drying removed moisture, and Chelating state calcium, Chelating state magnesium, chelated ferrous iron, Chelating state is made
Copper, Chelating state zinc, Chelating state boron, Chelating state manganese and Chelating state molybdenum；
3）Broken, screening：Using grinder respectively Chelating state calcium, Chelating state magnesium, chelated ferrous iron, Chelating state copper, Chelating state zinc,
Chelating state boron, Chelating state manganese and Chelating state molybdenum and other raw material components are ground into little particle respectively, cross 50-100 mesh sieves, spare；
4）It is mixed：By Chelating state calcium broken, after sieving, Chelating state magnesium, chelated ferrous iron, Chelating state copper, Chelating state zinc, chela
It closes state boron, Chelating state manganese and Chelating state molybdenum and other raw material components is added sequentially in fertilizer mixing stirrer, mix at room temperature
Stirring 30-60 minutes is closed, stirs evenly each raw material components to get the special water-soluble powder fertilizer of the humic acid type sweet cherry.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109627085A (en) * | 2018-12-26 | 2019-04-16 | 龙蟒大地农业有限公司 | A kind of foliar fertilizer and preparation method thereof |
| CN111153737A (en) * | 2020-01-10 | 2020-05-15 | 广西绿浪生物技术有限公司 | Efficient composite water-soluble fertilizer and preparation method and application thereof |
| CN111533598A (en) * | 2020-04-03 | 2020-08-14 | 纳雍县万寿玛瑙红樱桃有限公司 | Nutrient solution for improving quality of agate red cherries and application thereof |
-
2017
- 2017-12-22 CN CN201711400938.2A patent/CN108101701A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109627085A (en) * | 2018-12-26 | 2019-04-16 | 龙蟒大地农业有限公司 | A kind of foliar fertilizer and preparation method thereof |
| CN111153737A (en) * | 2020-01-10 | 2020-05-15 | 广西绿浪生物技术有限公司 | Efficient composite water-soluble fertilizer and preparation method and application thereof |
| CN111533598A (en) * | 2020-04-03 | 2020-08-14 | 纳雍县万寿玛瑙红樱桃有限公司 | Nutrient solution for improving quality of agate red cherries and application thereof |
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Application publication date: 20180601 |