CN108086046A - 一种高效防水牛皮纸及其制备方法 - Google Patents
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Abstract
本发明公开了一种高效防水牛皮纸及其制备方法,包括原纸基层以及涂布在原纸基层上的,所述原纸基层包括以下重量比:冷杉、松木、楠木、杨木、木屑、木制家具边角料、甘蔗杆、芭蕉茎、动物毛发、造纸添加剂、填料;所述涂布层为防水涂布层,所述涂布层包括阳离子淀粉、全氟烷基化合物、丙烯酸树脂、聚乙烯醇、偶氮二异丁脒盐酸盐、功能单体、动物胶、其余为蒸馏水;制成一种高效防水牛皮纸,其具有使用方便、造价便宜、防水效果好的效果。
Description
技术领域
本发明涉及一种高效防水牛皮纸及其制备方法。
背景技术
牛皮纸是一种常见的包装纸材料,其强度比普通的包装纸高,表面呈黄色或黄褐色,其具有非常优越的抗拉性和防破裂性,在一定的拉扯下都不会破裂,常用纸状态下呈卷筒和平板两种形状,但也可以用于信封纸、胶封纸装、沥青纸等场所使用。
牛皮纸在按功能分的情况下可分为包装牛皮纸、高效防水牛皮纸、防潮牛皮纸、防锈牛皮纸、打版牛皮纸、制程牛皮纸、绝缘牛皮纸板、牛皮贴纸等,牛皮纸在使用过程中起最主要的特性是抗拉以及相当好的防水性能,市面上的防水性主要由各种添加剂来获得,但现有的添加剂包括一些混凝剂、消泡剂、絮凝剂、填料等材料都不具备防水性能,且现有加工厂往往都以利益为重,都是怎么便宜怎么生产,不同的添加剂合理添加所得到的效果完全不同,专利号CN201510952750.3公开了一种牛皮纸的生产工艺,其通过各种树木的打浆度和湿重来进行调节,而树木的打浆度相对于防水效果来说关系不是很大,主要是靠添加剂来进行改变,但市面上缺少一种防水性比较好的牛皮纸。
发明内容
本发明要解决的技术问题是提供一种使用方便、造价便宜、防水效果好的高效防水牛皮纸。
为解决上述问题,本发明采用如下技术方案:一种高效防水牛皮纸,包括原纸基层以及涂布在原纸基层上的涂布层,所述原纸基层包括以下重量比:冷杉10~15份、松木10~15份、楠木10~15份、杨木10~15份、木屑10~20份、木制家具边角料5~10份、甘蔗杆5~10份、芭蕉茎5~10份、动物毛发5~10份、造纸添加剂5~8份、填料8~13份;
所述涂布层为防水涂布层,所述涂布层包括阳离子淀粉10~13份、全氟烷基化合物5~15份、丙烯酸树脂8~13份、聚乙烯醇5~8份、偶氮二异丁脒盐酸盐2~5份、功能单体3~7份、动物胶17~25份、其余为蒸馏水。
进一步的方案为:所述原纸基层包括以下重量比:冷杉10份、松木10份、楠木15份、杨木15份、木屑10份、木制家具边角料5份、甘蔗杆5份、芭蕉茎5份、动物毛发5份、造纸添加剂5份、填料10份;
所述涂布层为防水涂布层,所述涂布层包括阳离子淀粉10份、全氟烷基化合物5份、丙烯酸树脂8份、聚乙烯醇5份、偶氮二异丁脒盐酸盐2份、功能单体3份、动物胶17份、其余为蒸馏水。
进一步的方案为:所述原纸基层包括以下重量比:冷杉15份、松木15份、楠木15份、杨木15份、木屑20份、木制家具边角料10份、甘蔗杆10份、芭蕉茎10份、动物毛发10份、造纸添加剂8份、填料13份;
所述涂布层为防水涂布层,所述涂布层包括阳离子淀粉13份、全氟烷基化合物15份、丙烯酸树脂13份、聚乙烯醇8份、偶氮二异丁脒盐酸盐5份、功能单体7份、动物胶25份、其余为蒸馏水。
进一步的方案为:所述原纸基层在调浆的过程中最终PH值为8。
进一步的方案为:所述造纸添加剂包括湿强剂、消泡剂、絮凝剂和混凝剂,所述湿强剂为聚酰胺环氧树脂、聚苯乙烯、甲基丙烯酸缩水甘油酯或二乙醇胺改性聚酰胺多胺环氧氯丙烷其中一种或两种以上。
一种高效防水牛皮纸的制备方法,包括以下步骤:包括
1)、纸浆制备:首先把木屑、木制家具边角料用切割机切碎成小颗粒状,然后放入到碎浆机内碎浆,碎浆后进行碎浆筛选净化去除多余的木质素,以及去除木屑、木制家具边角料中多余的杂质形成废纸浆,提高纤维的接触面积,然后把冷杉、松木、楠木、杨木、甘蔗杆、芭蕉茎、动物毛发利用蒸馏法进行处理形成树木原浆,处理后废纸浆和树木原浆的的浓度为4.5%~6.8%并混合搅拌一起;
2)、动物胶配置:将动物胶加入到温水中温度为30℃~35℃之间的温水中浸泡,使其充分膨胀后然后放入到搅碎机内破碎,然后放入到蒸馏机内加热水升温煮沸,温度为70℃~75℃,时间为1小时,等胶体完全溶解后降温至55℃~60℃待用;
3)、涂布层制备:将丙烯酸树脂和聚乙烯醇倒入到蒸馏水中混合搅拌,在搅拌的同时升温至85℃,搅拌时间为10min待用,然后将阳离子淀粉、全氟烷基化合物步骤2)中制得的动物胶原液倒入到蒸馏水中混合搅拌,在搅拌的同时升温至90℃,搅拌时间为15min待用;再把偶氮二异丁脒盐酸盐、功能单体倒入到动物胶原液中,并同时倒入步骤3)中前两部所制得的溶液,在60℃~75℃之间的温度下搅拌时间为45min制得涂布层溶液;
4)、成品纸制造:把步骤1)所制得的纸浆经过散浆、除杂质、***、打浆、配制各种添加剂的混合、纸料的流送、头箱、网部、压榨部、干燥部、表面施胶、干燥、压光制得原纸基层,然后把步骤3)所得到的溶液最后涂布到原纸基层上制得防水牛皮纸。
本发明的有益效果是:
本发明采用木屑、木制家具边角料作为铺料来进行制浆,木屑大多数为刨花或其它行业所遗弃的可再生能源,以及木制家具边角料同木屑一样都是可再生利用资源,把其加入到制浆中可有效降低成本以及不会影响纸张的性能,涂布层采用阳离子淀粉、全氟烷基化合物、丙烯酸树脂、聚乙烯醇、偶氮二异丁脒盐酸盐、功能单体、动物胶为添加剂,此混合溶液可以有效的使纸张的防水效果增加,聚乙烯醇成膜度高,与其它试剂一起使用,可以减少防水剂的缺失,提高留着率,同时,动物胶的使用可以在纸张表面形成一层很薄的胶体混合结构,可以有效的减少水分子的进入,全氟烷基化合物的添加可以保持纸张原有的透气、印刷度以及其它普遍拥有的特性,并能提高降解率,更加环保,最主要的是具有优越的防水性能。
具体实施方式
下面对本发明的优选实施例进行详细阐述,以使本发明的优点和特征能更易于被本领域技术人员理解,从而对本发明的保护范围做出更为清楚明确的界定。
实施例一
包括原纸基层以及涂布在原纸基层上的涂布层,所述原纸基层包括以下重量比:冷杉10份、松木10份、楠木15份、杨木15份、木屑10份、木制家具边角料5份、甘蔗杆5份、芭蕉茎5份、动物毛发5份、造纸添加剂5份、填料10份;所述涂布层为防水涂布层,所述涂布层包括阳离子淀粉10份、全氟烷基化合物5份、丙烯酸树脂8份、聚乙烯醇5份、偶氮二异丁脒盐酸盐2份、功能单体3份、动物胶17份、其余为蒸馏水。
一种高效防水牛皮纸的制备方法,包括以下步骤:包括
1)、纸浆制备:首先把木屑、木制家具边角料用切割机切碎成小颗粒状,然后放入到碎浆机内碎浆,碎浆后进行碎浆筛选净化去除多余的木质素,以及去除木屑、木制家具边角料中多余的杂质形成废纸浆,提高纤维的接触面积,然后把冷杉、松木、楠木、杨木、甘蔗杆、芭蕉茎、动物毛发利用蒸馏法进行处理形成树木原浆,处理后废纸浆和树木原浆的的浓度为5%并混合搅拌一起;
2)、动物胶配置:将动物胶加入到温水中温度为35℃之间的温水中浸泡,使其充分膨胀后然后放入到搅碎机内破碎,然后放入到蒸馏机内加热水升温煮沸,温度为70℃,时间为1小时,等胶体完全溶解后降温至55℃待用;
3)、涂布层制备:将丙烯酸树脂和聚乙烯醇倒入到蒸馏水中混合搅拌,在搅拌的同时升温至85℃,搅拌时间为10min待用,然后将阳离子淀粉、全氟烷基化合物步骤2)中制得的动物胶原液倒入到蒸馏水中混合搅拌,在搅拌的同时升温至90℃,搅拌时间为15min待用;再把偶氮二异丁脒盐酸盐、功能单体倒入到动物胶原液中,并同时倒入步骤3)中前两部所制得的溶液,在60℃之间的温度下搅拌时间为45min制得涂布层溶液;
4)、成品纸制造:把步骤1)所制得的纸浆经过散浆、除杂质、***、打浆、配制各种添加剂的混合、纸料的流送、头箱、网部、压榨部、干燥部、表面施胶、干燥、压光制得原纸基层,然后把步骤3)所得到的溶液最后涂布到原纸基层上制得防水牛皮纸。
实施例二
包括原纸基层以及涂布在原纸基层上的涂布层,所述原纸基层包括以下重量比:所述原纸基层包括以下重量比:冷杉15份、松木15份、楠木15份、杨木15份、木屑20份、木制家具边角料10份、甘蔗杆10份、芭蕉茎10份、动物毛发10份、造纸添加剂8份、填料13份;所述涂布层为防水涂布层,所述涂布层包括阳离子淀粉13份、全氟烷基化合物15份、丙烯酸树脂13份、聚乙烯醇8份、偶氮二异丁脒盐酸盐5份、功能单体7份、动物胶25份、其余为蒸馏水。
一种高效防水牛皮纸的制备方法,包括以下步骤:包括
1)、纸浆制备:首先把木屑、木制家具边角料用切割机切碎成小颗粒状,然后放入到碎浆机内碎浆,碎浆后进行碎浆筛选净化去除多余的木质素,以及去除木屑、木制家具边角料中多余的杂质形成废纸浆,提高纤维的接触面积,然后把冷杉、松木、楠木、杨木、甘蔗杆、芭蕉茎、动物毛发利用蒸馏法进行处理形成树木原浆,处理后废纸浆和树木原浆的的浓度为6.2%并混合搅拌一起;
2)、动物胶配置:将动物胶加入到温水中温度为33℃之间的温水中浸泡,使其充分膨胀后然后放入到搅碎机内破碎,然后放入到蒸馏机内加热水升温煮沸,温度为70℃℃,时间为1小时,等胶体完全溶解后降温至60℃待用;
3)、涂布层制备:将丙烯酸树脂和聚乙烯醇倒入到蒸馏水中混合搅拌,在搅拌的同时升温至85℃,搅拌时间为10min待用,然后将阳离子淀粉、全氟烷基化合物步骤2)中制得的动物胶原液倒入到蒸馏水中混合搅拌,在搅拌的同时升温至90℃,搅拌时间为15min待用;再把偶氮二异丁脒盐酸盐、功能单体倒入到动物胶原液中,并同时倒入步骤3)中前两部所制得的溶液,在70℃之间的温度下搅拌时间为45min制得涂布层溶液;
4)、成品纸制造:把步骤1)所制得的纸浆经过散浆、除杂质、***、打浆、配制各种添加剂的混合、纸料的流送、头箱、网部、压榨部、干燥部、表面施胶、干燥、压光制得原纸基层,然后把步骤3)所得到的溶液最后涂布到原纸基层上制得防水牛皮纸。
实施例三
包括原纸基层以及涂布在原纸基层上的涂布层,所述原纸基层包括以下重量比:冷杉12份、松木12份、楠木15份、杨木13份、木屑1520份、木制家具边角料10份、甘蔗杆10份、芭蕉茎10份、动物毛发10份、造纸添加剂6份、填料10份;所述涂布层为防水涂布层,所述涂布层包括阳离子淀粉13份、全氟烷基化合物10份、丙烯酸树脂8份、聚乙烯醇7份、偶氮二异丁脒盐酸盐3份、功能单体3份、动物胶20份、其余为蒸馏水。
一种高效防水牛皮纸的制备方法,包括以下步骤:包括
1)、纸浆制备:首先把木屑、木制家具边角料用切割机切碎成小颗粒状,然后放入到碎浆机内碎浆,碎浆后进行碎浆筛选净化去除多余的木质素,以及去除木屑、木制家具边角料中多余的杂质形成废纸浆,提高纤维的接触面积,然后把冷杉、松木、楠木、杨木、甘蔗杆、芭蕉茎、动物毛发利用蒸馏法进行处理形成树木原浆,处理后废纸浆和树木原浆的的浓度为6.8%并混合搅拌一起;
2)、动物胶配置:将动物胶加入到温水中温度为35℃之间的温水中浸泡,使其充分膨胀后然后放入到搅碎机内破碎,然后放入到蒸馏机内加热水升温煮沸,温度为75℃,时间为1小时,等胶体完全溶解后降温至60℃待用;
3)、涂布层制备:将丙烯酸树脂和聚乙烯醇倒入到蒸馏水中混合搅拌,在搅拌的同时升温至85℃,搅拌时间为10min待用,然后将阳离子淀粉、全氟烷基化合物步骤2)中制得的动物胶原液倒入到蒸馏水中混合搅拌,在搅拌的同时升温至90℃,搅拌时间为15min待用;再把偶氮二异丁脒盐酸盐、功能单体倒入到动物胶原液中,并同时倒入步骤3)中前两部所制得的溶液,在75℃之间的温度下搅拌时间为45min制得涂布层溶液;
4)、成品纸制造:把步骤1)所制得的纸浆经过散浆、除杂质、***、打浆、配制各种添加剂的混合、纸料的流送、头箱、网部、压榨部、干燥部、表面施胶、干燥、压光制得原纸基层,然后把步骤3)所得到的溶液最后涂布到原纸基层上制得防水牛皮纸。
实施例四
包括原纸基层以及涂布在原纸基层上的涂布层,所述原纸基层包括以下重量比:冷杉15份、松木15份、楠木15份、杨木10份、木屑20份、木制家具边角料10份、甘蔗杆10份、芭蕉茎10份、动物毛发5份、造纸添加剂8份、填料10份;所述涂布层为防水涂布层,所述涂布层包括阳离子淀粉13份、全氟烷基化合物15份、丙烯酸树脂13份、聚乙烯醇5份、偶氮二异丁脒盐酸盐2份、功能单体3份、动物胶17份、其余为蒸馏水。
一种高效防水牛皮纸的制备方法,包括以下步骤:包括
1)、纸浆制备:首先把木屑、木制家具边角料用切割机切碎成小颗粒状,然后放入到碎浆机内碎浆,碎浆后进行碎浆筛选净化去除多余的木质素,以及去除木屑、木制家具边角料中多余的杂质形成废纸浆,提高纤维的接触面积,然后把冷杉、松木、楠木、杨木、甘蔗杆、芭蕉茎、动物毛发利用蒸馏法进行处理形成树木原浆,处理后废纸浆和树木原浆的的浓度为6.8%并混合搅拌一起;
2)、动物胶配置:将动物胶加入到温水中温度为35℃之间的温水中浸泡,使其充分膨胀后然后放入到搅碎机内破碎,然后放入到蒸馏机内加热水升温煮沸,温度为75℃,时间为1小时,等胶体完全溶解后降温至60℃待用;
3)、涂布层制备:将丙烯酸树脂和聚乙烯醇倒入到蒸馏水中混合搅拌,在搅拌的同时升温至85℃,搅拌时间为10min待用,然后将阳离子淀粉、全氟烷基化合物步骤2)中制得的动物胶原液倒入到蒸馏水中混合搅拌,在搅拌的同时升温至90℃,搅拌时间为15min待用;再把偶氮二异丁脒盐酸盐、功能单体倒入到动物胶原液中,并同时倒入步骤3)中前两部所制得的溶液,在60℃的温度下搅拌时间为45min制得涂布层溶液;
4)、成品纸制造:把步骤1)所制得的纸浆经过散浆、除杂质、***、打浆、配制各种添加剂的混合、纸料的流送、头箱、网部、压榨部、干燥部、表面施胶、干燥、压光制得原纸基层,然后把步骤3)所得到的溶液最后涂布到原纸基层上制得防水牛皮纸
以上所述,仅为本发明的具体实施方式,但本发明的保护范围并不局限于此,任何不经过创造性劳动想到的变化或替换,都应涵盖在本实用新保护范围为准。
Claims (6)
1.一种高效防水牛皮纸,其特征在于:包括原纸基层以及涂布在原纸基层上的涂布层,
所述原纸基层包括以下重量比:冷杉10~15份、松木10~15份、楠木10~15份、杨木10~15份、木屑10~20份、木制家具边角料5~10份、甘蔗杆5~10份、芭蕉茎5~10份、动物毛发5~10份、造纸添加剂5~8份、填料8~13份;
所述涂布层为防水涂布层,所述涂布层包括阳离子淀粉10~13份、全氟烷基化合物5~15份、丙烯酸树脂8~13份、聚乙烯醇5~8份、偶氮二异丁脒盐酸盐2~5份、功能单体3~7份、动物胶17~25份、其余为蒸馏水。
2.一种高效防水牛皮纸,其特征在于:包括原纸基层以及涂布在原纸基层上的涂布层,
所述原纸基层包括以下重量比:冷杉10份、松木10份、楠木15份、杨木15份、木屑10份、木制家具边角料5份、甘蔗杆5份、芭蕉茎5份、动物毛发5份、造纸添加剂5份、填料10份;
所述涂布层为防水涂布层,所述涂布层包括阳离子淀粉10份、全氟烷基化合物5份、丙烯酸树脂8份、聚乙烯醇5份、偶氮二异丁脒盐酸盐2份、功能单体3份、动物胶17份、其余为蒸馏水。
3.一种高效防水牛皮纸,其特征在于:包括原纸基层以及涂布在原纸基层上的,
所述原纸基层包括以下重量比:冷杉15份、松木15份、楠木15份、杨木15份、木屑20份、木制家具边角料10份、甘蔗杆10份、芭蕉茎10份、动物毛发10份、造纸添加剂8份、填料13份;
所述涂布层为防水涂布层,所述涂布层包括阳离子淀粉13份、全氟烷基化合物15份、丙烯酸树脂13份、聚乙烯醇8份、偶氮二异丁脒盐酸盐5份、功能单体7份、动物胶25份、其余为蒸馏水。
4.一种高效防水牛皮纸,其特征在于:所述原纸基层在调浆的过程中最终PH值为8。
5.一种高效防水牛皮纸,其特征在于:所述造纸添加剂包括湿强剂、消泡剂、絮凝剂和混凝剂,所述湿强剂为聚酰胺环氧树脂、聚苯乙烯、甲基丙烯酸缩水甘油酯或二乙醇胺改性聚酰胺多胺环氧氯丙烷其中一种或两种以上。
6.根据权利要求1所述的一种高效防水牛皮纸的制备方法,其特征在于:包括以下步骤:
1)、纸浆制备:首先把木屑、木制家具边角料用切割机切碎成小颗粒状,然后放入到碎浆机内碎浆,碎浆后进行碎浆筛选净化去除多余的木质素,以及去除木屑、木制家具边角料中多余的杂质形成废纸浆,提高纤维的接触面积,然后把冷杉、松木、楠木、杨木、甘蔗杆、芭蕉茎、动物毛发利用蒸馏法进行处理形成树木原浆,处理后废纸浆和树木原浆的的浓度为4.5%~6.8%并混合搅拌一起;
2)、动物胶配置:将动物胶加入到温水中温度为30℃~35℃之间的温水中浸泡,使其充分膨胀后然后放入到搅碎机内破碎,然后放入到蒸馏机内加热水升温煮沸,温度为70℃~75℃,时间为1小时,等胶体完全溶解后降温至55℃~60℃待用;
3)、涂布层制备:将丙烯酸树脂和聚乙烯醇倒入到蒸馏水中混合搅拌,在搅拌的同时升温至85℃,搅拌时间为10min待用,然后将阳离子淀粉、全氟烷基化合物步骤2)中制得的动物胶原液倒入到蒸馏水中混合搅拌,在搅拌的同时升温至90℃,搅拌时间为15min待用;再把偶氮二异丁脒盐酸盐、功能单体倒入到动物胶原液中,并同时倒入步骤3)中前两部所制得的溶液,在60℃~75℃之间的温度下搅拌时间为45min制得涂布层溶液;
4)、成品纸制造:把步骤1)所制得的纸浆经过散浆、除杂质、***、打浆、配制各种添加剂的混合、纸料的流送、头箱、网部、压榨部、干燥部、表面施胶、干燥、压光制得原纸基层,然后把步骤3)所得到的溶液最后涂布到原纸基层上制得防水牛皮纸。
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CN109577074A (zh) * | 2018-12-27 | 2019-04-05 | 上海纳米技术及应用国家工程研究中心有限公司 | 一种疏水高耐磨纸浆材料的制备方法及其产品 |
CN111622020A (zh) * | 2020-04-30 | 2020-09-04 | 福建省闽清双棱纸业有限公司 | 一种在长度方向抗拉性能强的防水牛皮纸及其制备方法 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2008031603A (ja) * | 2006-07-31 | 2008-02-14 | Daio Paper Corp | 片艶クラフト紙及びその製造方法 |
JP2010229564A (ja) * | 2009-03-25 | 2010-10-14 | Daio Paper Corp | クラフト紙 |
CN104499341A (zh) * | 2014-11-25 | 2015-04-08 | 南通新世纪机电有限公司 | 本色牛皮纸的制造工艺 |
CN105568736A (zh) * | 2015-12-19 | 2016-05-11 | 北海光利彩色印刷有限公司 | 牛皮纸的生产工艺 |
CN106192552A (zh) * | 2016-08-12 | 2016-12-07 | 海南金海浆纸业有限公司 | 一种高松厚度涂布白牛皮纸及其制备方法 |
CN106592332A (zh) * | 2016-11-28 | 2017-04-26 | 浙江大胜达包装有限公司 | 含氟防水纸质包装材料的制备方法 |
-
2017
- 2017-12-12 CN CN201711316893.0A patent/CN108086046A/zh active Pending
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2008031603A (ja) * | 2006-07-31 | 2008-02-14 | Daio Paper Corp | 片艶クラフト紙及びその製造方法 |
JP2010229564A (ja) * | 2009-03-25 | 2010-10-14 | Daio Paper Corp | クラフト紙 |
CN104499341A (zh) * | 2014-11-25 | 2015-04-08 | 南通新世纪机电有限公司 | 本色牛皮纸的制造工艺 |
CN105568736A (zh) * | 2015-12-19 | 2016-05-11 | 北海光利彩色印刷有限公司 | 牛皮纸的生产工艺 |
CN106192552A (zh) * | 2016-08-12 | 2016-12-07 | 海南金海浆纸业有限公司 | 一种高松厚度涂布白牛皮纸及其制备方法 |
CN106592332A (zh) * | 2016-11-28 | 2017-04-26 | 浙江大胜达包装有限公司 | 含氟防水纸质包装材料的制备方法 |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109577074A (zh) * | 2018-12-27 | 2019-04-05 | 上海纳米技术及应用国家工程研究中心有限公司 | 一种疏水高耐磨纸浆材料的制备方法及其产品 |
CN111622020A (zh) * | 2020-04-30 | 2020-09-04 | 福建省闽清双棱纸业有限公司 | 一种在长度方向抗拉性能强的防水牛皮纸及其制备方法 |
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