CN108085776A - A kind of high intensity anticracking ship hawser and preparation method thereof - Google Patents
A kind of high intensity anticracking ship hawser and preparation method thereof Download PDFInfo
- Publication number
- CN108085776A CN108085776A CN201711295478.1A CN201711295478A CN108085776A CN 108085776 A CN108085776 A CN 108085776A CN 201711295478 A CN201711295478 A CN 201711295478A CN 108085776 A CN108085776 A CN 108085776A
- Authority
- CN
- China
- Prior art keywords
- parts
- hawser
- ship
- anticracking
- high intensity
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
- D01F1/106—Radiation shielding agents, e.g. absorbing, reflecting agents
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/06—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyolefin as constituent
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/12—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyamide as constituent
-
- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B1/00—Constructional features of ropes or cables
- D07B1/02—Ropes built-up from fibrous or filamentary material, e.g. of vegetable origin, of animal origin, regenerated cellulose, plastics
-
- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B2401/00—Aspects related to the problem to be solved or advantage
- D07B2401/20—Aspects related to the problem to be solved or advantage related to ropes or cables
- D07B2401/202—Environmental resistance
-
- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B2401/00—Aspects related to the problem to be solved or advantage
- D07B2401/20—Aspects related to the problem to be solved or advantage related to ropes or cables
- D07B2401/2055—Improving load capacity
-
- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B2501/00—Application field
- D07B2501/20—Application field related to ropes or cables
- D07B2501/2061—Ship moorings
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Artificial Filaments (AREA)
Abstract
The present invention relates to apparel manufacturing fields, and in particular to a kind of high intensity anticracking ship hawser and preparation method thereof；Its ingredient includes：Fypro, polypropylene fibre, stearic acid, microcrystalline wax, glass fibre, siloxanes, silicon wax, anticracking fiber, ultraviolet absorber, salt resistance alkaline agent, anti-aging agent, ester based quaternary ammonium salt and appropriate amount of deionized water；Ship cable prepared by the present invention has many advantages, such as that sun-proof ability, ultraviolet-resistent property, resistance to ag(e)ing, intensity are high, cracking resistance is good and service life grow it is good；Stearic acid, microcrystalline wax, glass fibre and Fypro interaction cooperation in raw material make 35 times of the strength enhancing of hawser.In addition the present invention makes the anti crack performance of hawser significantly be changed by adding siloxanes, stearic acid, silicon wax and anticracking fiber；The mutual cooperation of polypropylene fibre, salt resistance alkaline agent and ester based quaternary ammonium salt so that line density bottom, flexibility be good, easy to operate and safe operation.
Description
Technical field
The present invention relates to apparel manufacturing fields, and in particular to a kind of high intensity anticracking ship hawser and its preparation side
Method.
Background technology
Ship cable is except light specific gravity, intensity is high, shock resistance and wearability it is good in addition to, have corrosion-resistant, resistance to mildew and rot, resistance to damage by worms
Advantage.Intensity and wear resistance such as polyamide fibre hawser are more than fiber crops, cotton hawser several times, and polypropylene fibre hawser proportion is less than water, can float on water
Face, it is easy and safe to operate.Chemical fibre hawser by processing structure be divided into 3 strands, multiply coil buckling hawser and 8 strands, multiply compile two class of stranded cable rope.
3 strands of hawsers are a diameter of 4~50 millimeters general, and 8 strands of hawsers are a diameter of 35~120 millimeters general.Chemical fibre hawser is removed for ship system
Outside cable, communications and transportation, industry, mine, physical culture and fishery etc. are also widely used in.
Such as Chinese Patent Application No. is a kind of wheel Cable rope for ship with higher toughness of CN201510734146.3, is related to
Take turns Cable rope for ship knitting skill field, by melt soft dose, bottle piece PT, softening agent, brombutyl, epoxidized soybean oil, sodium aluminate,
Amino silicon oil emulsion, nylon yarn, UV resistant agent, salt resistance alkaline agent, refined mineral oil, sodium hydroxide and nonionic surfactant
It prepares, weave.The hawser of technical solution braiding provided by the present invention does not have good ductile strength tightly but also has
There are superior saline-alkali tolerance energy and anti-uv-ray, have good effect for the use of ocean operation, and in the present invention
Used coating auxiliary agent also passes through special development and matches, and plays an important role of remarkable waterproof, the erosion for resisting seawater, right
Hawser has good protective effect.
The quality of currently marketed ship cable still has much room for improvement, for example, currently marketed ship cable do not only exist it is anti-
The shortcomings that solarization property and resistance to ag(e)ing are poor, also there are the shortcomings of intensity is low, cracking resistance difference and service life is short, this also makes present
The use scope of commercially available ship cable compares limitation.
The content of the invention
In view of the deficiencies of the prior art, the present invention provides a kind of high intensity anticracking ship hawser, not only with anti-Sai
Property and resistance to ag(e)ing it is good the advantages of, also there are the advantages that intensity is high, cracking resistance is good and service life is long.
In order to achieve the above object, the present invention is achieved by the following technical programs：
A kind of high intensity anticracking ship hawser, ingredient is by weight：75-82 parts of Fypro, polypropylene are fine
20-26 parts of dimension, 5-8 parts of stearic acid, 3.5-4.8 parts of microcrystalline wax, 2.6-3.4 parts of glass fibre, 1.6-2.3 parts of siloxanes, silicon
0.9-1.6 parts of wax, 5-8 parts of anticracking fiber, 4.8-6.2 parts of ultraviolet absorber, 9.5-12.3 parts of salt resistance alkaline agent, antioxidant MB 3.2-
4.3 parts, 1.4-2.2 parts of ester based quaternary ammonium salt and appropriate amount of deionized water.
Preferably, a kind of preparation method of high intensity anticracking ship hawser, comprises the following steps：
A, all raw materials in addition to Fypro, polypropylene fibre and deionized water are placed in pulverizer and carry out powder
It is broken, it is then ground by grinder, obtains blending ingredients, it is spare；
B, the blending ingredients obtained by step a are uniformly mixed with absolute ethyl alcohol by solid-liquid ratio 35-40g/L, using ultrasonic wave
Extracting solution is extracted to obtain, 60-80 DEG C of ultrasonic wave extraction temperature filters extracting solution, and filtrate is after being concentrated in vacuo, being freeze-dried, i.e.,
Obtain extract；
C, the extract in step b is placed in high-speed stirred kettle, 6-9 times of deionized water is heated into stirred tank, is risen
Temperature is stirred 65-80min to 95-110 DEG C, obtains mixed solution；
D, Fypro and polypropylene fibre are placed in double screw extruder, melting is kneaded, squeezes out and is granulated, and obtains
To masterbatch mix, 150-175 DEG C of temperature in double screw extruder, screw speed 120-160r/min.
E, mixed solution in the masterbatch mix in step d and step c is placed in double screw extruder, is melt into melting too
Spinning solution, then through filament spinning component spinning temperature be 200 DEG C -260 DEG C, component pressure be 120~280bar under conditions of spinning
Strand is formed, strand is by cooling down blowing, cooling, curing, package, formation hawser long filament；
F, the hawser long filament in step e according to actual needs, is woven into finished product ship cable by rope-making equipment.
Preferably, the ultra-violet absorber agent select salicylate, benzophenone, benzotriazole, triazines and hindered amine its
In three kinds or four kinds.
Preferably, the salt resistance alkaline agent selects arasaponin, mannitol, ascorbic acid and potassium pyrophosphate, parts by weight：Three
Seven 0.15~0.3 part of total saposins, 2~8 parts of mannitol, 2~6 parts of ascorbic acid, 80~93 parts of potassium pyrophosphate
Preferably, the rotating speed of the step c high speed mixers is 1500-1800r/min.
Preferably, the melting time in the step e is 75-95min.
Advantageous effect：
The present invention is with Fypro, polypropylene fibre, stearic acid, microcrystalline wax, glass fibre, siloxanes, silicon wax, anti-
Fiber, ultraviolet absorber, salt resistance alkaline agent, anti-aging agent and ester based quaternary ammonium salt are split as the raw material for preparing ship cable, it is prepared
Ship cable has many advantages, such as that sun protection, resistance to ag(e)ing, intensity are high, cracking resistance is good and service life grow it is good.Wherein polyamide
The intensity and wear resistance of hawser prepared by fiber are more than fiber crops, cotton hawser several times, stearic acid, microcrystalline wax, glass in raw material
Glass fiber and Fypro interaction cooperation make 3-5 times of the strength enhancing of hawser.In addition the present invention is by adding silica
Alkane, stearic acid, silicon wax and anticracking fiber, make the anti crack performance of hawser significantly be changed.Hawser prepared by polypropylene fibre
Proportion is less than water, can bubble through the water column, the mutual cooperation of polypropylene fibre, salt resistance alkaline agent and ester based quaternary ammonium salt causes line density
Bottom, flexibility are good, easy to operate and safe operation.Adding in ultraviolet absorber makes the sun-proof performance enhancement of hawser.
Specific embodiment
To make the purpose, technical scheme and advantage of the embodiment of the present invention clearer, below in conjunction with the embodiment of the present invention,
Technical solution in the embodiment of the present invention is clearly and completely described, it is clear that described embodiment is the present invention one
Divide embodiment, instead of all the embodiments.Based on the embodiments of the present invention, those of ordinary skill in the art are not making
All other embodiments obtained under the premise of creative work, belong to the scope of protection of the invention.
Embodiment 1：
A kind of high intensity anticracking ship hawser, ingredient is by weight：75 parts of Fypro, polypropylene fibre 26
Part, 5 parts of stearic acid, 3.5 parts of microcrystalline wax, 2.6 parts of glass fibre, 2.3 parts of siloxanes, 0.9 part of silicon wax, 7 parts of anticracking fiber, purple
Outer 4.8 parts of absorbent, 9.5 parts of salt resistance alkaline agent, 3.2 parts of antioxidant MB, 1.4 parts of ester based quaternary ammonium salt and appropriate amount of deionized water.
A kind of preparation method of high intensity anticracking ship hawser, comprises the following steps：
A, all raw materials in addition to Fypro, polypropylene fibre and deionized water are placed in pulverizer and carry out powder
It is broken, it is then ground by grinder, obtains blending ingredients, it is spare；
B, the blending ingredients obtained by step a are uniformly mixed with absolute ethyl alcohol by solid-liquid ratio 35g/L, using ultrasonic wave extraction
Extracting solution is obtained, 67 DEG C of ultrasonic wave extraction temperature filters extracting solution, and filtrate is after being concentrated in vacuo, being freeze-dried to get extraction
Object；
C, the extract in step b is placed in high-speed stirred kettle, 6 times of deionized water, heating is heated into stirred tank
To 110 DEG C, 65min is stirred, obtains mixed solution；
D, Fypro and polypropylene fibre are placed in double screw extruder, melting is kneaded, squeezes out and is granulated, and obtains
To masterbatch mix, 150 DEG C of temperature in double screw extruder, screw speed 120r/min.
E, mixed solution in the masterbatch mix in step d and step c is placed in double screw extruder, is melt into melting too
Spinning solution, then through filament spinning component spinning temperature be 200 DEG C, component pressure be 120bar under conditions of spinning formed strand, silk
Item is by cooling down blowing, cooling, curing, package, formation hawser long filament；
F, the hawser long filament in step e according to actual needs, is woven into finished product ship cable by rope-making equipment.
Salicylate, benzotriazole and triazines are selected in ultra-violet absorber agent.
Salt resistance alkaline agent selects arasaponin, mannitol, ascorbic acid and potassium pyrophosphate, parts by weight：Arasaponin 0.3
Part, 2 parts of mannitol, 6 parts of ascorbic acid, 80 parts of potassium pyrophosphate
The rotating speed of step c high speed mixers is 1700r/min.
Melting time in step e is 75min.
Embodiment 2：
A kind of high intensity anticracking ship hawser, ingredient is by weight：77 parts of Fypro, polypropylene fibre 24
Part, 6 parts of stearic acid, 3.9 parts of microcrystalline wax, 2.9 parts of glass fibre, 1.9 parts of siloxanes, 1.1 parts of silicon wax, 6 parts of anticracking fiber, purple
Outer 5.4 parts of absorbent, 10.4 parts of salt resistance alkaline agent, 3.6 parts of antioxidant MB, 1.8 parts of ester based quaternary ammonium salt and appropriate amount of deionized water.
A kind of preparation method of high intensity anticracking ship hawser, comprises the following steps：
A, all raw materials in addition to Fypro, polypropylene fibre and deionized water are placed in pulverizer and carry out powder
It is broken, it is then ground by grinder, obtains blending ingredients, it is spare；
B, the blending ingredients obtained by step a are uniformly mixed with absolute ethyl alcohol by solid-liquid ratio 36g/L, using ultrasonic wave extraction
Extracting solution is obtained, ultrasonic wave extraction temperature 60 C filters extracting solution, and filtrate is after being concentrated in vacuo, being freeze-dried to get extraction
Object；
C, the extract in step b is placed in high-speed stirred kettle, 7 times of deionized water, heating is heated into stirred tank
To 95 DEG C, 70min is stirred, obtains mixed solution；
D, Fypro and polypropylene fibre are placed in double screw extruder, melting is kneaded, squeezes out and is granulated, and obtains
To masterbatch mix, 175 DEG C of temperature in double screw extruder, screw speed 135r/min.
E, mixed solution in the masterbatch mix in step d and step c is placed in double screw extruder, is melt into melting too
Spinning solution, then through filament spinning component spinning temperature be 245 DEG C, component pressure be 160bar under conditions of spinning formed strand, silk
Item is by cooling down blowing, cooling, curing, package, formation hawser long filament；
F, the hawser long filament in step e according to actual needs, is woven into finished product ship cable by rope-making equipment.
Benzophenone, triazines and hindered amine are selected in ultra-violet absorber agent.
Salt resistance alkaline agent selects arasaponin, mannitol, ascorbic acid and potassium pyrophosphate, parts by weight：Arasaponin
0.25 part, 4 parts of mannitol, 2 parts of ascorbic acid, 80~84 parts of potassium pyrophosphate
The rotating speed of step c high speed mixers is 1600r/min.
Melting time in step e is 80min.
Embodiment 3：
A kind of high intensity anticracking ship hawser, ingredient is by weight：79 parts of Fypro, polypropylene fibre 20
Part, 7 parts of stearic acid, 4.8 parts of microcrystalline wax, 3.1 parts of glass fibre, 1.6 parts of siloxanes, 1.3 parts of silicon wax, 5 parts of anticracking fiber, purple
Outer 5.8 parts of absorbent, 12.3 parts of salt resistance alkaline agent, 3.9 parts of antioxidant MB, 2.2 parts of ester based quaternary ammonium salt and appropriate amount of deionized water.
A kind of preparation method of high intensity anticracking ship hawser, comprises the following steps：
A, all raw materials in addition to Fypro, polypropylene fibre and deionized water are placed in pulverizer and carry out powder
It is broken, it is then ground by grinder, obtains blending ingredients, it is spare；
B, the blending ingredients obtained by step a are uniformly mixed with absolute ethyl alcohol by solid-liquid ratio 37/L, using ultrasonic wave extraction
Extracting solution is obtained, 72 DEG C of ultrasonic wave extraction temperature filters extracting solution, and filtrate is after being concentrated in vacuo, being freeze-dried to get extraction
Object；
C, the extract in step b is placed in high-speed stirred kettle, 8 times of deionized water, heating is heated into stirred tank
To 100 DEG C, 75min is stirred, obtains mixed solution；
D, Fypro and polypropylene fibre are placed in double screw extruder, melting is kneaded, squeezes out and is granulated, and obtains
To masterbatch mix, 165 DEG C of temperature in double screw extruder, screw speed 145r/min.
E, mixed solution in the masterbatch mix in step d and step c is placed in double screw extruder, is melt into melting too
Spinning solution, then through filament spinning component spinning temperature be 223 DEG C, component pressure be 220bar under conditions of spinning formed strand, silk
Item is by cooling down blowing, cooling, curing, package, formation hawser long filament；
F, the hawser long filament in step e according to actual needs, is woven into finished product ship cable by rope-making equipment.
Salicylate, benzophenone, triazines and hindered amine are selected in ultra-violet absorber agent.
Salt resistance alkaline agent selects arasaponin, mannitol, ascorbic acid and potassium pyrophosphate, parts by weight：Arasaponin
0.15 part, 6 parts of mannitol, 4 parts of ascorbic acid, 88 parts of potassium pyrophosphate
The rotating speed of step c high speed mixers is 1500r/min.
Melting time in step e is 85min.
Embodiment 4：
A kind of high intensity anticracking ship hawser, ingredient is by weight：82 parts of Fypro, polypropylene fibre 22
Part, 8 parts of stearic acid, 4.4 parts of microcrystalline wax, 3.4 parts of glass fibre, 2.1 parts of siloxanes, 1.6 parts of silicon wax, 8 parts of anticracking fiber, purple
Outer 6.2 parts of absorbent, 11.5 parts of salt resistance alkaline agent, 4.3 parts of antioxidant MB, 2 parts of ester based quaternary ammonium salt and appropriate amount of deionized water.
A kind of preparation method of high intensity anticracking ship hawser, comprises the following steps：
A, all raw materials in addition to Fypro, polypropylene fibre and deionized water are placed in pulverizer and carry out powder
It is broken, it is then ground by grinder, obtains blending ingredients, it is spare；
B, the blending ingredients obtained by step a are uniformly mixed with absolute ethyl alcohol by solid-liquid ratio 40g/L, using ultrasonic wave extraction
Extracting solution is obtained, 80 DEG C of ultrasonic wave extraction temperature filters extracting solution, and filtrate is after being concentrated in vacuo, being freeze-dried to get extraction
Object；
C, the extract in step b is placed in high-speed stirred kettle, 9 times of deionized water, heating is heated into stirred tank
To 105 DEG C, 65-80min is stirred, obtains mixed solution；
D, Fypro and polypropylene fibre are placed in double screw extruder, melting is kneaded, squeezes out and is granulated, and obtains
To masterbatch mix, 170 DEG C of temperature in double screw extruder, screw speed 160r/min.
E, mixed solution in the masterbatch mix in step d and step c is placed in double screw extruder, is melt into melting too
Spinning solution, then through filament spinning component spinning temperature be 260 DEG C, component pressure be 280bar under conditions of spinning formed strand, silk
Item is by cooling down blowing, cooling, curing, package, formation hawser long filament；
F, the hawser long filament in step e according to actual needs, is woven into finished product ship cable by rope-making equipment.
Benzophenone, benzotriazole, triazines and hindered amine are selected in ultra-violet absorber agent.
Salt resistance alkaline agent selects arasaponin, mannitol, ascorbic acid and potassium pyrophosphate, parts by weight：Arasaponin
0.19 part, 8 parts of mannitol, 5 parts of ascorbic acid, 93 parts of potassium pyrophosphate
The rotating speed of step c high speed mixers is 1800r/min.
Melting time in step e is 95min.
Be after tested, 0.78MPa, 0.79MPa by the shear strength of the ship cable of upper 4 embodiments preparation,
0.81MPa and 0.77MPa.Adhesion strength is 0.29MPa, 0.31MPa, 0.30MPa and 0.29MPa.Ship cable is immersed in
20 DEG C, 720h does not have found that cracking, aliquation or obscission occur for ship cable in the brine that mass concentration is 7%.Ozone aging
It is 2 grades.Absorption of UV is 95%, 93%, 96% and 97%
It should be noted that herein, relational terms such as first and second and the like are used merely to a reality
Body or operation are distinguished with another entity or operation, are deposited without necessarily requiring or implying between these entities or operation
In any this actual relation or order.Moreover, term " comprising ", "comprising" or its any other variant are intended to
Non-exclusive inclusion, so that process, method, article or equipment including a series of elements not only will including those
Element, but also including other elements that are not explicitly listed or further include as this process, method, article or equipment
Intrinsic element.In the absence of more restrictions, the element limited by sentence "including a ...", it is not excluded that
Also there are other identical elements in process, method, article or equipment including the element.
The above embodiments are merely illustrative of the technical solutions of the present invention, rather than its limitations；Although with reference to the foregoing embodiments
The present invention is described in detail, it will be understood by those of ordinary skill in the art that：It still can be to foregoing each implementation
Technical solution recorded in example modifies or carries out equivalent substitution to which part technical characteristic；And these modification or
It replaces, the essence of appropriate technical solution is not made to depart from the spirit and scope of various embodiments of the present invention technical solution.
Claims (6)
1. a kind of high intensity anticracking ship hawser, which is characterized in that its ingredient is by weight：75-82 parts of Fypro,
20-26 parts of polypropylene fibre, 5-8 parts of stearic acid, 3.5-4.8 parts of microcrystalline wax, 2.6-3.4 parts of glass fibre, siloxanes 1.6-
2.3 parts, it is 0.9-1.6 parts of silicon wax, 5-8 parts of anticracking fiber, 4.8-6.2 parts of ultraviolet absorber, 9.5-12.3 parts of salt resistance alkaline agent, anti-old
MB3.2-4.3 parts of agent, 1.4-2.2 parts of ester based quaternary ammonium salt and appropriate amount of deionized water.
2. a kind of preparation method of high intensity anticracking ship hawser according to claim 1, which is characterized in that including with
Lower step：
A, all raw materials in addition to Fypro, polypropylene fibre and deionized water are placed in pulverizer and crushed, so
It is ground afterwards by grinder, obtains blending ingredients, it is spare；
B, the blending ingredients obtained by step a are uniformly mixed with absolute ethyl alcohol by solid-liquid ratio 35-40g/L, using ultrasonic wave extraction
Extracting solution, 60-80 DEG C of ultrasonic wave extraction temperature filters extracting solution, and filtrate is after being concentrated in vacuo, being freeze-dried to get carrying
Take object；
C, the extract in step b is placed in high-speed stirred kettle, 6-9 times of deionized water is heated into stirred tank, is warming up to
95-110 DEG C, 65-80min is stirred, obtains mixed solution；
D, Fypro and polypropylene fibre are placed in double screw extruder, melting is kneaded, squeezes out and is granulated, and is mixed
Master batch is closed, 150-175 DEG C of temperature in double screw extruder, screw speed 120-160r/min.
E, mixed solution in the masterbatch mix in step d and step c is placed in double screw extruder, is melt into melting too spinning
Liquid, then through filament spinning component spinning temperature be 200-260 DEG C, component pressure be 120-280bar under conditions of spinning formed silk
Item, strand is by cooling down blowing, cooling, curing, package, formation hawser long filament；
F, the hawser long filament in step e according to actual needs, is woven into finished product ship cable by rope-making equipment.
3. a kind of high intensity anticracking ship hawser according to claim 1, it is characterised in that：The ultra-violet absorber
Salicylate, benzophenone, benzotriazole, triazines and three kinds or four kinds therein of hindered amine are selected in agent.
4. a kind of high intensity anticracking ship hawser according to claim 1, it is characterised in that：The salt resistance alkaline agent is selected
Arasaponin, mannitol, ascorbic acid and potassium pyrophosphate, parts by weight：0.15-0.3 parts of arasaponin, 2-8 parts of mannitol,
2-6 parts of ascorbic acid, 80-93 parts of potassium pyrophosphate.
5. a kind of preparation method of high intensity anticracking ship hawser according to claim 2, it is characterised in that：The step
The rotating speed of rapid c high speed mixers is 1500-1800r/min.
6. a kind of preparation method of high intensity anticracking ship hawser according to claim 2, it is characterised in that：The step
Melting time in rapid e is 75-95min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711295478.1A CN108085776A (en) | 2017-12-08 | 2017-12-08 | A kind of high intensity anticracking ship hawser and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711295478.1A CN108085776A (en) | 2017-12-08 | 2017-12-08 | A kind of high intensity anticracking ship hawser and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108085776A true CN108085776A (en) | 2018-05-29 |
Family
ID=62174122
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711295478.1A Pending CN108085776A (en) | 2017-12-08 | 2017-12-08 | A kind of high intensity anticracking ship hawser and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108085776A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109082023A (en) * | 2018-06-07 | 2018-12-25 | 盐城神威制绳有限公司 | A kind of preparation method of salt tolerant anticorrosion macromolecule rope plastic composites |
| CN111996824A (en) * | 2020-08-21 | 2020-11-27 | 江苏神力船舶设备有限公司 | Manufacturing method of low-temperature-resistant mooring rope for ship |
-
2017
- 2017-12-08 CN CN201711295478.1A patent/CN108085776A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109082023A (en) * | 2018-06-07 | 2018-12-25 | 盐城神威制绳有限公司 | A kind of preparation method of salt tolerant anticorrosion macromolecule rope plastic composites |
| CN109082023B (en) * | 2018-06-07 | 2021-01-05 | 盐城神威制绳有限公司 | Preparation method of plastic composite material for salt-resistant and anti-corrosion polymer rope |
| CN111996824A (en) * | 2020-08-21 | 2020-11-27 | 江苏神力船舶设备有限公司 | Manufacturing method of low-temperature-resistant mooring rope for ship |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105693100B (en) | A kind of high-performance glass fiber composition and its glass fibre and composite material | |
| CN112140264A (en) | Transparent cellulose composite material and preparation method thereof | |
| CN108085776A (en) | A kind of high intensity anticracking ship hawser and preparation method thereof | |
| CN101568674B (en) | Composite fiber of cellulose-polyvinylalcohol and preparation method thereof | |
| CN103789873B (en) | A kind of regenerated bark cored structure composite fibre and preparation method thereof | |
| CN105111632A (en) | Novel modified polyvinyl chloride plastics | |
| CN102230237A (en) | Poultry feather protein viscose silk and manufacturing method thereof | |
| CN109880180B (en) | Nano-cellulose/cellulose compound, reinforced polylactic acid 3D printing material and preparation method thereof | |
| CN102851773A (en) | Production method of uvioresistant fiber | |
| CN109517146B (en) | Environment-friendly anti-ultraviolet polyester for fibers and application thereof | |
| CN113502555A (en) | Preparation method of ultrahigh molecular weight polyethylene fiber with strength greater than 39cN/dtex | |
| CN103774281A (en) | Process for preparing health seacell fiber spinning | |
| CN102321931B (en) | Recycling and re-spinning method of ultra-high molecular weight polyethylene gel waste silk | |
| CN108739690B (en) | Fishing net with excellent aging resistance | |
| CN113999443A (en) | Coating material for mariculture support and preparation method thereof | |
| CN106752995A (en) | A kind of polyvinyl butyral film and preparation method thereof | |
| CN104499064B (en) | Anti-pilling shell fabric spinning method | |
| CN106801364A (en) | A kind of fruit cultivating bag paper and its production technology | |
| CN102701604A (en) | Warp slurry of fiberglass electronic textile yarn | |
| CN106149086B (en) | A kind of superpower melt-spun slivers processing method of foreign fishery netting excessively | |
| CN109943905B (en) | Artificial wool containing plant nano powder | |
| CN106381554A (en) | Sunproof type nylon fiber wire for weaving fishing net | |
| CN108677249A (en) | A kind of raising silkworm cocoon reelability rate, the silk cocoon processing method of silk production rate | |
| CN104817826B (en) | For producing the FDY fiber master batch of permeation-proof light and thin fabric | |
| CN108715659B (en) | Method for improving strength of transparent plastic woven bag |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20180529 |