CN108085008A - Hardened reclamation of salinep-alkali soil material and modification method based on structure local microenvironment - Google Patents

Hardened reclamation of salinep-alkali soil material and modification method based on structure local microenvironment Download PDF

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CN108085008A
CN108085008A CN201711169107.9A CN201711169107A CN108085008A CN 108085008 A CN108085008 A CN 108085008A CN 201711169107 A CN201711169107 A CN 201711169107A CN 108085008 A CN108085008 A CN 108085008A
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soil
hardened
alkali soil
salinep
reclamation
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邵安林
徐连生
刘润华
马旭峰
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Ansteel Mining Co Ltd
Angang Group Mining Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K17/00Soil-conditioning materials or soil-stabilising materials
    • C09K17/40Soil-conditioning materials or soil-stabilising materials containing mixtures of inorganic and organic compounds
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01BSOIL WORKING IN AGRICULTURE OR FORESTRY; PARTS, DETAILS, OR ACCESSORIES OF AGRICULTURAL MACHINES OR IMPLEMENTS, IN GENERAL
    • A01B79/00Methods for working soil
    • A01B79/02Methods for working soil combined with other agricultural processing, e.g. fertilising, planting
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2101/00Agricultural use
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Soil Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Environmental Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Soil Conditioners And Soil-Stabilizing Materials (AREA)
  • Cultivation Of Plants (AREA)

Abstract

The purpose of the present invention is to solve be particularly problem present in the modification method of hardened type saline-alkali soil to saline-alkali soil in the prior art, a kind of hardened reclamation of salinep-alkali soil material and modification method based on structure local microenvironment are provided, belongs to reclamation of salinep-alkali soil technical field.This method in hardened serious saline-alkali soil by building local microenvironment, hardened serious saline-alkali soil region is centered on subenvironment material, generate class " fertile island effect ", so as to improve root system of plant or seed surrounding soil structure and growing environment, seed germination rate, planting percent and yield are improved, and reduces soil salt content.And the improved materials can improve the quality of saline-alkali soil, realize the long-time stability of saline-alkali soil quality improvement.

Description

Hardened reclamation of salinep-alkali soil material and modification method based on structure local microenvironment
Technical field
The invention belongs to reclamation of salinep-alkali soil technical fields, and in particular to a kind of based on the hardened saline and alkaline of structure local microenvironment Native improved materials and modification method.
Background technology
Saline-alkali soil is solonchak and alkaline earth and the general name of various salinization and alkali soil.Wherein, solonchak refers to containing largely may be used Dissolubility salt and prevent most plants salt content be typically up to more than 0.6% from the soil that grows;Alkaline earth refers to Sodium by substitution The percentage of ionic cation replacement amount(ESP)Strong basicity soil more than 20%.The physics and chemical property of salinized soil all compared with Difference is mainly shown as that salinity or basicity are excessively high, causes root system of plant water shortage or is poisoned, and the soil texture glues weight, aggregate Less, soil hardening when arid is totally unfavorable to agricultural production.
In the prior art, administered frequently with engineering water conservancy measure or chemical modifying measure.Currently used engineering Water resources industry include level land, drainage trenching canal, plough, rotary tillage, soaked field, build salt discharge pipeline and salt discharge hole etc., such as CN The method in 103621209A improvement improvement salt-soda soil, CN 204810883U salt discharge alkali pipe, CN101347790A improvement are saline and alkaline Ground ground method, CN 202587801U salt-soda soils salt discharge alkali pipe, 1051651 67A method for desalting salinized soil of CN, CN 102349371A Saline-Sodics paddy field quick desalination alkali ploughs method of soil preparation, CN 204968401U salt-soda soil salt discharge alkali hidden pipe, CN A kind of coastal alkaline land cotton desalinization of soil by flooding or leaching row alkali device of the salt discharge alkali mechanism in 203791335U salt-soda soils, CN 204733557U, CN This kind of method such as 104054425 A alkaline land improvings systems and modification method is mainly reduced using gutter drainage or vertical drainage Water level reduces saline and alkaline rising, is improved by irrigating desalinization of soil by flooding or leaching alkali etc. or will be saline and alkaline by being laid with salt discharge pipeline and salt discharge hole The salinity on ground is gone out by salt discharge hole and salt discharging pipe outside field, achievees the purpose that finally to reduce soil alkaline, improvement soil.Also by Structure is improved every salt deposit, e.g., heavy salinized ground administering method, 102232328 A of CN in 104115586 A one kind of CN A kind of implantation methods, 105393666 A saline and alkali land improvement methods of CN, the CN of the method and salt-soda soil for improveing salt-soda soil A kind of methods in rebuilding and improving salt-soda soil of 1759943 A, 105165167 A method for desalting salinized soil of CN, CN 102550159A salt-soda soils suppression control salt method and salt-soda soil suppression control salt system etc., this kind of method is usually in salt-soda soil certain depth In the range of structure every salt deposit(Clinker, quartz sand etc.), grouting or set gas permeability antiseepage aggregate layer(Quartz sand, slag, haydite or Glass is micro- etc.)The methods of prevent underground water move up so that underground water can not carry a large amount of salt and enter most crops root system Growth district so as to long-term cropping, while so that salt-soda soil is gradually improved.
It is a kind of method being widely used at present using modifying agent improvement, as 102936503 A of CN contain iron tailings Soil ventilation improvement synergist and preparation method thereof, a kind of anti-accumulation of salt in the surface soil alkaline agents prepared using iron tailings of 102936502 A of CN And its application in salt-soda soil, a kind of saline alkali soil conditioners of 10,627 8522 A of CN, CN101624523A one kind are saline and alkaline Soil conditioner, a kind of salt-soda soil fertilizers of 102775250 A of CN, 106220415 A of CN are a kind of to be improved for salt affected soil Functional water-soluble fertilizer and its application, 103922846 A saline and alkali land improvement methods of CN, 106146198 A salt resistance alkali of CN Organic fertilizer, 102517030 A alkaline land modifying agents of CN, CN101481281A comprehensive treatment agent for soda alkaline land and its make With method, a kind of methods for improveing salt-soda soil of 104871678 A of CN etc., this kind of method is mainly by applying organic fertilizer, nothing The modifying agents such as machine fertilizer, conditioning agent, microbial manure improve soil texture, increase retention capacity of soil, improve soil nutrient or Using absorption, displacement, neutralization, fertilizer conservation, every the methods of salt improve alkaline land soil.
In existing method, engineering waterpower improvement usually invest it is larger, improvement cost it is excessively high.Water source of fresh water is generally used for fill The perfect area of the water conservancy projects such as foot, irrigation and drainage, for the obstructed varieties in saline-alkali areas of drought, water resources shortage, draining then not It is applicable in.Chemical modifying general raw material composition is complex, without extensive adaptability, and operation and management are stringenter, soil The earth curing time is very long.The biological modification method cycle is longer, slowly effect, and has higher requirement to biological species.It is especially right In the saline-alkali soil of heavy texture, hardened phenomenon often occurs, soil permeability, gas permeability are poor, cause around seed or plant root Oxygen lacks, and salinity directly contacts with plant epidermis cell and generate serious murder by poisoning, causes seed that cannot sprout or planting percent It reduces, difficulty of governance is larger.Therefore, it is necessary to the modification method that hardened type saline-alkali soil is particularly to saline-alkali soil is further studied.
The content of the invention
The purpose of the present invention is to solve the modification methods for being particularly hardened type saline-alkali soil to saline-alkali soil in the prior art Present in problem, provide it is a kind of based on structure local microenvironment hardened reclamation of salinep-alkali soil material and modification method.The party Method by building local microenvironment in hardened serious saline-alkali soil, so as to improve root system of plant or seed surrounding soil structure and Growing environment promotes seed sprouting and root growth.And the improved materials can improve the quality of saline-alkali soil, realize saline-alkali soil The long-time stability of quality improvement.
One of technical scheme is a kind of hardened reclamation of salinep-alkali soil material based on structure local microenvironment, by Iron tailings sand, fertile soil, salt resistance alkaline agent and complexing water-retaining agent composition:
Wherein, the iron tailings sand and mass percentage humous are 10 ~ 30% and 70 ~ 90%, total amount 100%;
The addition of the salt resistance alkaline agent is to make the soil Huang entropy soil moisture content of iron tailings sand and humic earth mixtures between 12 ~ 15%, PH is 6.7 ± 0.5;
The addition of the complexing water-retaining agent is that the soil of iron tailings sand, fertile soil and salt resistance alkaline agent mixture is made to fit entropy soil moisture content to exist Between 16 ~ 18% and make the plasticity index of composite soil for 9 ~ 12.
Further, above-mentioned improved materials, in the iron tailings sand, sand grains(Particle size range is 0.05 mm≤sand grains < 2mm)Content is 5 ~ 10%, powder(Particle size range is 0.002 mm≤powder < 0.05mm)Content is 60 ~ 70% and clay(Grain size Scope is < 0.002mm)Content is 25 ~ 35%;Total amount is 100%.
Further, above-mentioned improved materials, the salt resistance alkaline agent include hydrolysis of polymaleic anhydride and polyacrylic acid;Preferably , the salt resistance alkaline agent is the hydrolysis of polymaleic anhydride of solid content 48 ~ 50%, and molecular weight is 400 ~ 800, the pH of 1% aqueous solution For 2 ~ 3.
Further, above-mentioned improved materials, the water-retaining agent that is complexed is anion-polyacrylamide, pH effective ranges 5 ~ 13, it remains to play preferable complexing in basic conditions.
The two of technical scheme are, the preparation method of above-mentioned improved materials be take in proportion iron tailings sand and Fertile soil adds in salt resistance alkaline agent, makes the soil Huang entropy soil moisture content of composite soil between 12 ~ 15% after mixing, pH is 6.7 ± 0.5;Again Complexing water-retaining agent is added in, the soil of composite soil is made to fit entropy soil moisture content between 16 ~ 18% and makes the plasticity index of composite soil for 9 ~ 12, So as to which the improved materials be made.
The three of technical scheme are that a kind of hardened reclamation of salinep-alkali soil method based on structure local microenvironment is adopted With above-mentioned improved materials, include the following steps:
1)Crop seed to be planted with the improved materials is mixed, and mixture is made to form agglomerate, so as to form preferential species Son is sprouted and the subenvironment material of root system extension;
2)The subenvironment material built is transferred in hardened saline-alkali soil region and carries out normal production operation, farming and field pipe Manage same field crop;Saline-alkali soil region generates class " fertile island effect " centered on subenvironment material, improve seed germination rate, into Seedling rate and yield, and reduce soil salt content.
Further, the mass ratio of above-mentioned modification method, the crop seed and the improved materials is 1:100~300.
Compared with prior art, beneficial effects of the present invention are:
1. present invention process is simple, easy to implement, pollution-free, raw material sources are extensive, cheap, and production cost is low.
It is 2. with obvious effects to the hardened reclamation of salinep-alkali soil of heavy texture.In the method for the present invention, built in hardened saline-alkali soil Local microenvironment with certain plasticity, the subenvironment by permeable, the ventilative iron tailings sand with rib block structure, with compared with The compositions such as good fertility property and the fertile soil of structure, non-hollow billet gap, the big crack of iron tailings sand composition are more, the complexing of addition Water-retaining agent can effectively maintain the stability and plasticity of seed surrounding local environment, and the salt resistance alkaline agent of addition can be neutralized effectively Alkaline components around seed build local weakly acidic pH environment.Crop seed is placed in subenvironment, when it is normally sprouted and extend After going out a part of root system, resistance greatly enhances, and generates class " fertile island effect ", organic acid secreted by root system etc. influences week Surrounding environment accumulates organic matter and nutrient, can effectively improve planting percent and yield, at the same reduce hardened saline-alkali soil soil salt content and Soil hardening.
3. and the improved materials can improve the quality of saline-alkali soil, realize the long-time stability of saline-alkali soil quality improvement.
4. reduce the cost that improved texture of fermented dairy products glues the hardened saline-alkali soil of weight.Since iron tailings sand is discarded for iron ore mine production Object, improvement are realized using iron tailings sand and it are recycled, and reduce improvement cost.
Specific embodiment
Below by way of specific embodiment, the invention will be further described.
The iron tailings sand used in following embodiment, from Anshan mining company Tailings Dam, is changed for Anshan type iron tailings It learns in component, SiO2The harmful components such as content 76.1%, total iron content 11.31%, heavy metal are extremely low, meet Ministry of Agriculture's a great number of elements The toxic element limit standard of fertilizer.Iron tailings sand sand grains(Particle size range is 0.05 mm≤sand grains < 2mm)Content for 5 ~ 10%, Powder(Particle size range is 0.002 mm≤powder < 0.05mm)Content is 60 ~ 70% and clay(Particle size range is < 0.002mm) Content is 25 ~ 35%.
Embodiment 1
Improve hardening saline-alkali soil plot is treated in selection(Area 30m2, < 0.01mm clay contents 34.3%, soil salt content is 4.25 ‰, pH 8.62), level land.In the suitable cultivated phase, by the iron tailings sand of mass percent 20%(PH is 9.65)And quality The fertile soil of percentage 80% is homogenously mixed together, and then sprays hydrolysis of polymaleic anhydride, and the soil moisture content for controlling mixed soil is 12%(Yellow entropy), pH6.5 then sprays anion-polyacrylamide(PH effective ranges 5 ~ 14), stir evenly, control soil Soil moisture content is 18%(Suitable entropy), wheat seed and mixed soil are then pressed 1:100 ratio mixes, and keeps centainly Plasticity(Plasticity index 9).Then strip-type sowing is carried out in plot to be improved(It prevents from pulverizing the shape for destroying subenvironment material), Other farming and the same field crop of field management, and control 1 is set(30m2Hardened saline-alkali soil plot)With control 2(It will be with this The same amount of Anshan type iron tailings of embodiment, fertile soil, hydrolysis of polymaleic anhydride and anion-polyacrylamide are directly turned over In 30m2Hardened saline-alkali soil plot in).Wheat seeding rate, planting percent are measured during plant growth, yield and soil are surveyed after harvest Earth salt content, pH.
Improved results are shown in Table 1.
Soil physical chemistry and Biological indicators monitoring result after a kind of table is planted
Embodiment 2
Improve hardening saline-alkali soil plot is treated in selection(Area 30m2, < 0.01mm clay contents 34.3%, soil salt content is 4.25 ‰, pH 8.62), level land.In the suitable cultivated phase, by the iron tailings sand of mass percent 10%(PH is 9.65)And quality The fertile soil of percentage 90% is homogenously mixed together, and then sprays hydrolysis of polymaleic anhydride, and it is 15% to control mixed soil soil moisture content (Yellow entropy), then pH sprays anion-polyacrylamide 6.8(PH effective ranges 5 ~ 14), stir evenly, control soil moisture in the soil Feelings are 16%(Suitable entropy), wheat seed and mixed soil are finally pressed 1:200 ratio mixes, and protects mixed soil Hold certain plasticity(Plasticity index 12).Then strip-type sowing is carried out in plot to be improved(It prevents from pulverizing and destroys subenvironment material The shape of material), other farming and the same field crop of field management, and control is set(30m2Hardened saline-alkali soil plot).Growth Period measures wheat seeding rate, planting percent, and yield, soil salt content, pH are surveyed after harvest.
Improved results are shown in Table 2.
Soil physical chemistry and Biological indicators monitoring result after table 2 is improved
Embodiment 3
Improve hardening saline-alkali soil plot is treated in selection(Area 30m2, < 0.01mm clay contents 34.3%, soil salt content is 4.25 ‰, pH 8.62), level land.In the suitable cultivated phase, by the iron tailings sand of mass percent 30%(PH is 9.65)And quality The fertile soil of percentage 70% is homogenously mixed together, and then sprays hydrolysis of polymaleic anhydride, and it is 14% to control mixed soil soil moisture content (Yellow entropy), then pH 6.2 sprays anion-polyacrylamide(PH effective ranges 5 ~ 14), stir evenly, control soil moisture in the soil Feelings are 17%(Suitable entropy), wheat seed and mixed soil are then pressed 1:300 ratio mixes, and keeps certain modeling Property(Plasticity index 10).Then strip-type sowing is carried out in plot to be improved(It prevents from pulverizing the shape for destroying subenvironment material), Other farming and the same field crop of field management, and control is set(30m2Hardened saline-alkali soil plot).Growth period measures small Wheat emergence rate, planting percent survey yield, soil salt content, pH after harvest.
Improved results are shown in Table 3.
Soil physical chemistry and Biological indicators monitoring result after the improvement of 3 subenvironment of table

Claims (8)

1. a kind of hardened reclamation of salinep-alkali soil material based on structure local microenvironment, which is characterized in that by iron tailings sand, humic Soil, salt resistance alkaline agent and complexing water-retaining agent composition:
Wherein, the iron tailings sand and mass percentage humous are 10 ~ 30% and 70 ~ 90%;
The addition of the salt resistance alkaline agent is that the soil Huang entropy soil moisture content of iron tailings sand and humic earth mixtures is made to be that 12 ~ 15%, pH is 6.7±0.5;
The addition of the complexing water-retaining agent is that the soil of iron tailings sand, fertile soil and salt resistance alkaline agent mixture is made to fit entropy soil moisture content to be 16 ~ 18%, and make the plasticity index of composite soil for 9 ~ 12.
2. a kind of hardened reclamation of salinep-alkali soil material based on structure local microenvironment according to claim 1, feature exist In in the iron tailings sand, sand grain content is that 5 ~ 10%, silt content is that 60 ~ 70%, clay content is 25 ~ 35%.
3. a kind of hardened reclamation of salinep-alkali soil material based on structure local microenvironment according to claim 1, feature exist In the salt resistance alkaline agent includes hydrolysis of polymaleic anhydride and polyacrylic acid.
4. a kind of hardened reclamation of salinep-alkali soil material based on structure local microenvironment according to claim 3, feature exist In the specification of the hydrolysis of polymaleic anhydride is:Solid content 48 ~ 50%, molecular weight are 400 ~ 800, the pH of 1% aqueous solution for 2 ~ 3。
5. a kind of hardened reclamation of salinep-alkali soil material based on structure local microenvironment according to claim 1, feature exist In the water-retaining agent that is complexed is anion-polyacrylamide, pH effective ranges 5 ~ 13.
6. a kind of preparation method of hardened reclamation of salinep-alkali soil material based on structure local microenvironment described in claim 1, It is characterized in that, takes iron tailings sand and fertile soil in proportion, salt resistance alkaline agent is added in after mixing, the soil Huang entropy soil moisture content for making composite soil is 12 ~ 15%, pH are 6.7 ± 0.5;Complexing water-retaining agent is added, the soil of composite soil is made to fit entropy soil moisture content as 16 ~ 18%, and makes mixing The plasticity index of soil is 9 ~ 12, so as to which the improved materials be made.
7. a kind of hardened reclamation of salinep-alkali soil method based on structure local microenvironment, employs improvement material described in claim 1 Material, which is characterized in that include the following steps:
1)Crop seed to be planted with the improved materials is mixed, and mixture is made to form agglomerate, so as to form preferential species Son is sprouted and the subenvironment material of root system extension;
2)The subenvironment material built is transferred in hardened saline-alkali soil region and carries out plantation operation.
8. a kind of hardened reclamation of salinep-alkali soil method based on structure local microenvironment according to claim 7, feature exist In the mass ratio of the crop seed and the improved materials is 1:100~300.
CN201711169107.9A 2017-11-22 2017-11-22 Hardened reclamation of salinep-alkali soil material and modification method based on structure local microenvironment Pending CN108085008A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113462596A (en) * 2021-06-28 2021-10-01 山东土木启生物科技有限公司 Microbial agent for improving soil salinization
CN113598005A (en) * 2021-09-09 2021-11-05 新疆水利水电科学研究院 Method for planting cotton in saline-alkali soil

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Publication number Priority date Publication date Assignee Title
CN102936502A (en) * 2012-10-26 2013-02-20 鞍钢集团矿业公司 Saline-alkali reoccurrence preventing agent prepared from iron tailings, and application thereof in saline-alkali land
CN104355895A (en) * 2014-11-19 2015-02-18 柳州市潮林机械有限公司 Special nutritional soil for osmanthus tree and preparation method thereof
CN105272766A (en) * 2015-11-26 2016-01-27 北京清迈华清控股(集团)有限公司 Method for producing novel saline-alkaline restoration fertilizer by utilizing high-silicon iron tailings and product
CN105819963A (en) * 2016-03-21 2016-08-03 北京清迈华清控股(集团)有限公司 Saline-alkali soil repairing novel fertilizer produced by taking high-silicon iron tailings as raw materials

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102936502A (en) * 2012-10-26 2013-02-20 鞍钢集团矿业公司 Saline-alkali reoccurrence preventing agent prepared from iron tailings, and application thereof in saline-alkali land
CN104355895A (en) * 2014-11-19 2015-02-18 柳州市潮林机械有限公司 Special nutritional soil for osmanthus tree and preparation method thereof
CN105272766A (en) * 2015-11-26 2016-01-27 北京清迈华清控股(集团)有限公司 Method for producing novel saline-alkaline restoration fertilizer by utilizing high-silicon iron tailings and product
CN105819963A (en) * 2016-03-21 2016-08-03 北京清迈华清控股(集团)有限公司 Saline-alkali soil repairing novel fertilizer produced by taking high-silicon iron tailings as raw materials

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113462596A (en) * 2021-06-28 2021-10-01 山东土木启生物科技有限公司 Microbial agent for improving soil salinization
CN113598005A (en) * 2021-09-09 2021-11-05 新疆水利水电科学研究院 Method for planting cotton in saline-alkali soil

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