CN102674962B - Matrix formula suitable for recovering ion type rare earth tailings vegetation - Google Patents

Matrix formula suitable for recovering ion type rare earth tailings vegetation Download PDF

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CN102674962B
CN102674962B CN 201210137521 CN201210137521A CN102674962B CN 102674962 B CN102674962 B CN 102674962B CN 201210137521 CN201210137521 CN 201210137521 CN 201210137521 A CN201210137521 A CN 201210137521A CN 102674962 B CN102674962 B CN 102674962B
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plant
fertilizer
culture medium
soil culture
soil
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CN102674962A (en
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李春林
高军
黄劲松
何冬明
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QINGDAO GUANZHONG ECOLOGICAL CO Ltd
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Abstract

The invention discloses a matrix formula suitable for recovering ion type rare earth tailings vegetation, which comprises two parts including a plant growth soil culture medium and fertilizer, wherein the plant growth soil culture medium comprises clay, carbendazim, plant fiber, stabilizing agent, agglomerating agent, organic matter, clear water and seeds; and the fertilizer comprises diammonium phosphate, potassium chloride, potassium sulfate, calcium magnesium phosphate fertilizer, bentonite, compound fertilizer and ammonium sulfate. The matrix formula for recovering the vegetation has the acidity of ion type rare earth tailings soil, has the function of providing nutrient elements such as nitrogen, phosphorus and potassium, and has water-retaining property, nutrient preserving capability and air permeability, thus being suitable for the growth of plants; and a preparation method of the matrix formula is carried out in a layered way, and is low in consumption and operable.

Description

A kind of substrate formula that is suitable for the Revegetation of ion type rareearth mine tailing
Technical field
The present invention relates to a kind of Revegetation substrate formula, especially a kind of Revegetation substrate formula that is specifically designed to ion type rareearth mine tailing side slope can be widely used in the fields such as soil conservation, mine recovery, territory greening, traffic engineering, urban construction.
Background technology
Patent documentation CN200510047466.8 discloses a kind of plant culture for hill afforestating, formed by bark, balloonflower root, local soil, plant ash, carbon dust, breaking, paper pulp, green stone, fertilizer, grass-seed, flower seed, the seeds of trees, water-holding agent, solidifying agent, tackiness agent, water extracter raw material, be mixed and made into plant culture, the plant culture of making is sowed grass seeds by duster on the massif scar, is the greening backing that a kind of vegetation seed and soil are lumped together.
Patent documentation CN02115391.4 discloses a kind of mixed planting material for rocky slope and equipment thereof, constructional method, described slope of rock mass intermingle raw material are a kind of composition, evenly are mixed with at normal temperatures by soil, organic matter, composite fertilizer, water-holding agent, cement, pH adjusting agent, plant seed and water to form.One of its core content is that cement is used as binding agent.Can find out that from disclosed content the organic content of its mixed planting material (weight percent) is 2.5 ~ 5.0.Plant is take draft as main.
The big area bare side sloping can occur in the rare earth mining process, ion type rareearth mine tailing side slope soil property is loose, and severe water and soil erosion there is not yet Patents for the Revegetation soil base material prescription in this field.In the recovery process of rare earth, need to add a large amount of oxalic acid (H 2C 2O 4) make it to precipitate extraction with the rare earth sulfate solution effect, isolate rare earth oxalate, so contain a large amount of H in the solution +Remain in the soil, cause soil acidity to increase.NH in the mine tailing 4 +Ion is superfluous, so nitrogen content is abundanter, in addition residual water-soluble SO in a large number in the mine tailing soil 4 2-Ion, these sulfate ions can constantly reduce under the leaching of rainwater, but because the bottom, stockyard is covered with plastic film, so at ponding zone SO 4 2-Ionic concn is relatively high.Plant when absorbing moisture, SO 4 2-Ion is also sucked in the plant materials together, if SO 4 2-Ionic concn is too high, can directly cause murder by poisoning to plant, and slight murder by poisoning can cause plant defoliation, and is heavy then can cause plant death.Because soil depletion, outside denitrogenating, the nutrient deficiencies such as phosphorus, potassium, magnesium and calcium are difficult to be recovered by natural process, perhaps need a very long time, must repair by manual type.As the matrix of plant-growth, must improve soil, this is the key of ion type rareearth ore mine tailing ecological recovery and reconstruction.
Summary of the invention
The object of the present invention is to provide a kind of in and the rare-earth tailing soil acidity, nutritious, produce and low, the effective plant recovery substrate formula of use cost.
Technical scheme of the present invention is: a kind of Revegetation substrate formula that is suitable for the ion type rareearth mine tailing, it is characterized in that, be comprised of plant-growth soil culture medium and fertilizer two portions, this plant-growth soil culture medium is comprised of clay, derosal, vegetable fibre, stablizer, an agent, organic matter, clear water and seed; This fertilizer is comprised of diammonium phosphate, Repone K, vitriolate of tartar, fused(calcium magnesium)phosphate, wilkinite, composite fertilizer and ammonium sulfate.
Each component proportion of described plant-growth soil culture medium is as follows: clay 1m 3Derosal 0.2 ~ 0.5kg; Vegetable fibre 10 ~ 13 kg; Stablizer 1.0 ~ 1.5kg; Granule agent 0.09 ~ 0.15kg; Organic 60 ~ 65kg; Clear water 0.45 ~ 0.6 m 3Seed 4.3 ~ 5.5kg;
Each component ratio of described fertilizer is: diammonium phosphate 1.3 ~ 1.5kg; Repone K 0.5 ~ 0.8kg; Vitriolate of tartar 0.3 ~ 0.5kg; Fused(calcium magnesium)phosphate 5.0 ~ 5.8kg; Wilkinite 8.3 ~ 9.1kg; Composite fertilizer 5.0 ~ 5.6kg; Ammonium sulfate 0.3 ~ 0.9kg.
In the described clay particle dia greater than the coarse sand of 0.02mm and fine content less than 50%.
The raw material of described organic matter includes but not limited to one or more in agricultural crop straw, trees brush wood, rice husk, saw powder, the industrial plant tankage; With raw material through primary election, pulverizing, compost, fermentation, drying, sieve, sterilization, measurement flow make.
The carbon-nitrogen ratio of described organic matter is controlled between 25 ~ 30:1.
Described vegetable fibre is the flocculence lignocellulose.
Described stabilizer function is: the crumb structure of the plant-growth soil culture medium that forms through this preparation method can be stablized lastingly, make substratum have good resistance of rainwater washing against ability, can form a stable thin film layer on the substratum top layer, suppress inner moisture evaporation.Simultaneously again can be when excessive rainfall, rainwater can flow away from the substratum top layer.
Described agent mainly is to make the mud compound that the granuleization reaction occurs in this preparation method, allows substratum form good crumb structure.
Described derosal plays disinfection.The present invention need use cleaning water, and the pH value of described water is 6.5 ~ 7.5, temperature between 15 ~ 25 ℃, must not use dirt, oil-containing, highly basic, strong acid, saliferous large, contain the water harmful to plant-growth such as organic impurity.
Derosal, stablizer, an agent, vegetable fibre all are this area conventional materials.
Edaphic condition for the acid soil of improveing the ion type rareearth mine tailing and nitrogen, phosphorus, potassium deficiency, build the soil matrix that is fit to plant-growth, plant growth medium prescription of the present invention needs the layering preparation, is divided into from bottom to up bottom, middle level, sealing coat and top layer.
The proportioning of the plant-growth soil culture medium of described each layer is all consistent, and its prescription is: clay: 1m 3Derosal: 0.2 ~ 0.5kg; Vegetable fibre: 10 ~ 13 kg; Stablizer: 1.0 ~ 1.5kg; Granule agent: 0.09 ~ 0.15kg; Organic: 60 ~ 65kg; Clear water: 0.45 ~ 0.6 m 3Seed: 4.3 ~ 5.5kg;
The fertilizer formula of described each layer is different, and fertilizer formula is as follows:
Bottom: directly cover on the rare-earth tailing every 1m 3The fertilizer that the plant-growth soil culture medium adds comprises: diammonium phosphate: 1.3 ~ 1.5kg; Repone K: 0.5 ~ 0.8kg; Vitriolate of tartar: 0.3 ~ 0.5kg.Wherein phosphorus and the potassium movability in soil in diammonium phosphate (N∶P ratio is about 1:4) and the Repone K is relatively strong, be placed on bottom and can infiltrate the soil layer depths, reach the purpose of long-term fertilizer, phosphorus, potassium element in the soil are provided, and diammonium phosphate meta-alkalescence, acidic substance that can neutralize ions type rare-earth mineral mine tailing can be selected powdery during use, effect can be better.
Middle level: every 1m 3The plant-growth soil culture medium adds fused(calcium magnesium)phosphate 5.0 ~ 5.8kg.Because it is acid that ion type rareearth ore mine tailing soil is, although full phosphorus, full potassium content are high, the phosphorus of this part, potassium element can not directly be absorbed by plant.This fused(calcium magnesium)phosphate is alkalescence, can provide a large amount of, and the moderate-element such as calcium, magnesium, phosphorus.Alkali wherein divides CaO can precipitate part SO 4 2-Ion, simultaneously in and the too much acidic substance of rare-earth tailing.
Sealing coat: every 1m 3The plant-growth soil culture medium adds wilkinite 8.3 ~ 9.1kg.Wilkinite has very strong water absorbability, can absorption be equivalent to the water of 8 ~ 20 times of own vols and be expanded to 30 times, in water medium, can disperse to be soliquid, and have certain viscosity, thixotropy and an oilness, have plasticity-and cohesiveness with the adulterant of silt etc., stronger cation exchange capacity (CEC) and adsorptive power are arranged.
Top layer (being Seed Layer): every 1m 3The plant-growth soil culture medium adds composite fertilizer: 5.0 ~ 5.6kg; Ammonium sulfate: 0.3 ~ 0.9kg; Seed: 4.3 ~ 5.5kg.The composite fertilizer's nitrogen phosphoris and potassium fertilizer ratio that uses is 13:10:10, and other adds the deficiency that ammonium sulfate can replenish Seedling Stage nitrogen.
A kind of method for preparing above-mentioned ion type rareearth mine tailing Revegetation matrix is characterized in that, prepares at first in accordance with the following steps described plant-growth soil culture medium:
A, proportionally clay, organic matter, vegetable fibre, stablizer, fertilizer and seed are joined in the container that fills proper amount of clear water, uniform stirring obtained the mud compound after 6 ~ 12 minutes; Each component proportion of described plant-growth soil culture medium is: clay: 1m 3Derosal: 0.2 ~ 0.5kg; Vegetable fibre: 10 ~ 13 kg; Stablizer: 1.0 ~ 1.5kg; Granule agent: 0.09 ~ 0.15kg; Organic: 60 ~ 65kg; Clear water: 0.45 ~ 0.6 m 3Seed: 4.3 ~ 5.5kg.
B, inject first proper amount of clear water (temperature is advisable at 15 ℃ ~ 30 ℃) in another container, add the granule agent of prescription quantity again, uniform stirring 10 ~ 15 minutes obtains an agent solution.
In the mud compound that C, the granule agent solution gradation adding A step that the B step is made make, fully mix, until till obviously seeing soil and moisture separating, this reaction process is the soil granular reaction.
The excessive moisture that occurs in the granuleization reaction of D, the C step of draining, the soil that obtains are described plant-growth soil culture medium.
Then each layer fertilizer according to described ratio mixes with the plant-growth soil culture medium for preparing respectively, lays from bottom to top layer layering, is the described substrate formula that is suitable for the Revegetation of ion type rareearth mine tailing.
Advantage of the present invention is: have neutralize ions type rare-earth tailing soil acidity, water conservation, fertilizer conservation, permeable, ventilative, the performance of the nutritive elements such as nitrogen, phosphorus, potassium is provided, extremely be fit to plant-growth; This plant growth culture medium can be sowed grass seeds by duster with spray seeder, has extremely strong erosion resistance, can resist stormy erosion, thoroughly prevents soil water and soil leakage.
Embodiment
The present invention will be further described below in conjunction with specific embodiment:
Embodiment 1
Place: Ganzhou City, Jiangxi Province, rare-earth tailing, gradient 1:0.6, construction in September.
Plant-growth soil culture medium proportioning is as follows:
Clay, 1m 3Derosal, 0.3kg; Vegetable fibre, 11 kg; Stablizer, 1.3kg; The granule agent, 0.11kg; Organic matter, 62kg; Clear water, 0.5 m 3
Each layer fertilizer ratio is as follows:
Every 1m 3The component that clay adds comprises:
Bottom: diammonium phosphate, 1.4kg; Repone K, 0.65kg; Vitriolate of tartar, 0.35kg;
Middle level: fused(calcium magnesium)phosphate, 5.2kg;
Sealing coat: wilkinite, 8.5kg;
Seed Layer: composite fertilizer, 5.3kg; Ammonium sulfate, 0.5kg;
Wherein, the proportioning of plant seed is as follows:
Locust tree, 438g; False indigo, 531 g; Torch tree, 363 g; Yellow wood, 438g; Stem or leaf of Shrub Lespedeza, 438g; Black chaste tree, 438g; Bermuda grass, 30 g; Rye grass, 18 g; Festuca Arundinacea, 30g; Schima superba, 282g; Paulownia elongata, 219g; Fructus Choerospondiatis, 531g; Chinese toon, 438g; Liriodendron chinense, 438g; The bark of eucommia, 375 g; Dalbergia balansae Prain, 312g.
Use this Revegetation substrate formula, the locust tree seed germination was namely arranged in the 7th day after sowing grass seeds by duster, and domatic hydro-thermal in order.Construct after 3 months, vegetation growth state is good, and is domatic multiple green, stoped soil erosion.

Claims (1)

1. a Revegetation substrate formula that is suitable for the ion type rareearth mine tailing is characterized in that its fertilizer is comprised of diammonium phosphate, Repone K, vitriolate of tartar, fused(calcium magnesium)phosphate, wilkinite, composite fertilizer and ammonium sulfate; 1m 3In the plant-growth soil culture medium, each component ratio that adds described fertilizer is: diammonium phosphate: 1.3 ~ 1.5kg; Repone K: 0.5 ~ 0.8kg; Vitriolate of tartar: 0.3 ~ 0.5kg; Fused(calcium magnesium)phosphate: 5.0 ~ 5.8kg; Wilkinite: 8.3 ~ 9.1kg; Composite fertilizer: 5.0 ~ 5.6kg; Ammonium sulfate: 0.3 ~ 0.9kg; Described Revegetation substrate formula needs the layering preparation, is divided into from bottom to up bottom, middle level, sealing coat and top layer;
The fertilizer formula of described each layer is different, and fertilizer formula is as follows:
Bottom: directly cover on the rare-earth tailing every 1m 3The plant-growth soil culture medium adds diammonium phosphate 1.3 ~ 1.5kg; Repone K 0.5 ~ 0.8kg; Vitriolate of tartar 0.3 ~ 0.5kg;
Middle level: every 1m 3The plant-growth soil culture medium adds fused(calcium magnesium)phosphate 5.0 ~ 5.8kg;
Sealing coat: every 1m 3The plant-growth soil culture medium adds wilkinite 8.3 ~ 9.1kg;
Top layer: every 1m 3The plant-growth soil culture medium adds composite fertilizer 5.0 ~ 5.6kg; Ammonium sulfate 0.3 ~ 0.9kg; Seed 4.3 ~ 5.5kg; Nitrogen phosphoris and potassium fertilizer ratio in the described composite fertilizer is 13:10:10;
Each component proportion of described plant-growth soil culture medium is as follows: clay 1m 3Derosal 0.2 ~ 0.5kg; Vegetable fibre 10 ~ 13 kg; Stablizer 1.0 ~ 1.5kg; Granule agent 0.09 ~ 0.15kg; Organic 60 ~ 65kg; Clear water 0.45 ~ 0.6 m 3Seed 4.3 ~ 5.5kg;
In the described clay particle dia greater than the coarse sand of 0.02mm and fine content less than 50%;
The raw material of described organic matter includes but not limited to one or more in agricultural crop straw, trees brush wood, rice husk, saw powder, the industrial plant tankage; With raw material through primary election, pulverizing, compost, fermentation, drying, sieve, sterilization, measurement flow make; The carbon-nitrogen ratio of described organic matter is controlled between 25 ~ 30:1;
Described vegetable fibre is the flocculence lignocellulose;
Described seed is specifically selected: locust tree, false indigo, torch tree, yellow wood, Stem or leaf of Shrub Lespedeza, black chaste tree, Bermuda grass, rye grass, Festuca Arundinacea, Schima superba, Paulownia elongata, Fructus Choerospondiatis, Chinese toon, Liriodendron chinense, the bark of eucommia and Dalbergia balansae Prain.
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Citations (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB376934A (en) * 1931-06-25 1932-07-21 Kali Forschungsanstalt Gmbh An improved process for the production of mixed fertilisers
US3950159A (en) * 1972-05-16 1976-04-13 Ici Australia Limited Products and processes
US5286272A (en) * 1992-03-20 1994-02-15 Biamonte Richard L Water soluble potassium phosphate caking inhibitor for fertilizer
CN1156712A (en) * 1996-10-15 1997-08-13 清华大学 Bio-fertilizer and its producing process
CN1292988A (en) * 2000-10-27 2001-05-02 四川省励自生态与环境工程技术有限公司 Bed for planting vegetation on rock slope to protect it
CN1403422A (en) * 2002-10-14 2003-03-19 深圳市芭田生态工程股份有限公司 Drum peletizing process of molten ammonium nitrate-urea slurry to produce granulated composite fertilizer
CN1426982A (en) * 2001-12-20 2003-07-02 丁奕翔 Special purpose bioorganic-inorganic long lasting compound (mixed) fertilizer
CN101696130A (en) * 2009-09-11 2010-04-21 湖南茂源林业有限责任公司 Dedicated compound fertilizer for hybrid liriodendrons and using method thereof
CN101743793A (en) * 2009-12-31 2010-06-23 青岛高次团粒生态技术有限公司 Plant growth soil culture medium and preparation method thereof
CN102180740A (en) * 2011-05-05 2011-09-14 安徽亚环生物科技有限公司 Polynary moisture and fertility preserving compound fertilizer and preparation method thereof
CN102241542A (en) * 2010-05-15 2011-11-16 夏道广 Water-retaining and long-acting compound fertilizer
CN102417394A (en) * 2011-12-05 2012-04-18 刘书芳 Formula of bulk blending fertilizer special for Chinese toona
CN102425176A (en) * 2011-09-01 2012-04-25 刘芳 Ecological brick for fast restoring vegetation on coal gangue dump slope and manufacture method of ecological brick

Patent Citations (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB376934A (en) * 1931-06-25 1932-07-21 Kali Forschungsanstalt Gmbh An improved process for the production of mixed fertilisers
US3950159A (en) * 1972-05-16 1976-04-13 Ici Australia Limited Products and processes
US5286272A (en) * 1992-03-20 1994-02-15 Biamonte Richard L Water soluble potassium phosphate caking inhibitor for fertilizer
CN1156712A (en) * 1996-10-15 1997-08-13 清华大学 Bio-fertilizer and its producing process
CN1292988A (en) * 2000-10-27 2001-05-02 四川省励自生态与环境工程技术有限公司 Bed for planting vegetation on rock slope to protect it
CN1426982A (en) * 2001-12-20 2003-07-02 丁奕翔 Special purpose bioorganic-inorganic long lasting compound (mixed) fertilizer
CN1403422A (en) * 2002-10-14 2003-03-19 深圳市芭田生态工程股份有限公司 Drum peletizing process of molten ammonium nitrate-urea slurry to produce granulated composite fertilizer
CN101696130A (en) * 2009-09-11 2010-04-21 湖南茂源林业有限责任公司 Dedicated compound fertilizer for hybrid liriodendrons and using method thereof
CN101743793A (en) * 2009-12-31 2010-06-23 青岛高次团粒生态技术有限公司 Plant growth soil culture medium and preparation method thereof
CN102241542A (en) * 2010-05-15 2011-11-16 夏道广 Water-retaining and long-acting compound fertilizer
CN102180740A (en) * 2011-05-05 2011-09-14 安徽亚环生物科技有限公司 Polynary moisture and fertility preserving compound fertilizer and preparation method thereof
CN102425176A (en) * 2011-09-01 2012-04-25 刘芳 Ecological brick for fast restoring vegetation on coal gangue dump slope and manufacture method of ecological brick
CN102417394A (en) * 2011-12-05 2012-04-18 刘书芳 Formula of bulk blending fertilizer special for Chinese toona

Non-Patent Citations (6)

* Cited by examiner, † Cited by third party
Title
李冰等.香根草对稀土矿废弃地土壤环境影响分析.《嘉应学院学报》.2011,第29卷(第5期),
杨时桐.水土流失区稀土矿废矿区治理新方法探讨.《亚热带水土保持》.2007,第19卷(第2期),
氮磷对刺槐生长和蛋白质组分的影响;郑辉等;《河北农业大学学报》;20060930;第29卷(第5期);第44-45页 *
水土流失区稀土矿废矿区治理新方法探讨;杨时桐;《亚热带水土保持》;20070630;第19卷(第2期);第44-46页 *
郑辉等.氮磷对刺槐生长和蛋白质组分的影响.《河北农业大学学报》.2006,第29卷(第5期),
香根草对稀土矿废弃地土壤环境影响分析;李冰等;《嘉应学院学报》;20110531;第29卷(第5期);第60-64页 *

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