CN108084864A - A kind of glass screen protection UV coating colloids - Google Patents
A kind of glass screen protection UV coating colloids Download PDFInfo
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- CN108084864A CN108084864A CN201711338817.XA CN201711338817A CN108084864A CN 108084864 A CN108084864 A CN 108084864A CN 201711338817 A CN201711338817 A CN 201711338817A CN 108084864 A CN108084864 A CN 108084864A
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- screen protection
- glass screen
- organic silicon
- coating
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/28—Nitrogen-containing compounds
- C08K2003/282—Binary compounds of nitrogen with aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
- C08K2003/382—Boron-containing compounds and nitrogen
- C08K2003/385—Binary compounds of nitrogen with boron
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/10—Transparent films; Clear coatings; Transparent materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of glass screen protection UV coating colloids, and component and quality proportioning are as follows：40 parts~50 parts of performed polymer；20 parts~30 parts of crosslinking agent；5 parts~10 parts of photoinitiator；1 part~5 parts of levelling agent；5 parts~15 parts of additive；1 part~5 parts of coolant.Preferably, the performed polymer is urethane acrylate, organic silicon acrylic ester forms, and wherein urethane acrylate, organic silicon acrylic ester mass ratio are 10：1.Preferably, the additive is one or more in carbon fiber, silica, diamond.Preferably, the coolant is graphene, aluminium nitride, boron nitride, aluminium oxide are after nanosizing crushes, by weight 1：1：1：1 mixes.The membrane body transparency that is formed after use of the present invention is high, slickness is good, and wearability is high and rapid heat dissipation, meets sci-tech product use demand.
Description
Technical field
The present invention relates to ultraviolet fixed line technical field of coatings, are specially a kind of glass screen protection UV coating colloids.
Background technology
Photocureable coating is also known as photoactive coating, is known as ultraviolet-curing paint using ultraviolet light as the paint solidification energy.It is purple
Outer light（UV）It is coating material solidified to be not required to heat, can on the inflammable ground such as paper, plastics, leather and timber rapid film-forming.It is purple
Outer photocureable coating is mainly by photosensitive resin, photosensitizer（Photoinitiator）It is formed with diluent, while adds in some additives, such as
Heat stabilizer adds in pigment and filler when preparing colored paint.Photocureable coating advantage is that hardening time is short（Part second is to rather
Clock）, solidification temperature is low, volatile matter is low, to save the energy, resource-saving, nuisanceless, efficient coating new varieties；The drawback is that from
Prevented by fundamental mode photocureable coating solidification process by oxygen, surface cure is bad.
Existing sci-tech product is largely applied in life, and one that the screen of sci-tech product is that it is more fragile
Point, just at present, the screen of glass can approximately be considered as a kind of consumptive material, abrasion and the comparable height of breakage rate, usually
All it is that pad pasting is protected to realize, however the adhesive force of pad pasting is limited, followed by influences the heat dissipation of product itself, what is more important
Pad pasting cracky is, it is necessary to frequent replacement.
The content of the invention
It is an object of the invention to provide a kind of glass screen protection UV coating colloids, to solve in above-mentioned background technology
The problem of proposition.
To achieve the above object, the present invention provides following technical solution：A kind of glass screen protection UV coating colloids,
Component and quality proportioning are as follows：
40 parts~50 parts of performed polymer；
20 parts~30 parts of crosslinking agent；
5 parts~10 parts of photoinitiator；
1 part~5 parts of levelling agent；
5 parts~15 parts of additive；
1 part~5 parts of coolant.
Preferably, the performed polymer is urethane acrylate, organic silicon acrylic ester forms, wherein polyurethane propylene
Acid esters, organic silicon acrylic ester mass ratio are 10：1.
Preferably, the levelling agent is organic silicon modified by polyether, polyester resin change properties of organic silicon, polyacrylate, acrylic acid
Alkali holds one or more in resin, dimethyl silicone polymer, polymethylphenylsiloxane, Organo-modified polysiloxanes.
Preferably, the crosslinking agent is tripropylene glycol diacrylate, trimethylolpropane trimethacrylate, Ji Wusi
Alcohol triacrylate, pentaerythritol tetraacrylate, six acrylate of pentaerythrite, hydroxy-ethyl acrylate, hydroxyethyl methacrylate
It is one or more in ethyl ester.
Preferably, the photoinitiator is 2- hydroxy-2-methyl -1- phenyl -1- propyl ketone, 2,4,6- trimethylbenzene first
It is one or more in acyl group diphenyl phosphine oxide, 1- hydroxyls-ring Ethyl-phenyl ketone, benzoin dimethylether, benzophenone.
Preferably, the additive is one or more in carbon fiber, silica, diamond.
Preferably, the coolant is graphene, aluminium nitride, boron nitride, aluminium oxide are after nanosizing crushes, by weight
Measure ratio 1：1：1：1 mixes.
Compared with prior art, the beneficial effects of the invention are as follows：
1. using urethane acrylate, organic silicon acrylic ester as performed polymer, acquisition paint solidification is rapid, and the film formed
Body transparency is high, slickness is good；
2. being with the addition of carbon fiber, silica, the material of diamond uniform wearability in coating, subtle particle increases greatly
It is big to form the wearability after membrane body, substantially increase service life；
3. being with the addition of coolant in coating, i.e. graphene, aluminium nitride, boron nitride, aluminium oxide, substantially increase after forming membrane body
Heat dissipation effect, meet sci-tech product use demand.
The membrane body transparency that is formed after use of the present invention is high, slickness is good, and wearability is high and rapid heat dissipation, meets scientific and technological production
Product use demand.
Specific embodiment
Below in conjunction in the embodiment of the present invention, the technical solution in the embodiment of the present invention is clearly and completely retouched
It states, it is clear that described embodiment is only part of the embodiment of the present invention, instead of all the embodiments.Based on the present invention
In embodiment, the every other implementation that those of ordinary skill in the art are obtained without making creative work
Example, belongs to the scope of protection of the invention.
The present invention provides a kind of glass screen protection UV coating colloids, and component and quality proportioning are as follows：
40 parts~50 parts of performed polymer；
20 parts~30 parts of crosslinking agent；
5 parts~10 parts of photoinitiator；
1 part~5 parts of levelling agent；
5 parts~15 parts of additive；
1 part~5 parts of coolant.
Preferably, the performed polymer is urethane acrylate, organic silicon acrylic ester forms, wherein polyurethane propylene
Acid esters, organic silicon acrylic ester mass ratio are 10：1.
Preferably, the levelling agent is organic silicon modified by polyether, polyester resin change properties of organic silicon, polyacrylate, acrylic acid
Alkali holds one or more in resin, dimethyl silicone polymer, polymethylphenylsiloxane, Organo-modified polysiloxanes.
Preferably, the crosslinking agent is tripropylene glycol diacrylate, trimethylolpropane trimethacrylate, Ji Wusi
Alcohol triacrylate, pentaerythritol tetraacrylate, six acrylate of pentaerythrite, hydroxy-ethyl acrylate, hydroxyethyl methacrylate
It is one or more in ethyl ester.
Preferably, the photoinitiator is 2- hydroxy-2-methyl -1- phenyl -1- propyl ketone, 2,4,6- trimethylbenzene first
It is one or more in acyl group diphenyl phosphine oxide, 1- hydroxyls-ring Ethyl-phenyl ketone, benzoin dimethylether, benzophenone.
Preferably, the additive is one or more in carbon fiber, silica, diamond.
Preferably, the coolant is graphene, aluminium nitride, boron nitride, aluminium oxide are after nanosizing crushes, by weight
Measure ratio 1：1：1：1 mixes.
Embodiment 1
43 parts of performed polymer；
27 parts of crosslinking agent；
7 parts of photoinitiator；
3 parts of levelling agent；
9 parts of additive；
2 parts of coolant.
Preferably, the performed polymer is urethane acrylate, organic silicon acrylic ester forms, wherein polyurethane propylene
Acid esters, organic silicon acrylic ester mass ratio are 10：1.
Preferably, the levelling agent is organic silicon modified by polyether, polyester resin change properties of organic silicon, polyacrylate, acrylic acid
Alkali holds one or more in resin, dimethyl silicone polymer, polymethylphenylsiloxane, Organo-modified polysiloxanes.
Preferably, the crosslinking agent is tripropylene glycol diacrylate, trimethylolpropane trimethacrylate, Ji Wusi
Alcohol triacrylate, pentaerythritol tetraacrylate, six acrylate of pentaerythrite, hydroxy-ethyl acrylate, hydroxyethyl methacrylate
It is one or more in ethyl ester.
Preferably, the photoinitiator is 2- hydroxy-2-methyl -1- phenyl -1- propyl ketone, 2,4,6- trimethylbenzene first
It is one or more in acyl group diphenyl phosphine oxide, 1- hydroxyls-ring Ethyl-phenyl ketone, benzoin dimethylether, benzophenone.
Preferably, the additive is one or more in carbon fiber, silica, diamond.
Preferably, the coolant is graphene, aluminium nitride, boron nitride, aluminium oxide are after nanosizing crushes, by weight
Measure ratio 1：1：1：1 mixes.
Embodiment 2
48 parts of performed polymer；
30 parts of crosslinking agent；
10 parts of photoinitiator；
5 parts of levelling agent；
15 parts of additive；
5 parts of coolant.
Preferably, the performed polymer is urethane acrylate, organic silicon acrylic ester forms, wherein polyurethane propylene
Acid esters, organic silicon acrylic ester mass ratio are 10：1.
Preferably, the levelling agent is organic silicon modified by polyether, polyester resin change properties of organic silicon, polyacrylate, acrylic acid
Alkali holds one or more in resin, dimethyl silicone polymer, polymethylphenylsiloxane, Organo-modified polysiloxanes.
Preferably, the crosslinking agent is tripropylene glycol diacrylate, trimethylolpropane trimethacrylate, Ji Wusi
Alcohol triacrylate, pentaerythritol tetraacrylate, six acrylate of pentaerythrite, hydroxy-ethyl acrylate, hydroxyethyl methacrylate
It is one or more in ethyl ester.
Preferably, the photoinitiator is 2- hydroxy-2-methyl -1- phenyl -1- propyl ketone, 2,4,6- trimethylbenzene first
It is one or more in acyl group diphenyl phosphine oxide, 1- hydroxyls-ring Ethyl-phenyl ketone, benzoin dimethylether, benzophenone.
Preferably, the additive is one or more in carbon fiber, silica, diamond.
Preferably, the coolant is graphene, aluminium nitride, boron nitride, aluminium oxide are after nanosizing crushes, by weight
Measure ratio 1：1：1：1 mixes.
Embodiment 3
45 parts of performed polymer；
26 parts of crosslinking agent；
5 parts of photoinitiator；
5 parts of levelling agent；
11 parts of additive；
4 parts of coolant.
Preferably, the performed polymer is urethane acrylate, organic silicon acrylic ester forms, wherein polyurethane propylene
Acid esters, organic silicon acrylic ester mass ratio are 10：1.
Preferably, the levelling agent is organic silicon modified by polyether, polyester resin change properties of organic silicon, polyacrylate, acrylic acid
Alkali holds one or more in resin, dimethyl silicone polymer, polymethylphenylsiloxane, Organo-modified polysiloxanes.
Preferably, the crosslinking agent is tripropylene glycol diacrylate, trimethylolpropane trimethacrylate, Ji Wusi
Alcohol triacrylate, pentaerythritol tetraacrylate, six acrylate of pentaerythrite, hydroxy-ethyl acrylate, hydroxyethyl methacrylate
It is one or more in ethyl ester.
Preferably, the photoinitiator is 2- hydroxy-2-methyl -1- phenyl -1- propyl ketone, 2,4,6- trimethylbenzene first
It is one or more in acyl group diphenyl phosphine oxide, 1- hydroxyls-ring Ethyl-phenyl ketone, benzoin dimethylether, benzophenone.
Preferably, the additive is one or more in carbon fiber, silica, diamond.
Preferably, the coolant is graphene, aluminium nitride, boron nitride, aluminium oxide are after nanosizing crushes, by weight
Measure ratio 1：1：1：1 mixes.
The four kinds of coating and the uv curing coating of existing market that embodiment 1,2,3 is obtained, be coated in five pieces it is identical
On iron plate, iron plate bottom all sets the identical heater of power, under 20 DEG C of interiors, heats 30s, detects iron plate upper temp；
It is simultaneously rubbed its surface to penetrating using identical sand paper, statistics is as shown in table 1 below.
Table 1
| Sample | Embodiment 1 | Embodiment 2 | Embodiment 3 | Market product |
| Temperature | 34℃ | 44℃ | 39℃ | 20℃ |
| Number | 4641 | 6894 | 7754 | 1250 |
Although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, it is possible to understand that
Can these embodiments be carried out with a variety of variations, modification without departing from the principles and spirit of the present invention, replace and become
Type, the scope of the present invention is defined by the appended.
Claims (7)
1. a kind of glass screen protection UV coating colloids, it is characterised in that：Its component and quality proportioning are as follows：
40 parts~50 parts of performed polymer；
20 parts~30 parts of crosslinking agent；
5 parts~10 parts of photoinitiator；
1 part~5 parts of levelling agent；
5 parts~15 parts of additive；
1 part~5 parts of coolant.
2. a kind of glass screen protection UV coating colloids according to claim 1, it is characterised in that：The performed polymer
It is formed for urethane acrylate, organic silicon acrylic ester, wherein urethane acrylate, organic silicon acrylic ester mass ratio are
10：1.
3. a kind of glass screen protection UV coating colloids according to claim 1, it is characterised in that：The levelling agent
Hold resin, dimethyl silicone polymer, poly- first for organic silicon modified by polyether, polyester resin change properties of organic silicon, polyacrylate, propylene soda acid
It is one or more in base phenyl siloxane, Organo-modified polysiloxanes.
4. a kind of glass screen protection UV coating colloids according to claim 1, it is characterised in that：The crosslinking agent
For tripropylene glycol diacrylate, trimethylolpropane trimethacrylate, pentaerythritol triacrylate, pentaerythrite tetrapropylene
It is one or more in acid esters, six acrylate of pentaerythrite, hydroxy-ethyl acrylate, hydroxyethyl methacrylate.
5. a kind of glass screen protection UV coating colloids according to claim 1, it is characterised in that：Described is light-initiated
Agent is 2- hydroxy-2-methyl -1- phenyl -1- propyl ketone, 2,4,6- trimethyl benzoyl diphenyl bases phosphine oxide, 1- hydroxyls-ring
It is one or more in Ethyl-phenyl ketone, benzoin dimethylether, benzophenone.
6. a kind of glass screen protection UV coating colloids according to claim 1, it is characterised in that：The additive
It is one or more for middle carbon fiber, silica, diamond.
7. a kind of glass screen protection UV coating colloids according to claim 1, it is characterised in that：The coolant
It is graphene, aluminium nitride, boron nitride, aluminium oxide after nanosizing crushes, by weight 1：1：1：1 mixes.
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| CN201711338817.XA CN108084864A (en) | 2017-12-14 | 2017-12-14 | A kind of glass screen protection UV coating colloids |
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|---|---|---|---|
| CN201711338817.XA CN108084864A (en) | 2017-12-14 | 2017-12-14 | A kind of glass screen protection UV coating colloids |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109486368A (en) * | 2018-11-28 | 2019-03-19 | 湖南阳光新材料有限公司 | A kind of super abrasive PVC pipeline interlayer coatings |
| CN109777283A (en) * | 2018-11-28 | 2019-05-21 | 湖南阳光新材料有限公司 | A kind of glass screen protective glue of ultra-violet curing |
| CN109796853A (en) * | 2018-11-28 | 2019-05-24 | 湖南阳光新材料有限公司 | A kind of ultraviolet light solidification heat conduction and heat radiation vehicle reflector coating and preparation method thereof |
| CN109810625A (en) * | 2018-11-28 | 2019-05-28 | 湖南阳光新材料有限公司 | A kind of frosting cure process ultraviolet-curing paint and preparation method thereof |
| CN110591607A (en) * | 2019-08-22 | 2019-12-20 | 昆山博益鑫成高分子材料有限公司 | UV (ultraviolet) curing pressure-sensitive adhesive and preparation method thereof |
| CN117050668A (en) * | 2023-08-16 | 2023-11-14 | 东莞中能膜业科技有限公司 | Protective film applied to new energy battery shell and preparation method thereof |
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| CN104263234A (en) * | 2014-10-27 | 2015-01-07 | 芜湖县双宝建材有限公司 | Anticorrosive ultraviolet curing coating with high hardness |
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| CN104263234A (en) * | 2014-10-27 | 2015-01-07 | 芜湖县双宝建材有限公司 | Anticorrosive ultraviolet curing coating with high hardness |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109486368A (en) * | 2018-11-28 | 2019-03-19 | 湖南阳光新材料有限公司 | A kind of super abrasive PVC pipeline interlayer coatings |
| CN109777283A (en) * | 2018-11-28 | 2019-05-21 | 湖南阳光新材料有限公司 | A kind of glass screen protective glue of ultra-violet curing |
| CN109796853A (en) * | 2018-11-28 | 2019-05-24 | 湖南阳光新材料有限公司 | A kind of ultraviolet light solidification heat conduction and heat radiation vehicle reflector coating and preparation method thereof |
| CN109810625A (en) * | 2018-11-28 | 2019-05-28 | 湖南阳光新材料有限公司 | A kind of frosting cure process ultraviolet-curing paint and preparation method thereof |
| CN110591607A (en) * | 2019-08-22 | 2019-12-20 | 昆山博益鑫成高分子材料有限公司 | UV (ultraviolet) curing pressure-sensitive adhesive and preparation method thereof |
| CN117050668A (en) * | 2023-08-16 | 2023-11-14 | 东莞中能膜业科技有限公司 | Protective film applied to new energy battery shell and preparation method thereof |
| CN117050668B (en) * | 2023-08-16 | 2024-01-30 | 东莞中能膜业科技有限公司 | Protective film applied to new energy battery shell and preparation method thereof |
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