CN106336759A - Aqueous acrylate heat-conduction coating material and preparation method thereof - Google Patents
Aqueous acrylate heat-conduction coating material and preparation method thereof Download PDFInfo
- Publication number
- CN106336759A CN106336759A CN201610719651.5A CN201610719651A CN106336759A CN 106336759 A CN106336759 A CN 106336759A CN 201610719651 A CN201610719651 A CN 201610719651A CN 106336759 A CN106336759 A CN 106336759A
- Authority
- CN
- China
- Prior art keywords
- heat
- acrylic acid
- acid esters
- water soluble
- conductive coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention provides an aqueous acrylate heat-conduction coating material, which adopts an acrylate copolymer emulsion as a base material, adopts alumina, zinc oxide, aluminum nitride, boron nitride, carbon nano-tubes, graphene and other inorganic particles having high thermal conductivity as a heat-conduction filler, and comprises water, an adhesion accelerator and other auxiliary agents. According to the present invention, the aqueous acrylate heat-conduction coating material has advantages of safety, environmental protection, good adhesion and high thermal conductivity, can be coated on the surface of electronic components, light apparatuses and other structures, further has advantages of improvement of heat dissipating efficiency, and prevention of performance reduction, instability, service life shortening and other problems caused by insufficient heat dissipating, and has the wide application prospect.
Description
Technical field
The invention belongs to coatings chemistry field, in particular it relates to a kind of water soluble acrylic acid esters heat-conductive coating and its preparation
Method.
Background technology
Electronic component operationally can produce more heat transfer, for not affecting its stability in use and life-span and accelerating to radiate,
Generally install the higher metal fin of heat conductivity additional, but, the heat emissivity coefficient of metal surface is very low, is not having convection heat transfer' heat-transfer by convection
Under conditions of, the heat of metal surface is difficult to distribute.Improve the radiation efficiency of metal surface by coating technology, be to carry
The important channel of highly metallic material heat dispersion.The today developing rapidly in electronics industry, heat-conductive coating is by extensive concern.
At present, coating market being used mostly is solvent based coating, wherein contains substantial amounts of organic solvent, is using
In journey, the volatilization of solvent not only can be to producing environment, and some harmful substances also can threaten the safety of human body simultaneously.
Therefore, it can replace solvent based coating from environmentally friendly water paint.But water paint there is also certain shortcoming, need
Improve the dispersibility of adhesive force in metal surface and filler.
A kind of therefore, it is necessary to safety and environmental protection is provided, and the preferable heat-conductive coating of adhesive force, dispersibility.
Content of the invention
For solving the above-mentioned problems in the prior art, the invention provides a kind of water soluble acrylic acid esters heat-conductive coating
And preparation method thereof.
Therefore, first purpose of the present invention is to provide a kind of water soluble acrylic acid esters heat-conductive coating.
Second object of the present invention is to provide the preparation method of described water soluble acrylic acid esters heat-conductive coating.
In order to solve above-mentioned technical problem, the technical solution used in the present invention is as follows:
A kind of water soluble acrylic acid esters heat-conductive coating, wherein, with acrylate copolymer emulsion as base material, selected from oxidation
Aluminum, zinc oxide, aluminium nitride, boron nitride, CNT, Graphene etc. have at least one in the inorganic particulate of high thermal conductivity coefficient
For heat filling, water, adhesion promoter and other auxiliary agent composition.
Preferably, the mass fraction of each component consists of: acrylate copolymer emulsion 50-100 part, heat filling 5-
60 parts, adhesion promoter 5-10 part, water 10-30 part, other auxiliary agent 0-3 parts.
Preferably, at least one in CNT, Graphene for the described heat filling.
Preferably, described aluminium oxide, zinc oxide, aluminium nitride, boron nitride can be joined using different-grain diameter, the particle of shape
Close and use, size is 50nm-20 μm, shape of particle includes spherical, spherical, lamellar, bar-shaped etc..
Preferably, described heat filling need to be modified using silane coupler from when CNT, Graphene
So as to can be uniformly dispersed in aqueous, modified CNT, the mass fraction of modified Graphene are 5-20 for pretreatment
Part.Preferably, described silane coupler is selected from kh550, kh560, kh570, kh602, a-171, described is silane coupled
The addition of agent is described CNT, the 1-5% (mass fraction) of Graphene.
Preferably, described adhesion promoter includes sulfydryl siloxanes, amino silicone, alkylsiloxane.Preferably
, described sulfydryl siloxanes is τ-mercaptopropyl trimethoxysilane, and described amino silicone is propyl epoxide
Silane, described alkylsiloxane is τ-(methacryloxy) propyl trimethoxy silicane.It is furthermore preferred that described attachment
Power accelerator is τ-mercaptopropyl trimethoxysilane.
Preferably, described water is deionized water, use as solvent.
Preferably, described other auxiliary agents be selected from firming agent, defoamer, dispersant, wetting agent, levelling agent, thickening agent,
Two or more in film former.Further, described firming agent is selected from aziridine, isocyanates etc..Described froth breaking
Agent is selected from emulsified silicone oil, dimethicone etc..Described dispersant is selected from triethyl group hexyl phosphoric acid, lauryl sulphate acid
Sodium, methyl anyl alcohol etc..Described wetting agent is selected from propylene glycol, glycerol etc..Described levelling agent is polydimethylsiloxane.Institute
The thickening agent stated is hydroxyethyl cellulose.Described film former is selected from Lauryl Alcohol ester, propylene glycol phenylate etc..
Preferably, the preparation method of the water soluble acrylic acid esters heat-conductive coating of the present invention is as follows:
1) water-and acrylate emulsion, heat filling, water mixing are added blender, control rotating speed 800-2000rpm, stir
Mix time 0.5-2h；
2) add other auxiliary agents and adhesion promoter successively in blender, control rotating speed 800-2000rpm, stirring
Time 0.5-2h, obtains final product.
Beneficial effect: the invention provides with acrylate copolymer emulsion as base material, aluminium oxide, zinc oxide, aluminium nitride,
Boron nitride, CNT, Graphene etc. have high thermal conductivity coefficient inorganic particulate be heat filling, water, adhesion promoter with
And the water soluble acrylic acid esters heat-conductive coating of other auxiliary agent composition, have the advantages that safety and environmental protection, adhesive force is good, thermal conductivity is high,
It is applied to the body structure surfaces such as electronic devices and components, light fixture, it is possible to increase radiating efficiency, prevent because of the performance fall that is insufficient and leading to that radiates
Low, unstable and the problems such as service life shortens, there is extensive prospects for commercial application.
Specific embodiment
Below in conjunction with specific embodiment, the present invention will be further described.It should be understood that following examples are merely to illustrate this
Invention is not for restriction the scope of the present invention.
In addition to especially indicating, used in following examples, raw material is all commercially available.
Used in following examples, modified CNT, the method for modifying of Graphene are this area conventional method, tool
Body is as follows:
1) weigh 1g CNT or Graphene to be placed in 200ml concentrated sulphuric acid molten with the nitration mixture of concentrated nitric acid (volume ratio is 3:1)
Aoxidize in liquid, after being heated to 60 DEG C of stirring 8-10h, decompression sucking filtration simultaneously washs to neutrality, vacuum drying oven drying for standby；
2) weigh the CNT after 1g oxidation or Graphene is placed in 200ml deionized water and adds after dispersion 30min
(silane coupler can be selected for kh550, kh560, kh570, kh602, a- to the silane coupler methanol solution of 0.033g-0.160g
171 etc., solvent is methanol, Solute mass fraction 30%), stir and be stirred at room temperature the stirring of speed 80-100r/min
24h, removes supernatant liquid after centrifugation, the black precipitate obtaining is washed with deionized 3 times, then washs 2 with absolute methanol
Secondary, and 12h is dried in 60-70 DEG C in vacuum drying oven and obtains final product.
Embodiment 1
By 60 parts of water-and acrylate emulsions, 30 parts of heat filling aluminium oxidies, after 10 parts of water mixing, add high speed dispersor
Middle stirring, wherein heat filling are that the spherical aluminium oxide that 9-11 μm of ball-aluminium oxide is 1.8-2.0 μm with particle diameter is pressed for particle diameter
Mass ratio mixes for 3:1, and control rotating speed is 1500rpm, after being sufficiently stirred for 1h, 0.05 part of defoamer emulsified silicone oil of addition, and 2.5 parts
Film former Lauryl Alcohol ester and 5 parts of adhesion promoter τ-mercaptopropyl trimethoxysilanes, control rotating speed 1500rpm, continue
Mixing time 1h, is heat-conductive coating after mix homogeneously.
Embodiment 2
Difference from Example 1 is, adhesion promoter is changed to propyl TMOS, 5 parts of addition.
Embodiment 3
Difference from Example 1 is, without adhesion promoter.
Embodiment 4
Difference from Example 1 is, heat filling aluminium oxide addition is changed to 50 parts.
Embodiment 5
Difference from Example 1 is, heat filling is changed to modified carbon nano-tube, and addition is 10 parts.
Embodiment 6
Difference from Example 1 is, heat filling is changed to modified graphene, and addition is 5 parts.
Embodiment 7-12
The heat-conductive coating of preparation in above example 1-6 is carried out adhesive force test and Determination of conductive coefficients respectively.
Adhesive force test reference gb/t 9286-1998 cross cut test method is coated in after naturally drying on aluminium sheet and is tested, attached
Put forth effort level reference gb/t 9286-1998 cross cut test method and have six ranks of 0-5, wherein 0 represents that cut edge is completely flat
Sliding, none lattice comes off, and adhesive force is optimal；1-5 adhesive force reduces successively；Wherein 0-2 preferably adhesion results.
Determination of conductive coefficients method: be applied to mould release membrance surface after the completion of heat-conductive coating configuration, take off after naturally drying
Obtain final product the heat conducting coating sample that thickness is 20-100 μm, the square being cut into 50 × 50mm is swashed with netzsch lfa 447
Its heat conductivity tested by light conductometer.
Test result is as shown in table 1.
Table 1 adhesive force and Determination of conductive coefficients result
The adhesive force test result of comparing embodiment 1-3 understands, the adhesive force on aluminium sheet after addition adhesion promoter
There is lifting by a relatively large margin, can reach no any coming off when τ-mercaptopropyl trimethoxysilane is added to 5 parts.
Comparing embodiment 1 and embodiment 2, the addition of two kinds of adhesion promoters is 5 parts, and test result shows τ-mercapto
Propyl trimethoxy silicane is more better than the effect of propyl TMOS.
Comparing embodiment 1 and embodiment 4, when the addition of heat filling aluminium oxide increases, the heat conductivity of coating also has
A certain degree of lifting, can increase or decrease the addition of filler to reach different radiatings according to the use requirement of different places
Purpose.
Comparing embodiment 1 and embodiment 5,6, when filler is changed to CNT or the Graphene of modification, even if little
Addition also can reach higher thermal conductivity it is adaptable to the higher place of cooling requirements.
Described above, can not parse is limited determines the design philosophy of the present invention.Hold identical in the technical field of the present invention
Skill can be by the technical thought of the present invention with various form improvement change, and such improvement and change are interpreted as belonging to
In protection scope of the present invention.
Claims (11)
1. a kind of water soluble acrylic acid esters heat-conductive coating is it is characterised in that with acrylate copolymer emulsion as base material, selected from oxygen
At least one in change aluminum, zinc oxide, aluminium nitride, boron nitride, CNT, Graphene is heat filling, and water, adhesive force promote
Agent and other auxiliary agent composition.
2. water soluble acrylic acid esters heat-conductive coating according to claim 1 is it is characterised in that the mass parts array of each component
Become: acrylate copolymer emulsion 50-100 part, heat filling 5-60 part, adhesion promoter 5-10 part, water 10-30 part,
Other auxiliary agent 0-3 parts.
3. water soluble acrylic acid esters heat-conductive coating according to claim 1 is it is characterised in that described aluminium oxide, oxidation
Zinc, aluminium nitride, boron nitride are used cooperatively using the particle of different-grain diameter, shape, and the size of described particle is 50nm-20 μ
M, the shape of described particle includes spherical, spherical, lamellar, bar-shaped.
4. water soluble acrylic acid esters heat-conductive coating according to claim 1 is it is characterised in that described heat filling is selected
Pretreatment need to be modified using silane coupler so as to can be uniformly dispersed in aqueous when CNT, Graphene, modified
CNT, the mass fraction of modified Graphene be 5-20 part.
5. water soluble acrylic acid esters heat-conductive coating according to claim 4 is it is characterised in that described silane coupler selects
From kh550, kh560, kh570, kh602, a-171, the addition of described silane coupler is described CNT, graphite
The 1-5% (mass fraction) of alkene.
6. water soluble acrylic acid esters heat-conductive coating according to claim 1 is it is characterised in that described adhesion promoter
Including sulfydryl siloxanes, amino silicone, alkylsiloxane.
7. water soluble acrylic acid esters heat-conductive coating according to claim 6 is it is characterised in that described sulfydryl siloxanes is
τ-mercaptopropyl trimethoxysilane, described amino silicone is propyl TMOS, described alkylsiloxane
For τ-(methacryloxy) propyl trimethoxy silicane.
8. water soluble acrylic acid esters heat-conductive coating according to claim 1 is it is characterised in that described water is deionization
Water, uses as solvent.
9. water soluble acrylic acid esters heat-conductive coating according to claim 1 is it is characterised in that described other auxiliary agents are selected from
Two or more in firming agent, defoamer, dispersant, wetting agent, levelling agent, thickening agent, film former.
10. water soluble acrylic acid esters heat-conductive coating according to claim 9 is it is characterised in that described firming agent is selected from
Aziridine, isocyanates, described defoamer is selected from emulsified silicone oil, dimethicone, and it is own that described dispersant is selected from triethyl group
Base phosphoric acid, sodium lauryl sulphate, methyl anyl alcohol, described wetting agent is selected from propylene glycol, glycerol, and described levelling agent is poly- two
Methylsiloxane, described thickening agent is hydroxyethyl cellulose, and described film former is selected from Lauryl Alcohol ester, propylene glycol phenylate.
The preparation method of the 11. water soluble acrylic acid esters heat-conductive coatings according to any one of claim 1-10, its feature
It is, comprise the following steps:
1) described water-and acrylate emulsion, described heat filling, the mixing of described water are added blender, control rotating speed 800-
2000rpm, mixing time 0.5-2h；
2) add other auxiliary agents described and described adhesion promoter in blender successively, control rotating speed 800-2000rpm,
Mixing time 0.5-2h, obtains final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610719651.5A CN106336759A (en) | 2016-08-24 | 2016-08-24 | Aqueous acrylate heat-conduction coating material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610719651.5A CN106336759A (en) | 2016-08-24 | 2016-08-24 | Aqueous acrylate heat-conduction coating material and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106336759A true CN106336759A (en) | 2017-01-18 |
Family
ID=57825286
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610719651.5A Pending CN106336759A (en) | 2016-08-24 | 2016-08-24 | Aqueous acrylate heat-conduction coating material and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106336759A (en) |
Cited By (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106928793A (en) * | 2017-05-09 | 2017-07-07 | 广东德瑞源新材料科技有限公司 | A kind of heat radiation coating and fin based on Graphene |
| CN107603432A (en) * | 2017-10-13 | 2018-01-19 | 浙江亘元涂料科技有限公司 | A kind of high heat conduction priming paint |
| CN107722828A (en) * | 2017-09-29 | 2018-02-23 | 广东冠能电力科技发展有限公司 | The special antifouling wet coating material of reactor and its manufacture method |
| CN107760128A (en) * | 2017-11-08 | 2018-03-06 | 常州烯材碳材料科技有限公司 | A kind of water paint of high heat dispersion and preparation method thereof |
| CN107903751A (en) * | 2017-11-30 | 2018-04-13 | 深圳天元羲王材料科技有限公司 | A kind of graphene heat radiation coating and preparation method thereof |
| CN108050878A (en) * | 2017-11-27 | 2018-05-18 | 浙江兴益风机电器有限公司 | It is a kind of using graphene as the composition prescription and manufacturing process of the heat exchanger chip of matrix |
| CN108084821A (en) * | 2017-12-14 | 2018-05-29 | 深圳市国创珈伟石墨烯科技有限公司 | Novel graphite alkene glass soaking coating and preparation method thereof |
| CN108084864A (en) * | 2017-12-14 | 2018-05-29 | 湖南阳光新材料有限公司 | A kind of glass screen protection UV coating colloids |
| CN108395782A (en) * | 2018-03-12 | 2018-08-14 | 合肥尚强电气科技有限公司 | Heat dissipation coating for electronic product and preparation method thereof |
| CN108641551A (en) * | 2018-05-28 | 2018-10-12 | 广东金刚玻璃科技股份有限公司 | A kind of fire resistant coating and preparation method thereof |
| CN109206961A (en) * | 2018-09-08 | 2019-01-15 | 中山励诺包装制品有限公司 | A kind of graphene conductive heat-conductive coating and preparation method thereof |
| CN109252177A (en) * | 2018-08-02 | 2019-01-22 | 无锡金科涂装有限公司 | A kind of metal surface Infiltration Technics |
| CN109401497A (en) * | 2018-10-26 | 2019-03-01 | 惠州市强茂化工科技有限公司 | Water based emulsion and preparation method thereof based on polyacrylate |
| IT201700121057A1 (en) * | 2017-10-25 | 2019-04-25 | Verniciature Bresciane S R L | PAINT FOR HIGH TEMPERATURES AND METHOD OF REALIZATION |
| CN109896752A (en) * | 2019-04-16 | 2019-06-18 | 常州亚玛顿股份有限公司 | A kind of graphene cooling coating film glass and preparation method thereof |
| CN110066138A (en) * | 2019-03-23 | 2019-07-30 | 上海雷鸟涂料有限公司 | A kind of heat-resistance type lacquer and its preparation process |
| CN110066115A (en) * | 2019-04-16 | 2019-07-30 | 常州亚玛顿股份有限公司 | A kind of color coating glass and preparation method enhancing solar photovoltaic assembly heat dissipation performance |
| CN110105869A (en) * | 2019-04-09 | 2019-08-09 | 广东墨睿科技有限公司 | A kind of modified graphene heat radiation coating and preparation method thereof |
| CN110305559A (en) * | 2019-07-10 | 2019-10-08 | 四川轻化工大学 | A kind of corrosion resistant heat-conductive coating and preparation method thereof |
| CN110467838A (en) * | 2019-08-07 | 2019-11-19 | 安庆市泽烨新材料技术推广服务有限公司 | A kind of waterborne conductive coating and preparation method thereof |
| CN110760233A (en) * | 2018-07-26 | 2020-02-07 | 深圳沃伦特科技有限公司 | Heat-conducting composite coating and heat-conducting coating prepared from same |
| CN110776797A (en) * | 2019-11-14 | 2020-02-11 | 立邦涂料（中国）有限公司 | Two-dimensional boron nitride modified emulsion paint and preparation method thereof |
| CN110845874A (en) * | 2019-11-11 | 2020-02-28 | 西南科技大学 | Preparation method of aqueous micro-nano flaky graphite material |
| WO2020073616A1 (en) * | 2018-06-05 | 2020-04-16 | 广东美的制冷设备有限公司 | Heat exchanger, air conditioner, and refrigeration device |
| CN111578355A (en) * | 2019-02-15 | 2020-08-25 | 天津市豪升新能源技术研究所 | Electric activation phase change latent heat energy-saving radiator |
| CN112552754A (en) * | 2020-12-10 | 2021-03-26 | 哈工大机器人(中山)无人装备与人工智能研究院 | Preparation method of graphene heat dissipation coating |
| CN112679652A (en) * | 2019-10-18 | 2021-04-20 | 上海飞凯光电材料股份有限公司 | Waterproof oil-stain-resistant resin, paint and preparation method |
| CN113831819A (en) * | 2021-10-08 | 2021-12-24 | 北京旭碳新材料科技有限公司 | Epoxy anticorrosive coating composition, epoxy anticorrosive coating, and preparation method and application thereof |
| CN114213882A (en) * | 2021-12-31 | 2022-03-22 | 东莞市安宿泰电子科技有限公司 | High-temperature-resistant heat-dissipation coating and preparation method thereof |
| CN114539860A (en) * | 2021-12-31 | 2022-05-27 | 苏州卓纳纳米技术有限公司 | Preparation method of ultrahigh-heat-conductivity graphene carbon nanotube composite material |
| CN114854326A (en) * | 2021-02-04 | 2022-08-05 | 德莎欧洲股份公司 | Acrylic acid adhesive tape and electronic product comprising same |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20150010759A1 (en) * | 2012-03-02 | 2015-01-08 | Arakawa Chemical Industries, Ltd. | Heat dissipating coating composition and heat dissipating coating film |
| CN104592831A (en) * | 2015-01-13 | 2015-05-06 | 苏州环明电子科技有限公司 | Heat-conducting coating and preparation method of heat-conducting film |
| CN104629603A (en) * | 2015-02-11 | 2015-05-20 | 上海理工大学 | Graphene-containing metal surface treatment agent and preparation method of anti-corrosion coating |
| CN104817930A (en) * | 2015-05-05 | 2015-08-05 | 济宁利特纳米技术有限责任公司 | Heat-conductive and anti-corrosion coating based on graphene functional material and preparation method of same |
| CN105086784A (en) * | 2015-04-29 | 2015-11-25 | 宁波职业技术学院 | Graphene modified thermal conductive coating |
| CN105419632A (en) * | 2015-12-28 | 2016-03-23 | 太仓耀华玻璃有限公司 | High light transmittance coating for LED luminescent glass and manufacturing method thereof |
| CN105505161A (en) * | 2015-09-30 | 2016-04-20 | 无锡同创石墨烯应用科技有限公司 | Graphite-modified water-based conductive coating composition and preparation method thereof |
| CN105820736A (en) * | 2016-04-30 | 2016-08-03 | 宁波墨西科技有限公司 | Graphene heat dissipation coating applied to LED lamps and preparation method of graphene heat dissipation coating |
-
2016
- 2016-08-24 CN CN201610719651.5A patent/CN106336759A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20150010759A1 (en) * | 2012-03-02 | 2015-01-08 | Arakawa Chemical Industries, Ltd. | Heat dissipating coating composition and heat dissipating coating film |
| CN104592831A (en) * | 2015-01-13 | 2015-05-06 | 苏州环明电子科技有限公司 | Heat-conducting coating and preparation method of heat-conducting film |
| CN104629603A (en) * | 2015-02-11 | 2015-05-20 | 上海理工大学 | Graphene-containing metal surface treatment agent and preparation method of anti-corrosion coating |
| CN105086784A (en) * | 2015-04-29 | 2015-11-25 | 宁波职业技术学院 | Graphene modified thermal conductive coating |
| CN104817930A (en) * | 2015-05-05 | 2015-08-05 | 济宁利特纳米技术有限责任公司 | Heat-conductive and anti-corrosion coating based on graphene functional material and preparation method of same |
| CN105505161A (en) * | 2015-09-30 | 2016-04-20 | 无锡同创石墨烯应用科技有限公司 | Graphite-modified water-based conductive coating composition and preparation method thereof |
| CN105419632A (en) * | 2015-12-28 | 2016-03-23 | 太仓耀华玻璃有限公司 | High light transmittance coating for LED luminescent glass and manufacturing method thereof |
| CN105820736A (en) * | 2016-04-30 | 2016-08-03 | 宁波墨西科技有限公司 | Graphene heat dissipation coating applied to LED lamps and preparation method of graphene heat dissipation coating |
Non-Patent Citations (1)
| Title |
|---|
| 涂料工艺编委会: "《涂料工艺》", 31 December 1997, 化学工业出版社 * |
Cited By (37)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106928793A (en) * | 2017-05-09 | 2017-07-07 | 广东德瑞源新材料科技有限公司 | A kind of heat radiation coating and fin based on Graphene |
| CN107722828A (en) * | 2017-09-29 | 2018-02-23 | 广东冠能电力科技发展有限公司 | The special antifouling wet coating material of reactor and its manufacture method |
| CN107603432A (en) * | 2017-10-13 | 2018-01-19 | 浙江亘元涂料科技有限公司 | A kind of high heat conduction priming paint |
| IT201700121057A1 (en) * | 2017-10-25 | 2019-04-25 | Verniciature Bresciane S R L | PAINT FOR HIGH TEMPERATURES AND METHOD OF REALIZATION |
| US11549023B2 (en) | 2017-10-25 | 2023-01-10 | Verniciature Bresciane S.R.L. | Paint for high temperature and method of preparing the paint |
| WO2019081995A1 (en) * | 2017-10-25 | 2019-05-02 | Verniciature Bresciane S.R.L. | Paint for high temperature and method of preparing the paint |
| CN107760128A (en) * | 2017-11-08 | 2018-03-06 | 常州烯材碳材料科技有限公司 | A kind of water paint of high heat dispersion and preparation method thereof |
| CN108050878A (en) * | 2017-11-27 | 2018-05-18 | 浙江兴益风机电器有限公司 | It is a kind of using graphene as the composition prescription and manufacturing process of the heat exchanger chip of matrix |
| CN108050878B (en) * | 2017-11-27 | 2019-10-18 | 浙江兴益风机电器有限公司 | It is a kind of using graphene as the composition prescription of the heat exchanger chip of matrix and manufacturing process |
| CN107903751A (en) * | 2017-11-30 | 2018-04-13 | 深圳天元羲王材料科技有限公司 | A kind of graphene heat radiation coating and preparation method thereof |
| CN108084864A (en) * | 2017-12-14 | 2018-05-29 | 湖南阳光新材料有限公司 | A kind of glass screen protection UV coating colloids |
| CN108084821A (en) * | 2017-12-14 | 2018-05-29 | 深圳市国创珈伟石墨烯科技有限公司 | Novel graphite alkene glass soaking coating and preparation method thereof |
| CN108395782A (en) * | 2018-03-12 | 2018-08-14 | 合肥尚强电气科技有限公司 | Heat dissipation coating for electronic product and preparation method thereof |
| CN108641551A (en) * | 2018-05-28 | 2018-10-12 | 广东金刚玻璃科技股份有限公司 | A kind of fire resistant coating and preparation method thereof |
| WO2020073616A1 (en) * | 2018-06-05 | 2020-04-16 | 广东美的制冷设备有限公司 | Heat exchanger, air conditioner, and refrigeration device |
| CN110760233A (en) * | 2018-07-26 | 2020-02-07 | 深圳沃伦特科技有限公司 | Heat-conducting composite coating and heat-conducting coating prepared from same |
| CN109252177A (en) * | 2018-08-02 | 2019-01-22 | 无锡金科涂装有限公司 | A kind of metal surface Infiltration Technics |
| CN109206961A (en) * | 2018-09-08 | 2019-01-15 | 中山励诺包装制品有限公司 | A kind of graphene conductive heat-conductive coating and preparation method thereof |
| CN109401497A (en) * | 2018-10-26 | 2019-03-01 | 惠州市强茂化工科技有限公司 | Water based emulsion and preparation method thereof based on polyacrylate |
| CN111578355A (en) * | 2019-02-15 | 2020-08-25 | 天津市豪升新能源技术研究所 | Electric activation phase change latent heat energy-saving radiator |
| CN110066138B (en) * | 2019-03-23 | 2021-07-06 | 上海雷鸟涂料有限公司 | Temperature-resistant real stone paint and preparation process thereof |
| CN110066138A (en) * | 2019-03-23 | 2019-07-30 | 上海雷鸟涂料有限公司 | A kind of heat-resistance type lacquer and its preparation process |
| CN110105869A (en) * | 2019-04-09 | 2019-08-09 | 广东墨睿科技有限公司 | A kind of modified graphene heat radiation coating and preparation method thereof |
| CN110066115A (en) * | 2019-04-16 | 2019-07-30 | 常州亚玛顿股份有限公司 | A kind of color coating glass and preparation method enhancing solar photovoltaic assembly heat dissipation performance |
| CN109896752A (en) * | 2019-04-16 | 2019-06-18 | 常州亚玛顿股份有限公司 | A kind of graphene cooling coating film glass and preparation method thereof |
| CN110305559A (en) * | 2019-07-10 | 2019-10-08 | 四川轻化工大学 | A kind of corrosion resistant heat-conductive coating and preparation method thereof |
| CN110467838A (en) * | 2019-08-07 | 2019-11-19 | 安庆市泽烨新材料技术推广服务有限公司 | A kind of waterborne conductive coating and preparation method thereof |
| CN112679652A (en) * | 2019-10-18 | 2021-04-20 | 上海飞凯光电材料股份有限公司 | Waterproof oil-stain-resistant resin, paint and preparation method |
| CN112679652B (en) * | 2019-10-18 | 2023-08-29 | 上海飞凯材料科技股份有限公司 | Waterproof and oil-dirt-proof resin, paint and preparation method thereof |
| CN110845874A (en) * | 2019-11-11 | 2020-02-28 | 西南科技大学 | Preparation method of aqueous micro-nano flaky graphite material |
| CN110776797A (en) * | 2019-11-14 | 2020-02-11 | 立邦涂料（中国）有限公司 | Two-dimensional boron nitride modified emulsion paint and preparation method thereof |
| CN112552754A (en) * | 2020-12-10 | 2021-03-26 | 哈工大机器人(中山)无人装备与人工智能研究院 | Preparation method of graphene heat dissipation coating |
| CN114854326A (en) * | 2021-02-04 | 2022-08-05 | 德莎欧洲股份公司 | Acrylic acid adhesive tape and electronic product comprising same |
| CN113831819A (en) * | 2021-10-08 | 2021-12-24 | 北京旭碳新材料科技有限公司 | Epoxy anticorrosive coating composition, epoxy anticorrosive coating, and preparation method and application thereof |
| CN114213882A (en) * | 2021-12-31 | 2022-03-22 | 东莞市安宿泰电子科技有限公司 | High-temperature-resistant heat-dissipation coating and preparation method thereof |
| CN114539860A (en) * | 2021-12-31 | 2022-05-27 | 苏州卓纳纳米技术有限公司 | Preparation method of ultrahigh-heat-conductivity graphene carbon nanotube composite material |
| CN114213882B (en) * | 2021-12-31 | 2022-07-05 | 东莞市安宿泰电子科技有限公司 | High-temperature-resistant heat-dissipation coating and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106336759A (en) | Aqueous acrylate heat-conduction coating material and preparation method thereof | |
| CN104517664B (en) | Graphene cluster based carbon system electric heating slurry as well as preparation method and application thereof | |
| CN109266187B (en) | Heat dissipation coating containing isocyanate modified graphene and preparation method thereof | |
| CN107903751B (en) | Graphene heat dissipation coating and preparation method thereof | |
| CN109988484A (en) | A kind of graphene water-based cooling coating and preparation method thereof | |
| CN107793763B (en) | High-temperature-resistant heat-conducting silicone grease and preparation method thereof | |
| CN104693968A (en) | High heat conduction and dissipation coating and preparation method thereof | |
| CN106369312A (en) | LED lamp with independent heat dissipation driver | |
| CN108485361B (en) | Graphene-containing infrared low-emissivity coating | |
| CN114015117B (en) | Heat-conducting filler and ageing-resistant organic silicon heat-conducting gel prepared from heat-conducting filler | |
| CN105441034A (en) | Rubber modified phase change heat conduction interface material and preparation method | |
| CN103087614A (en) | Insulating heat conduction high-temperature resistant electrical appliance coating and preparation method thereof | |
| CN107955519A (en) | A kind of UV radiation curing heat radiation coatings containing graphene and preparation method thereof | |
| CN108276867A (en) | A kind of graphene heat radiation coating and preparation method thereof | |
| CN107163710B (en) | A kind of graphene fluorine carbon metal paint and preparation method thereof | |
| CN110105869A (en) | A kind of modified graphene heat radiation coating and preparation method thereof | |
| CN102746769B (en) | Thermosetting heat conduction and radiation coating and preparation method thereof | |
| CN102732132A (en) | Environment-friendly insulation paint used on non-oriented electrical steel, and preparation method thereof | |
| CN108598051A (en) | A kind of graphene carbon nano pulp of high heat conduction and preparation method thereof | |
| CN105419672A (en) | Preparation method of high-heat-dissipation electric-conductive glue used for high-power LED | |
| CN106752516A (en) | A kind of heat radiation coating of electronic device and preparation method thereof | |
| CN105143370A (en) | Aqueous coating material, heat-dissipating member, metallic part, and electronic device | |
| CN109627943A (en) | A kind of multifunctional coating and its preparation method and application suitable for battery case | |
| CN106366721A (en) | Heat dissipation coating and preparation method thereof | |
| CN113480875A (en) | Aluminum oxide modified graphene, graphene heat dissipation coating and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170118 |