CN108084760A - A kind of metal furniture coating not easy to foaming to come off and preparation method thereof - Google Patents
A kind of metal furniture coating not easy to foaming to come off and preparation method thereof Download PDFInfo
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- CN108084760A CN108084760A CN201711381906.2A CN201711381906A CN108084760A CN 108084760 A CN108084760 A CN 108084760A CN 201711381906 A CN201711381906 A CN 201711381906A CN 108084760 A CN108084760 A CN 108084760A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
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- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
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Abstract
The invention discloses a kind of metal furniture coating not easy to foaming to come off, are made of the raw material below according to parts by weight:82 87 parts of lauric acid modified alkyd resin, 20 25 parts of polyvinyl alcohol, 14 18 parts of polyacrylamide, 8 12 parts of toluene di-isocyanate(TDI), 16 20 parts of maleic anhydride, 7 11 parts of polymethylphenylsiloxane, 25 parts of dimethyl silicone polymer, 36 parts of dipentene, 58 parts of castor oil, 23 parts of hydroquinone, 15 19 parts of mica powder, 12 16 parts of barium sulfate.The invention also discloses the preparation methods of the metal furniture coating not easy to foaming to come off.Metal furniture paint adhesion prepared by the present invention is strong, the phenomenon that being less prone to blistering, come off, ensure that the appearance for ringing metal furniture.
Description
Technical field
The present invention relates to coatings for furniture technical fields, are specifically a kind of metal furniture coating not easy to foaming to come off and its system
Preparation Method.
Background technology
With the development and extension of modern furniture theory, present metal furniture is with its distinctive expressive force, gradually
A popular selection in being selected as many furniture, the metal material used in metal furniture, it is easy to accomplish process automation, machine
Tool degree is high, is conducive to improve labor efficiency, and reduces product cost, this is that wooden furniture is incomparable.Used in metal furniture
Thin-wall pipes and thin plate can arbitrarily be bent or one-pass molding.The different shapings such as construction side, circle, point, flat, can be by metal material
The processing such as punching press, forging, casting, molding, the welding of material obtain the metal furniture of different modeling.Both have the function of to use, can also pass through
The colorful surface decoration effect of the processing technologys such as modeling acquisition is applied in plating, spraying;With social city, technicalization, hommization
Development, metal furniture have obtained vigorous growth, and more and more metal furnitures come into operation.
With the development of metal furniture, metal furniture coating is increasingly taken seriously.Existing metal furniture coating attachment
Power is poor, the phenomenon that being susceptible to blistering in use, come off, influences the appearance of metal furniture.
The content of the invention
It is an object of the invention to provide a kind of metal furniture coating not easy to foaming to come off and preparation method thereof, to solve
The problems mentioned above in the background art.
To achieve the above object, the present invention provides following technical solution:
A kind of metal furniture coating not easy to foaming to come off, is made of the raw material below according to parts by weight:Lauric acid is modified
82-87 parts of alkyd resin, 20-25 parts of polyvinyl alcohol, 14-18 parts of polyacrylamide, 8-12 parts of toluene di-isocyanate(TDI), maleic
16-20 parts of dicarboxylic anhydride, 7-11 parts of polymethylphenylsiloxane, 2-5 parts of dimethyl silicone polymer, 3-6 parts of dipentene, castor oil 5-
8 parts, 2-3 parts of hydroquinone, 15-19 parts of mica powder, 12-16 parts of barium sulfate.
As further embodiment of the present invention:It is made of the raw material below according to parts by weight:Lauric acid modified alkyd resin
83-86 parts, 21-24 parts of polyvinyl alcohol, 15-17 parts of polyacrylamide, 9-11 parts of toluene di-isocyanate(TDI), maleic anhydride
17-19 parts, it is 8-10 parts of polymethylphenylsiloxane, 3-4 parts of dimethyl silicone polymer, 4-5 parts of dipentene, 6-7 parts of castor oil, right
2.2-2.8 parts of benzenediol, 16-18 parts of mica powder, 13-15 parts of barium sulfate.
As further scheme of the invention:It is made of the raw material below according to parts by weight:Lauric acid acid modified alcoholic tree
84 parts of fat, 23 parts of polyvinyl alcohol, 16 parts of polyacrylamide, 10 parts of toluene di-isocyanate(TDI), 18 parts of maleic anhydride, poly- methyl
9 parts of phenyl siloxane, 3.5 parts of dimethyl silicone polymer, 5 parts of dipentene, 6 parts of castor oil, 2.5 parts of hydroquinone, mica powder 17
Part, 14 parts of barium sulfate.
The preparation method of the metal furniture coating not easy to foaming to come off, step are as follows:
1) mica powder and barium sulfate are weighed, after merging, is sent into calcining furnace, the calcination processing 50- at 520-550 DEG C
60min, discharging obtain the first mixture;
2) the first mixture is put into sand mill, adds water, then add in toluene di-isocyanate(TDI) and hydroquinone, be sanded
40-50min is handled, discharging obtains the second mixture;
3) lauric acid modified alkyd resin, polyvinyl alcohol and maleic anhydride are weighed, is put into reaction kettle, in 80-
85 DEG C, 20-30min is stirred under 300-500rpm, obtain the 3rd mixture;
4) reaction kettle in step 3) is cooled to 60-70 DEG C, takes polyacrylamide, polymethylphenylsiloxane and poly- two
Methylsiloxane is added in into the 3rd mixture, and 35-40min is stirred under 300-500rpm, obtains the 4th mixture;
5) temperature of reaction kettle in step 4) is kept, takes dipentene, castor oil and the second mixture, is added in the 4th mixing
In object, 50-60min is stirred under 700-900rpm, is discharged, obtains the 5th mixture;
6) the 5th mixture is put into sand mill, sanded treatment 1-2h, discharged, you can.
As further scheme of the invention:In step 2), the addition of the water is the first total weight of the mixture
2-3 times.
Compared with prior art, the beneficial effects of the invention are as follows:
Metal furniture paint adhesion prepared by the present invention is strong, good film-forming property, can firmly be attached to metal furniture table
Face the phenomenon that being less prone to blistering in use, come off, ensure that the appearance for ringing metal furniture, extend metal furniture
Service life, have important market value and social value.
Specific embodiment
Technical scheme is described in more detail With reference to embodiment.
Embodiment 1
A kind of metal furniture coating not easy to foaming to come off, is made of the raw material below according to parts by weight:Lauric acid is modified
82 parts of alkyd resin, 20 parts of polyvinyl alcohol, 14 parts of polyacrylamide, 8 parts of toluene di-isocyanate(TDI), 16 parts of maleic anhydride,
7 parts of polymethylphenylsiloxane, 2 parts of dimethyl silicone polymer, 3 parts of dipentene, 5 parts of castor oil, 2 parts of hydroquinone, mica powder
15 parts, 12 parts of barium sulfate.
In the present embodiment, the preparation method of the metal furniture coating not easy to foaming to come off, step is as follows:
1) mica powder and barium sulfate are weighed, after merging, is sent into calcining furnace, the calcination processing 50min at 520 DEG C, discharging,
Obtain the first mixture;
2) the first mixture is put into sand mill, adds water, then add in toluene di-isocyanate(TDI) and hydroquinone, be sanded
40min is handled, discharging obtains the second mixture, wherein, the addition of the water is 2 times of the first total weight of the mixture;
3) lauric acid modified alkyd resin, polyvinyl alcohol and maleic anhydride are weighed, is put into reaction kettle, 80
DEG C, 20min is stirred under 300rpm, obtain the 3rd mixture;
4) reaction kettle in step 3) is cooled to 60 DEG C, takes polyacrylamide, polymethylphenylsiloxane and poly- diformazan
Radical siloxane is added in into the 3rd mixture, is stirred 35min at 300 rpm, obtains the 4th mixture;
5) temperature of reaction kettle in step 4) is kept, takes dipentene, castor oil and the second mixture, is added in the 4th mixing
In object, 50min is stirred under 700rpm, is discharged, obtains the 5th mixture;
6) the 5th mixture is put into sand mill, sanded treatment 1h, discharged, you can.
Embodiment 2
A kind of metal furniture coating not easy to foaming to come off, is made of the raw material below according to parts by weight:Lauric acid is modified
83 parts of alkyd resin, 21 parts of polyvinyl alcohol, 15 parts of polyacrylamide, 11 parts of toluene di-isocyanate(TDI), 19 parts of maleic anhydride,
10 parts of polymethylphenylsiloxane, 3 parts of dimethyl silicone polymer, 4 parts of dipentene, 6 parts of castor oil, 2.8 parts of hydroquinone, mica
18 parts of powder, 15 parts of barium sulfate.
In the present embodiment, the preparation method of the metal furniture coating not easy to foaming to come off, step is as follows:
1) mica powder and barium sulfate are weighed, after merging, is sent into calcining furnace, the calcination processing 52min at 530 DEG C, discharging,
Obtain the first mixture;
2) the first mixture is put into sand mill, adds water, then add in toluene di-isocyanate(TDI) and hydroquinone, be sanded
45min is handled, discharging obtains the second mixture, wherein, the addition of the water is 2.4 times of the first total weight of the mixture;
3) lauric acid modified alkyd resin, polyvinyl alcohol and maleic anhydride are weighed, is put into reaction kettle, 80
DEG C, 23min is stirred under 350rpm, obtain the 3rd mixture;
4) reaction kettle in step 3) is cooled to 65 DEG C, takes polyacrylamide, polymethylphenylsiloxane and poly- diformazan
Radical siloxane is added in into the 3rd mixture, and 35min is stirred under 400rpm, obtains the 4th mixture;
5) temperature of reaction kettle in step 4) is kept, takes dipentene, castor oil and the second mixture, is added in the 4th mixing
In object, 52min is stirred under 700rpm, is discharged, obtains the 5th mixture;
6) the 5th mixture is put into sand mill, sanded treatment 1.5h, discharged, you can.
Embodiment 3
A kind of metal furniture coating not easy to foaming to come off, is made of the raw material below according to parts by weight:Lauric acid is modified
84 parts of alkyd resin, 23 parts of polyvinyl alcohol, 16 parts of polyacrylamide, 10 parts of toluene di-isocyanate(TDI), 18 parts of maleic anhydride,
9 parts of polymethylphenylsiloxane, 3.5 parts of dimethyl silicone polymer, 5 parts of dipentene, 6 parts of castor oil, 2.5 parts of hydroquinone, cloud
17 parts of female powder, 14 parts of barium sulfate.
In the present embodiment, the preparation method of the metal furniture coating not easy to foaming to come off, step is as follows:
1) mica powder and barium sulfate are weighed, after merging, is sent into calcining furnace, the calcination processing 55min at 540 DEG C, discharging,
Obtain the first mixture;
2) the first mixture is put into sand mill, adds water, then add in toluene di-isocyanate(TDI) and hydroquinone, be sanded
45min is handled, discharging obtains the second mixture, wherein, the addition of the water is 2.5 times of the first total weight of the mixture;
3) lauric acid modified alkyd resin, polyvinyl alcohol and maleic anhydride are weighed, is put into reaction kettle, 82
DEG C, 25min is stirred under 400rpm, obtain the 3rd mixture;
4) reaction kettle in step 3) is cooled to 65 DEG C, takes polyacrylamide, polymethylphenylsiloxane and poly- diformazan
Radical siloxane is added in into the 3rd mixture, and 38min is stirred under 400rpm, obtains the 4th mixture;
5) temperature of reaction kettle in step 4) is kept, takes dipentene, castor oil and the second mixture, is added in the 4th mixing
In object, 55min is stirred at 800 rpm, is discharged, and obtains the 5th mixture;
6) the 5th mixture is put into sand mill, sanded treatment 1.5h, discharged, you can.
Embodiment 4
A kind of metal furniture coating not easy to foaming to come off, is made of the raw material below according to parts by weight:Lauric acid is modified
86 parts of alkyd resin, 24 parts of polyvinyl alcohol, 17 parts of polyacrylamide, 9 parts of toluene di-isocyanate(TDI), 17 parts of maleic anhydride,
8 parts of polymethylphenylsiloxane, 4 parts of dimethyl silicone polymer, 5 parts of dipentene, 7 parts of castor oil, 2.2 parts of hydroquinone, mica
16 parts of powder, 13 parts of barium sulfate.
In the present embodiment, the preparation method of the metal furniture coating not easy to foaming to come off, step is as follows:
1) mica powder and barium sulfate are weighed, after merging, is sent into calcining furnace, the calcination processing 57min at 540 DEG C, discharging,
Obtain the first mixture;
2) the first mixture is put into sand mill, adds water, then add in toluene di-isocyanate(TDI) and hydroquinone, be sanded
48min is handled, discharging obtains the second mixture, wherein, the addition of the water is 3 times of the first total weight of the mixture;
3) lauric acid modified alkyd resin, polyvinyl alcohol and maleic anhydride are weighed, is put into reaction kettle, 85
DEG C, 25min is stirred under 400rpm, obtain the 3rd mixture;
4) reaction kettle in step 3) is cooled to 70 DEG C, takes polyacrylamide, polymethylphenylsiloxane and poly- diformazan
Radical siloxane is added in into the 3rd mixture, and 40min is stirred under 400rpm, obtains the 4th mixture;
5) temperature of reaction kettle in step 4) is kept, takes dipentene, castor oil and the second mixture, is added in the 4th mixing
In object, 55min is stirred at 800 rpm, is discharged, and obtains the 5th mixture;
6) the 5th mixture is put into sand mill, sanded treatment 2h, discharged, you can.
Embodiment 5
A kind of metal furniture coating not easy to foaming to come off, is made of the raw material below according to parts by weight:Lauric acid is modified
87 parts of alkyd resin, 25 parts of polyvinyl alcohol, 18 parts of polyacrylamide, 12 parts of toluene di-isocyanate(TDI), 20 parts of maleic anhydride,
11 parts of polymethylphenylsiloxane, 5 parts of dimethyl silicone polymer, 6 parts of dipentene, 8 parts of castor oil, 3 parts of hydroquinone, mica powder
19 parts, 16 parts of barium sulfate.
In the present embodiment, the preparation method of the metal furniture coating not easy to foaming to come off, step is as follows:
1) mica powder and barium sulfate are weighed, after merging, is sent into calcining furnace, the calcination processing 60min at 550 DEG C, discharging,
Obtain the first mixture;
2) the first mixture is put into sand mill, adds water, then add in toluene di-isocyanate(TDI) and hydroquinone, be sanded
50min is handled, discharging obtains the second mixture, wherein, the addition of the water is 3 times of the first total weight of the mixture;
3) lauric acid modified alkyd resin, polyvinyl alcohol and maleic anhydride are weighed, is put into reaction kettle, 85
DEG C, 30min is stirred under 500rpm, obtain the 3rd mixture;
4) reaction kettle in step 3) is cooled to 70 DEG C, takes polyacrylamide, polymethylphenylsiloxane and poly- diformazan
Radical siloxane is added in into the 3rd mixture, is stirred 40min at 500 rpm, obtains the 4th mixture;
5) temperature of reaction kettle in step 4) is kept, takes dipentene, castor oil and the second mixture, is added in the 4th mixing
In object, 60min is stirred under 900rpm, is discharged, obtains the 5th mixture;
6) the 5th mixture is put into sand mill, sanded treatment 2h, discharged, you can.
Metal furniture paint adhesion prepared by the present invention is strong, good film-forming property, can firmly be attached to metal furniture table
Face the phenomenon that being less prone to blistering in use, come off, ensure that the appearance for ringing metal furniture, extend metal furniture
Service life, have important market value and social value.
The better embodiment of the present invention is explained in detail above, but the present invention is not limited to above-mentioned embodiment party
Formula, can also be on the premise of present inventive concept not be departed from the knowledge that one skilled in the relevant art possesses
Various changes can be made.
Claims (5)
1. a kind of metal furniture coating not easy to foaming to come off, which is characterized in that be made of the raw material below according to parts by weight:Month
82-87 parts of cinnamic acid modified alkyd resin, 20-25 parts of polyvinyl alcohol, 14-18 parts of polyacrylamide, toluene di-isocyanate(TDI) 8-12
Part, 16-20 parts of maleic anhydride, 7-11 parts of polymethylphenylsiloxane, 2-5 parts of dimethyl silicone polymer, dipentene 3-6
Part, 5-8 parts of castor oil, 2-3 parts of hydroquinone, 15-19 parts of mica powder, 12-16 parts of barium sulfate.
2. the metal furniture coating not easy to foaming to come off according to claim 1, which is characterized in that by below according to weight
The raw material composition of part:83-86 parts of lauric acid modified alkyd resin, 21-24 parts of polyvinyl alcohol, 15-17 parts of polyacrylamide, toluene
9-11 parts of diisocyanate, 17-19 parts of maleic anhydride, 8-10 parts of polymethylphenylsiloxane, dimethyl silicone polymer 3-4
Part, 4-5 parts of dipentene, 6-7 parts of castor oil, 2.2-2.8 parts of hydroquinone, 16-18 parts of mica powder, 13-15 parts of barium sulfate.
3. the metal furniture coating not easy to foaming to come off according to claim 2, which is characterized in that by below according to weight
The raw material composition of part:84 parts of lauric acid modified alkyd resin, 23 parts of polyvinyl alcohol, 16 parts of polyacrylamide, toluene diisocynate
10 parts of ester, 18 parts of maleic anhydride, 9 parts of polymethylphenylsiloxane, 3.5 parts of dimethyl silicone polymer, 5 parts of dipentene, castor
6 parts of sesame oil, 2.5 parts of hydroquinone, 17 parts of mica powder, 14 parts of barium sulfate.
4. a kind of preparation method of metal furniture coating not easy to foaming to come off as described in claim 1-3 is any, feature
It is, step is as follows:
1) mica powder and barium sulfate are weighed, after merging, is sent into calcining furnace, calcination processing 50-60min, goes out at 520-550 DEG C
Material obtains the first mixture;
2) the first mixture is put into sand mill, adds water, then add in toluene di-isocyanate(TDI) and hydroquinone, sanded treatment
40-50min, discharging obtain the second mixture;
3) lauric acid modified alkyd resin, polyvinyl alcohol and maleic anhydride are weighed, is put into reaction kettle, 80-85 DEG C,
20-30min is stirred under 300-500rpm, obtains the 3rd mixture;
4) reaction kettle in step 3) is cooled to 60-70 DEG C, takes polyacrylamide, polymethylphenylsiloxane and poly dimethyl
Siloxanes is added in into the 3rd mixture, and 35-40min is stirred under 300-500rpm, obtains the 4th mixture;
5) temperature of reaction kettle in step 4) is kept, dipentene, castor oil and the second mixture is taken, adds in the 4th mixture
In, 50-60min is stirred under 700-900rpm, is discharged, obtains the 5th mixture;
6) the 5th mixture is put into sand mill, sanded treatment 1-2h, discharged, you can.
5. the preparation method of the metal furniture coating not easy to foaming to come off according to claim 4, which is characterized in that step
2) in, the addition of the water is 2-3 times of the first total weight of the mixture.
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