CN108084367A - A kind of antibiotic property acrylic resin - Google Patents
A kind of antibiotic property acrylic resin Download PDFInfo
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- CN108084367A CN108084367A CN201711478310.4A CN201711478310A CN108084367A CN 108084367 A CN108084367 A CN 108084367A CN 201711478310 A CN201711478310 A CN 201711478310A CN 108084367 A CN108084367 A CN 108084367A
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- antibiotic property
- acrylic resin
- property acrylic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/12—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polysiloxanes
- C08F283/124—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polysiloxanes on to polysiloxanes having carbon-to-carbon double bonds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
- C09D151/08—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Plant Pathology (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
The invention discloses a kind of antibiotic property acrylic resins, are prepared by the raw material of following mass fraction：16 25 parts of silester, 35 42 parts of vinyltriethoxysilane, 26 parts of acetic acid, 60 70 parts of acrylics monomer, 24 parts of initiator, 36 parts of n-butanol, 10 50 parts of acryloxyethyldimethyl ethyl phosphonium bromide ammonium.The antibiotic property acrylic resin antibacterial effect of the present invention is more notable, and health environment-friendly, performance reaches conventional criteria, and synthetic method is simple, easy to operate, at low cost to be suitable for promoting.
Description
Technical field
The present invention relates to technical field of aqueous paint, and in particular to a kind of antibiotic property acrylic resin.
Background technology
There is higher hardness, excellent gloss and chemical-resistant after acrylic coating film forming, and cost is relatively low, extensively
It is applied to automobile, building and furniture industry generally.Traditional solvent-type acrylic coating can discharge largely in film forming procedure
Volatile organic compounds pollutes the environment.But there are still many deficiencies, such as hardness of film for water-borne acrylic coatings
Relatively low, wearability is not fine, and anti-microbial property is not good enough, hinders its development.
The content of the invention
The technical problems to be solved by the invention are to provide a kind of antibiotic property acrylic resin, be carried for water paint industry
Coating industry is used for for a kind of excellent acrylic resin of anti-microbial property.
To achieve the above object, the present invention is achieved by the following technical solutions：
A kind of antibiotic property acrylic resin, is prepared by the raw material of following mass fraction：
16-25 parts of silester, 35-42 parts of vinyltriethoxysilane, 2-6 parts of acetic acid, acrylics monomer 60-
70 parts, 2-4 parts of initiator, 3-6 parts of n-butanol, 10-50 parts of acryloxyethyldimethyl ethyl phosphonium bromide ammonium.
As a preferred embodiment, the acrylic ester monomer is selected from butyl acrylate, hydroxypropyl acrylate, acrylic acid hydroxyl
One kind or several in ethyl ester, acrylic acid, methyl methacrylate, hydroxy propyl methacrylate and isobornyl methacrylate
Kind.
As a preferred embodiment, the initiator is selected from azodiisobutyronitrile, di-tert-butyl peroxide and peroxidating two
One or more of isopropylbenzene.
As a preferred embodiment, the antibiotic property acrylic resin is prepared by the raw material of following mass fraction：Silicic acid second
20 parts of ester, 42 parts of vinyltriethoxysilane, 2 parts of acetic acid, 60 parts of acrylics monomer, 2 parts of initiator, 3 parts of n-butanol,
10 parts of acryloxyethyldimethyl ethyl phosphonium bromide ammonium.
As a preferred embodiment, the antibiotic property acrylic resin is prepared by the raw material of following mass fraction：Silicic acid second
16 parts of ester, 30 parts of vinyltriethoxysilane, 5 parts of acetic acid, 70 parts of acrylics monomer, 3 parts of initiator, 4 parts of n-butanol,
30 parts of acryloxyethyldimethyl ethyl phosphonium bromide ammonium.
As a preferred embodiment, the antibiotic property acrylic resin is prepared by the raw material of following mass fraction：Silicic acid second
25 parts of ester, 35 parts of vinyltriethoxysilane, 6 parts of acetic acid, 65 parts of acrylics monomer, 4 parts of initiator, 6 parts of n-butanol,
50 parts of acryloxyethyldimethyl ethyl phosphonium bromide ammonium.
As a preferred embodiment, the preparation method of the antibiotic property acrylic resin is as follows：
(1) acryloxyethyldimethyl ethyl phosphonium bromide ammonium is dissolved by heating in n-butanol；
(2) it is uniformly mixed with the silester of the component and vinyltriethoxysilane, is warming up to 70-90 DEG C afterwards
And catalyst is slowly added under the temperature conditionss and carries out reaction 3-4h, then it is evaporated under reduced pressure obtained polysiloxane prepolymers；
(3) nitrogen is passed through, polysiloxane prepolymers obtained are warming up to 110-120 DEG C, are added under the temperature conditionss
The acrylic ester monomer and initiator of the component, carry out copolyreaction, and reaction terminates to can be prepared by antibiotic property acrylic acid tree
Fat.
As a preferred embodiment, the preparation method of the antibiotic property acrylic resin is as follows：
(1) acryloxyethyldimethyl ethyl phosphonium bromide ammonium is dissolved by heating in n-butanol；
(2) it is uniformly mixed with the silester of the component and vinyltriethoxysilane, is warming up to 80 DEG C afterwards simultaneously
Catalyst is slowly added under the temperature conditionss and carries out reaction 3h, then is evaporated under reduced pressure obtained polysiloxane prepolymers；
(3) nitrogen is passed through, polysiloxane prepolymers obtained are warming up to 115 DEG C, under the temperature conditionss described in addition
The acrylic ester monomer and initiator of component, carry out copolyreaction, and reaction terminates to can be prepared by antibiotic property acrylic resin.
As a preferred embodiment, the preparation method of the antibiotic property acrylic resin is as follows：
(1) acryloxyethyldimethyl ethyl phosphonium bromide ammonium is dissolved by heating in n-butanol；
(2) it is uniformly mixed with the silester of the component and vinyltriethoxysilane, is warming up to 90 DEG C afterwards simultaneously
Catalyst is slowly added under the temperature conditionss and carries out reaction 3.5h, then is evaporated under reduced pressure obtained polysiloxane prepolymers；
(3) nitrogen is passed through, polysiloxane prepolymers obtained are warming up to 120 DEG C, under the temperature conditionss described in addition
The acrylic ester monomer and initiator of component, carry out copolyreaction, and reaction terminates to can be prepared by antibiotic property acrylic resin.
As a preferred embodiment, the preparation method leads to the range of viscosities for measuring antibiotic property acrylic resin under the conditions of 30 DEG C
For 70-100 seconds.
Beneficial effects of the present invention：
1st, antibiotic property acrylic resin antibacterial effect of the present invention is more notable, health environment-friendly.
2nd, antibiotic property acrylic resin of the present invention paint adhesion, hardness, be hit after extent of the destruction, resistance to acid and alkali
Reach conventional criteria.
3rd, preparation method of the invention is simple, easy to operate, at low cost, economic and environment-friendly, suitable for the application of every profession and trade, purposes
Scope is wide.
Specific embodiment
Embodiment 1：
Antibiotic property acrylic resin is prepared by the raw material of following mass fraction：20 parts of silester, three second of vinyl
42 parts of oxysilane, 2 parts of acetic acid, 60 parts of acrylics monomer, 2 parts of initiator, 3 parts of n-butanol, acrylyl oxy-ethyl diformazan
10 parts of base ethyl phosphonium bromide ammonium.
The preparation method of the antibiotic property acrylic resin：
(1) acryloxyethyldimethyl ethyl phosphonium bromide ammonium is dissolved by heating in n-butanol；
(2) it is uniformly mixed with the silester of the component and vinyltriethoxysilane, is warming up to 80 DEG C afterwards simultaneously
Catalyst is slowly added under the temperature conditionss and carries out reaction 3h, then is evaporated under reduced pressure obtained polysiloxane prepolymers；
(3) nitrogen is passed through, polysiloxane prepolymers obtained are warming up to 115 DEG C, under the temperature conditionss described in addition
The acrylic ester monomer and initiator of component, carry out copolyreaction, and reaction terminates to can be prepared by antibiotic property acrylic resin.
Wherein, the preparation method is led under the conditions of 30 DEG C measured the range of viscosities of antibiotic property acrylic resin as 70 seconds.
Embodiment 2：
Antibiotic property acrylic resin is prepared by the raw material of following mass fraction：The antibiotic property acrylic resin by
The raw material of following mass fraction is prepared：16 parts of silester, 30 parts of vinyltriethoxysilane, 5 parts of acetic acid, acrylic acid
70 parts of lipid monomer, 3 parts of initiator, 4 parts of n-butanol, 30 parts of acryloxyethyldimethyl ethyl phosphonium bromide ammonium.
The preparation method of the antibiotic property acrylic resin：
(1) acryloxyethyldimethyl ethyl phosphonium bromide ammonium is dissolved by heating in n-butanol；
(2) it is uniformly mixed with the silester of the component and vinyltriethoxysilane, is warming up to 90 DEG C afterwards simultaneously
Catalyst is slowly added under the temperature conditionss and carries out reaction 3.5h, then is evaporated under reduced pressure obtained polysiloxane prepolymers；
(3) nitrogen is passed through, polysiloxane prepolymers obtained are warming up to 120 DEG C, under the temperature conditionss described in addition
The acrylic ester monomer and initiator of component, carry out copolyreaction, and reaction terminates to can be prepared by antibiotic property acrylic resin.
Wherein, the preparation method is led under the conditions of 30 DEG C measured the range of viscosities of antibiotic property acrylic resin as 90 seconds.
Embodiment 3：
Antibiotic property acrylic resin is prepared by the raw material of following mass fraction：25 parts of silester, three second of vinyl
35 parts of oxysilane, 6 parts of acetic acid, 65 parts of acrylics monomer, 4 parts of initiator, 6 parts of n-butanol, acrylyl oxy-ethyl diformazan
50 parts of base ethyl phosphonium bromide ammonium.
The preparation method of the antibiotic property acrylic resin：
(1) acryloxyethyldimethyl ethyl phosphonium bromide ammonium is dissolved by heating in n-butanol；
(2) it is uniformly mixed with the silester of the component and vinyltriethoxysilane, is warming up to 85 DEG C afterwards simultaneously
Catalyst is slowly added under the temperature conditionss and carries out reaction 4h, then is evaporated under reduced pressure obtained polysiloxane prepolymers；
(3) nitrogen is passed through, polysiloxane prepolymers obtained are warming up to 110 DEG C, under the temperature conditionss described in addition
The acrylic ester monomer and initiator of component, carry out copolyreaction, and reaction terminates to can be prepared by antibiotic property acrylic resin.
Wherein, the preparation method is led under the conditions of 30 DEG C measured the range of viscosities of antibiotic property acrylic resin as 100 seconds.
Coating antibiosis performance detection：Weigh a certain amount of embodiment 1-3 antibiotic properties acrylic resin, titanium dioxide, quartz sand
And silicon powder, uniform grinding is thoroughly mixed, adds in solvent butyl acetate, is thoroughly mixed uniformly, by GB/T
Method as defined in 4789.2-2008 measures viable count, third antibiotic property acrylic resin of the invention to Escherichia coli, Pseudomonas aeruginosa and
The antibacterial effect of aspergillus niger is more notable, and paint adhesion, hardness, be hit after extent of the destruction, resistance to acid and alkali reaches
Conventional criteria.Film produced by the present invention has preferable antibiotic property and traditional performance.
Coating prepared by the present invention has the antibiotic property of long-acting stabilization, and its preparation method is simple, easy to operate, at low cost,
Economic and environment-friendly, suitable for the application of every profession and trade, purposes scope is wide.
Basic principle of the invention and main feature and advantages of the present invention has been shown and described above.The skill of the industry
Art personnel it should be appreciated that the present invention is not limited to the above embodiments, the above embodiments and description only describe
The principle of the present invention, without departing from the spirit and scope of the present invention, various changes and modifications of the present invention are possible, these
Changes and improvements all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and
Its equivalent thereof.
Claims (10)
1. a kind of antibiotic property acrylic resin, which is characterized in that be prepared by the raw material of following mass fraction：Silester
16-25 parts, 35-42 parts of vinyltriethoxysilane, 2-6 parts of acetic acid, 60-70 parts of acrylics monomer, initiator 2-4
Part, 3-6 parts of n-butanol, 10-50 parts of acryloxyethyldimethyl ethyl phosphonium bromide ammonium.
2. antibiotic property acrylic resin according to claim 1, characteristic are：The acrylic ester monomer is selected from
Butyl acrylate, hydroxypropyl acrylate, hydroxy-ethyl acrylate, acrylic acid, methyl methacrylate, hydroxy propyl methacrylate and
One or more of isobornyl methacrylate.
3. antibiotic property acrylic resin according to claim 1, characteristic are：It is different that the initiator is selected from azo two
One or more of butyronitrile, di-tert-butyl peroxide and cumyl peroxide.
4. antibiotic property acrylic resin according to claim 1, which is characterized in that prepared by the raw material of following mass fraction
It forms：20 parts of silester, 42 parts of vinyltriethoxysilane, 2 parts of acetic acid, 60 parts of acrylics monomer, initiator 2
Part, 3 parts of n-butanol, 10 parts of acryloxyethyldimethyl ethyl phosphonium bromide ammonium.
5. antibiotic property acrylic resin according to claim 1, which is characterized in that prepared by the raw material of following mass fraction
It forms：16 parts of silester, 30 parts of vinyltriethoxysilane, 5 parts of acetic acid, 70 parts of acrylics monomer, initiator 3
Part, 4 parts of n-butanol, 30 parts of acryloxyethyldimethyl ethyl phosphonium bromide ammonium.
6. antibiotic property acrylic resin according to claim 1, which is characterized in that prepared by the raw material of following mass fraction
It forms：25 parts of silester, 35 parts of vinyltriethoxysilane, 6 parts of acetic acid, 65 parts of acrylics monomer, initiator 4
Part, 6 parts of n-butanol, 50 parts of acryloxyethyldimethyl ethyl phosphonium bromide ammonium.
7. according to claim 1-6 any one of them antibiotic property acrylic resins, which is characterized in that preparation method is as follows：
(1) acryloxyethyldimethyl ethyl phosphonium bromide ammonium is dissolved by heating in n-butanol；
(2) be uniformly mixed with the silester of the component and vinyltriethoxysilane, be warming up to afterwards 70-90 DEG C and
Catalyst is slowly added under the temperature conditionss and carries out reaction 3-4h, then is evaporated under reduced pressure obtained polysiloxane prepolymers；
(3) nitrogen is passed through, polysiloxane prepolymers obtained are warming up to 110-120 DEG C, under the temperature conditionss described in addition
The acrylic ester monomer and initiator of component, carry out copolyreaction, and reaction terminates to can be prepared by antibiotic property acrylic resin.
8. antibiotic property acrylic resin according to claim 7, which is characterized in that preparation method is as follows：
(1) acryloxyethyldimethyl ethyl phosphonium bromide ammonium is dissolved by heating in n-butanol；
(2) it is uniformly mixed with the silester of the component and vinyltriethoxysilane, is warming up to 80 DEG C afterwards and at this
Catalyst is slowly added under temperature conditionss and carries out reaction 3h, then is evaporated under reduced pressure obtained polysiloxane prepolymers；
(3) nitrogen is passed through, polysiloxane prepolymers obtained are warming up to 115 DEG C, the component is added under the temperature conditionss
Acrylic ester monomer and initiator, carry out copolyreaction, reaction terminates that antibiotic property acrylic resin is made.
9. antibiotic property acrylic resin according to claim 7, which is characterized in that preparation method is as follows：
(1) acryloxyethyldimethyl ethyl phosphonium bromide ammonium is dissolved by heating in n-butanol；
(2) it is uniformly mixed with the silester of the component and vinyltriethoxysilane, is warming up to 90 DEG C afterwards and at this
Catalyst is slowly added under temperature conditionss and carries out reaction 3.5h, then is evaporated under reduced pressure obtained polysiloxane prepolymers；
(3) nitrogen is passed through, polysiloxane prepolymers obtained are warming up to 120 DEG C, the component is added under the temperature conditionss
Acrylic ester monomer and initiator, carry out copolyreaction, reaction terminates that antibiotic property acrylic resin is made.
10. antibiotic property acrylic resin preparation method according to claim 7, it is characterised in that：The preparation method exists
Lead under the conditions of 30 DEG C and measure the range of viscosities of antibiotic property acrylic resin as 70-100 seconds.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711478310.4A CN108084367A (en) | 2017-12-29 | 2017-12-29 | A kind of antibiotic property acrylic resin |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711478310.4A CN108084367A (en) | 2017-12-29 | 2017-12-29 | A kind of antibiotic property acrylic resin |
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| Publication Number | Publication Date |
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| CN108084367A true CN108084367A (en) | 2018-05-29 |
Family
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711478310.4A Withdrawn CN108084367A (en) | 2017-12-29 | 2017-12-29 | A kind of antibiotic property acrylic resin |
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| Country | Link |
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| CN (1) | CN108084367A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108948254A (en) * | 2018-07-06 | 2018-12-07 | 莱阳红安化工有限公司 | A kind of feature of environmental protection acrylic resin and preparation method thereof |
| CN111234134A (en) * | 2020-02-28 | 2020-06-05 | 南京长江涂料有限公司 | High-performance glycidyl versatate modified polysiloxane resin and preparation method thereof |
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| CN101812278A (en) * | 2010-05-20 | 2010-08-25 | 上海西怡新材料科技有限公司 | Ultraviolet curable organic silicon-acrylic resin electronic adhesive and application thereof |
| CN102391529A (en) * | 2011-07-14 | 2012-03-28 | 杭州师范大学 | Preparation method of silicone resin type organic/inorganic hybrid material for packaging |
| CN103555251A (en) * | 2013-10-18 | 2014-02-05 | 中山职业技术学院 | High-heat-conductivity high-reliability ultraviolet-curing LED (light-emitting diode) electrically-conductive silver adhesive and preparation method thereof |
| CN103923267A (en) * | 2014-04-14 | 2014-07-16 | 英德市雅家涂料有限公司 | Polyester-modified acrylic resin with antibacterial function and preparation method thereof |
| CN107033296A (en) * | 2017-05-08 | 2017-08-11 | 南京长江涂料有限公司 | Extra-weather-proof polysiloxane-modified acrylic resin and finish paint preparation method |
-
2017
- 2017-12-29 CN CN201711478310.4A patent/CN108084367A/en not_active Withdrawn
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101812278A (en) * | 2010-05-20 | 2010-08-25 | 上海西怡新材料科技有限公司 | Ultraviolet curable organic silicon-acrylic resin electronic adhesive and application thereof |
| CN102391529A (en) * | 2011-07-14 | 2012-03-28 | 杭州师范大学 | Preparation method of silicone resin type organic/inorganic hybrid material for packaging |
| CN103555251A (en) * | 2013-10-18 | 2014-02-05 | 中山职业技术学院 | High-heat-conductivity high-reliability ultraviolet-curing LED (light-emitting diode) electrically-conductive silver adhesive and preparation method thereof |
| CN103923267A (en) * | 2014-04-14 | 2014-07-16 | 英德市雅家涂料有限公司 | Polyester-modified acrylic resin with antibacterial function and preparation method thereof |
| CN107033296A (en) * | 2017-05-08 | 2017-08-11 | 南京长江涂料有限公司 | Extra-weather-proof polysiloxane-modified acrylic resin and finish paint preparation method |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108948254A (en) * | 2018-07-06 | 2018-12-07 | 莱阳红安化工有限公司 | A kind of feature of environmental protection acrylic resin and preparation method thereof |
| CN108948254B (en) * | 2018-07-06 | 2019-06-04 | 莱阳红安化工有限公司 | A kind of feature of environmental protection acrylic resin and preparation method thereof |
| CN111234134A (en) * | 2020-02-28 | 2020-06-05 | 南京长江涂料有限公司 | High-performance glycidyl versatate modified polysiloxane resin and preparation method thereof |
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Application publication date: 20180529 |
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