CN107651879B - Cement whiskering inhibitor - Google Patents
Cement whiskering inhibitor Download PDFInfo
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- CN107651879B CN107651879B CN201711033854.XA CN201711033854A CN107651879B CN 107651879 B CN107651879 B CN 107651879B CN 201711033854 A CN201711033854 A CN 201711033854A CN 107651879 B CN107651879 B CN 107651879B
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- cement
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- whiskering
- cellulose
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B40/00—Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
- C04B40/0028—Aspects relating to the mixing step of the mortar preparation
- C04B40/0039—Premixtures of ingredients
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
The invention discloses a cement whiskering inhibitor, which at least comprises: boric acid, activated carbon powder, tributyl phosphate, silicon micropowder, ferrous sulfate and kaolin. The cement efflorescence inhibitor can obviously improve the efflorescence resistance and durability of cement base materials under the condition of ensuring that the performance of cement mortar and concrete cement base materials is not reduced or is improved. Therefore, the quality, the aesthetic feeling and the durability of the appearance of the building are greatly improved, and the maintenance cost of the building is reduced.
Description
Technical Field
The invention relates to the field of building materials, in particular to a cement whiskering inhibitor.
Background
Ordinary concrete is silicate, silicate ions are subjected to hydrolysis reaction when meeting air or water vapor in a wall body, generated hydroxide is combined with metal ions to form hydroxide with low solubility (the chemical property is alkaline), the hydroxide is separated out from the wall body when the temperature rises, the hydroxide is separated out on the surface of concrete cement along with gradual evaporation of water, and the hydroxide accumulates over the month, so that the original decorative coating or paint and the like are jacked up and do not adhere to the wall surface any more, and whitening, peeling and falling occur, and the process is called as 'saltpetering'. The blank room can be directly separated out, the decorated blank room can be swelled, skinned and fallen off by coating, paint and the like. Does not fade for years and seriously affects the appearance.
The information disclosed in this background section is only for enhancement of understanding of the general background of the invention and should not be taken as an acknowledgement or any form of suggestion that this information forms the prior art already known to a person skilled in the art.
Disclosure of Invention
The invention aims to provide a cement whiskering inhibitor, so as to overcome the defect that whiskering affects the appearance of cement products.
To achieve the above object, the present invention provides a cement whiskering inhibitor comprising at least: boric acid, activated carbon powder, tributyl phosphate, silicon micropowder, ferrous sulfate and kaolin.
Preferably, in the above technical scheme, the cement whiskering inhibitor at least comprises, in parts by weight: 3-9 parts of boric acid, 10-15 parts of activated carbon powder, 1-4 parts of tributyl phosphate, 8-16 parts of silica micropowder, 3-9 parts of ferrous sulfate and 7-14 parts of kaolin.
Preferably, in the above technical solution, the cement whiskering inhibitor further includes: acetone, cellulose ether, nonylphenol polyoxyethylene ether, bauxite powder, zeolite powder, benzoic acid, modified tapioca starch, calcium formate and triisopropanolamine.
Preferably, in the above technical scheme, the cement whiskering inhibitor further includes, in parts by weight: 5-11 parts of acetone, 2-6 parts of cellulose ether, 1-3 parts of nonylphenol polyoxyethylene ether, 6-14 parts of bauxite powder, 5-11 parts of zeolite powder, 2-5 parts of benzoic acid, 7-14 parts of modified tapioca starch, 1-3 parts of calcium formate and 2-7 parts of triisopropanolamine.
Preferably, in the above technical solution, the cellulose ether is one or more of hydroxyethyl methyl cellulose, carboxymethyl cellulose, ethyl cellulose, benzyl cellulose, hydroxyethyl cellulose, and hydroxypropyl methyl cellulose.
Preferably, in the above technical solution, when the cement whiskering inhibitor is used, the mass ratio of the cement whiskering inhibitor to the cement is 0.1-0.5: 100.
Compared with the prior art, the invention has the following beneficial effects: the cement efflorescence inhibitor can obviously improve the efflorescence resistance and durability of cement base materials under the condition of ensuring that the performance of cement mortar and concrete cement base materials is not reduced or is improved. Therefore, the quality, the aesthetic feeling and the durability of the appearance of the building are greatly improved, and the maintenance cost of the building is reduced.
Detailed Description
The following detailed description of the present invention will be given with reference to specific examples, but it should be understood that the scope of the present invention is not limited to the specific embodiments.
Example 1
The cement whiskering inhibitor at least comprises the following components in parts by weight: 5 parts of boric acid, 13 parts of activated carbon powder, 3 parts of tributyl phosphate, 12 parts of silicon micropowder, 6 parts of ferrous sulfate, 9 parts of kaolin, 8 parts of acetone, 4 parts of cellulose ether, 2 parts of nonylphenol polyoxyethylene ether, 11 parts of bauxite powder, 7 parts of zeolite powder, 3 parts of benzoic acid, 11 parts of modified tapioca starch, 2 parts of calcium formate and 4 parts of triisopropanolamine.
The cellulose ether is hydroxyethyl methyl cellulose and carboxymethyl cellulose, and the mixing mass ratio is 1: 1.
When the cement whiskering inhibitor is used, the mass ratio of the cement whiskering inhibitor to cement is 0.3: 100.
Example 2
The cement whiskering inhibitor at least comprises the following components in parts by weight: 3 parts of boric acid, 15 parts of activated carbon powder, 4 parts of tributyl phosphate, 8 parts of silicon micropowder, 3 parts of ferrous sulfate, 14 parts of kaolin, 5 parts of acetone, 2 parts of cellulose ether, 3 parts of nonylphenol polyoxyethylene ether, 6 parts of bauxite powder, 11 parts of zeolite powder, 2 parts of benzoic acid, 14 parts of modified tapioca starch, 1 part of calcium formate and 7 parts of triisopropanolamine.
The cellulose ether is ethyl cellulose.
When the cement whiskering inhibitor is used, the mass ratio of the cement whiskering inhibitor to cement is 0.1: 100.
Example 3
The cement whiskering inhibitor at least comprises the following components in parts by weight: 9 parts of boric acid, 10 parts of activated carbon powder, 1 part of tributyl phosphate, 16 parts of silicon micropowder, 9 parts of ferrous sulfate, 7 parts of kaolin, 11 parts of acetone, 6 parts of cellulose ether, 1 part of nonylphenol polyoxyethylene ether, 14 parts of bauxite powder, 5 parts of zeolite powder, 5 parts of benzoic acid, 7 parts of modified tapioca starch, 3 parts of calcium formate and 2 parts of triisopropanolamine.
The cellulose ether is benzyl cellulose.
When the cement whiskering inhibitor is used, the mass ratio of the cement whiskering inhibitor to cement is 0.5: 100.
Comparative example 1
The cement whiskering inhibitor at least comprises the following components in parts by weight: 8 parts of acetone, 4 parts of cellulose ether, 2 parts of nonylphenol polyoxyethylene ether, 11 parts of bauxite powder, 7 parts of zeolite powder, 3 parts of benzoic acid, 11 parts of modified tapioca starch, 2 parts of calcium formate and 4 parts of triisopropanolamine.
The cellulose ether is hydroxyethyl methyl cellulose and carboxymethyl cellulose, and the mixing mass ratio is 1: 1.
When the cement whiskering inhibitor is used, the mass ratio of the cement whiskering inhibitor to cement is 0.3: 100.
Comparative example 2
This comparative example is a blank test, i.e. cement, without the addition of a cement saltpetering inhibitor.
The performance test method of the wall flooding resistant mortar of the examples and the comparative examples refers to JC/T1024-2007 standard of wall facing mortar, and the performance test is shown in Table 1.
Table 1: mortar Performance testing
The foregoing descriptions of specific exemplary embodiments of the present invention have been presented for purposes of illustration and description. It is not intended to limit the invention to the precise form disclosed, and obviously many modifications and variations are possible in light of the above teaching. The exemplary embodiments were chosen and described in order to explain certain principles of the invention and its practical application to enable one skilled in the art to make and use various exemplary embodiments of the invention and various alternatives and modifications as are suited to the particular use contemplated. It is intended that the scope of the invention be defined by the claims and their equivalents.
Claims (3)
1. The cement whiskering inhibitor is characterized by being prepared from the following raw materials in parts by weight: 3-9 parts of boric acid, 10-15 parts of activated carbon powder, 1-4 parts of tributyl phosphate, 8-16 parts of silica micropowder, 3-9 parts of ferrous sulfate and 7-14 parts of kaolin; 5-11 parts of acetone, 2-6 parts of cellulose ether, 1-3 parts of nonylphenol polyoxyethylene ether, 6-14 parts of bauxite powder, 5-11 parts of zeolite powder, 2-5 parts of benzoic acid, 7-14 parts of modified tapioca starch, 1-3 parts of calcium formate and 2-7 parts of triisopropanolamine.
2. The inhibitor for cement whiskering according to claim 1, wherein the cellulose ether is one or more selected from the group consisting of hydroxyethyl methyl cellulose, carboxymethyl cellulose, ethyl cellulose, benzyl cellulose, hydroxyethyl cellulose, and hydroxypropyl methyl cellulose.
3. The inhibitor for cement whiskering according to claim 1, wherein a mass ratio of the inhibitor for cement whiskering to cement when the inhibitor for cement whiskering is used is 0.1 to 0.5: 100.
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CN201711033854.XA CN107651879B (en) | 2017-10-30 | 2017-10-30 | Cement whiskering inhibitor |
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CN201711033854.XA CN107651879B (en) | 2017-10-30 | 2017-10-30 | Cement whiskering inhibitor |
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CN107651879A CN107651879A (en) | 2018-02-02 |
CN107651879B true CN107651879B (en) | 2020-12-15 |
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Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN112897926A (en) * | 2021-02-23 | 2021-06-04 | 佳木斯市松江水泥有限公司 | Saltpetering inhibitor for portland cement |
CN114835431A (en) * | 2022-05-26 | 2022-08-02 | 四川能投建工集团有限公司 | Saltpetering inhibitor suitable for 3D printing of cement-based material and use method thereof |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2001096257A2 (en) * | 2000-06-13 | 2001-12-20 | Mineral Resource Technologies, Llc | Masonry cement composition and method of making |
CN101913794A (en) * | 2010-08-13 | 2010-12-15 | 江苏尼高科技有限公司 | Cement mortar saltpetering inhibition additive |
CN102173730A (en) * | 2011-01-21 | 2011-09-07 | 煤炭科学研究总院 | High-moisture filling material and preparation method thereof |
CN102234190A (en) * | 2010-04-29 | 2011-11-09 | 北京仁创科技集团有限公司 | Mixture for water-permeable preform and water-permeable preform and manufacturing method |
CN104761287A (en) * | 2015-04-24 | 2015-07-08 | 深圳市科玺化工有限公司 | Cement floor crystallization hardener and preparation method thereof |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN105503031B (en) * | 2015-12-30 | 2018-01-30 | 卓达新材料科技集团威海股份有限公司 | A kind of suppression alkaline agent for Portland cement |
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Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2001096257A2 (en) * | 2000-06-13 | 2001-12-20 | Mineral Resource Technologies, Llc | Masonry cement composition and method of making |
CN102234190A (en) * | 2010-04-29 | 2011-11-09 | 北京仁创科技集团有限公司 | Mixture for water-permeable preform and water-permeable preform and manufacturing method |
CN101913794A (en) * | 2010-08-13 | 2010-12-15 | 江苏尼高科技有限公司 | Cement mortar saltpetering inhibition additive |
CN102173730A (en) * | 2011-01-21 | 2011-09-07 | 煤炭科学研究总院 | High-moisture filling material and preparation method thereof |
CN104761287A (en) * | 2015-04-24 | 2015-07-08 | 深圳市科玺化工有限公司 | Cement floor crystallization hardener and preparation method thereof |
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Effective date of registration: 20201125 Address after: No.88, block 8, Dongsheng Road, Shuangliu Park, Chengdu Jiaolong industrial port, Chengdu, Sichuan 610020 Applicant after: SICHUAN YUTONG BUILDING MATERIAL Co.,Ltd. Address before: 532699 Department of science and technology 312, Pingxiang municipal administrative center, Chongzuo, the Guangxi Zhuang Autonomous Region Applicant before: Li Jianlian |
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