CN108049169B - Antistatic polyester fabric - Google Patents

Antistatic polyester fabric Download PDF

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Publication number
CN108049169B
CN108049169B CN201810029814.6A CN201810029814A CN108049169B CN 108049169 B CN108049169 B CN 108049169B CN 201810029814 A CN201810029814 A CN 201810029814A CN 108049169 B CN108049169 B CN 108049169B
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solvent
polyester fabric
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modified
modified polyester
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CN108049169A (en
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孙跃
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Zhangjiagang jinbode Textile Co., Ltd
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Zhangjiagang Jinbode Textile Co Ltd
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/83—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
    • A—HUMAN NECESSITIES
    • A41—WEARING APPAREL
    • A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D19/00—Gloves
    • A41D19/015—Protective gloves
    • A—HUMAN NECESSITIES
    • A41—WEARING APPAREL
    • A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D31/00—Materials specially adapted for outerwear
    • A41D31/04—Materials specially adapted for outerwear characterised by special function or use
    • A—HUMAN NECESSITIES
    • A41—WEARING APPAREL
    • A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D31/00—Materials specially adapted for outerwear
    • A41D31/04—Materials specially adapted for outerwear characterised by special function or use
    • A41D31/26—Electrically protective, e.g. preventing static electricity or electric shock
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/45—Oxides or hydroxides of elements of Groups 3 or 13 of the Periodic Table; Aluminates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
    • D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03—Polysaccharides or derivatives thereof
    • A—HUMAN NECESSITIES
    • A41—WEARING APPAREL
    • A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D2400/00—Functions or special features of garments
    • A41D2400/10—Heat retention or warming
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/32—Polyesters

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Abstract

The application discloses an antistatic polyester fabric, a polyester fabric is dipped in a nano-silver composite solvent for 30min, the polyester fabric is washed by a large amount of distilled water and then dried at 40 ℃ to obtain a modified polyester fabric A, (2) the modified polyester fabric A is dipped in a nano-silica modified solvent for 20min, the modified polyester fabric A is washed by a large amount of distilled water and then dried at 35 ℃ to obtain a modified polyester fabric B, (3) the modified polyester fabric B is added into an indium tin oxide nanocrystalline composite solution for 1h, the modified polyester fabric A is washed by a large amount of distilled water and then dried at 40 ℃ to obtain a modified polyester fabric C, the modified polyester fabric C is dipped in a magnetic-nano-silver composite modified solvent for 30min, the modified polyester fabric C is washed by a large amount of distilled water and then dried at 40 ℃ to obtain the final antistatic modified polyester fabric.

Description

Antistatic polyester fabric
The invention relates to a warm-keeping antistatic glove, which has the original application number of 201610936529.3 and the application date of 2016, 11 and 01.
Technical Field
The invention relates to a polyester fabric, in particular to an antistatic polyester fabric.
Background
Gloves are important protection tools in daily life and industrial production, traditional glove knitting or polyester gloves do not have antistatic performance, can not eliminate static on operational environment and the operating personnel, are suitable for in the middle of dustless environment, and need an antistatic polyester fabric.
Disclosure of Invention
Aiming at the problems in the prior art, the invention provides the antistatic polyester fabric which is good in antistatic effect.
In order to achieve the purpose, the invention adopts the technical scheme that: an antistatic polyester fabric, the treatment process of the antistatic polyester fabric comprises the following steps:
1. soaking the polyester fabric in the nano-silver composite solvent for 30min, washing with a large amount of distilled water, drying at 40 ℃ to obtain a modified polyester fabric A,
the preparation method of the nano-silver composite solvent comprises the following steps: mixing 0.1-10% of alkylated cyclodextrin aqueous solution and 0.01-1.0 mol/L of silver ammonia solution in a volume ratio of 1: 100-1: 10, and stirring at 10-100 ℃ for 1-120 min to obtain nano silver composite solution with the average particle size of 1-100 nm)
2. The modified polyester fabric A is soaked in a nano-silica modified solvent for 20min, washed by a large amount of distilled water and dried at 35 ℃ to obtain a modified polyester fabric B, wherein the preparation method of the nano-silica modified solvent comprises the following steps: firstly dispersing nano-silica particles in a solvent, then adding lactic acid, and carrying out dehydration polycondensation reaction to obtain silica nano-particles with lactic acid oligomers grafted on the surfaces; (2) dispersing the modified silicon dioxide particles in a solvent, and adding high molecular weight polylactic acid; the weight ratio of the nano silicon dioxide to the polylactic acid is 1: 20.
3. Adding the modified polyester fabric B into the indium tin oxide nanocrystalline composite solution for 1h, washing by a large amount of distilled water, drying at 40 ℃ to obtain a modified polyester fabric C,
the preparation method of the indium tin oxide nanocrystalline composite solution comprises the following steps: directly dispersing ITO (indium tin oxide) nanocrystals in a polar organic solvent to form an ITO nanocrystal dispersion liquid; providing an ITO precursor fluid comprising: mixing the precursor liquid of In and the precursor liquid of Sn, and fully stirring at room temperature to form ITO precursor liquid; and uniformly mixing the ITO nanocrystalline dispersion liquid and the ITO precursor liquid, and shearing and dispersing to form the indium tin oxide nanocrystalline composite solution.
And (3) soaking the modified polyester fabric C in the magnetic-nano silver composite modified solvent for 30min, washing by using a large amount of distilled water, and drying at 40 ℃ to obtain the final antistatic modified polyester fabric.
The preparation method of the magnetic-nano silver composite modified solvent comprises the following steps: firstly dispersing nano-silica particles in a solvent, then adding lactic acid, and carrying out dehydration polycondensation reaction to obtain silica nano-particles with lactic acid oligomers grafted on the surfaces; (2) dispersing the modified silicon dioxide particles in a solvent, and adding high molecular weight polylactic acid; the weight ratio of the nano silicon dioxide to the polylactic acid is 1: 15; stirring to obtain the solvent A.
According to the total iron concentration of 0.15mol/L, the molar ratio of ferrous ions to hydroxide ions is Fe2 +: OH ═ 1: 5, respectively weighing ferrous sulfate and sodium hydroxide, then adding sodium hydroxide and fully stirring to obtain a ferrous sulfate and sodium hydroxide mixed solution; adding 8g of hexadecyl trimethyl ammonium bromide and 8g of chitosan into each liter of the mixed solution of ferrous sulfate and sodium hydroxide, and stirring to form a solvent B, wherein the ratio of the solvent A to the solvent B is 6: 1.
The antistatic polyester fabric is an antistatic polyester fabric, and the antistatic polyester fabric has a good antistatic effect after being subjected to multiple modification treatments.
Detailed Description
Example 1
The treatment process of the antistatic polyester fabric comprises the following steps:
1. soaking the polyester fabric in the nano-silver composite solvent for 30min, washing with a large amount of distilled water, drying at 40 ℃ to obtain a modified polyester fabric A,
the preparation method of the nano-silver composite solvent comprises the following steps: mixing 0.1-10% of alkylated cyclodextrin aqueous solution and 0.01-1.0 mol/L of silver ammonia solution in a volume ratio of 1: 100-1: 10, and stirring at 10-100 ℃ for 1-120 min to obtain nano silver composite solution with the average particle size of 1-100 nm)
2. The modified polyester fabric A is soaked in a nano-silica modified solvent for 20min, washed by a large amount of distilled water and dried at 35 ℃ to obtain a modified polyester fabric B, wherein the preparation method of the nano-silica modified solvent comprises the following steps: firstly dispersing nano-silica particles in a solvent, then adding lactic acid, and carrying out dehydration polycondensation reaction to obtain silica nano-particles with lactic acid oligomers grafted on the surfaces; (2) dispersing the modified silicon dioxide particles in a solvent, and adding high molecular weight polylactic acid; the weight ratio of the nano silicon dioxide to the polylactic acid is 1: 20.
3. Adding the modified polyester fabric B into the indium tin oxide nanocrystalline composite solution for 1h, washing by a large amount of distilled water, drying at 40 ℃ to obtain a modified polyester fabric C,
the preparation method of the indium tin oxide nanocrystalline composite solution comprises the following steps: directly dispersing ITO (indium tin oxide) nanocrystals in a polar organic solvent to form an ITO nanocrystal dispersion liquid; providing an ITO precursor fluid comprising: mixing the precursor liquid of In and the precursor liquid of Sn, and fully stirring at room temperature to form ITO precursor liquid; and uniformly mixing the ITO nanocrystalline dispersion liquid and the ITO precursor liquid, and shearing and dispersing to form the indium tin oxide nanocrystalline composite solution.
And (3) soaking the modified polyester fabric C in the magnetic-nano silver composite modified solvent for 30min, washing by using a large amount of distilled water, and drying at 40 ℃ to obtain the final antistatic modified polyester fabric.
The preparation method of the magnetic-nano silver composite modified solvent comprises the following steps: firstly dispersing nano-silica particles in a solvent, then adding lactic acid, and carrying out dehydration polycondensation reaction to obtain silica nano-particles with lactic acid oligomers grafted on the surfaces; (2) dispersing the modified silicon dioxide particles in a solvent, and adding high molecular weight polylactic acid; the weight ratio of the nano silicon dioxide to the polylactic acid is 1: 15; stirring to obtain the solvent A.
According to the total iron concentration of 0.15mol/L, the molar ratio of ferrous ions to hydroxide ions is Fe2 +: OH ═ 1: 5, respectively weighing ferrous sulfate and sodium hydroxide, then adding sodium hydroxide and fully stirring to obtain a ferrous sulfate and sodium hydroxide mixed solution; adding 8g of hexadecyl trimethyl ammonium bromide and 8g of chitosan into each liter of the mixed solution of ferrous sulfate and sodium hydroxide, and stirring to form a solvent B, wherein the ratio of the solvent A to the solvent B is 6: 1.
Example 2
The preparation process is the same as that of example 1, except that in the preparation process of the magnetic-nano silver composite modified solvent, the ratio of the solvent A to the solvent B is 7: 1.
Example 3
The preparation process is the same as that of example 1, except that in the preparation process of the magnetic-nano silver composite modified solvent, the ratio of the solvent A to the solvent B is 10: 1.
Example 4
The preparation process is the same as that of example 1, except that in the preparation process of the magnetic-nano silver composite modified solvent, the ratio of the solvent A to the solvent B is 3: 1.
Example 5
The preparation process is the same as that of example 1, except that in the preparation process of the magnetic-nano silver composite modified solvent, the ratio of the solvent A to the solvent B is 2: 1.
Example 6
The preparation process is the same as that of example 1, except that in the preparation process of the magnetic-nano silver composite modified solvent, the ratio of the solvent A to the solvent B is 1: 1.
Example 7
The preparation process is the same as that of example 1, except that in the preparation process of the magnetic-nano silver composite modified solvent, the ratio of the solvent A to the solvent B is 1: 2.
Example 8
The preparation process is the same as that of example 1, except that in the preparation process of the magnetic-nano silver composite modified solvent, the ratio of the solvent A to the solvent B is 1: 6.
Comparative example 1
The modified polyester fabric C prepared in example 1.
Comparative example 2
The treatment process of the antistatic polyester fabric comprises the following steps:
1. soaking the polyester fabric in the nano-silver composite solvent for 30min, washing with a large amount of distilled water, drying at 40 ℃ to obtain a modified polyester fabric A,
the preparation method of the nano-silver composite solvent comprises the following steps: mixing 0.1-10% of alkylated cyclodextrin aqueous solution and 0.01-1.0 mol/L of silver ammonia solution in a volume ratio of 1: 100-1: 10, and stirring at 10-100 ℃ for 1-120 min to obtain nano silver composite solution with the average particle size of 1-100 nm)
2. The modified polyester fabric A is soaked in a nano-silica modified solvent for 20min, washed by a large amount of distilled water and dried at 35 ℃ to obtain a modified polyester fabric B, wherein the preparation method of the nano-silica modified solvent comprises the following steps: firstly dispersing nano-silica particles in a solvent, then adding lactic acid, and carrying out dehydration polycondensation reaction to obtain silica nano-particles with lactic acid oligomers grafted on the surfaces; (2) dispersing the modified silicon dioxide particles in a solvent, and adding high molecular weight polylactic acid; the weight ratio of the nano silicon dioxide to the polylactic acid is 1: 20.
3. And (3) soaking the modified polyester fabric B in the magnetic-nano silver composite modified solvent for 30min, washing by using a large amount of distilled water, and drying at 40 ℃ to obtain the final antistatic modified polyester fabric.
The preparation method of the magnetic-nano silver composite modified solvent comprises the following steps: firstly dispersing nano-silica particles in a solvent, then adding lactic acid, and carrying out dehydration polycondensation reaction to obtain silica nano-particles with lactic acid oligomers grafted on the surfaces; (2) dispersing the modified silicon dioxide particles in a solvent, and adding high molecular weight polylactic acid; the weight ratio of the nano silicon dioxide to the polylactic acid is 1: 15; stirring to obtain the solvent A.
According to the total iron concentration of 0.15mol/L, the molar ratio of ferrous ions to hydroxide ions is Fe2 +: OH ═ 1: 5, respectively weighing ferrous sulfate and sodium hydroxide, then adding sodium hydroxide and fully stirring to obtain a ferrous sulfate and sodium hydroxide mixed solution; adding 8g of hexadecyl trimethyl ammonium bromide and 8g of chitosan into each liter of the mixed solution of ferrous sulfate and sodium hydroxide, and stirring to form a solvent B. The solvent A and the solvent B are mixed according to the proportion of 6:1 to prepare the magnetic-nano silver composite modified solvent.
Comparative example 3
The treatment process of the antistatic polyester fabric comprises the following steps:
1. soaking the polyester fabric in the nano-silver composite solvent for 30min, washing with a large amount of distilled water, drying at 40 ℃ to obtain a modified polyester fabric A,
the preparation method of the nano-silver composite solvent comprises the following steps: mixing 0.1-10% of alkylated cyclodextrin aqueous solution and 0.01-1.0 mol/L of silver ammonia solution in a volume ratio of 1: 100-1: 10, and stirring at 10-100 ℃ for 1-120 min to obtain nano silver composite solution with the average particle size of 1-100 nm)
2. The modified polyester fabric A is prepared by the following steps of,
3. adding the modified polyester fabric A into the indium tin oxide nanocrystalline composite solution for 1h, washing by a large amount of distilled water, drying at 40 ℃ to obtain a modified polyester fabric B,
the preparation method of the indium tin oxide nanocrystalline composite solution comprises the following steps: directly dispersing ITO (indium tin oxide) nanocrystals in a polar organic solvent to form an ITO nanocrystal dispersion liquid; providing an ITO precursor fluid comprising: mixing the precursor liquid of In and the precursor liquid of Sn, and fully stirring at room temperature to form ITO precursor liquid; and uniformly mixing the ITO nanocrystalline dispersion liquid and the ITO precursor liquid, and shearing and dispersing to form the indium tin oxide nanocrystalline composite solution.
And (3) soaking the modified polyester fabric B in the magnetic-nano silver composite modified solvent for 30min, washing by using a large amount of distilled water, and drying at 40 ℃ to obtain the final antistatic modified polyester fabric.
The preparation method of the magnetic-nano silver composite modified solvent comprises the following steps: firstly dispersing nano-silica particles in a solvent, then adding lactic acid, and carrying out dehydration polycondensation reaction to obtain silica nano-particles with lactic acid oligomers grafted on the surfaces; (2) dispersing the modified silicon dioxide particles in a solvent, and adding high molecular weight polylactic acid; the weight ratio of the nano silicon dioxide to the polylactic acid is 1: 15; stirring to obtain the solvent A.
According to the total iron concentration of 0.15mol/L, the molar ratio of ferrous ions to hydroxide ions is Fe2 +: OH ═ 1: 5, respectively weighing ferrous sulfate and sodium hydroxide, then adding sodium hydroxide and fully stirring to obtain a ferrous sulfate and sodium hydroxide mixed solution; adding 8g of hexadecyl trimethyl ammonium bromide and 8g of chitosan into each liter of the mixed solution of ferrous sulfate and sodium hydroxide, and stirring to form a solvent B.
The solvent A and the solvent B are mixed according to the proportion of 6:1 to prepare the magnetic-nano silver composite modified solvent.
Antistatic performance test:
the surface specific resistance is that the finished polyester fabric is cut into a plurality of samples with the width of 1cm, the samples are balanced for more than 12 hours under the environment of constant temperature and humidity (20 ℃ and the humidity is 70%), an insulation resistance tester is used for testing the resistance value, the average value of 20 times of values is taken, and the surface specific resistance value of the finished polyester fabric is obtained.
Figure 557042DEST_PATH_IMAGE001
After the terylene is modified for many times, the terylene is finally soaked in the magnetic-nano silver composite modified solvent, particularly when the solvent A and the solvent B are in a ratio of 6:1 to 7:1, the prepared modified terylene has the best antistatic effect, and other proportions have no obvious antistatic effect.

Claims (1)

1. The antistatic polyester fabric is characterized in that the preparation method comprises the following steps:
(1) soaking the polyester fabric in the nano-silver composite solvent for 30min, washing with a large amount of distilled water, drying at 40 ℃ to obtain a modified polyester fabric A,
the preparation method of the nano-silver composite solvent comprises the following steps: mixing 0.1-10% of alkylated cyclodextrin aqueous solution and 0.01-1.0 mol/L of silver ammonia solution in a volume ratio of 1: 100-1: 10, stirring for 1-120 min at the temperature of 10-100 ℃ to obtain the nano silver composite solvent with the average particle size of 1-100 nm,
(2) the modified polyester fabric A is soaked in a nano-silica modified solvent for 20min, washed by a large amount of distilled water and dried at 35 ℃ to obtain a modified polyester fabric B, wherein the preparation method of the nano-silica modified solvent comprises the following steps: firstly dispersing nano-silica particles in a solvent, then adding lactic acid, and carrying out dehydration polycondensation reaction to obtain silica nano-particles with lactic acid oligomers grafted on the surfaces; dispersing the modified silicon dioxide particles in a solvent, and adding high molecular weight polylactic acid; the weight ratio of the nano silicon dioxide to the polylactic acid is 1: 20;
(3) adding the modified polyester fabric B into the indium tin oxide nanocrystalline composite solution for 1h, washing by a large amount of distilled water, drying at 40 ℃ to obtain a modified polyester fabric C,
the preparation method of the indium tin oxide nanocrystalline composite solution comprises the following steps: directly dispersing ITO (indium tin oxide) nanocrystals in a polar organic solvent to form an ITO nanocrystal dispersion liquid; providing an ITO precursor fluid comprising: mixing the precursor liquid of In and the precursor liquid of Sn, and fully stirring at room temperature to form ITO precursor liquid; uniformly mixing the ITO nanocrystalline dispersion liquid and the ITO precursor liquid, and shearing and dispersing to form the indium tin oxide nanocrystalline composite solution;
soaking the modified polyester fabric C in the magnetic-nano composite modified solvent for 30min, washing with a large amount of distilled water, and drying at 40 ℃ to obtain the final antistatic modified polyester fabric;
the preparation method of the magnetic-nano composite modified solvent comprises the following steps: firstly dispersing nano-silica particles in a solvent, then adding lactic acid, and carrying out dehydration polycondensation reaction to obtain silica nano-particles with lactic acid oligomers grafted on the surfaces; dispersing the modified silicon dioxide particles in a solvent, and adding high molecular weight polylactic acid; the weight ratio of the nano silicon dioxide to the polylactic acid is 1: 15; stirring to obtain a solvent A;
according to the total iron concentration of 0.15mol/L, the molar ratio of ferrous ions to hydroxide ions is Fe2 +: OH ═ 1: 5, respectively weighing ferrous sulfate and sodium hydroxide, then adding sodium hydroxide and fully stirring to obtain a ferrous sulfate and sodium hydroxide mixed solution; adding 8g of hexadecyl trimethyl ammonium bromide and 8g of chitosan into each liter of the mixed solution of ferrous sulfate and sodium hydroxide, and stirring to form a solvent B; the solvent A and the solvent B are mixed according to the mass ratio of 6: 1.
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Families Citing this family (2)

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Publication number Priority date Publication date Assignee Title
CN108677525A (en) * 2018-05-06 2018-10-19 邳州易萨新型材料有限公司 A kind of preparation method of novel antistatic polyester fabric
CN112695517B (en) * 2020-12-16 2022-12-23 苏州飞睿纺织有限公司 Magnetic polyester fabric and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6656388B1 (en) * 1997-10-29 2003-12-02 The Board Of Governors For Higher Education, State Rhode Island And Providence Plantations Conducting polymers for coatings and antielectrostatic applications
CN1944529A (en) * 2006-10-19 2007-04-11 上海大学 Process for preparing biologically degradable SiO2/poly lactic acid nano composite material
CN101638846A (en) * 2009-08-31 2010-02-03 仙桃新发塑料制品有限公司 Bacteriostatic antistatic multifunctional non-woven fabric
CN103161065A (en) * 2013-03-26 2013-06-19 西安工程大学 Method for modifying polyester fabric by using magnetic nanometer iron oxide
CN105463833A (en) * 2015-12-02 2016-04-06 马鞍山金姿纺织装饰用品有限公司 Preparation method of antistatic polyester fabric

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5224363A (en) * 1988-12-16 1993-07-06 Golden Needles Knitting & Glove Co., Inc. Method of making garment, garment, and strand material
GB9725033D0 (en) * 1997-11-26 1998-01-28 Boc Group Plc Handling cryogenic liquids
CN2346812Y (en) * 1998-05-11 1999-11-03 王秉厚 Thermal insulating materials
CN100537867C (en) * 2006-12-22 2009-09-09 中国人民解放军海军医学研究所 The blended yarn of a kind of uvioresistant, antibiotic double wet-guide quick-drying and method for making and application
CN202525156U (en) * 2011-12-27 2012-11-14 凌从伍 Touch screen glove
CN105962487A (en) * 2016-05-31 2016-09-28 强新正品（苏州）环保材料科技有限公司 Multifunctional insulating glove

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6656388B1 (en) * 1997-10-29 2003-12-02 The Board Of Governors For Higher Education, State Rhode Island And Providence Plantations Conducting polymers for coatings and antielectrostatic applications
CN1944529A (en) * 2006-10-19 2007-04-11 上海大学 Process for preparing biologically degradable SiO2/poly lactic acid nano composite material
CN101638846A (en) * 2009-08-31 2010-02-03 仙桃新发塑料制品有限公司 Bacteriostatic antistatic multifunctional non-woven fabric
CN103161065A (en) * 2013-03-26 2013-06-19 西安工程大学 Method for modifying polyester fabric by using magnetic nanometer iron oxide
CN105463833A (en) * 2015-12-02 2016-04-06 马鞍山金姿纺织装饰用品有限公司 Preparation method of antistatic polyester fabric

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