CN108034978A - A kind of processing method for lifting aluminum alloy materials corrosion resistant characteristic - Google Patents

A kind of processing method for lifting aluminum alloy materials corrosion resistant characteristic Download PDF

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Publication number
CN108034978A
CN108034978A CN201711335461.4A CN201711335461A CN108034978A CN 108034978 A CN108034978 A CN 108034978A CN 201711335461 A CN201711335461 A CN 201711335461A CN 108034978 A CN108034978 A CN 108034978A
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aluminum alloy
alloy materials
titanium dioxide
parts
processing
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汪民
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Ma'anshan Xinhui Aluminum Industry Co Ltd
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Ma'anshan Xinhui Aluminum Industry Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D11/00Electrolytic coating by surface reaction, i.e. forming conversion layers
    • C25D11/02Anodisation
    • C25D11/04Anodisation of aluminium or alloys based thereon
    • C25D11/06Anodisation of aluminium or alloys based thereon characterised by the electrolytes used
    • C25D11/08Anodisation of aluminium or alloys based thereon characterised by the electrolytes used containing inorganic acids
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D11/00Electrolytic coating by surface reaction, i.e. forming conversion layers
    • C25D11/02Anodisation
    • C25D11/04Anodisation of aluminium or alloys based thereon
    • C25D11/06Anodisation of aluminium or alloys based thereon characterised by the electrolytes used
    • C25D11/10Anodisation of aluminium or alloys based thereon characterised by the electrolytes used containing organic acids
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D11/00Electrolytic coating by surface reaction, i.e. forming conversion layers
    • C25D11/02Anodisation
    • C25D11/04Anodisation of aluminium or alloys based thereon
    • C25D11/16Pretreatment, e.g. desmutting

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  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
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Abstract

The invention discloses a kind of processing method for lifting aluminum alloy materials corrosion resistant characteristic, include the following steps:(1)Surface grinding process,(2)Cleaning treatment,(3)Radiation treatment,(4)Anodized,(5)Isothermal holding.The present invention provides a kind of surface treatment method of aluminium alloy, and the aluminum alloy surface characteristic after it is handled is good, has the qualities such as good wear-resisting, corrosion resistant, intensity, effectively extends the service life of aluminum alloy materials, and application value is higher.

Description

A kind of processing method for lifting aluminum alloy materials corrosion resistant characteristic
Technical field
The invention belongs to aluminium alloy working process technical field, and in particular to a kind of lifting aluminum alloy materials corrosion resistant characteristic Processing method.
Background technology
It is a series of that aluminium alloy has the advantages that density is small, specific strength is high, corrosion resistance and good moldability, cost are low etc., is navigating The fields such as empty space flight, ship, building, bridge, electric power, automobile, nuclear industry and weapon industry suffer from being widely applied.But because of aluminium Performance is more active, and the bad phenomenons such as Damage of Corroded can occur when using under normal operation, need to carry out at surface it more Used after reason.Aluminium alloy surface treatment method has much at present, comparative maturity, using more widely have Physical, change Method, physical-chemical process and synthesis.Anodizing is a kind of one of common method, by electrochemical method in aluminium alloy Surface forms conversion film, to improve the characteristic of aluminum alloy surface.And existing processing method technique is simple, the aluminium after alignment processing Alloy surface quality-improving is bad, it is necessary to further improve.
The content of the invention
The purpose of the present invention is for it is existing the problem of, there is provided it is a kind of lifted aluminum alloy materials corrosion resistant characteristic processing side Method.
The present invention is achieved by the following technical solutions:
A kind of processing method for lifting aluminum alloy materials corrosion resistant characteristic, includes the following steps:
(1)Surface grinding process:
First with surface polishing of the 500 mesh sand paper to aluminum alloy materials once, then polished once with 800 mesh sand paper, finally Polishing chip is blown away with compressed air;
(2)Cleaning treatment:
By step(1)Aluminum alloy materials after processing are put into 8 ~ 10min of immersion treatment in salpeter solution, after the completion of take out and spend Ionized water is spare after rinsing one time;
(3)Radiation treatment:
By step(2)Aluminum alloy materials after processing are put into progress ultraviolet irradiation processing in ultraviolet irradiation instrument, complete After take out it is spare;
(4)Anodized:
By step(3)Aluminum alloy materials after processing are put into electrolysis treatment fluid, and the temperature that heating keeps being electrolysed treatment fluid is 40 ~ 44 DEG C, it is 0.4 ~ 0.6A/dm to control current density2, aluminum alloy materials are taken out after handling 8 ~ 10min;The electrolysis processing Liquid by following parts by weight material composition:15 ~ 18 parts of sulfuric acid, 5 ~ 7 parts of citric acids, 4 ~ 6 parts of phytic acid, 2 ~ 4 parts of sodium chloride, 3 ~ 6 parts Titanium dioxide, 1.5 ~ 2.5 parts of sodium pyrophosphates, 0.8 ~ 1.2 part of magnesium stearate, 0.4 ~ 0.8 part of nonylphenol polyoxyethylene ether, 3 ~ 5 parts Silane coupling agent, 360 ~ 380 parts of water;
(5)Isothermal holding:
By step(4)Aluminum alloy materials after processing, which are put into insulating box, carries out isothermal holding, is taken out after 20 ~ 25min.
Further, step(2)Described in salpeter solution mass fraction be 9 ~ 11%.
Further, step(3)Described in ultraviolet irradiation processing when wavelength be 290 ~ 320nm, the power of irradiation For 600 ~ 700W.
Further, step(4)Described in titanium dioxide be by the titanium dioxide mixing of three kinds of variable grain sizes and Into being specifically divided into titanium dioxide A, titanium dioxide B and titanium dioxide C, the corresponding weight ratio of three is 2 ~ 3:7~8:4 ~ 5, it is described The granular size of titanium dioxide A is 40 ~ 50 μm, and the granular size of titanium dioxide B is 0.8 ~ 5 μm, the granular size of titanium dioxide C For 0.05 ~ 0.2 μm.
Further, step(5)Described in isothermal holding when to control temperature in insulating box be 140 ~ 150 DEG C.
The present invention improves the anode oxidative treatment method of aluminum alloy surface, wherein in anodized process Before, ultraviolet irradiation processing has first been carried out to aluminum alloy surface, the content of surface reactive group has been effectively improved, enhances Its surface-active, beneficial to the effect of follow-up anodized, during anodized, uniqueness has prepared a kind of electricity Treatment fluid is solved, being smoothed out for electrolytic oxidation is ensure that wherein arranging in pairs or groups jointly with sulfuric acid, citric acid, phytic acid and forming sour environment, The sodium chloride of addition enhances the conductive capability of electrolysis treatment fluid, the efficiency of electrolysis processing is improved, in order to further improve electricity The effect of film forming is solved, and with the addition of titanium dioxide content, it is mixed by the titanium dioxide of three kinds of variable grain sizes, It can go out different size of pit in aluminium and aluminum alloy surface electrochemical etching during electrolysis processing, utilize this titanium dioxide filler component To be filled, and under the mating reaction of silane coupling agent so that titanium dioxide and three oxidations of anodized generation The crosslinking of two alumites combines, and then enhances compactness, wearability, rotproofness of film forming etc., improves the quality of processing, The isothermal holding carried out after anodized process, improves the stability of film layer.
The present invention has the following advantages compared with prior art:
The present invention provides a kind of surface treatment method of aluminium alloy, and the aluminum alloy surface characteristic after it is handled is good, has fine Wear-resisting, corrosion resistant, the quality such as intensity, effectively extend service lifes of aluminum alloy materials, application value is higher.
Embodiment
Embodiment 1
A kind of processing method for lifting aluminum alloy materials corrosion resistant characteristic, includes the following steps:
(1)Surface grinding process:
First with surface polishing of the 500 mesh sand paper to aluminum alloy materials once, then polished once with 800 mesh sand paper, finally Polishing chip is blown away with compressed air;
(2)Cleaning treatment:
By step(1)Aluminum alloy materials after processing are put into immersion treatment 8min in salpeter solution, after the completion of take out spend from Sub- water is spare after rinsing one time;
(3)Radiation treatment:
By step(2)Aluminum alloy materials after processing are put into progress ultraviolet irradiation processing in ultraviolet irradiation instrument, complete After take out it is spare;
(4)Anodized:
By step(3)Aluminum alloy materials after processing are put into electrolysis treatment fluid, and the temperature that heating keeps being electrolysed treatment fluid is 40 DEG C, it is 0.4A/dm to control current density2, aluminum alloy materials are taken out after handling 8min;The electrolysis treatment fluid by weighing as follows Measure the material composition of part:15 parts of sulfuric acid, 5 parts of citric acids, 4 parts of phytic acid, 2 parts of sodium chloride, 3 parts of titanium dioxide, 1.5 parts of pyrophosphoric acids Sodium, 0.8 part of magnesium stearate, 0.4 part of nonylphenol polyoxyethylene ether, 3 parts of silane coupling agents, 360 parts of water;
(5)Isothermal holding:
By step(4)Aluminum alloy materials after processing, which are put into insulating box, carries out isothermal holding, is taken out after 20min.
Further, step(2)Described in salpeter solution mass fraction be 9%.
Further, step(3)Described in ultraviolet irradiation processing when wavelength be 290 ~ 300nm, the power of irradiation For 600W.
Further, step(4)Described in titanium dioxide be by the titanium dioxide mixing of three kinds of variable grain sizes and Into being specifically divided into titanium dioxide A, titanium dioxide B and titanium dioxide C, the corresponding weight ratio of three is 2:7:4, the titanium dioxide The granular size of titanium A is 40 ~ 50 μm, and the granular size of titanium dioxide B is 0.8 ~ 5 μm, and the granular size of titanium dioxide C is 0.05 ~0.2μm。
Further, step(5)Described in isothermal holding when to control temperature in insulating box be 140 DEG C.
Embodiment 2
A kind of processing method for lifting aluminum alloy materials corrosion resistant characteristic, includes the following steps:
(1)Surface grinding process:
First with surface polishing of the 500 mesh sand paper to aluminum alloy materials once, then polished once with 800 mesh sand paper, finally Polishing chip is blown away with compressed air;
(2)Cleaning treatment:
By step(1)Aluminum alloy materials after processing are put into immersion treatment 9min in salpeter solution, after the completion of take out spend from Sub- water is spare after rinsing one time;
(3)Radiation treatment:
By step(2)Aluminum alloy materials after processing are put into progress ultraviolet irradiation processing in ultraviolet irradiation instrument, complete After take out it is spare;
(4)Anodized:
By step(3)Aluminum alloy materials after processing are put into electrolysis treatment fluid, and the temperature that heating keeps being electrolysed treatment fluid is 42 DEG C, it is 0.5A/dm to control current density2, aluminum alloy materials are taken out after handling 9min;The electrolysis treatment fluid by weighing as follows Measure the material composition of part:17 parts of sulfuric acid, 6 parts of citric acids, 5 parts of phytic acid, 3 parts of sodium chloride, 5 parts of titanium dioxide, 2 parts of sodium pyrophosphates, 1 Part magnesium stearate, 0.6 part of nonylphenol polyoxyethylene ether, 4 parts of silane coupling agents, 370 parts of water;
(5)Isothermal holding:
By step(4)Aluminum alloy materials after processing, which are put into insulating box, carries out isothermal holding, is taken out after 23min.
Further, step(2)Described in salpeter solution mass fraction be 10%.
Further, step(3)Described in ultraviolet irradiation processing when wavelength be 300 ~ 310nm, the power of irradiation For 660W.
Further, step(4)Described in titanium dioxide be by the titanium dioxide mixing of three kinds of variable grain sizes and Into being specifically divided into titanium dioxide A, titanium dioxide B and titanium dioxide C, the corresponding weight ratio of three is 2.5:7.6:4.7, it is described The granular size of titanium dioxide A is 40 ~ 50 μm, and the granular size of titanium dioxide B is 0.8 ~ 5 μm, the granular size of titanium dioxide C For 0.05 ~ 0.2 μm.
Further, step(5)Described in isothermal holding when to control temperature in insulating box be 146 DEG C.
Embodiment 3
A kind of processing method for lifting aluminum alloy materials corrosion resistant characteristic, includes the following steps:
(1)Surface grinding process:
First with surface polishing of the 500 mesh sand paper to aluminum alloy materials once, then polished once with 800 mesh sand paper, finally Polishing chip is blown away with compressed air;
(2)Cleaning treatment:
By step(1)Aluminum alloy materials after processing are put into immersion treatment 10min in salpeter solution, after the completion of take out spend from Sub- water is spare after rinsing one time;
(3)Radiation treatment:
By step(2)Aluminum alloy materials after processing are put into progress ultraviolet irradiation processing in ultraviolet irradiation instrument, complete After take out it is spare;
(4)Anodized:
By step(3)Aluminum alloy materials after processing are put into electrolysis treatment fluid, and the temperature that heating keeps being electrolysed treatment fluid is 44 DEG C, it is 0.6A/dm to control current density2, aluminum alloy materials are taken out after handling 10min;The electrolysis treatment fluid is by as follows The material composition of parts by weight:18 parts of sulfuric acid, 7 parts of citric acids, 6 parts of phytic acid, 4 parts of sodium chloride, 6 parts of titanium dioxide, 2.5 parts of pyrophosphoric acids Sodium, 1.2 parts of magnesium stearates, 0.8 part of nonylphenol polyoxyethylene ether, 5 parts of silane coupling agents, 380 parts of water;
(5)Isothermal holding:
By step(4)Aluminum alloy materials after processing, which are put into insulating box, carries out isothermal holding, is taken out after 25min.
Further, step(2)Described in salpeter solution mass fraction be 11%.
Further, step(3)Described in ultraviolet irradiation processing when wavelength be 300 ~ 320nm, the power of irradiation For 700W.
Further, step(4)Described in titanium dioxide be by the titanium dioxide mixing of three kinds of variable grain sizes and Into being specifically divided into titanium dioxide A, titanium dioxide B and titanium dioxide C, the corresponding weight ratio of three is 3:8:5, the titanium dioxide The granular size of titanium A is 40 ~ 50 μm, and the granular size of titanium dioxide B is 0.8 ~ 5 μm, and the granular size of titanium dioxide C is 0.05 ~0.2μm。
Further, step(5)Described in isothermal holding when to control temperature in insulating box be 150 DEG C.
Comparative example 1
This comparative example 1 compared with Example 2, eliminates step(3)Radiation treatment operates, and method and step in addition is homogeneous Together.
Comparative example 2
This comparative example 2 compared with Example 2, eliminates step(4)Titanium dioxide in anodized in titanium dioxide Titanium B component, method and step all same in addition.
Comparative example 3
This comparative example 3 compared with Example 2, in step(4)In anodized, with etc. mass parts commercially available titanium dioxide Titanium substitutes titanium dioxide content, method and step all same in addition.
Comparative example 4
This comparative example 4 compared with Example 2, in step(4)In anodized, titanium dioxide content is eliminated, is removed In addition method and step all same.
Control group
Existing aluminum alloy surface anode oxidative treatment method.
In order to contrast effect of the present invention, select with a collection of manufactured aluminum alloy materials as experimental subjects, respectively with above-mentioned Embodiment 2, comparative example 1, comparative example 2, comparative example 3, comparative example 4, the method described in control group carry out Processing, after the completion of it is tested for the property, specific correction data is as shown in table 1 below:
Table 1
Corrosion potential Ecorr(V) Corrosion current density icorr(A/cm2 Weight loss(mg)
Embodiment 2 -0.972 0.015 0.30
Comparative example 1 -1.164 0.184 0.74
Comparative example 2 -1.204 0.295 1.07
Comparative example 3 -1.256 0.364 1.16
Comparative example 4 -1.304 0.426 1.44
Control group -1.365 0.497 1.68
Note:Corrosion potential and corrosion current density described in upper table 1 are obtained by electro-chemical test, and concrete mode is Using the aluminium alloy after alignment processing as working electrode, using platinum electrode as auxiliary electrode, with mercuric oxide electrode and saturation calomel For electrode as reference electrode, electrolytic solution is the NaCl solution of mass fraction 4.5%, measures the tower of different aluminum alloys electrode samples Fei Er curves, the surface sweeping scope for controlling test potential are open circuit potential ± 1.5V, and scan frequency is arranged to 0.5mV/s, thus Go out corrosion potential and corrosion current density;The weight loss is that NaCl solution immersion is carried out to the aluminium alloy after processing in fact Test, to further demonstrate that its corrosion resistance characteristic, corresponding aluminium alloy is specifically processed into identical volume size(Length and width are a height of: 10cm×5 cm×5cm), it is then immersed in the NaCl neutral solutions that mass fraction is 7%, immersion detects its corrosion and loses after 5 days Weight.
Processing method of the present invention can significantly improve the surface corrosion characteristics of aluminum alloy materials it can be seen from upper table 1, prolong Its service life, great application value are grown.

Claims (5)

1. a kind of processing method for lifting aluminum alloy materials corrosion resistant characteristic, it is characterised in that include the following steps:
(1)Surface grinding process:
First with surface polishing of the 500 mesh sand paper to aluminum alloy materials once, then polished once with 800 mesh sand paper, finally Polishing chip is blown away with compressed air;
(2)Cleaning treatment:
By step(1)Aluminum alloy materials after processing are put into 8 ~ 10min of immersion treatment in salpeter solution, after the completion of take out and spend Ionized water is spare after rinsing one time;
(3)Radiation treatment:
By step(2)Aluminum alloy materials after processing are put into progress ultraviolet irradiation processing in ultraviolet irradiation instrument, complete After take out it is spare;
(4)Anodized:
By step(3)Aluminum alloy materials after processing are put into electrolysis treatment fluid, and the temperature that heating keeps being electrolysed treatment fluid is 40 ~ 44 DEG C, it is 0.4 ~ 0.6A/dm to control current density2, aluminum alloy materials are taken out after handling 8 ~ 10min;The electrolysis processing Liquid by following parts by weight material composition:15 ~ 18 parts of sulfuric acid, 5 ~ 7 parts of citric acids, 4 ~ 6 parts of phytic acid, 2 ~ 4 parts of sodium chloride, 3 ~ 6 parts Titanium dioxide, 1.5 ~ 2.5 parts of sodium pyrophosphates, 0.8 ~ 1.2 part of magnesium stearate, 0.4 ~ 0.8 part of nonylphenol polyoxyethylene ether, 3 ~ 5 parts Silane coupling agent, 360 ~ 380 parts of water;
(5)Isothermal holding:
By step(4)Aluminum alloy materials after processing, which are put into insulating box, carries out isothermal holding, is taken out after 20 ~ 25min.
A kind of 2. processing method for lifting aluminum alloy materials corrosion resistant characteristic according to claim 1, it is characterised in that step (2)Described in salpeter solution mass fraction be 9 ~ 11%.
A kind of 3. processing method for lifting aluminum alloy materials corrosion resistant characteristic according to claim 1, it is characterised in that step (3)Described in ultraviolet irradiation processing when wavelength be 290 ~ 320nm, the power of irradiation is 600 ~ 700W.
A kind of 4. processing method for lifting aluminum alloy materials corrosion resistant characteristic according to claim 1, it is characterised in that step (4)Described in titanium dioxide be to be mixed by the titanium dioxide of three kinds of variable grain sizes, be specifically divided into titanium dioxide A, Titanium dioxide B and titanium dioxide C, the corresponding weight ratio of three are 2 ~ 3:7~8:4 ~ 5, the granular size of the titanium dioxide A is 40 ~ 50 μm, the granular size of titanium dioxide B is 0.8 ~ 5 μm, and the granular size of titanium dioxide C is 0.05 ~ 0.2 μm.
A kind of 5. processing method for lifting aluminum alloy materials corrosion resistant characteristic according to claim 1, it is characterised in that step (5)Described in isothermal holding when to control temperature in insulating box be 140 ~ 150 DEG C.
CN201711335461.4A 2017-12-14 2017-12-14 A kind of processing method for lifting aluminum alloy materials corrosion resistant characteristic Pending CN108034978A (en)

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CN109023471A (en) * 2018-10-09 2018-12-18 长春工业大学 A kind of aluminium alloy and preparation method thereof
CN110184574A (en) * 2019-05-17 2019-08-30 安徽省汉甲机电设备科技有限公司 A kind for the treatment of process improving steel surface coating adhesion

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Publication number Priority date Publication date Assignee Title
CN109023471A (en) * 2018-10-09 2018-12-18 长春工业大学 A kind of aluminium alloy and preparation method thereof
CN110184574A (en) * 2019-05-17 2019-08-30 安徽省汉甲机电设备科技有限公司 A kind for the treatment of process improving steel surface coating adhesion
CN110184574B (en) * 2019-05-17 2020-09-01 西安致远航空科技有限公司 Treatment process for improving adhesive force of coating on steel surface

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Application publication date: 20180515