CN108034916A - A kind of electric arc spraying dusty material - Google Patents
A kind of electric arc spraying dusty material Download PDFInfo
- Publication number
- CN108034916A CN108034916A CN201711311294.XA CN201711311294A CN108034916A CN 108034916 A CN108034916 A CN 108034916A CN 201711311294 A CN201711311294 A CN 201711311294A CN 108034916 A CN108034916 A CN 108034916A
- Authority
- CN
- China
- Prior art keywords
- parts
- powder
- electric arc
- arc spraying
- powders
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000463 material Substances 0.000 title claims abstract description 33
- 238000010891 electric arc Methods 0.000 title claims abstract description 23
- 238000005507 spraying Methods 0.000 title claims abstract description 23
- 239000000843 powder Substances 0.000 claims abstract description 61
- 241000219991 Lythraceae Species 0.000 claims abstract description 16
- 235000014360 Punica granatum Nutrition 0.000 claims abstract description 16
- 235000013312 flour Nutrition 0.000 claims abstract description 16
- DALUDRGQOYMVLD-UHFFFAOYSA-N iron manganese Chemical compound [Mn].[Fe] DALUDRGQOYMVLD-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229910000616 Ferromanganese Inorganic materials 0.000 claims abstract description 13
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 11
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910018487 Ni—Cr Inorganic materials 0.000 claims abstract description 10
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 10
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000004411 aluminium Substances 0.000 claims abstract description 10
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 10
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000002041 carbon nanotube Substances 0.000 claims abstract description 10
- 229910021393 carbon nanotube Inorganic materials 0.000 claims abstract description 10
- VNNRSPGTAMTISX-UHFFFAOYSA-N chromium nickel Chemical compound [Cr].[Ni] VNNRSPGTAMTISX-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000000203 mixture Substances 0.000 claims abstract description 10
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 10
- 239000010703 silicon Substances 0.000 claims abstract description 10
- 239000010936 titanium Substances 0.000 claims abstract description 10
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 10
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910052749 magnesium Inorganic materials 0.000 claims description 8
- 239000011777 magnesium Substances 0.000 claims description 8
- 229910052796 boron Inorganic materials 0.000 claims description 6
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 5
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 5
- 239000002245 particle Substances 0.000 claims description 5
- 229910052750 molybdenum Inorganic materials 0.000 claims description 4
- 239000011733 molybdenum Substances 0.000 claims description 4
- 239000011248 coating agent Substances 0.000 abstract description 6
- 238000000576 coating method Methods 0.000 abstract description 6
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 239000007769 metal material Substances 0.000 description 4
- 235000016768 molybdenum Nutrition 0.000 description 4
- 239000007921 spray Substances 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 1
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229910052863 mullite Inorganic materials 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 238000002161 passivation Methods 0.000 description 1
- 230000000505 pernicious effect Effects 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/12—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the method of spraying
- C23C4/131—Wire arc spraying
-
- B22F1/0003—
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/04—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
- C23C4/06—Metallic material
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Coating By Spraying Or Casting (AREA)
Abstract
The invention discloses a kind of electric arc spraying dusty material, by following material composition：Nickel chromium triangle powder, ferro-boron powder, molybdenum powder, silicon ferrozirconium powder, aluminium powder, magnesium powder, titanium valve, ferromanganese powder, carbon nanotubes, pomegranate mountain flour.The present invention provides a kind of electric arc spraying dusty material of formulated, common by each component coordinates, and effectively improves the integrated quality of spray-on coating, improves the characteristics such as bond strength, impact strength, hardness, great application value.
Description
Technical field
The invention belongs to electric arc spraying processing technology field, and in particular to a kind of electric arc spraying dusty material.
Background technology
Easily there are the bad phenomenons such as get rusty, corrode, in order to change in use because surface-active is higher in metal material
It is apt to this problem, it is necessary to carry out protective treatment to its surface, relatively conventional has plating, coating spraying, passivation etc..Electric arc spraying is
It is one of them, it is to spray material molten to be sprayed using high energy arc to form a protection on the surface of metal material
Layer, and then lift the protection to metal material.But in existing electric arc spraying treatment process, sprayed on material component proportion used is not
It is good, cause the bond strength between the coating and metal base that are formed on the metal surface not high, so as to have impact at electric arc spraying
The effect of reason is, it is necessary to further improve.
The content of the invention
The purpose of the present invention is for it is existing the problem of, there is provided a kind of electric arc spraying dusty material.
The present invention is achieved by the following technical solutions：
A kind of electric arc spraying dusty material, by the material composition of following parts by weight：30 ~ 35 parts of nickel chromium triangle powder, 15 ~ 18 parts of ferro-borons
Powder, 1 ~ 3 part of molybdenum powder, 2 ~ 4 parts of silicon ferrozirconium powder, 8 ~ 12 parts of aluminium powders, 6 ~ 10 parts of magnesium powders, 4 ~ 7 parts of titanium valves, 3 ~ 5 parts of ferromanganese powders, 3 ~ 6 parts
Carbon nanotubes, 2 ~ 5 parts of pomegranate mountain flours.
Preferably, by the material composition of following parts by weight：33 ~ 35 parts of nickel chromium triangle powder, 17 ~ 18 parts of ferro-boron powder, 2 ~ 3 parts of molybdenum powders, 3
~ 4 parts of silicon ferrozirconium powder, 10 ~ 12 parts of aluminium powders, 8 ~ 10 parts of magnesium powders, 6 ~ 7 parts of titanium valves, 4 ~ 5 parts of ferromanganese powders, 5 ~ 6 parts of carbon nanotubes, 4 ~ 5 parts
Pomegranate mountain flour.
Preferably, by the material composition of following parts by weight：33 parts of nickel chromium triangle powder, 17 parts of ferro-boron powder, 2 parts of molybdenum powders, 3 parts of silicon ferrozirconiums
Powder, 10 parts of aluminium powders, 8 parts of magnesium powders, 6 parts of titanium valves, 4 parts of ferromanganese powders, 5 parts of carbon nanotubes, 4 parts of pomegranate mountain flours.
Further, the parts by weight content of boron element is not less than 24% in the ferro-boron powder.
Further, the parts by weight content of manganese element is not less than 80% in the ferromanganese powder.
Further, the particle diameter of the pomegranate mountain flour is 10 ~ 50 μm.
The present invention has the following advantages compared with prior art：
The present invention provides a kind of electric arc spraying dusty material of formulated, common by each component coordinates, and effectively carries
The integrated quality of spray-on coating has been risen, has improved the characteristics such as bond strength, impact strength, hardness, wherein the carbon nanometer added
Pipe enhances the binding ability between tissue everywhere, and pernicious gas component caused by electric arc processing can be adsorbed, and is lifted
The security of metal material, the pomegranate mountain flour of addition form the higher mullite phase constitution of hardness under the high temperature conditions, improve
The hardness of coating entirety.Finally the combination adhesive force between dusty material and metal base produced by the present invention has reached 30MPa
More than, more than 40% compared with usual spray material lift, while also there is very high toughness, and its 700 DEG C of high temperature hardness
HV0.3＞ 400, has good integrated quality, the great market competitiveness and popularizing value.
Embodiment
Embodiment 1
A kind of electric arc spraying dusty material, by the material composition of following parts by weight：30 parts of nickel chromium triangle powder, 15 parts of ferro-boron powder, 1 part of molybdenum
Powder, 2 parts of silicon ferrozirconium powder, 8 parts of aluminium powders, 6 parts of magnesium powders, 4 parts of titanium valves, 3 parts of ferromanganese powders, 3 parts of carbon nanotubes, 2 parts of pomegranate mountain flours.
Further, the parts by weight content of boron element is not less than 24% in the ferro-boron powder.
Further, the parts by weight content of manganese element is not less than 80% in the ferromanganese powder.
Further, the particle diameter of the pomegranate mountain flour is 10 ~ 50 μm.
Embodiment 2
A kind of electric arc spraying dusty material, by the material composition of following parts by weight：33 parts of nickel chromium triangle powder, 17 parts of ferro-boron powder, 2 parts of molybdenums
Powder, 3 parts of silicon ferrozirconium powder, 10 parts of aluminium powders, 8 parts of magnesium powders, 6 parts of titanium valves, 4 parts of ferromanganese powders, 5 parts of carbon nanotubes, 4 parts of pomegranate mountain flours.
Further, the parts by weight content of boron element is not less than 24% in the ferro-boron powder.
Further, the parts by weight content of manganese element is not less than 80% in the ferromanganese powder.
Further, the particle diameter of the pomegranate mountain flour is 10 ~ 50 μm.
Embodiment 3
A kind of electric arc spraying dusty material, by the material composition of following parts by weight：35 parts of nickel chromium triangle powder, 18 parts of ferro-boron powder, 3 parts of molybdenums
Powder, 4 parts of silicon ferrozirconium powder, 12 parts of aluminium powders, 10 parts of magnesium powders, 7 parts of titanium valves, 5 parts of ferromanganese powders, 6 parts of carbon nanotubes, 5 parts of pomegranate mountain flours.
Further, the parts by weight content of boron element is not less than 24% in the ferro-boron powder.
Further, the parts by weight content of manganese element is not less than 80% in the ferromanganese powder.
Further, the particle diameter of the pomegranate mountain flour is 10 ~ 50 μm.
It is detected after carrying out electric arc spraying experiment to powdery paints produced by the present invention, finds what this dusty material was formed
Combination adhesive force between coating and metal base has reached more than 30MPa, more than 40% compared with usual spray material lift, at the same time
Also there is very high toughness, and its hardness HV under 700 DEG C of hot environments0.3＞ 400, integrated quality is high, and popularization makes
With being worth.
Claims (6)
1. a kind of electric arc spraying dusty material, it is characterised in that by the material composition of following parts by weight：30 ~ 35 parts of nickel chromium triangle powder,
15 ~ 18 parts of ferro-boron powder, 1 ~ 3 part of molybdenum powder, 2 ~ 4 parts of silicon ferrozirconium powder, 8 ~ 12 parts of aluminium powders, 6 ~ 10 parts of magnesium powders, 4 ~ 7 parts of titanium valves, 3 ~ 5 parts of manganese
Iron powder, 3 ~ 6 parts of carbon nanotubes, 2 ~ 5 parts of pomegranate mountain flours.
2. a kind of electric arc spraying dusty material according to claim 1, it is characterised in that by the material of following parts by weight
Composition：33 ~ 35 parts of nickel chromium triangle powder, 17 ~ 18 parts of ferro-boron powder, 2 ~ 3 parts of molybdenum powders, 3 ~ 4 parts of silicon ferrozirconium powder, 10 ~ 12 parts of aluminium powders, 8 ~ 10 parts of magnesium
Powder, 6 ~ 7 parts of titanium valves, 4 ~ 5 parts of ferromanganese powders, 5 ~ 6 parts of carbon nanotubes, 4 ~ 5 parts of pomegranate mountain flours.
3. a kind of electric arc spraying dusty material according to claim 1, it is characterised in that by the material of following parts by weight
Composition：33 parts of nickel chromium triangle powder, 17 parts of ferro-boron powder, 2 parts of molybdenum powders, 3 parts of silicon ferrozirconium powder, 10 parts of aluminium powders, 8 parts of magnesium powders, 6 parts of titanium valves, 4 parts of manganese
Iron powder, 5 parts of carbon nanotubes, 4 parts of pomegranate mountain flours.
A kind of 4. electric arc spraying dusty material according to claim 1 ~ 3 any one, it is characterised in that the ferro-boron
The parts by weight content of boron element is not less than 24% in powder.
A kind of 5. electric arc spraying dusty material according to claim 1 ~ 3 any one, it is characterised in that the ferromanganese
The parts by weight content of manganese element is not less than 80% in powder.
A kind of 6. electric arc spraying dusty material according to claim 1 ~ 3 any one, it is characterised in that the pomegranate
The particle diameter of mountain flour is 10 ~ 50 μm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711311294.XA CN108034916A (en) | 2017-12-11 | 2017-12-11 | A kind of electric arc spraying dusty material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711311294.XA CN108034916A (en) | 2017-12-11 | 2017-12-11 | A kind of electric arc spraying dusty material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108034916A true CN108034916A (en) | 2018-05-15 |
Family
ID=62102397
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711311294.XA Pending CN108034916A (en) | 2017-12-11 | 2017-12-11 | A kind of electric arc spraying dusty material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108034916A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109136815A (en) * | 2018-07-23 | 2019-01-04 | 翟恩荣 | A kind of plasma surface melting and coating process |
| CN110760776A (en) * | 2019-09-24 | 2020-02-07 | 成都正恒动力股份有限公司 | Cr-free iron-based coating of cylinder inner hole and spraying method thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1876885A (en) * | 2006-06-30 | 2006-12-13 | 北京工业大学 | Wearable iron-based TiC-ceramic-containing powder cored wire for electric arc spraying |
| CN102321861A (en) * | 2011-10-13 | 2012-01-18 | 广东石油化工学院 | Powder cored wire for preparing carbon-nitrogen alloyed wear-resistant coating by arc spraying |
| CN103484808A (en) * | 2013-09-24 | 2014-01-01 | 无锡市福莱达石油机械有限公司 | Preparation method of carbon nano tube reinforcing NiCr-Cr3C2 coating |
| CN103628017A (en) * | 2013-12-12 | 2014-03-12 | 江西恒大高新技术股份有限公司 | B-C compound hard phase wear-resistant electric arc spraying cored wire |
| CN104630683A (en) * | 2015-02-09 | 2015-05-20 | 江西恒大高新技术股份有限公司 | Arc spraying material capable of resisting fluidized bed ash flushing and scaling |
| CN106244976A (en) * | 2016-09-18 | 2016-12-21 | 安徽克里斯特新材料有限公司 | Heat spraying method is used to prepare the method that Metal Substrate Graphene strengthens composite |
-
2017
- 2017-12-11 CN CN201711311294.XA patent/CN108034916A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1876885A (en) * | 2006-06-30 | 2006-12-13 | 北京工业大学 | Wearable iron-based TiC-ceramic-containing powder cored wire for electric arc spraying |
| CN102321861A (en) * | 2011-10-13 | 2012-01-18 | 广东石油化工学院 | Powder cored wire for preparing carbon-nitrogen alloyed wear-resistant coating by arc spraying |
| CN103484808A (en) * | 2013-09-24 | 2014-01-01 | 无锡市福莱达石油机械有限公司 | Preparation method of carbon nano tube reinforcing NiCr-Cr3C2 coating |
| CN103628017A (en) * | 2013-12-12 | 2014-03-12 | 江西恒大高新技术股份有限公司 | B-C compound hard phase wear-resistant electric arc spraying cored wire |
| CN104630683A (en) * | 2015-02-09 | 2015-05-20 | 江西恒大高新技术股份有限公司 | Arc spraying material capable of resisting fluidized bed ash flushing and scaling |
| CN106244976A (en) * | 2016-09-18 | 2016-12-21 | 安徽克里斯特新材料有限公司 | Heat spraying method is used to prepare the method that Metal Substrate Graphene strengthens composite |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109136815A (en) * | 2018-07-23 | 2019-01-04 | 翟恩荣 | A kind of plasma surface melting and coating process |
| CN110760776A (en) * | 2019-09-24 | 2020-02-07 | 成都正恒动力股份有限公司 | Cr-free iron-based coating of cylinder inner hole and spraying method thereof |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
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Application publication date: 20180515 |