CN108001063A - A kind of preparation method of laser holographic water transfer film - Google Patents

A kind of preparation method of laser holographic water transfer film Download PDF

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Publication number
CN108001063A
CN108001063A CN201711180535.1A CN201711180535A CN108001063A CN 108001063 A CN108001063 A CN 108001063A CN 201711180535 A CN201711180535 A CN 201711180535A CN 108001063 A CN108001063 A CN 108001063A
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China
Prior art keywords
laser holographic
water
film
layer
polyvinyl alcohol
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崔跃飞
崔若曦
李少香
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South China University of Technology SCUT
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South China University of Technology SCUT
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Priority to CN201711180535.1A priority Critical patent/CN108001063A/en
Publication of CN108001063A publication Critical patent/CN108001063A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/26Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
    • B41M5/40Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
    • B41M5/41Base layers supports or substrates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00Ancillary operations in connection with laminating processes
    • B32B38/10Removing layers, or parts of layers, mechanically or chemically
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/025Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet

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  • Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Decoration By Transfer Pictures (AREA)

Abstract

The invention discloses a kind of preparation process of laser holographic water transfer film.The preparation process includes step:(1)Moisten covering coating water-soluble resin liquid entirely in the laser holographic hum pattern pattern layer side using PET as the laser holographic transfer film of basement membrane, it is dry, form resin film layer;(2)The coating polyethylene alcohol solution on resin film layer, it is dry, form polyvinyl alcohol water solubility base membrane layer;(3)The film of laser holographic hum pattern pattern layer, resin film layer and polyvinyl alcohol water solubility base membrane layer one is peeled off, winds, obtains the laser holographic water transfer film.The basement membrane of laser holographic water transfer film prepared by the present invention is polyvinyl alcohol water-soluble thin film, and no longer it is plastic-based film, the film of preparation is laser holographic water transfer film, it is adapted to the transfer of curved surface and various Special-Shaped Surfaces, the prior art is overcome using plastic film as basement membrane and is only suitable for the defects of plane transfers, laser holographic printed decoration application field is expanded.

Description

A kind of preparation method of laser holographic water transfer film
Technical field
The present invention relates to the preparation of laser holographic transfer film, more particularly to a kind of preparation of laser holographic water transfer film Method.
Background technology
Laser film is the new material of the high-tech and environmental protection developed in recent years.The figure of laser holography shooting and producing Shape, word have peculiar bright brilliant, colors changing hue, multicoloured special-effect, it may be said that be it is current in the world other Any technology be all unable to reach with it is irreplaceable.Not only there is decoration, false proof, environmentally friendly etc., and it is of low cost, it is prolonged resistance to With, progressively obtain being widely recognized as and applying for packaging industry, be it is a kind of preferably high-end packaging material.Compared with traditional aluminium foil or Plastic composite, has the following advantages using upper laser film:Metal sense is strong, anti-oxidant, moisture-proof, weather-proof, ink-receptive energy Good, surface is adapted to various printings, can print various exquisite patterns;Nontoxic free from extraneous odour, since the product after transfer is free of film Layer, it is environmentally protective.It is extensive meanwhile laser film has higher safe-guarding and anti-counterfeiting, gorgeous color, dynamic psychedelic effects etc. Applied to every field such as packaging, printing, decorations.
Laser film is generally using computer dot matrix photoetching technique, 3D true color holographies technology, multiple and dynamic imaging techniques Deng, through be molded with rainbow dynamic, three-dimensional stereo effect hologram image be transferred to polyethylene terephthalate (PET), On bidirectional stretching polypropylene film (BOPP), polyvinyl chloride (PVC) or band coating base material, compound, thermoprint, transfer are then utilized Commodity packaging surface is set to obtain certain laser effect etc. mode.Divided from product composition composition, ripe at present is radium-shine Film product can be roughly divided into three kinds of BOPP laser films, PET laser films and PVC laser films.
At present, it is as follows to produce laser holographic transfer film technological process:
Existing laser holographic transfers (shifting) film, structure from top to bottom, successively including hum pattern pattern layer, protective layer (from Type layer) and basement membrane, the basement membrane used, should in production for films such as BOPP, PET, biaxially oriented polyester film (BOPET) or PVC Laser holographic transfer (shifting) film is all the transfer film using plastic film as base material, is all only suitable for plane transfer (shifting), The transfer of curved surface and Special-Shaped Surface cannot be carried out, is restricted application field.
The content of the invention
In view of the above-mentioned deficiencies in the prior art, it is an object of the present invention to provide a kind of preparation of laser holographic water transfer film Technique.The preparation process by using PET as the laser holographic transfer film of basement membrane laser holographic hum pattern pattern layer side according to Secondary coating is cast into resin film and polyvinyl alcohol water solubility basement membrane, then stripped, winding, original is attached to PET epilamellar radium-shine Holographic information pattern is transferred on polyvinyl alcohol water solubility basement membrane completely, obtains the laser holographic water transfer film;Prepare The basement membrane of laser holographic water transfer film is polyvinyl alcohol water-soluble thin film, and is no longer plastic-based film, the laser holographic of preparation Water transfer film overcomes the prior art using plastic film as basement membrane and only fits, it can be achieved that the transfer of curved surface and various Special-Shaped Surfaces The defects of closing plane transfer, makes laser holographic printed decoration application field be expanded.
The purpose of the present invention is achieved through the following technical solutions.
A kind of preparation process of laser holographic water transfer film, includes the following steps:
(1) covering is moistened entirely in the laser holographic hum pattern pattern layer side using PET as the laser holographic transfer film of basement membrane Water-soluble resin liquid is coated, it is dry, form resin film layer;
(2) the coating polyethylene alcohol solution on resin film layer, it is dry, form polyvinyl alcohol water solubility base membrane layer;
(3) to the film of laser holographic hum pattern pattern layer, resin film layer and polyvinyl alcohol water solubility base membrane layer one into Row is peeled off, and after stripping, original is attached to the epilamellar laser holographic information patterns of PET and is transferred to polyvinyl alcohol water solubility basement membrane completely On, winding, obtains the laser holographic water transfer film.
Further, in step (1), using PET as in the laser holographic transfer film of basement membrane, basement membrane is 30-60 μm of thickness Biaxial tension PET film (BOPET film), the thickness of laser holographic hum pattern pattern layer is 1-2.5 μm.
Further, in step (1), the water-soluble resin liquid includes water-soluble copolymer acrylic resin, water solubility altogether The water-soluble resin liquid of polyacrylamide resin, water-soluble poly maleic acid resin or water soluble polyurethane resin.
Carry out in laser holographic hum pattern pattern layer moistening covering coating film forming entirely using water-soluble resin liquid, selection into Film resin be with the stronger film-forming resin of surface-active, while the film-forming resin selected possess can complete water soluble characteristic, this is Since laser holographic hum pattern pattern layer is relatively thin (1-2.5 μm), pattern texture is careful, if not carried out first using water-soluble resin liquid Complete to moisten covering coating, the polyvinyl alcohol water solution coating subsequently carried out can be then not easy entirely because polyvinyl alcohol water solution viscosity is big The defects of moistening and covering, the polyvinyl alcohol water solubility basement membrane of formation is easily wrapped up in into air or produces bubble because of surface tension, Laser holographic hum pattern pattern layer cannot be transferred on polyvinyl alcohol water solubility basement membrane effectively and completely after causing film forming.
Further, in step (1), the viscosity of the water-soluble resin liquid is 300-1000 centipoises.
Further, in step (1), the solid content of the water-soluble resin liquid is 5-10%.
The water-soluble resin liquid used is low solid content and the water-soluble resin liquid of low viscosity, to ensure resin film layer pair Laser holographic hum pattern pattern layer being sufficiently humidified so as to and covering.
Further, in step (1), the thickness of the resin film layer is 1.5-3.0 μm, after resin film layer is formed, is then It is prepared by the coating that can carry out polyvinyl alcohol water solubility basement membrane.
Further, in step (2), the polyvinyl alcohol in the polyvinyl alcohol water solution is the polyethylene of partial alcoholysis Alcohol, includes the polyvinyl alcohol of model PVA2088, PVA1788, PVA1588 or PVA1388.
Further, in step (2), in the polyvinyl alcohol water solubility, the mass ratio of solute and water is 16-25:84- 75。
Further, in step (2), the solute is counted in parts by weight, including following component:100 parts of polyvinyl alcohol, 0.5-1.0 parts of 5-15 parts of conditioning agent SRTJ4060S, defoamer SRXP811,5-10 parts of polyethers plasticizer CX-3100.
Further, in step (2), the total solids content of the polyvinyl alcohol water solution is 16-25%.
Further, in step (2), the thickness of the polyvinyl alcohol water solubility base membrane layer is 30 μm of 20-.
Further, the laser holographic water transfer film of preparation, from top to bottom, successively including laser holographic information pattern Layer, resin film layer and polyvinyl alcohol water solubility base membrane layer, in laser holographic hum pattern pattern layer embedded resin film layer.
Compared with prior art, the invention has the advantages that and beneficial effect:
The basement membrane of laser holographic water transfer film prepared by preparation process of the present invention is polyvinyl alcohol water-soluble thin film, without It is plastic-based film again, in being transferred applied to laser holographic water, is adapted to the transfer of curved surface and various Special-Shaped Surfaces, overcomes the prior art Using plastic film as basement membrane, it is only suitable for the defects of plane transfer, laser holographic printed decoration application field is expanded.
Brief description of the drawings
Fig. 1 is the preparation process principle schematic of laser holographic water transfer film.
Embodiment
Make further specific detailed description, but this hair to technical solution of the present invention with reference to specific embodiment and attached drawing Bright implementation and protection domain not limited to this.
Existing laser holographic transfer film, structure are from top to bottom, (release including hum pattern pattern layer 1, protective layer successively Layer) 2 and basement membrane 3, the basement membrane 3 used is includes the film of BOPP, PET, biaxially oriented polyester film (BOPET) or PVC, structure Schematic diagram is as shown in Figure 1, be only suitable for plane transfer.
In the specific embodiment of the invention, preparation process principle schematic is as shown in Figure 1, using PET as the radium-shine complete of basement membrane The laser holographic hum pattern pattern layer side of breath transfer film coats successively is cast into resin film and polyvinyl alcohol water solubility basement membrane, then Stripped, winding, makes original be attached to the epilamellar laser holographic information patterns of PET and is transferred to polyvinyl alcohol water solubility basement membrane completely On, the laser holographic water transfer film is obtained, is included the following steps:
(1) using PET as basement membrane laser holographic transfer film (structure from top to bottom, successively including hum pattern pattern layer 1, Protective layer (release layer) 2 and basement membrane 3) laser holographic hum pattern pattern layer side moisten full covering coating water-soluble resin liquid, do It is dry, form resin film layer 4;
(2) the coating polyethylene alcohol solution on resin film layer, it is dry, form polyvinyl alcohol water solubility base membrane layer 5;
(3) to the thin of laser holographic hum pattern pattern layer 1, resin film layer 4 and the one of polyvinyl alcohol water solubility base membrane layer 5 Film is peeled off, and after stripping, original is attached to the epilamellar laser holographic information patterns of PET and is transferred to polyvinyl alcohol water solubility base completely On film, winding, obtains the laser holographic water transfer film;
The laser holographic water transfer film of preparation, from top to bottom, successively including laser holographic hum pattern pattern layer 1, resin film Layer 4 and polyvinyl alcohol water solubility base membrane layer 5, in 1 embedded resin film layer 4 of laser holographic hum pattern pattern layer.
The specific embodiment of the invention is prepared in the technique of laser holographic water transfer film, the radium using PET as basement membrane used Penetrate in hologram transfer film, basement membrane be 30-60 μm of thickness biaxial tension PET film (BOPET film), wide cut 600mm- 1200mm;The thickness of laser holographic hum pattern pattern layer is 2.5 μm of 1-.
Embodiment 1
Laser holographic water transfer film is prepared, raw material includes:
Using PET as basement membrane (thickness:30 μm, wide cut:Laser holographic transfer (print) film 600mm) prepared, laser holographic Information pattern layer thickness is 1 μm);
Water-soluble copolymer acrylic resin liquid (solids content:5%, viscosity is 300 centipoises);
Polyvinyl alcohol water solution (the solid prepared with polyvinyl alcohol 1788 for advocate peace other auxiliary film for additive, auxiliary agent Content:20%), the solute in solution according to the mass fraction, including:1,788 100 parts of polyvinyl alcohol, conditioning agent SRTJ4060S 5 Part, 0.5 part of defoamer SRXP811,3,100 5 parts of polyethers plasticizer CX- (conditioning agent SRTJ4060S, defoamer SRXP811 And polyethers plasticizer CX-3100 is purchased from Guangzhou ten thousand and holds new material Science and Technology Ltd.);In solution, solute and water Mass ratio is 20: 80;
Specific preparation process includes the following steps:
(1) in the laser holographic hum pattern pattern layer side using PET as the laser holographic transfer film of basement membrane, with blade coating mode Full moistening covering coating water-soluble copolymer acrylic resin liquid, it is dry, form the resin film layer that thickness is 1.5 μm;
(2) curtain coating coating polyethylene alcohol solution is carried out using narrow slit coventry type die head coventry on resin film layer, it is dry, it is cold after dry But shape, form the polyvinyl alcohol water solubility base membrane layer that thickness is 20 μm;
(3) it is sent into stripper roll, to laser holographic hum pattern pattern layer, resin film layer and polyvinyl alcohol water solubility base membrane layer The film of one carries out peel separation, and after stripping, original is attached to the epilamellar laser holographic information patterns 100% of PET and shifts completely To polyvinyl alcohol water solubility basement membrane, winding, obtains the laser holographic water transfer film;PET basement membranes are wound at the same time and are recycled.
The laser holographic water using polyvinyl alcohol water soluble film as basement membrane after winding shifts (print) film thickness as 21.5 μm (1 The hum pattern pattern layer of μ m-thick is embedded in the resin film layer of 1.5 μ m-thicks, and gross thickness is 21.5 μm), wide cut 600mm.
Embodiment 2
Laser holographic water transfer film is prepared, raw material includes:
Using PET as basement membrane (thickness:45 μm, wide cut:Laser holographic transfer (print) film 800mm) prepared, laser holographic Information pattern layer thickness is 1.5 μm);
Water-soluble poly maleic acid resin liquid (solids content:8%;Viscosity is 800 centipoises);
Polyvinyl alcohol water solution (the solid prepared with polyvinyl alcohol 1388 for advocate peace other auxiliary film for additive, auxiliary agent Content:25%), the solute in solution according to the mass fraction, including:1,388 100 parts of polyvinyl alcohol, conditioning agent SRTJ4060S 10 parts, 0.6 part of defoamer SRXP811, polyethers plasticizer CX-3100 6 parts of (conditioning agent SRTJ4060S, defoamers SRXP811 and polyethers plasticizer CX- 3100 is purchased from Guangzhou ten thousand and holds new material Science and Technology Ltd.);It is molten in solution The mass ratio of matter and water is 25:75;
Specific preparation process includes the following steps:
(1) in the laser holographic hum pattern pattern layer side using PET as the laser holographic transfer film of basement membrane, with blade coating mode Full moistening covering coating water-soluble poly maleic acid resin liquid, it is dry, form the resin film layer that thickness is 2.0 μm;
(2) curtain coating coating polyethylene alcohol solution is carried out using narrow slit coventry type die head coventry on resin film layer, it is dry, it is cold after dry But shape, form the polyvinyl alcohol water solubility base membrane layer that thickness is 25 μm;
(3) it is sent into stripper roll, to laser holographic hum pattern pattern layer, resin film layer and polyvinyl alcohol water solubility base membrane layer The film of one carries out peel separation, and after stripping, original is attached to the epilamellar laser holographic information patterns 100% of PET and shifts completely To polyvinyl alcohol water solubility basement membrane, winding, obtains the laser holographic water transfer film;PET basement membranes are wound at the same time and are recycled.
The laser holographic water using polyvinyl alcohol water soluble film as basement membrane after winding shifts (print) film thickness as 27 μm, wide Width 800mm.
Embodiment 3
Laser holographic water transfer film is prepared, raw material includes:
Using PET as basement membrane (thickness:60μm;Wide cut:Laser holographic transfer (print) film 1000mm) prepared;It is radium-shine complete It is 2.5 μm to cease information pattern layer thickness);
Water soluble polyurethane resin liquid (solids content:10%;Viscosity is 1000 centipoises);
Polyvinyl alcohol water solution (the solid prepared with polyvinyl alcohol 1588 for advocate peace other auxiliary film for additive, auxiliary agent Content:23%), the solute in solution according to the mass fraction, including:1,588 100 parts of polyvinyl alcohol, conditioning agent SRTJ4060S 12 parts, 0.8 part of defoamer SRXP811, polyethers plasticizer CX-3100 8 parts of (conditioning agent SRTJ4060S, defoamers SRXP811 and polyethers plasticizer CX- 3100 is purchased from Guangzhou ten thousand and holds new material Science and Technology Ltd.);It is molten in solution The mass ratio of matter and water is 23:77;
Specific preparation process includes the following steps:
(1) in the laser holographic hum pattern pattern layer side using PET as the laser holographic transfer film of basement membrane, with blade coating mode Full moistening covering coating water soluble polyurethane resin liquid, it is dry, form the resin film layer that thickness is 3.0 μm;
(2) curtain coating coating polyethylene alcohol solution is carried out using narrow slit coventry type die head coventry on resin film layer, it is dry, it is cold after dry But shape, form the polyvinyl alcohol water solubility base membrane layer that thickness is 30 μm;
(3) it is sent into stripper roll, to laser holographic hum pattern pattern layer, resin film layer and polyvinyl alcohol water solubility base membrane layer The film of one carries out peel separation, and after stripping, original is attached to the epilamellar laser holographic information patterns 100% of PET and shifts completely To polyvinyl alcohol water solubility basement membrane, winding, obtains the laser holographic water transfer film;PET basement membranes are wound at the same time and are recycled.
The laser holographic water using polyvinyl alcohol water soluble film as basement membrane after winding shifts (print) film thickness as 33 μm, wide Width 1200mm.
Embodiment 4
Laser holographic water transfer film is prepared, raw material includes:
Using PET as basement membrane (thickness:40μm;Wide cut:Laser holographic transfer (print) film 1000mm) prepared;It is radium-shine complete It is 2.0 μm to cease information pattern layer thickness);
Water-soluble poly maleic acid resin liquid (solids content:6%;Viscosity is 1000 centipoises);
Polyvinyl alcohol water solution (the solid prepared with polyvinyl alcohol 2088 for advocate peace other auxiliary film for additive, auxiliary agent Content:16%), the solute in solution according to the mass fraction, including:2,088 100 parts of polyvinyl alcohol, conditioning agent SRTJ4060S 15 parts, 1.0 parts of defoamer SRXP811, polyethers plasticizer CX-3100 10 parts of (conditioning agent SRTJ4060S, defoamers SRXP811 and polyethers plasticizer CX- 3100 is purchased from Guangzhou ten thousand and holds new material Science and Technology Ltd.);It is molten in solution The mass ratio of matter and water is 16:84;
Specific preparation process includes the following steps:
(1) in the laser holographic hum pattern pattern layer side using PET as the laser holographic transfer film of basement membrane, with blade coating mode Full moistening covering coating water soluble polyurethane resin liquid, it is dry, form the resin film layer that thickness is 2.5 μm;
(2) curtain coating coating polyethylene alcohol solution is carried out using narrow slit coventry type die head coventry on resin film layer, it is dry, it is cold after dry But shape, form the polyvinyl alcohol water solubility base membrane layer that thickness is 28 μm;
(3) it is sent into stripper roll, to laser holographic hum pattern pattern layer, resin film layer and polyvinyl alcohol water solubility base membrane layer The film of one carries out peel separation, and after stripping, original is attached to the epilamellar laser holographic information patterns 100% of PET and shifts completely To polyvinyl alcohol water solubility basement membrane, winding, obtains the laser holographic water transfer film;PET basement membranes are wound at the same time and are recycled.
The laser holographic water using polyvinyl alcohol water soluble film as basement membrane after winding shifts (print) film thickness as 30.5 μm, Wide cut 1000mm.
Above example is only preferrred embodiment of the present invention, is only used for explaining the present invention, is not intended to limit the present invention, this Field technology personnel without departing from spirit of the invention with made under principle any change, replacement, combine, simplification, modification Deng should be equivalent substitute mode, should be included within the scope of the present invention.

Claims (10)

1. a kind of preparation process of laser holographic water transfer film, it is characterised in that include the following steps:
(1)Covering coating is moistened entirely in the laser holographic hum pattern pattern layer side using PET as the laser holographic transfer film of basement membrane Water-soluble resin liquid, it is dry, form resin film layer;
(2)The coating polyethylene alcohol solution on resin film layer, it is dry, form polyvinyl alcohol water solubility base membrane layer;
(3)The film of laser holographic hum pattern pattern layer, resin film layer and polyvinyl alcohol water solubility base membrane layer one is shelled From winding, obtains the laser holographic water transfer film.
2. preparation process according to claim 1, it is characterised in that step(1)In, the laser holographic using PET as basement membrane In transfer film, basement membrane is the biaxial tension PET film of 30-60 μm of thickness, and the thickness of laser holographic hum pattern pattern layer is 1-2.5 µm。
3. preparation process according to claim 1, it is characterised in that step(1)In, the water-soluble resin liquid includes water Dissolubility co-polypropylene acid resin, water-soluble copolymer acrylamide resin, water-soluble poly maleic acid resin or soluble polyurethane tree The water-soluble resin liquid of fat.
4. preparation process according to claim 1, it is characterised in that step(1)In, the viscosity of the water-soluble resin liquid For 300-1000 centipoises.
5. preparation process according to claim 1, it is characterised in that step(1)In, the consolidating for water-soluble resin liquid contains Measure as 5-10%.
6. preparation process according to claim 1, it is characterised in that step(1)In, the thickness of the resin film layer is 1.5-3.0µm。
7. preparation process according to claim 1, it is characterised in that step(2)In, in the polyvinyl alcohol water solution, The mass ratio of solute and water is 16-25:84-75;The solute is counted in parts by weight, including following component:Polyvinyl alcohol 100 Part, 0.5-1.0 parts of 5-15 parts of conditioning agent SRTJ4060S, defoamer SRXP811, polyethers plasticizer CX-3100 5-10 Part.
8. preparation process according to claim 1, it is characterised in that step(2)In, in the polyvinyl alcohol water solution Polyvinyl alcohol is the polyvinyl alcohol of partial alcoholysis, includes the poly- second of model PVA2088, PVA1788, PVA1588 or PVA1388 Enol.
9. preparation process according to claim 1, it is characterised in that step(2)In, the polyvinyl alcohol water solubility basement membrane The thickness of layer is 20-30 μm.
10. preparation process according to claim 1, it is characterised in that the laser holographic water transfer film of preparation, by up to Under, successively including laser holographic hum pattern pattern layer, resin film layer and polyvinyl alcohol water solubility base membrane layer, laser holographic hum pattern In pattern layer embedded resin film layer.
CN201711180535.1A 2017-11-23 2017-11-23 A kind of preparation method of laser holographic water transfer film Pending CN108001063A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109591409A (en) * 2018-11-07 2019-04-09 深圳市深大极光科技有限公司 Film anti-fake material and preparation method
CN112026392A (en) * 2020-09-02 2020-12-04 明德新材料科技(浙江)股份有限公司 Texture segmentation method of water transfer printing pattern

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Publication number Priority date Publication date Assignee Title
CN101100144A (en) * 2007-07-23 2008-01-09 深圳劲嘉彩印集团股份有限公司 Moulded holographic graphics and text positioning transfer printing machine
CN103009857A (en) * 2012-12-21 2013-04-03 武汉虹之彩包装印刷有限公司 Electric aluminum sheet up to quality safety performance standard
CN106541723A (en) * 2016-11-02 2017-03-29 苏州万德福尔新材料有限公司 A kind of water transfer laser film and preparation method thereof
CN107268280A (en) * 2017-06-10 2017-10-20 烟台博源科技材料股份有限公司 A kind of non-woven fabric and its production technology

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101100144A (en) * 2007-07-23 2008-01-09 深圳劲嘉彩印集团股份有限公司 Moulded holographic graphics and text positioning transfer printing machine
CN103009857A (en) * 2012-12-21 2013-04-03 武汉虹之彩包装印刷有限公司 Electric aluminum sheet up to quality safety performance standard
CN106541723A (en) * 2016-11-02 2017-03-29 苏州万德福尔新材料有限公司 A kind of water transfer laser film and preparation method thereof
CN107268280A (en) * 2017-06-10 2017-10-20 烟台博源科技材料股份有限公司 A kind of non-woven fabric and its production technology

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109591409A (en) * 2018-11-07 2019-04-09 深圳市深大极光科技有限公司 Film anti-fake material and preparation method
CN112026392A (en) * 2020-09-02 2020-12-04 明德新材料科技(浙江)股份有限公司 Texture segmentation method of water transfer printing pattern

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