CN107987631A - Anti- sagging high transparency aqueous double-component coating filler and preparation method thereof - Google Patents
Anti- sagging high transparency aqueous double-component coating filler and preparation method thereof Download PDFInfo
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- CN107987631A CN107987631A CN201711139969.7A CN201711139969A CN107987631A CN 107987631 A CN107987631 A CN 107987631A CN 201711139969 A CN201711139969 A CN 201711139969A CN 107987631 A CN107987631 A CN 107987631A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/34—Filling pastes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/10—Transparent films; Clear coatings; Transparent materials
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- Chemical & Material Sciences (AREA)
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- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
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Abstract
The preparation method of anti-sagging high transparency aqueous double-component coating filler, is made of, the raw material mass mixture ratio of the component A is component A and anion-modified HDI polyisocyanates:Water-based emulsion 40 50%, dispersant 0.5 1.5%, wetting agent 0.2 0.5%, defoamer 0.2 0.5%, slow curing water 10 15%, mould inhibitor 0.1 0.2%, deionized water 5 10%, functional filler 40 50%, bentonite 0.1 1%, thickener 0.1 1.0%.Solve existing filler drying time length, hardness is low, easily sink, poor adhesive force the problems such as, fillibility is good, good toughness, to base material good seal, adhesive force is good, good toughness, and hardness is high, transparency is good, good film-forming property, not bleeding, grinability is good, without harmful components, safety and environmental protection, carrying at the same time to coating is strong, can be widely used for the filling of woodcare paint depth conduit.
Description
Technical field
The invention belongs to the Application in Chemical Engineering technical field of IPC classification C09D Coating material composition raw materials, is related to aqueous wooden ware painting
Expect improved technology, especially anti-sagging high transparency aqueous double-component coating filler and preparation method thereof.
Background technology
With low-carbon environment-friendly economic development, it is desirable to which environment-friendlywater-based water-based paint possesses safe and environment-friendly, convenient construction spy
Property.Water paint is exactly using coating of the water as diluent, without organic solvent, without benzene,toluene,xylene, formaldehyde, free TDI
Toxic heavy metal, nontoxic non-stimulated smell is harmless, free from environmental pollution, paint film is plentiful, it is sparkling and crystal-clear it is bright, pliability is good simultaneously
And there is water-fast, wear-resisting, ageing-resistant, color inhibition, fast drying, easy to use.It may be used at:Woodenware, metal, plastics,
During glass, building surface etc. are more in material.Start water paint by masses not approved, always protected for this new product people
There is very big suspection attitude, often there is producer to add organic solvent or diluent such as gasoline, dimethylbenzene, banana oil in water paint using initial stage
Cause many unnecessary troubles.
It is disclosed in the prior art to have a kind of double-composition polyurethane waterproof paint, it is a kind of two-component reaction-curable high score
Sub- water-repellent paint, wherein first component are the isocyanate-terminated performed polymers obtained by polyethers and isocyanates polycondensation, second component
The colored liquid being made of reinforcing agent, plasticizer, thickener, coagulant.In use, by the first and second components according to a certain percentage
Mix, after stirring evenly, brush in the substrate surface constructed of needs, it is reacted to be formed by curing high resilience, it is tough and tensile again
There is the waterproof coating of durability.In practice of construction, the mixing ratio of component A and component B often has necessarily with the requirement of producer
Deviation, in this test, when deliberately testing positive and negative 20% hardener dose deviation, the influence to coating property.Research hair
Existing, the paint film property of double-component waterborne polyurethane can't be produced because of the deviation of hardener dose significantly to be changed, this master
Have benefited from when being formulated design, the equivalent proportion of NCO/OH meets or exceeds 1.5:1, thus 20% hardener dose ought be added less
When, OH groups still can fully react, and when curing agent excess 20%, unnecessary curing agent can be into one with water reaction generation polyureas
Step enhancing performance.
Chinese patent application 201310123245.9 is more particularly to water-based high filling white coating.The water-based high filling is white
Color coating, including following raw material:150~300 parts of water-base resin, 22~60 parts of coalescents, titanium dioxide 60~150,
100~250 parts of talcum powder, 280~350 parts of filler, 100~300 parts of deionized water, 2 parts of pH adjusting agent, 2~4 parts of preservative,
Water-based 6~10 parts of wetting dispersing agent, 3~8 parts of aqueous defoamer, 4~10 parts of water-based thickener.
Chinese patent application 201310288625.8, which is related to, contains the high-grade water paint that titanium dioxide is used as filler material.
Including titanium dioxide filler material, the titanium dioxide filler material for titanium dioxide and glutinous rice flour mixture, the titanium dioxide filler material by
The 1%-50% titanium dioxides of quality meter and the glutinous rice flour of surplus form.Using above-mentioned technical proposal, glutinous rice flour and carbon in formula
Sour calcium, quick lime are used in mixed way, and generation is a kind of organic --- inorganic composite materials.
Chinese patent application 201710506736.X discloses a kind of hydrophobically modified nano barium sulfate filling aqueous polyurethane
The preparation method of coating, by nano barium sulfate powder, obtains chitosan molecular film after being wrapped up with chitosan colloidal sol
Coating modification nano barium sulfate, carries out intercalation and obtains polyether-tribasic alcohol N330 intercalation modifying nanometers after being mixed with polyether-tribasic alcohol N330
Barium sulfate compound, is main synthesis material together with methyl diphenylene diisocyanate, synthesizes Waterborne Polyurethane Prepolymer,
After addition crosslinking agent is crosslinked in infrared drying oven, carries out emulsion dispersion and form coating, coating of the invention has preferable
Actual application value, it may have good hydrophobic performance, suitable for building, decorating, purposes and the preparation method such as industry manufacture,
Its process conditions is simple, easy to operate, easily realizes.
However, when doing totally-enclosed effect for some deep conduits, when aqueous product is constructed relative to oil product, still suffer from
More deficiency, such as construction pass are more, and lacquer painting is soft, and transparency is low, easily collapses.
The content of the invention
The object of the present invention is to provide anti-sagging high transparency aqueous double-component coating filler and preparation method thereof, depth is being done
Conduit, during totally-enclosed effect, can fill that conduit, transparency are high, hardness is high, are not easy to collapse and easily construct well.
The purpose of the present invention will be realized by following technical measures:By component A and anion-modified HDI polyisocyanates
Composition, the raw material proportioning of the component A are:
Project | Mass percent/% |
Water-based emulsion | 40-50 |
Dispersant | 0.5-1.5 |
Wetting agent | 0.2-0.5 |
Defoamer | 0.2-0.5 |
Slow curing water | 10-15 |
Mould inhibitor | 0.1-0.2 |
Deionized water | 5-10 |
Functional filler | 40-50 |
Bentonite | 0.1-1 |
Thickener | 0.1-1.0 |
Filler preparation method, comprises the following steps:A. calculate by weight, water-based emulsion is added into container, in 800 revolutions per minute
Under the mixing speed of clock, dispersant, defoamer, wetting agent, mould inhibitor, slow curing water, deionized water are sequentially added;Stir evenly,
Adding functional filler, bentonite improves rotating speed, high speed dispersion 30 minutes, and after fineness qualification, viscosity is adjusted with thickener,
It is uniformly dispersed, component A is obtained by filtration;By component A:Anion-modified HDI polyisocyanates=1:0.1 quality proportioning allotment
Uniformly, that is, finished product is obtained.
Especially, comprise the following steps:A, by weight, 40 parts of water-based hydroxyl lotion is added into container, in 800r/
Min is sequentially added, dispersant, that is, 0.8 part of Bi Ke BYK190, wetting agent, that is, 0.2 part of Bi Ke BYK3455, mould inhibitor, that is, Troy
0.1 part of K20, defoamer, that is, 0.2 part of Bi Ke BYK024, slow curing water, that is, 10 parts of propane diols, 7.4 parts of deionized water, stirs evenly,
Add i.e. permanent 42 parts of the exhibition new material HZ-1009 acrylic resins powder of functional filler, bentonite, that is, Lockwood
0.6 part of LaponiteRDS, thickener, that is, 0.7 part of bright icepro PUR40, is obtained by filtration component A;B, by component A:Anion HDI is more
Isocyanates=1:0.1 quality proportioning allotment is uniform, obtains finished product.
Especially, comprise the following steps:A, by weight, 40 parts of water-based hydroxyl lotion is added into container, in 800r/
Min is sequentially added, and dispersant, that is, DOW Chemical is special good scattered easy 0.8 part fast, wetting agent, that is, 0.2 part of Bi Ke BYK3455, mould inhibitor
That is 0.1 part of Troy K20, defoamer, that is, 0.2 part of Bi Ke BYK024, slow curing water, that is, 10 parts of DOW Chemical propane diols, deionization
7.4 parts of water, stirs evenly, and adds i.e. permanent 42 parts of the exhibition new material HZ-1009 acrylic resins powder of functional filler, and bentonite is
0.6 part of Lockwood LaponiteRDS, thickener, that is, 0.7 part of bright icepro PUR40, is obtained by filtration component A;B, by component A:It is cloudy
IONS OF H DI polyisocyanates=1:0.1 quality proportioning allotment is uniform, that is, obtains finished product.
Especially, comprise the following steps:A, by weight, 40 parts of water-based hydroxyl lotion is added into container, in 800r/
Min is sequentially added, and dispersant, that is, DOW Chemical is special good scattered easy 0.8 part fast, wetting agent, that is, 0.2 part of Bi Ke BYK3455, mould inhibitor
That is 0.1 part of Troy K20,0.2 part of the high tego810 of defoamer, that is, enlightening, slow curing water, that is, 10 parts of DOW Chemical propane diols, deionization
7.4 parts of water, stirs evenly, and adds i.e. permanent 42 parts of the exhibition new material HZ-1009 acrylic resins powder of functional filler, bentonite Lip river
Gram 0.6 part of Wood LaponiteRDS, thickener, that is, 0.7 part of bright icepro PUR40, is obtained by filtration component A;B, by component A:It is cloudy from
Sub- HDI polyisocyanates=1:0.1 quality proportioning allotment is uniform, that is, obtains finished product.
Especially, auxiliary agent is formed by dispersant, defoamer, wetting agent, thickener, bentonite, mould inhibitor;By accounting for coating institute
With the mass percent meter of whole raw materials, the dosage of each raw material in the auxiliary agent is:Dispersant 0.5~1.5;Defoamer 0.2
~0.5;Wetting agent 0.2~0.5;Antiseptic 0.1~0.2, bentonite 0.1~1.0;Thickener 0.1~1.0.
Advantages of the present invention and effect:Chemical crosslink reaction is passed through using hydroxyl acrylic emulsion and polyisocyanates, it is raw
Into a kind of high performance polyether polyols, solves existing filler drying time length, hardness is low, easily sink, adhesive force
The problems such as poor, to ensure that coating has long-time stability.Fillibility is good, good toughness, and to base material good seal, adhesive force is good, toughness
Good, hardness is high, and transparency is good, good film-forming property, not bleeding, and grinability is good, without harmful components, safety and environmental protection, while to coating
Carrying it is strong, the construction requirement easy for construction for meeting practical operation, can be widely used for the filling of woodcare paint depth conduit.
Main performance test index includes:State parameter in a reservoir, is thick liquid after stirring evenly;Appearance of film, normally;
Application property, applies accessible;Bin stability (50 DEG C/7d), it is without exception;Grinability, easily polishing;Adhesive force (draw compartment away from
2mm)≤1 grade;Water resistance is without exception;Pencil hardness 2H.
Embodiment
The principle of the invention is, is made of component A and anion-modified HDI polyisocyanates, and the raw material of the component A is matched somebody with somebody
Than for:
Project | Mass percent/% |
Water-based emulsion | 40-50 |
Dispersant | 0.5-1.5 |
Wetting agent | 0.2-0.5 |
Defoamer | 0.2-0.5 |
Slow curing water | 10-15 |
Mould inhibitor | 0.1-0.2 |
Deionized water | 5-10 |
Functional filler | 40-50 |
Bentonite | 0.1-1 |
Thickener | 0.1-1.0 |
Filler preparation method, comprises the following steps:A. calculate by weight, water-based emulsion is added into container, 800
Rpm mixing speed under, sequentially add dispersant, defoamer, wetting agent, mould inhibitor, slow curing water, deionized water;Stirring
Uniformly, functional filler is added, bentonite improves rotating speed, high speed dispersion 30 minutes, after fineness qualification, is adjusted with thickener
Viscosity, is uniformly dispersed, and component A is obtained by filtration;By component A:Anion-modified HDI polyisocyanates=1:0.1 quality proportioning
Allotment is uniform, that is, obtains finished product.
With reference to embodiment, the invention will be further described.
Embodiment 1:A kind of filler preparation method, comprises the following steps:
A, by weight, 40 parts of water-based hydroxyl lotion is added into container, is sequentially added in 800r/min, dispersant is finished
Gram 0.8 part of BYK190, wetting agent, that is, 0.2 part of Bi Ke BYK3455, mould inhibitor, that is, 0.1 part of Troy K20, defoamer are finished
Gram 0.2 part of BYK024, slow curing water, that is, 10 parts of propane diols, 7.4 parts of deionized water, stirs evenly, and it is i.e. permanent to add functional filler
Open up 42 parts of new material HZ-1009 acrylic resins powder, bentonite, that is, 0.6 part of Lockwood LaponiteRDS, thickener, that is, bright
0.7 part of PUR40 is insulted, component A is obtained by filtration.
B, by component A:Anion HDI polyisocyanates=1:0.1 quality proportioning allotment is uniform, obtains finished product.
Main performance test index is as follows:
Test event | Test result |
State parameter in a reservoir | It is thick liquid after stirring evenly |
Appearance of film | Normally |
Application property | Apply accessible |
Bin stability (50 DEG C/7d) | It is without exception |
Grinability | Easily polishing |
Adhesive force (draws compartment away from 2mm) | ≤ 1 grade |
Water resistance | It is without exception |
Pencil hardness | 2H |
Embodiment 2:A kind of filler preparation method, comprises the following steps:
A, by weight, 40 parts of water-based hydroxyl lotion is added into container, is sequentially added in 800r/min, dispersant is made pottery
Family name's chemistry is special good scattered easy 0.8 part fast, wetting agent, that is, 0.2 part of Bi Ke BYK3455, mould inhibitor, that is, 0.1 part of Troy K20, defoaming
Agent, that is, 0.2 part of Bi Ke BYK024, slow curing water, that is, 10 parts of DOW Chemical propane diols, 7.4 parts of deionized water, stirs evenly, then adds
Enter i.e. permanent 42 parts of the exhibition new material HZ-1009 acrylic resins powder of functional filler, bentonite, that is, Lockwood LaponiteRDS
0.6 part, thickener, that is, 0.7 part of bright icepro PUR40, is obtained by filtration component A.
B, by component A:Anion HDI polyisocyanates=1:0.1 quality proportioning allotment is uniform, that is, obtains finished product.
Main performance test index is as follows:
Test event | Test result |
State parameter in a reservoir | It is thick liquid after stirring evenly |
Appearance of film | Normally |
Application property | Apply accessible |
Bin stability (50 DEG C/7d) | It is without exception |
Grinability | Easily polishing |
Adhesive force (draws compartment away from 2mm) | ≤ 1 grade |
Water resistance | It is without exception |
Pencil hardness | 2H |
Embodiment 3:A kind of filler preparation method, comprises the following steps:
A, by weight, 40 parts of water-based hydroxyl lotion is added into container, is sequentially added in 800r/min, dispersant is made pottery
Family name's chemistry is special good scattered easy 0.8 part fast, wetting agent, that is, 0.2 part of Bi Ke BYK3455, mould inhibitor, that is, 0.1 part of Troy K20, defoaming
0.2 part of the high tego810 of agent, that is, enlightening, slow curing water, that is, 10 parts of DOW Chemical propane diols, 7.4 parts of deionized water, stirs evenly, then adds
Enter i.e. permanent 42 parts of the exhibition new material HZ-1009 acrylic resins powder of functional filler, bentonite Lockwood LaponiteRDS 0.6
Part, thickener, that is, 0.7 part of bright icepro PUR40, is obtained by filtration component A.
B, by component A:Anion HDI polyisocyanates=1:0.1 quality proportioning allotment is uniform, that is, obtains finished product.
Main performance test index is as follows:
Test event | Test result |
State parameter in a reservoir | It is thick liquid after stirring evenly |
Appearance of film | Normally |
Application property | Apply accessible |
Bin stability (50 DEG C/7d) | It is without exception |
Grinability | Easily polishing |
Adhesive force (draws compartment away from 2mm) | ≤ 1 grade |
Water resistance | It is without exception |
Pencil hardness | 2H |
In the embodiment of the present invention, in coating component A:The hydroxyl group of water-based emulsion be able to can be improved with isocyanates reaction
Adhesive force, improves toughness, hardness, transparency and film forming, while strengthens the load-carrying properties to powder, increases paint film property hardness
And water resistance.Functional filler requirement, filling capacity is good, and the refractive index of refractive index and water-base resin is very close to so guarantee
Transparency, while hardness is high.
In the embodiment of the present invention, auxiliary agent is formed by dispersant, defoamer, wetting agent, thickener, bentonite, mould inhibitor;Press
Account for used in coating the mass percent meter of whole raw materials, the dosage of each raw material in the auxiliary agent is:Dispersant 0.5~1.5;
Defoamer 0.2~0.5;Wetting agent 0.2~0.5;Antiseptic 0.1~0.2, bentonite 0.1~1.0;Thickener 0.1~1.0.Its
In, dispersant is Bi Ke dispersants or Tao Shi dispersants;Defoamer is Bi Ke defoamers and Di Gao defoamers;Wetting agent is Bi Ke
Chemical company's wetting agent;Thickener is the thickener of bright icepro;Bentonite is Lockwood;Antimildew and antibacterial agent is the limited public affairs of Tuo Luoyi
The mould inhibitor of department.
In the present invention, filler can fill timber depth conduit, realize totally-enclosed effect.The preparation method of filler, prepares
Simply, it is easy to construct.
Claims (5)
1. the preparation method of anti-sagging high transparency aqueous double-component coating filler, it is characterised in that changed by component A and anion
Property HDI polyisocyanates composition, the raw material proportioning of the component A is:
Filler preparation method, comprises the following steps:A. calculate by weight, water-based emulsion is added into container, in 800 revolutions per minute
Under the mixing speed of clock, dispersant, defoamer, wetting agent, mould inhibitor, slow curing water, deionized water are sequentially added;Stir evenly,
Adding functional filler, bentonite improves rotating speed, high speed dispersion 30 minutes, and after fineness qualification, viscosity is adjusted with thickener,
It is uniformly dispersed, component A is obtained by filtration;By component A:Anion-modified HDI polyisocyanates=1:0.1 quality proportioning allotment is equal
It is even, that is, obtain finished product.
2. the preparation method of anti-sagging high transparency aqueous double-component coating filler as claimed in claim 1, it is characterised in that
Comprise the following steps:A, by weight, 40 parts of water-based hydroxyl lotion is added into container, is sequentially added in 800r/min, is disperseed
Agent, that is, 0.8 part of Bi Ke BYK190, wetting agent, that is, 0.2 part of Bi Ke BYK3455, mould inhibitor, that is, 0.1 part of Troy K20, defoamer
That is 0.2 part of Bi Ke BYK024, slow curing water, that is, 10 parts of propane diols, 7.4 parts of deionized water, stirs evenly, adds functional filler
I.e. permanent 42 parts of exhibition new material HZ-1009 acrylic resins powder, bentonite, that is, 0.6 part of Lockwood LaponiteRDS, thickener
I.e. bright 0.7 part of icepro PUR40, is obtained by filtration component A;B, by component A:Anion HDI polyisocyanates=1:0.1 quality is matched somebody with somebody
It is more uniform than allocating, obtain finished product.
3. the preparation method of anti-sagging high transparency aqueous double-component coating filler as claimed in claim 1, it is characterised in that
Comprise the following steps:A, by weight, 40 parts of water-based hydroxyl lotion is added into container, is sequentially added in 800r/min, is disperseed
Agent, that is, DOW Chemical is special good scattered easy 0.8 part fast, wetting agent, that is, 0.2 part of Bi Ke BYK3455, mould inhibitor, that is, Troy K20 0.1
Part, defoamer, that is, 0.2 part of Bi Ke BYK024, slow curing water, that is, 10 parts of DOW Chemical propane diols, 7.4 parts of deionized water, stirring is
It is even, add i.e. permanent 42 parts of the exhibition new material HZ-1009 acrylic resins powder of functional filler, bentonite, that is, Lockwood
0.6 part of LaponiteRDS, thickener, that is, 0.7 part of bright icepro PUR40, is obtained by filtration component A;B, by component A:Anion HDI is more
Isocyanates=1:0.1 quality proportioning allotment is uniform, that is, obtains finished product.
4. the preparation method of anti-sagging high transparency aqueous double-component coating filler as claimed in claim 1, it is characterised in that
Comprise the following steps:A, by weight, 40 parts of water-based hydroxyl lotion is added into container, is sequentially added in 800r/min, is disperseed
Agent, that is, DOW Chemical is special good scattered easy 0.8 part fast, wetting agent, that is, 0.2 part of Bi Ke BYK3455, mould inhibitor, that is, Troy K20 0.1
Part, 0.2 part of the high tego810 of defoamer, that is, enlightening, slow curing water, that is, 10 parts of DOW Chemical propane diols, 7.4 parts of deionized water, stirring is
It is even, add i.e. permanent 42 parts of the exhibition new material HZ-1009 acrylic resins powder of functional filler, bentonite Lockwood
0.6 part of LaponiteRDS, thickener, that is, 0.7 part of bright icepro PUR40, is obtained by filtration component A;B, by component A:Anion HDI is more
Isocyanates=1:0.1 quality proportioning allotment is uniform, that is, obtains finished product.
5. the preparation method of anti-sagging high transparency aqueous double-component coating filler as claimed in claim 1, it is characterised in that
Auxiliary agent is formed by dispersant, defoamer, wetting agent, thickener, bentonite, mould inhibitor;The matter of whole raw materials as used in accounting for coating
Percentages are measured, the dosage of each raw material in the auxiliary agent is:Dispersant 0.5~1.5;Defoamer 0.2~0.5;Wetting agent 0.2
~0.5;Antiseptic 0.1~0.2, bentonite 0.1~1.0;Thickener 0.1~1.0.
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Cited By (5)
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CN109554084A (en) * | 2018-11-06 | 2019-04-02 | 青岛展辰新材料有限公司 | A kind of transparent woodenware filler of high fillibility and preparation method thereof |
CN109929423A (en) * | 2019-03-06 | 2019-06-25 | 上海君子兰新材料股份有限公司 | Aqueous double-component woodware white paint for kitchen use |
CN110922806A (en) * | 2019-11-20 | 2020-03-27 | 上海巴德士化工新材料有限公司 | Water-based high-transparency filler for woodware and preparation method thereof |
CN114015337A (en) * | 2021-11-16 | 2022-02-08 | 赣州市博品家具有限公司 | Anti-collapse high-filling water-based woodware transparent primer and preparation method thereof |
CN114574025A (en) * | 2022-02-25 | 2022-06-03 | 维新制漆(江西)有限公司 | High-filling high-transparency two-component water-based putty and preparation method thereof |
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CN103360851A (en) * | 2012-03-30 | 2013-10-23 | 唐述华 | Development method of novel water-based timber rubbling coloring agent |
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