CN107938007A - The system and method for PTFE staple fibers is prepared using different molecular weight material - Google Patents

The system and method for PTFE staple fibers is prepared using different molecular weight material Download PDF

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Publication number
CN107938007A
CN107938007A CN201810004530.1A CN201810004530A CN107938007A CN 107938007 A CN107938007 A CN 107938007A CN 201810004530 A CN201810004530 A CN 201810004530A CN 107938007 A CN107938007 A CN 107938007A
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China
Prior art keywords
oriented film
staple fibers
different molecular
cavity volume
ptfe
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Pending
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CN201810004530.1A
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Chinese (zh)
Inventor
黄斌香
顾榴俊
金福忠
孙玲玲
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Jiangsu Jinyou New Material Co Ltd
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Jiangsu Jinyou New Material Co Ltd
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Priority to CN201810004530.1A priority Critical patent/CN107938007A/en
Publication of CN107938007A publication Critical patent/CN107938007A/en
Pending legal-status Critical Current

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    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D13/00Complete machines for producing artificial threads
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D1/00Treatment of filament-forming or like material
    • D01D1/04Melting filament-forming substances
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D1/00Treatment of filament-forming or like material
    • D01D1/06Feeding liquid to the spinning head
    • D01D1/065Addition and mixing of substances to the spinning solution or to the melt; Homogenising
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D11/00Other features of manufacture
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/42Formation of filaments, threads, or the like by cutting films into narrow ribbons or filaments or by fibrillation of films or filaments
    • D01D5/426Formation of filaments, threads, or the like by cutting films into narrow ribbons or filaments or by fibrillation of films or filaments by cutting films
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D7/00Collecting the newly-spun products
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01GPRELIMINARY TREATMENT OF FIBRES, e.g. FOR SPINNING
    • D01G1/00Severing continuous filaments or long fibres, e.g. stapling
    • D01G1/02Severing continuous filaments or long fibres, e.g. stapling to form staple fibres not delivered in strand form
    • D01G1/04Severing continuous filaments or long fibres, e.g. stapling to form staple fibres not delivered in strand form by cutting
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2321/00Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D10B2321/04Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polymers of halogenated hydrocarbons
    • D10B2321/042Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polymers of halogenated hydrocarbons polymers of fluorinated hydrocarbons, e.g. polytetrafluoroethene [PTFE]

Abstract

The invention discloses a kind of system and method that PTFE staple fibers are prepared using different molecular weight material, including sintering extrusion device, further includes mixed stirring device and acupuncture comb cuts device;The mixed stirring device is connected with sintering the feeding end of extrusion device, including:Cavity volume, the first feed pipe, the second feed pipe, motor, blender and discharge nozzle, first feed pipe and the second feed pipe are connected with cavity volume respectively, and blender is arranged in cavity volume, and motor is arranged on the top of cavity volume, and be connected with the blender in cavity volume, discharge nozzle is connected with cavity volume;The acupuncture comb, which cuts device, to be included:The road after the discharge end of sintering extrusion device, to unreel the oriented film unwinding device of oriented film, and is set in turn in puncture needle rod, cutting device, buncher, traversing gear and wrap-up behind oriented film unwinding device.The present invention can improve the production efficiency of PTFE staple fibers, the PTFE staple fibers for reducing cost, producing mass higher.

Description

The system and method for PTFE staple fibers is prepared using different molecular weight material
Technical field
The present invention relates to the preparation of PTFE staple fibers, is prepared more specifically to one kind using different molecular weight material The system and method for PTFE staple fibers.
Background technology
Polytetrafluoroethylene (PTFE) (PTFE) is unrivaled excellent with the other plastics of high temperature resistant, acid-alkali-corrosive-resisting, hydrolysis etc. Point, is made into staple fiber and can be made into high temperature resistance filtration material, the corrosion-resistant filtrate of chemical and medicine industry industry, PTFE non-woven fabrics etc., more To be widely used more.
The method of currently manufactured PTFE staple fibers has two kinds, the first is melt spinning method, due under PTFE molten conditions Mobility it is very poor, so cannot use common melt spinning method manufacture staple fiber.But use special method, i.e., it is logical Viscose glue is crossed as carrier, viscose glue melting lotion is mixed with the lotion that PTFE disperses and is integrated, then extruding spinning, then pass through height Temperature thermally decomposes adhesive component, retains PTFE components and becomes PTFE staple fibers, since viscose glue is always had by high temperature thermal decomposition Small ashes are remained in PTFE staple fibers, and are in coke yellow, so, method can only produce auburn short fibre in this Dimension.This manufacture method invests big, of high cost, complex process, and the staple strength produced is low, brown, and staple fiber should With being restricted.
The method of second of manufacture PTFE staple fiber is that film splits method, and exactly first PTFE dispersion resins are made with certain strong Length (longitudinal direction) direction of degree is in the oriented film of fibrosis, is then divided thin-film width (transverse direction) direction by the method for machinery Split, the linear fibrosis in longitudinal direction, this method can produce the fiber of white or other a variety of colors.Second of manufacturer Method investment is small, cost is low, and the PTFE staple fibers intensity produced is high, can produce multiple color as needed, so application is wide It is general.
Film, which splits legal system, to be made in PTFE staple fibers it is crucial that the method that film is split, this method can have many kinds, at present It is common be employed have two kinds, the first is that embossed is carried out on oriented film, i.e., along length (longitudinal direction) direction line of film Property and on width (transverse direction) direction of film with similar to the concave-convex of zigzag shape carry out embossed, width Strand break and then split, obtain fiber filament, then staple fiber is obtained by cut-out.Second method is to orient Film cuts into linearly and directly some crins in length direction in horizontal direction, is then carrying out bunchy heating, then lead to Crossing the processes such as repeatedly extruding, stretching, heating, stretching draws and attenuates the crin in beam, and becomes fiber, and staple fiber is formed through cut-out.
Film dividing into boundling twisting again after bar, is then stretched, extruded again by second method by extrusion stretching, heating Stretching, reheat stretching, and technique is so repeated several times, the crin after segmentation is pulled into fine fibre, the fibre fineness of this method Mainly as obtained from multiple stretching, still, since the used raw material of such method are typically all using same The PTFE dispersion resins of one batch, same molecular weight, then through in case of technological operation is improper, easily causing fibre during multi-drawing process The fracture of dimension, improves disqualification rate.
The content of the invention
In view of the above defects of the prior art, the object of the present invention is to provide one kind to use different molecular weight material Prepare the system and method for PTFE staple fibers, it is possible to increase the production efficiency of PTFE staple fibers, reduce cost, production mass more High PTFE staple fibers.
To achieve the above object, the present invention adopts the following technical scheme that:
On the one hand, a kind of system that PTFE staple fibers are prepared using different molecular weight material, including sintering extrusion device, also Device is cut including mixed stirring device and acupuncture comb;
The mixed stirring device is connected with sintering the feeding end of extrusion device, including:Cavity volume, the first feed pipe, second Feed pipe, motor, blender and discharge nozzle, the first feed pipe and the second feed pipe are connected with cavity volume respectively, and blender is arranged on In cavity volume, motor is arranged on the top of cavity volume, and is connected with the blender in cavity volume, and discharge nozzle is connected with cavity volume, and arranged on appearance The bottom of chamber, discharge nozzle are connected with sintering the feeding end of extrusion device;
The acupuncture comb, which cuts device, to be included:The road after the discharge end of sintering extrusion device, to unreel determining for oriented film To film unwinding device, and it is set in turn in puncture needle rod, cutting device, buncher, traversing dress behind oriented film unwinding device Put and wrap-up.
The blender includes rotation axis, and the stirring slurry being sheathed in rotation axis, rotation axis are connected with motor.
The puncture needle rod has a pair, is respectively arranged on oriented film over and under.
A diameter of 0.5~0.6mm of puncture needle on the puncture needle rod, needle point area≤0.001mm2, puncture The array pitch of draw point is 3~5mm, and density is 35~40/cm2
The cutting device includes:Erecting bed, the knife rest on erecting bed, the axis on knife rest, and lay In the blade on axis.
On the other hand, a kind of method that PTFE staple fibers are prepared using different molecular weight material, is comprised the following steps:
S1. the PTFE dispersion resins of two kinds of different molecular weights are ultrasonically treated 30~50 minutes at 25~35 DEG C;
S2. by the PTFE dispersion resins of two kinds of different molecular weights after step S1 processing respectively by the first feed pipe and Second feed pipe enters in cavity volume;
S3. start motor driving blender, the PTFE dispersion resins of two kinds of different molecular weights are stirred in cavity volume Mixing;
S4. mixed PTFE is disperseed tree by discharge nozzle, feeding end to enter in sintering extrusion device, by being molded, Push, calendering film forming, then through sintering, heating, stretching oriented film is made;
S5. between the oriented film obtained by step S4 being introduced a pair of of puncture needle rod by oriented film unwinding device, to fixed Punctured to film, make to form the pin hole arranged in length and breadth on oriented film;
S6. the oriented film after being punctured is transmitted to cutting device and is cut again, makes oriented film continuous in the longitudinal direction The long filament of linear single fiber state;
S7. the long filament obtained by step S6 is transmitted to buncher and carries out boundling;
S8. PTFE staple fibers are obtained after the long filament after boundling being passed sequentially through cut-out, shredding or pass sequentially through curling, are determined The PTFE staple fibers of curling are obtained after type, cut-out, shredding.
In the step S5, the needle point linear velocity of puncture needle rod is consistent with the linear velocity that oriented film is run.
In the step S6, the operation linear velocity of cutting device is more than 2~4 times of oriented film operation linear velocity.
In the step S4, the thickness of oriented film is 20~40um.
In the step S4, sintering temperature is 330~475 DEG C, and sintering time is 20~35 minutes.
It is provided by the present invention a kind of using different molecular weight material preparation PTFE staple fibers in above-mentioned technical solution System and method also there is some following beneficial effect:
1. the present invention admirably can be mixed the PTFE dispersion resins of two kinds of different molecular weights, easy to operate;
It is less energy consumption, efficient 2. present invention process advantages of simple, reliable;
It is low that 3. the present invention makes low price, small investment, maintenance cost;
4. the present invention utilizes the characteristic mixed between different molecular weight, the rigidity, toughness and tensile strength of product are improved;
5. this invention ensures that the being of close texture property of product.
Brief description of the drawings
Fig. 1 is the structure diagram of the present invention;
Fig. 2 is the structure diagram of mixed stirring device of the present invention;
Fig. 3 is the structure diagram of cutting device of the present invention;
Fig. 4 is the flow chart of the present invention.
Embodiment
Technical scheme is further illustrated with reference to the accompanying drawings and examples.
Incorporated by reference to shown in Fig. 1 to Fig. 3, one kind provided by the present invention prepares PTFE staple fibers using different molecular weight material System, including sintering extrusion device 1, further include mixed stirring device 2 and acupuncture comb cut device.
Preferably, the mixed stirring device 2 is connected with sintering the feeding end of extrusion device 1, including:Cavity volume 3, first into Expects pipe 4, the second feed pipe 5, motor 6, blender 7 and discharge nozzle 8, the first feed pipe 4 and the second feed pipe 5 respectively with cavity volume 3 It is connected, the PTFE dispersion resins of two kinds of different molecular weights can be made to enter in cavity volume 3, blender 7 is installed in cavity volume 3, to The PTFE dispersion resins of two kinds of different molecular weights are stirred mixing, motor 6 is installed on the top of cavity volume 3, and with cavity volume 3 Blender 7 be connected, to drive the rotation of blender 7, discharge nozzle 8 is connected with cavity volume 3, and is installed on the bottom of cavity volume 3, Discharge nozzle 8 is connected with sintering the feeding end of extrusion device 1, and the feedstock transportation after being stirred in cavity volume 3 is filled to extrusion is sintered Put 1 carry out next process.
Preferably, the acupuncture comb cuts device and includes:Be arranged at sintering extrusion device 1 discharge end after road, to unreel The oriented film unwinding device 10 of oriented film 9, and be set in turn in behind oriented film unwinding device 10 being carried out to oriented film 9 A pair of of puncture needle rod 11 of puncture, by the oriented film 9 after puncture cut into the cutting device 12 of long filament, the boundling by long filament boundling Device 13, traversing gear 14 and the wrap-up 15 wound to endless tow, oriented film unwinding device 10, puncture needle rod 11, divide A pair of of rubber rollers 16 are also provided between cutting apparatus 12 and buncher 13, to convey oriented film 9.
Preferably, the blender 7 includes rotation axis, and the stirring slurry being sheathed in rotation axis, rotation axis and motor It is connected, easy to disassemble and maintaining.
Preferably, a diameter of 0.5~0.6mm of the puncture needle on the puncture needle rod 11, needle point area≤ 0.001mm2, the array pitch of puncture needle is 3~5mm, and density is 35~40/cm2, the depth of insertion oriented film 9 for 0.3~ 1mm。
Preferably, the cutting device 12 includes:Erecting bed, the knife rest 121 being arranged on erecting bed, is arranged at knife rest Axis 122 on 121, and be uniformly arranged in the blade 123 on axis 122, spacer 124 is additionally provided between adjacent two blade 123, every Set 124 is socketed on axis 122, can prevent the play on axis 122 of blade 123.
Incorporated by reference to shown in Fig. 4, a kind of side that PTFE staple fibers are prepared using different molecular weight material provided by the present invention Method, comprises the following steps:
S1. the PTFE dispersion resins of two kinds of different molecular weights are ultrasonically treated 30~50 minutes at 25~35 DEG C;
S2. by the PTFE dispersion resins of two kinds of different molecular weights after step S1 processing respectively by the first feed pipe and Second feed pipe enters in cavity volume;
S3. start motor driving blender, the PTFE dispersion resins of two kinds of different molecular weights are stirred in cavity volume Mixing;
S4. mixed PTFE is disperseed tree by discharge nozzle, feeding end to enter in sintering extrusion device, by being molded, Push, calendering film forming, then through sintering, heating, stretch oriented film is made, sintering temperature is 330~475 DEG C, sintering time 20 ~35 minutes, the thickness of caused oriented film was 20~40um;
S5. between the oriented film obtained by step S4 being introduced a pair of of puncture needle rod by oriented film unwinding device, to fixed Punctured to film, make to form the pin hole arranged in length and breadth on oriented film, and the needle point linear velocity of puncture needle rod is run with oriented film Linear velocity it is consistent;
S6. the oriented film after being punctured is transmitted to cutting device and is cut again, makes oriented film continuous in the longitudinal direction The long filament of linear single fiber state, the operation linear velocity of cutting device are more than 2~4 times of oriented film operation linear velocity;
S7. the long filament obtained by step S6 is transmitted to buncher and carries out boundling;
S8. PTFE staple fibers are obtained after the long filament after boundling being passed sequentially through cut-out, shredding or pass sequentially through curling, are determined The PTFE staple fibers of curling are obtained after type, cut-out, shredding.
In conclusion the PTFE staple fibers that the present invention is produced are not only with short production cycle, product quality is stablized, and due to profit The chemical effect caused by the PTFE dispersion resins mixing of two kinds of different molecular weights, it is possible to increase product latitudinal strength, toughness.
Those of ordinary skill in the art it should be appreciated that the embodiment of the above be intended merely to explanation the present invention, And be not used as limitation of the invention, as long as in the spirit of the present invention, the change to embodiment described above Change, modification will all fall in the range of claims of the present invention.

Claims (10)

1. a kind of system that PTFE staple fibers are prepared using different molecular weight material, including sintering extrusion device, it is characterised in that: Further include mixed stirring device and acupuncture comb cuts device;
The mixed stirring device is connected with sintering the feeding end of extrusion device, including:Cavity volume, the first feed pipe, the second charging Pipe, motor, blender and discharge nozzle, the first feed pipe and the second feed pipe are connected with cavity volume respectively, and blender is arranged on cavity volume Interior, motor is arranged on the top of cavity volume, and is connected with the blender in cavity volume, and discharge nozzle is connected with cavity volume, and arranged on cavity volume Bottom, discharge nozzle are connected with sintering the feeding end of extrusion device;
The acupuncture comb, which cuts device, to be included:The road after the discharge end of sintering extrusion device, to unreel the oriented film of oriented film Unwinding device, and be set in turn in puncture needle rod behind oriented film unwinding device, cutting device, buncher, traversing gear and Wrap-up.
A kind of 2. system that PTFE staple fibers are prepared using different molecular weight material as claimed in claim 1, it is characterised in that: The blender includes rotation axis, and the stirring slurry being sheathed in rotation axis, rotation axis are connected with motor.
A kind of 3. system that PTFE staple fibers are prepared using different molecular weight material as claimed in claim 1, it is characterised in that: The puncture needle rod has a pair, is respectively arranged on oriented film over and under.
A kind of 4. system that PTFE staple fibers are prepared using different molecular weight material as claimed in claim 3, it is characterised in that: A diameter of 0.5~0.6mm of puncture needle on the puncture needle rod, needle point area≤0.001mm2, the row of puncture needle Away from being 35~40/cm for 3~5mm, density2
A kind of 5. system that PTFE staple fibers are prepared using different molecular weight material as claimed in claim 1, it is characterised in that: The cutting device includes:Erecting bed, the knife rest on erecting bed, the axis on knife rest, and be laid on axis Blade.
A kind of 6. method that PTFE staple fibers are prepared using different molecular weight material, it is characterised in that:Comprise the following steps:
S1. the PTFE dispersion resins of two kinds of different molecular weights are ultrasonically treated 30~50 minutes at 25~35 DEG C;
S2. the PTFE dispersion resins of two kinds of different molecular weights after step S1 processing are passed through into the first feed pipe and second respectively Feed pipe enters in cavity volume;
S3. start motor driving blender, the PTFE dispersion resins of two kinds of different molecular weights are stirred mixing in cavity volume;
S4. mixed PTFE is disperseed tree by discharge nozzle, feeding end to enter in sintering extrusion device, by being molded, pushing, Calendering film forming, then through sintering, heating, stretching oriented film is made;
S5. between the oriented film obtained by step S4 being introduced a pair of of puncture needle rod by oriented film unwinding device, to oriented film Punctured, make to form the pin hole arranged in length and breadth on oriented film;
S6. the oriented film after being punctured is transmitted to cutting device and is cut again, and it is in continuously line in the longitudinal direction to make oriented film The long filament of property single fiber state;
S7. the long filament obtained by step S6 is transmitted to buncher and carries out boundling;
S8. the long filament after boundling is passed sequentially through PTFE staple fibers are obtained after cut-out, shredding or pass sequentially through curling, sizing, The PTFE staple fibers of curling are obtained after cut-out, shredding.
A kind of 7. method that PTFE staple fibers are prepared using different molecular weight material as claimed in claim 6, it is characterised in that: In the step S5, the needle point linear velocity of puncture needle rod is consistent with the linear velocity that oriented film is run.
A kind of 8. method that PTFE staple fibers are prepared using different molecular weight material as claimed in claim 6, it is characterised in that: In the step S6, the operation linear velocity of cutting device is more than 2~4 times of oriented film operation linear velocity.
A kind of 9. method that PTFE staple fibers are prepared using different molecular weight material as claimed in claim 6, it is characterised in that: In the step S4, the thickness of oriented film is 20~40um.
10. a kind of method that PTFE staple fibers are prepared using different molecular weight material as claimed in claim 6, its feature are existed In:In the step S4, sintering temperature is 330~475 DEG C, and sintering time is 20~35 minutes.
CN201810004530.1A 2018-01-03 2018-01-03 The system and method for PTFE staple fibers is prepared using different molecular weight material Pending CN107938007A (en)

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CN111890587A (en) * 2020-08-11 2020-11-06 常州万容新材料科技有限公司 Method for manufacturing PTFE short fiber
CN111893591A (en) * 2020-08-11 2020-11-06 常州万容新材料科技有限公司 Preparation method of PTFE (polytetrafluoroethylene) long fibers
CN112726029A (en) * 2020-12-22 2021-04-30 杭州诺邦无纺股份有限公司 Filament non-woven composite material and preparation method thereof

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CN111890587A (en) * 2020-08-11 2020-11-06 常州万容新材料科技有限公司 Method for manufacturing PTFE short fiber
CN111893591A (en) * 2020-08-11 2020-11-06 常州万容新材料科技有限公司 Preparation method of PTFE (polytetrafluoroethylene) long fibers
CN112726029A (en) * 2020-12-22 2021-04-30 杭州诺邦无纺股份有限公司 Filament non-woven composite material and preparation method thereof

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