CN107936738A - A kind of fibrous woven multi-functional water-based coating and preparation method thereof - Google Patents
A kind of fibrous woven multi-functional water-based coating and preparation method thereof Download PDFInfo
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- CN107936738A CN107936738A CN201711215232.9A CN201711215232A CN107936738A CN 107936738 A CN107936738 A CN 107936738A CN 201711215232 A CN201711215232 A CN 201711215232A CN 107936738 A CN107936738 A CN 107936738A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
- C09D143/04—Homopolymers or copolymers of monomers containing silicon
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D123/00—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
- C09D123/02—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D123/04—Homopolymers or copolymers of ethene
- C09D123/08—Copolymers of ethene
- C09D123/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C09D123/0853—Vinylacetate
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
- C09D5/1668—Vinyl-type polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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Abstract
The invention discloses a kind of fibrous woven multi-functional water-based coating, according to the mass fraction, including following material component：15 30 parts of organosilicon-modified acrylic emulsion, 10 25 parts of ethylene and vinyl acetate copolymer water dispersion emulsion, 15 parts of wax emulsion, 15 parts of organic silicone powder, 15 parts of nano barium sulfate, 0.01 0.2 parts of Camphora extract, 0.01 0.2 parts of mint extract, 0.05 0.5 parts of nano zine oxide etc..In addition present invention also offers a kind of preparation method of simple and practicable fabric fibrous woven multi-functional water-based coating.The coating being prepared through above-mentioned formula and method has good adhesive force, pliability and weatherability, with suitable film thickness, also have the characteristics that at the same time smooth phozy, colour-fast, feel and fragrance, refresh oneself, insect prevention, resistance to burning, easy to clean, restraining and sterilizing bacteria, the multi-efficiency such as environmental protection, therefore have the very strong market competitiveness.
Description
Technical field
The invention belongs to paint field, specifically, is related to a kind of fibrous woven multi-functional water-based coating and its preparation
Method.
Background technology
VOC is the English abbreviation of volatile organic compounds, harmful chemicals in usually said wall finiss
Matter just refers to VOC (except heavy metal).These volatile organic compounds include the materials such as formaldehyde, ammonia, ethylene glycol, esters.When
When VOC reaches a certain concentration, the symptom such as headache, Nausea and vomiting, weak can be caused, can even trigger twitch, stupor when serious,
Liver, kidney, brain and nervous system are injured, causes the serious consequences such as failure of memory.And common coating applies for solvent borne
Expect, can discharge a variety of volatile organic compounds such as toluene, benzene, dimethylbenzene under room temperature, both pollute the environment, aggravate photochemical
The air combined pollutions such as smog pollution, region gray haze, acid rain are learned, and can give people to bring health hazard.
General fabrics are mostly oil paint with coating, have higher VOC, very big wound is caused to human body and environment
Evil.In recent years, as environment increasingly deteriorates, haze is increasingly severe, and requirement of the society to environmental protection is higher and higher, development environmental protection
Coating have become the common recognition of people, and water paint has the characteristics that low VOC and more green, becomes the side developed at present
To, but even water paint, still containing a certain amount of VOC, so developing the ultralow painting of function admirable, VOC content
Material becomes the developing direction of coating industry.
At the same time, general fabric face is coarse, for a long time using easy fluffing, and since it is direct staining,
The problem of being often accompanied with fading, not only influences beauty, but also influences comfortable.And fabric coating is less at present, and mostly oiliness
Coating, therefore, develops a kind of fabric that is applied to and uses the coating on spinning, by the external coating last layer paint film that spins, making
It is flexible, smooth, phozy, colour-fast and other effects that it reaches feel, while fabric had fragrance, refreshed oneself, is insect prevention, fire-retardant
Etc. it is multiple the effect of be also coating industry technical staff need make great efforts research a direction.
The content of the invention
The present invention is in order to solve above-mentioned technical problem, there is provided a kind of fibrous woven multi-functional water-based coating, by matter
Measure number meter, including following material component：15-30 parts of organosilicon-modified acrylic emulsion, ethylene and vinyl acetate copolymer water
10-25 parts of dispersion emulsion, 1-5 parts of wax emulsion, 1-5 parts of organic silicone powder, 1-5 parts of nano barium sulfate, Camphora extract 0.01-
0.2 part, 0.01-0.2 parts of mint extract, 0.05-0.5 parts of nano zine oxide, 0.1-1 parts of Ludox, PH conditioning agents 0.1-0.2
Part, 0.1-0.2 parts of defoamer, 1-3 parts of coalescents, 0.3-0.5 parts of dispersant, 0.3-0.5 parts of substrate wetting agents, deionized water
5-10 parts, 5-10 parts of fire retardant.
Further, the material component of the coating further includes 1-20 parts of pigment,
Based on the above technical solutions, the present invention can also be improved as follows.
Further, the pigment is preferably the superfine pigment of three face Fine Chemical Co., Ltd of Suzhou.
Further, the organosilicon-modified acrylic emulsion is preferably the WC- of Anhui Zhong En Chemical Co., Ltd.s
SA108。
Further, the ethylene and vinyl acetate copolymer water dispersion emulsion is preferably that U.S.'s Celanese is total to the net of color
Taste lotion VAE1608.
Further, the wax emulsion is preferably the UN-08 of Shanghai You En Chemical Co., Ltd.s.
Further, the organic silicone powder is polymethylsilsesquioxane, is preferably Guangzhou Ba Tai Chemical Co., Ltd.s
BT-9273 silicone powders.
Further, the nano barium sulfate is preferably this Micro nano barium sulfates of German Saha profit.
Further, the Camphora extract is preferably the Camphora extract of 5 Ye Cao bio tech ltd of Xi'an.
Further, the mint extract is preferably the mint extract of Xi'an Olympic Competition bio tech ltd.
Further, the nano zine oxide is preferably the nano zinc oxide powder of the dense nanosecond science and technology Co., Ltd of Nantong darcy
Body.
Further, the Ludox is preferably the JN20-30-6 of Region of Kaihua County Long Bang Ludox factory.
Further, the PH conditioning agents be dimethylethanolamine, one or both of multifunctional assistant AMP-95, it is excellent
Select the dimethylethanolamine of BASF Aktiengesellschaft and the multifunctional assistant AMP-95 of Dow chemical industry.
Further, the defoamer defoams the 941PL of foam inhibitor, preferably MOUSSEX companies for phosphoric acid lipid hydrophobicity
And defoaming effect the auxiliary agent B YK-028 or BYK024 of organic silicon defoamer (BIC Corp) BYK, two types defoamer mix
Close and use, ratio is 1:1 or so.
Further, the coalescents are the net taste type coalescents AF of environmental protection of propylene glycol phenyl ethers, are preferably Guangzhou
The net taste type coalescents AF of environmental protection of the propylene glycol phenyl ethers of Yu Tai Chemical Industry Science Co., Ltd.
Further, the dispersant is polyester modification polyphosphoric acid esters dispersant, preferably (angstrom husband's Kona) AFCONA's
AFCONA-5010。
Further, the substrate wetting agents be Siloxane-Oxyalkylene Copolymers class wetting agent, the preferably Tego- of TEGO
100th, one or both of AFCONA-3031 of AFCONA.
Further, the fire retardant is preferably the Doher-6502 of Dongguan City dongle Chemical Co., Ltd..
It is in beneficial effects of the present invention with each raw material components in multi-functional water-based coating in a kind of above-mentioned fibrous woven：
Organosilicon-modified acrylic emulsion in the present invention selects the WC-SA108 of Anhui Zhong En Chemical Co., Ltd.s, the type
Number organosilicon-modified acrylic emulsion there is prominent scrub resistance and bonding force, good water resistance compared to similar product
Energy and luster, high-hardness and high.
The net taste that ethylene and vinyl acetate copolymer water dispersion emulsion in the present invention selects U.S.'s Celanese to be total to color is newborn
Liquid VAE1608, it is a kind of non-plasticizing based on ethylene and vinyl acetate copolymer water dispersion emulsion.The lotion has low gas
The characteristics of taste, low VOC, and VOC content is almost nil, can the coating stablized of formulating low-temperature, while there is the scrub resistance of brilliance
Energy, outstanding mobility and levelability, have excellent covering power, color stuffing intermiscibility is good, without APEO, it is not necessary to which film forming helps
Agent, without antifreezing agent, the advantages of freeze-thaw is also splendid.
Wax emulsion in the present invention selects the UN-08 of Shanghai You En Chemical Co., Ltd.s, and UN-08 is nonionic high glaze wax
Agent, has good covering power and glossiness, and using in primary coat, middle painting, after hot light, it is bright smooth can to assign leathering
Appearance；And UN-08 is used in mixed way the feel that can effectively improve top coat in top coat with high glaze polyurethane resin, and not
The phenomenon that the brightness of influence top coat and appearance are whitened.
Organic silicone powder in the present invention is polymethylsilsesquioxane, specific selection Guangzhou Ba Tai Chemical Co., Ltd.s
BT-9273 silicone powders, the silicone powder of the model are to use true spherical structure polysiloxane polymer made of special process technology
The high-performance organic-inorganic hybrid material of class, has an insoluble insoluble thermosetting property, and the advantages of collecting inorganic particle and organic powder is
One, has good lubricity, moreover it is possible to promote pigment to disperse, prevent pigment and particle agglomerate, strengthen the self-cleaning of coating, hate
The performances such as water-based, water proofing property, resistance to soiling, scrub resistance (automatically cleaning characteristic, reach lotus leaf effect).It is applied in the present invention
The advantages of show：It can make the temperature in use of coating increase；The mechanical property of coating can be improved；It can make to prevent metal powder
Reunite Deng sedimentation；Make coating that there is good water-fast, resistant effect, there is automatically cleaning and scrub performance, it is possible to increase film
Hydrophobic, oleophobic stain, the action effect such as anti-slide mark, the anti-fingerprint marking.
Nano barium sulfate in the present invention selects this Micro nano barium sulfates of German Saha profit, the nano-sulfur of the model
Sour barium refraction index is low, and color is in neutrality, and is particularly suitable for the film coating of high brightness.
Camphora extract in the present invention selects the Camphora extract of 5 Ye Cao bio tech ltd of Xi'an, the model
Camphora extract be natural plant extracts, have effects that desinsection is antipruritic.
Mint extract in the present invention selects the mint extract of Xi'an Olympic Competition bio tech ltd, the model
Mint extract is natural mint extract, rich in menthol and peppermint oil dementholized, has special fragrance, cool feeling.
Nano zine oxide in the present invention selects the nanometer Zinc oxide powder of the dense nanosecond science and technology Co., Ltd of Nantong darcy, should
Nanometer Zinc oxide powder volume is fluffy, particle diameter is small, specific surface area is big, and dosage is few, and antibacterial sterilization ability is excellent.By itself and nano silver
Sterilization is compared：Bactericidal nano-silver significant effect, but it also has damage for benign cell, and zinc is human essential elements, safety
Health；Nano silver is easy to change, influences coloured light, and nano zine oxide then avoids this shortcoming；Nano silver category contact sterilization, and nano oxygen
Change zinc and not only can contact formula sterilization, good antibacterial sterilization effect can be still played under conditions of Guang Heshui.
Ludox in the present invention selects the JN20-30-6 of Region of Kaihua County Long Bang Ludox factory, and the Ludox of the model is
A kind of water base inorganic silicon compound, has good against weather, water proofing property, fire resisting, washable, resistance tocrocking.In the present invention
The use of middle Ludox can reduce sedimentation, be watered tolerance height, make coating application more convenient, at the same with the present invention
Fire retardant collocation use, it is better.
PH conditioning agents in the present invention are dimethylethanolamine, one or both of multifunctional assistant AMP-95, specifically
The dimethylethanolamine of BASF Aktiengesellschaft and the multifunctional assistant AMP-95 of Dow chemical industry are selected, in view of general water
Property coating ph value between 8-9, the acid-base property of the adjustable system of both PH conditioning agents.In addition, both pH value conditioning agents
Not only there is the effect for adjusting pH value, and in view of be organic substance in itself, therefore also there is the characteristic of certain auxiliary film forming.
Defoamer in the present invention defoams foam inhibitor, the specific 941PL for selecting MOUSSEX companies for phosphoric acid lipid hydrophobicity
And defoaming effect the auxiliary agent B YK-028 or BYK024 of organic silicon defoamer (BIC Corp) BYK, two types defoamer mix
Close and use, ratio is 1:1 or so.In water-based body coating system, a small amount of 941PL that adds does not interfere with paint film appearance not only, also
Can possess good defoaming suds effect；BYK-028 and BYK024 is organic silicon defoamer, can be in production process without VOC
Any stage is easily added in dispersions of polyurethanes.Two kinds of defoamer is used in mixed way by the present invention, this can be made to disappear
Infusion also has excellent environment-friendly function while possessing excellent defoaming effect.
Coalescents in the present invention are the net taste type coalescents AF of environmental protection of propylene glycol phenyl ethers, specifically select Guangzhou space
The net taste type coalescents AF of environmental protection of the propylene glycol phenyl ethers of safe Chemical Industry Science Co., Ltd.Propane diols used in the present invention
The net taste type coalescents AF of environmental protection of phenylate class has asepsis environment-protecting characteristic, the VOC significant effects to reducing coating.And this hair
The coalescents AF (242.7 DEG C of boiling point DEG C) of the bright specific higher boiling environmental protection of selection is environmentally friendly auxiliary agent, is the strong of emulsion polymer
Solvent, can effectively reduce the minimum film formation temperature of emulsion paint, improve the scrub resistance and film quality of emulsion paint；Can substantially it change
Kind filming performance, improves glossiness, intensity and the anti-grinded hardness index of paint film and promotes levelability；Possesses excellent wet film
, weatherability and color developing can be improved, while also there is excellent environment protecting.
Dispersant in the present invention is polyester modification polyphosphoric acid esters dispersant, the specific AFCONA- for selecting AFCONA
5010, AFCONA-5010 be the dispersant with high efficiency for aiming at inorganic particulate and designing, and is also had in hydroxy acrylic acid dual-component coating
There is catalytic reaction.
Substrate wetting agents in the present invention are the wetting agent of Siloxane-Oxyalkylene Copolymers class, the Tego- of specific selection TEGO
100th, one or both of AFCONA-3031 of AFCONA, two kinds of auxiliary agents can play the role of slip agent, levelling agent,
Reach paint film and seem more plentiful.
Fire retardant in the present invention selects the Doher-6502 of Dongguan City dongle Chemical Co., Ltd., the fire retardant of the model
It is a kind of efficient halogen-free environmental protection fire retarding agent, is exclusively used in the product such as all kinds of cottons, polyester, blended, viscose, there is fabulous fire-retardant effect
Fruit, and the performances such as the color and luster of fabric, pliability will not be changed.
Pigment in the present invention selects the superfine pigment of three face Fine Chemical Co., Ltd of Suzhou, which has fineness
Well, the advantages of stability is good, and cost is low, specific Color tunable section, is no longer specifically listed herein.
Present invention also offers a kind of preparation method of fibrous woven multi-functional water-based coating, comprise the following steps：
Step a：Weighed according to formula ratio, take 1/2 deionized water in formula ratio, 1/2 PH conditioning agents, 1/ first
2 defoamer and the dispersant of whole amount, nano barium sulfate, nano zine oxide, mint extract, Ludox, pigment, wax breast
Liquid, organic silicone powder, Camphora extract, fire retardant are put into blender, and 10- is stirred with the speed of 900-1200r/min
20 minutes, then take out mixture and ground by grinder, it is spare；
Step b：Blender mixing speed is adjusted to 400-600r/min, is sequentially added under the stirring in formula ratio
The deionized water of residue 1/2,1/2 pH value conditioning agent, the ethylene and vinyl acetate copolymer of 1/2 defoamer and whole amount
Water dispersion emulsion, organosilicon-modified acrylic emulsion, coalescents, substrate wetting agents, then the mixing speed of blender is adjusted to
900-1200r/min, is stirred 5-15 minutes at such speeds；Then the mixture in step a is added, in 600-700r/
5-15 minutes are stirred under the speed of min, finally using obtaining finished product after the filter-cloth filtering of 300 mesh.
Further, in step a, after the ground machine grinding of mixture, fineness must be less than 10 μm.
The present invention has the beneficial effect that：
1st, the present invention selects the coalescents of water soluble acrylic acid dispersion and higher boiling environmental protection, can obtain high glaze, high dress
Decorations property, the water-based lacquer coat of high hydrophobicity.Meanwhile the water paint VOC≤30g/L for selecting water-base resin system to prepare, smell
It is very low, it can prevent pollution environment, it is more more environmentally-friendly than existing water paint.
2nd, the present invention selects organic silicone powder, wax emulsion and organosilicon-modified acrylic emulsion, in terms of filming performance：Reach
Good water-fast, resistant effect have been arrived, there is automatically cleaning and scrub performance, pollution repeatedly wipes good (the automatically cleaning spy of persistence
Property, reach lotus leaf effect).In terms of stability and usability：With good lubricity, moreover it is possible to promote pigment to disperse, prevent
Pigment and particle agglomerate.Its main performance is shown：It can make the temperature in use of coating increase；The mechanical property of coating can be improved
Energy；It can make to prevent the sedimentations such as powder from reuniting.
3rd, the present invention selects organosilicon-modified acrylic emulsion as film forming matter, compared with similar products, in hardness, attached
Put forth effort, have great raising in terms of pollution resistance and weatherability, while there is outstanding water-alkali resistance, excellent spot-resistant.
4th, the use of organosilicon-modified acrylic emulsion can also improve the pliability and hydrophobic performance of coating in the present invention,
While the fillers such as nano barium sulfate of arranging in pairs or groups, the hardness of coating was not only improved, but also the toughness of coating can be improved.
5th, the Camphora extract in the present invention and mint extract are natural extract, environmentally protective, have and refresh oneself, drive
The effect of worm.
6th, the coating after present invention coating has the characteristics that fire-retardant, can prevent the burning of fabric, effective fire preventing.
7th, the present invention is by introducing nano zine oxide, has achieveed the purpose that persistently, gently sterilize.
Embodiment
The principle of the present invention and feature are described below in conjunction with specific embodiment, illustrated embodiment is served only for explaining this
Invention, is not intended to limit the scope of the present invention.
Embodiment 1：
A kind of fibrous woven multi-functional water-based coating, its according to the mass fraction, including following material component：Organosilicon changes
15 parts of acrylic emulsion of property, 10 parts of ethylene and vinyl acetate copolymer water dispersion emulsion, 1 part of wax emulsion, 1 part of organic silicone powder,
1 part of nano barium sulfate, 0.01 part of Camphora extract, 0.01 part of mint extract, 0.05 part of nano zine oxide, 0.1 part of Ludox,
0.1 part of PH conditioning agents, 0.1 part of defoamer, 1 part of coalescents, 0.3 part of dispersant, 0.3 part of substrate wetting agents, deionized water 5
Part, 5 parts of fire retardant.
Wherein, in the present embodiment, the organosilicon-modified acrylic emulsion is the WC- of Anhui Zhong En Chemical Co., Ltd.s
SA108；Ethylene and vinyl acetate copolymer water dispersion emulsion is total to the net taste lotion VAE1608 of color for U.S.'s Celanese；Wax breast
Liquid is the UN-08 of Shanghai You En Chemical Co., Ltd.s；Organic silicone powder is the BT-9273 silicone of Guangzhou Ba Tai Chemical Co., Ltd.s
Powder；Nano barium sulfate is this Micro nano barium sulfates of German Saha profit；Camphora extract has for 5 leaf grass biotechnology of Xi'an
The Camphora extract of limit company；Mint extract is the mint extract of Xi'an Olympic Competition bio tech ltd；It is nano oxidized
Zinc is the nanometer Zinc oxide powder of the dense nanosecond science and technology Co., Ltd of Nantong darcy；Ludox is Region of Kaihua County Long Bang Ludox factory
JN20-30-6；Coalescents help for the net taste type film forming of environmental protection of the propylene glycol phenyl ethers of Guangzhou Yu Tai Chemical Industry Science Co., Ltd
Agent AF；Dispersant is the AFCONA-5010 of (angstrom husband's Kona) AFCONA；Fire retardant is Dongguan City dongle Chemical Co., Ltd.
Doher-6502；PH conditioning agents are the dimethylethanolamine of BASF Aktiengesellschaft；Defoamer is the 941PL of MOUSSEX companies
And the defoaming effect auxiliary agent B YK-028 of organic silicon defoamer (BIC Corp) BYK, two types defoamer are used in mixed way,
Ratio is 1:1；Substrate wetting agents are the Tego-100 of TEGO.
A kind of preparation method of above-mentioned fibrous woven multi-functional water-based coating is as follows：
Step a：Weighed according to formula ratio, take 1/2 deionized water in formula ratio, 1/2 PH conditioning agents, 1/ first
2 defoamer and the dispersant of whole amount, nano barium sulfate, nano zine oxide, mint extract, Ludox, pigment, wax breast
Liquid, organic silicone powder, Camphora extract, fire retardant are put into blender, are stirred 20 minutes with the speed of 900r/min, so
Mixture is taken out afterwards is ground to fineness less than 10 μm by grinder, it is spare；
Step b：Blender mixing speed is adjusted to 400r/min, is sequentially added under the stirring remaining in formula ratio
1/2 deionized water, 1/2 pH value conditioning agent, the ethylene and vinyl acetate copolymer moisture of 1/2 defoamer and whole amount
Lotion, organosilicon-modified acrylic emulsion, coalescents, substrate wetting agents are dissipated, then the mixing speed of blender is adjusted to 900r/
Min, is stirred 15 minutes at such speeds；Then the mixture in step a is added, is stirred under the speed of 600r/min mixed
Close 15 minutes, finally using obtaining finished product after the filter-cloth filtering of 300 mesh.
Embodiment 2：
A kind of fibrous woven multi-functional water-based coating, its according to the mass fraction, including following material component：Organosilicon changes
20 parts of acrylic emulsion of property, 20 parts of ethylene and vinyl acetate copolymer water dispersion emulsion, 3 parts of wax emulsion, 2 parts of organic silicone powder,
3 parts of nano barium sulfate, 0.1 part of Camphora extract, 0.1 part of mint extract, 0.3 part of nano zine oxide, 0.5 part of Ludox, PH
0.2 part of conditioning agent, 0.1 part of defoamer, 2 parts of coalescents, 0.4 part of dispersant, 0.4 part of substrate wetting agents, 5 parts of deionized water,
7 parts of fire retardant, 12 parts of pigment.
Wherein, in the present embodiment, the pigment is the superfine pigment of three face Fine Chemical Co., Ltd of Suzhou；PH conditioning agents
For the multifunctional assistant AMP-95 of Dow chemical industry；Defoamer is the 941PL and organic silicon defoamer of MOUSSEX companies
The defoaming effect auxiliary agent B YK024 of (BIC Corp) BYK, two types defoamer are used in mixed way, ratio 1:1.1；Base material soaks
Agent is the AFCONA-3031 of AFCONA.The selection of other raw materials is consistent with embodiment 1, does not repeat herein.
A kind of preparation method of above-mentioned fibrous woven multi-functional water-based coating is as follows：
Step a：Weighed according to formula ratio, take 1/2 deionized water in formula ratio, 1/2 PH conditioning agents, 1/ first
2 defoamer and the dispersant of whole amount, nano barium sulfate, nano zine oxide, mint extract, Ludox, pigment, wax breast
Liquid, organic silicone powder, Camphora extract, fire retardant are put into blender, are stirred 15 minutes with the speed of 1000r/min,
Then take out mixture and be ground to fineness less than 10 μm by grinder, it is spare；
Step b：Blender mixing speed is adjusted to 500r/min, is sequentially added under the stirring remaining in formula ratio
1/2 deionized water, 1/2 pH value conditioning agent, the ethylene and vinyl acetate copolymer moisture of 1/2 defoamer and whole amount
Lotion, organosilicon-modified acrylic emulsion, coalescents, substrate wetting agents are dissipated, then the mixing speed of blender is adjusted to
1000r/min, is stirred 10 minutes at such speeds；Then the mixture in step a is added, under the speed of 650r/min
10 minutes are stirred, finally using obtaining finished product after the filter-cloth filtering of 300 mesh.
Embodiment 3：
A kind of fibrous woven multi-functional water-based coating, its according to the mass fraction, including following material component：Organosilicon changes
30 parts of acrylic emulsion of property, 25 parts of ethylene and vinyl acetate copolymer water dispersion emulsion, 5 parts of wax emulsion, 5 parts of organic silicone powder,
5 parts of nano barium sulfate, 0.2 part of Camphora extract, 0.2 part of mint extract, 0.5 part of nano zine oxide, 1 part of Ludox, PH tune
Save 0.2 part of agent, 0.2 part of defoamer, 3 parts of coalescents, 0.5 part of dispersant, 0.5 part of substrate wetting agents, 10 parts of deionized water, resistance
Fire 10 parts of agent, 20 parts of pigment.
Wherein, in the present embodiment, the pigment is the superfine pigment of three face Fine Chemical Co., Ltd of Suzhou；PH conditioning agents
For the dimethylethanolamine of BASF Aktiengesellschaft and the multifunctional assistant AMP-95 of Dow chemical industry；Defoamer is
The defoaming effect auxiliary agent B YK-028 of the 941PL and organic silicon defoamer (BIC Corp) BYK of MOUSSEX companies, two species
Type defoamer is used in mixed way, ratio 1.1:1；Substrate wetting agents are the AFCONA-3031 of the Tego-100 and AFCONA of TEGO.
The selection of other raw materials is consistent with embodiment 1, does not repeat herein.
A kind of preparation method of above-mentioned fibrous woven multi-functional water-based coating is as follows：
Step a：Weighed according to formula ratio, take 1/2 deionized water in formula ratio, 1/2 PH conditioning agents, 1/ first
2 defoamer and the dispersant of whole amount, nano barium sulfate, nano zine oxide, mint extract, Ludox, pigment, wax breast
Liquid, organic silicone powder, Camphora extract, fire retardant are put into blender, are stirred 10 minutes with the speed of 1200r/min,
Then take out mixture and be ground to fineness less than 10 μm by grinder, it is spare；
Step b：Blender mixing speed is adjusted to 600r/min, is sequentially added under the stirring remaining in formula ratio
1/2 deionized water, 1/2 pH value conditioning agent, the ethylene and vinyl acetate copolymer moisture of 1/2 defoamer and whole amount
Lotion, organosilicon-modified acrylic emulsion, coalescents, substrate wetting agents are dissipated, then the mixing speed of blender is adjusted to
1200r/min, is stirred 5 minutes at such speeds；Then the mixture in step a is added, under the speed of 700r/min
5 minutes are stirred, finally using obtaining finished product after the filter-cloth filtering of 300 mesh.
Comparative example 1：
A kind of fibrous woven multi-functional water-based coating, its according to the mass fraction, including following material component：Organosilicon changes
10 parts of acrylic emulsion of property, 35 parts of ethylene and vinyl acetate copolymer water dispersion emulsion, 1 part of wax emulsion, 1 part of organic silicone powder,
1 part of nano barium sulfate, 0.01 part of Camphora extract, 0.01 part of mint extract, 0.05 part of nano zine oxide, 0.1 part of Ludox,
0.1 part of PH conditioning agents, 0.1 part of defoamer, 2 parts of coalescents, 0.3 part of dispersant, 0.3 part of substrate wetting agents, deionized water 5
Part, 5 parts of fire retardant.
Comparative example 2：
A kind of fibrous woven multi-functional water-based coating, its according to the mass fraction, including following material component：Organosilicon changes
20 parts of acrylic emulsion of property, 20 parts of ethylene and vinyl acetate copolymer water dispersion emulsion, 3 parts of wax emulsion, Camphora extract 0.1
Part, 0.1 part of mint extract, 0.3 part of nano zine oxide, 0.5 part of Ludox, 0.2 part of PH conditioning agents, 0.1 part of defoamer, film forming
3 parts of auxiliary agent, 0.4 part of dispersant, 0.4 part of substrate wetting agents, 5 parts of deionized water, 7 parts of fire retardant, 12 parts of pigment.
Comparative example 3：
A kind of fibrous woven multi-functional water-based coating, its according to the mass fraction, including following material component：Organosilicon changes
50 parts of acrylic emulsion of property, 2 parts of ethylene and vinyl acetate copolymer water dispersion emulsion, 5 parts of organic silicone powder, 5 parts of wax emulsion, camphor tree
0.2 part of brain extract, 0.2 part of mint extract, 5 parts of nano barium sulfate, 0.5 part of nano zine oxide, 1 part of Ludox, PH are adjusted
0.2 part of agent, 0.2 part of defoamer, 5 parts of coalescents, 0.5 part of dispersant, 0.5 part of substrate wetting agents, 10 parts of deionized water are fire-retardant
10 parts of agent, 20 parts of pigment.
By the indices in comparative example 1-3 are detected with discovery, 1 paint film water resistance of comparative example is poor；Comparative example 2
Lack machine silicone powder, paint film hydrophobic performance is poor, lacks barium sulfate, and paint film is not fine and close enough, and water resistance is poor；3 paint film of comparative example is hard
Degree is poor, and glass transition temperature (Tg) is low, and water resistance is poor.
The sample of the multifunctional fibre weaving sealing wax obtained below for embodiment 1-3 technical solutions of the present invention into
Row Experiment of correlation detection, execution conditions are：Dip-coating, will knit line and is passed through from the pond equipped with paint solution, 80-100 DEG C, baking drying
1min.Following table table 1 is the test result of experiment：
Table 1
It can be seen from the above that there is well attached using fibrous woven prepared by technical solution of the present invention multi-functional water-based coating
Put forth effort, pliability, weatherability and fire resistance, there is suitable film thickness.
Present invention is mainly applied to fabric with spinning, coating is reached phozy by adding organic film forming matter, do not take off
The characteristics of color, make fabric that there is smooth feel (to cause fabric stiff using wax than conventional by using flexible, smooth film forming matter
It is hard different), it is special standby to be suitable for the thick lines such as woollen blanket and gather around fabric.And by introducing herbal plant extract, fabric is set to be provided with virtue
It is fragrant, refresh oneself, insect prevention the effect of, by introducing environmental protection fire retarding agent, the flame resistance energy of fabric is improved, so that the hair of fire preventing
It is raw.In addition, in view of coating has the characteristics that surface energy is low, friction coefficient is small, easy slip, thus also have excellent non-stick and
Property easy to clean, further, the present invention are also more with action effect, functions such as long Kubo color, high glaze, persistently sterilization, environmental protection
Sample, has the stronger market competitiveness.
By the present invention in that with two kinds of lotions, organosilicon-modified acrylic emulsion and ethylene and vinyl acetate copolymer moisture
Lotion is dissipated, physical film deposition, paint film is soft, while the good organosilicon-modified acrylic emulsion of hydrophobicity and opposite glass transition temperature
Good hydrophobic, flexible and hardness paint film can also be formed by spending high acetate ethylene copolymer water dispersion emulsion；By using having
Auxiliary agent and the fillers such as machine silicon class lotion, wetting, influence the surface tension of paint film, improve the hydrophobicity of paint film, so as to lift paint film
Hydrophobic protective.
The mass fraction of organosilicon-modified acrylic emulsion is defined to 15-30 parts by the present invention, this is because, if quality
Number is less than 15 parts, then paint film hydrophobicity is poor, and water resistance is poor；If mass fraction is higher than 30 parts, paint film is soft, barrier propterty
Difference.
The mass fraction of ethylene and vinyl acetate copolymer water dispersion emulsion is defined to 10-25 parts by the present invention, this be because
For if mass fraction is less than 10 parts, paint film is soft, and not fine and close enough, barrier propterty is poor, and water resistance is poor；If mass fraction
Higher than 25 parts, then paint film hydrophobic performance is poor, and water resistance is poor.
The mass fraction of organic silicone powder is defined to 1-5 parts by the present invention, this is because, if mass fraction is less than 1 part,
Then paint film is not fine and close enough, and hydrophobicity reduces, and water resistance is poor；If mass fraction is higher than 5 parts, paint film also can be loose, fine and close
Property reduce, barrier propterty decline.
The mass fraction of nano barium sulfate is defined to 1-5 parts by the present invention, this is because, if mass fraction is less than 1 part,
Then paint film is not fine and close enough, poor water resistance；If mass fraction is higher than 5 parts, hardness of paint film improves, and paint film is crisp, gloss of film drop
Low, water resistance reduces.
The mass fraction of mint extract is defined to 0.01-0.2 parts by the present invention, this is because, if mass fraction is low
In 0.01 part, then performance of refreshing oneself reduces；If mass fraction is higher than 0.2 part, taste is too dense, and irritation is strong, can not only increase
Cost, can also reduce the gloss and water resistance of paint film.
The mass fraction of Camphora extract is defined to 0.01-0.2 parts by the present invention, this is because, if mass fraction is low
In 0.01 part, then disinsectization performance is poor；If mass fraction is higher than 0.2 part, not only irritation is strong, can also increase cost.
The mass fraction of nano zine oxide is defined to 0.05-0.5 parts by the present invention, this is because, if mass fraction is low
In 0.05 part, then bactericidal property reduces；If mass fraction is higher than 0.5 part, it is steady that gloss of film, compactness and former paint can be reduced
It is qualitative.
The mass fraction of Ludox is defined to 0.1-1 parts by the present invention, this is because, if mass fraction is less than 0.1 part,
Then hardness of paint film is low；If mass fraction is higher than 1 part, paint film is loose, easily cracking.
The mass fraction of PH conditioning agents is defined to 0.1-0.2 parts by the present invention, this is because, mass fraction is less than 0.1 part
Or mass fraction is higher than 0.2 part, original paint stability is all poor, and mass fraction is higher than 0.2 part, and VOC content can also rise.
The mass fraction of defoamer is defined to 0.1-0.2 parts by the present invention, this is because, if mass fraction is less than 0.1
Part, then antifoam performance is poor；If mass fraction is higher than 0.2 part, shrinkage cavity occurs, or even influence film forming.
The mass fraction of coalescents is defined to 1-3 parts by the present invention, this is because, if mass fraction is less than 1 part,
Reduce film forming and gloss；If mass fraction is higher than 3 parts, VOC increases, it is poor that original paints stability.
The mass fraction of dispersant is defined to 0.3-0.5 parts by the present invention, this is because, if mass fraction is less than 0.3
Part, then powder is not easy to disperse, and paint film color is unstable；If mass fraction is higher than 0.5 part, paint film poor water resistance.
The mass fraction of substrate wetting agents is defined to 0.3-0.5 parts by the present invention, this is because, if mass fraction is less than
0.3 part, then influence film forming；If mass fraction is higher than 0.5 part, of high cost, paint film appearance floating.
The mass fraction of fire retardant is defined to 5-10 parts by the present invention, this is because, if mass fraction is less than 5 parts,
Viscosity is low, and original paint is not easy to store and uses；If mass fraction is higher than 10 parts, viscosity is high, it is not easy to uses.
The mass fraction of wax emulsion is defined to 1-5 parts by the present invention, this is because, if mass fraction is less than 1 part, drop
Low hydrophobicity and paint film slickness；If mass fraction is higher than 5 parts, compact in paint film is reduced, reduces water resistance.
The mass fraction of pigment is defined to 1-20 parts by the present invention, this is because, the present invention can not add pigment, but one
If denier is added, if mass fraction is less than 1 part, paint film is not fine and close enough, poor water resistance；If mass fraction is higher than 20 parts,
Then paint film is crisp, and pliability is poor.
The above embodiments are merely illustrative of the technical scheme of the present invention and are not intended to be limiting thereof；The present invention is not limited to above-mentioned
Preferred embodiment, anyone should learn that the modification made under the enlightenment of the present invention or carries out some technical characteristics etc.
With replace, it is every with it is of the invention have it is same or similar as technical solution, belong to protection scope of the present invention.
Claims (10)
- A kind of 1. fibrous woven multi-functional water-based coating, it is characterised in that according to the mass fraction, including following material component：
- A kind of 2. fibrous woven multi-functional water-based coating according to claim 1, it is characterised in that：The material component Further include 1-20 parts of pigment.
- A kind of 3. fibrous woven multi-functional water-based coating according to claim 1, it is characterised in that：The coalescents For the net taste type coalescents AF of environmental protection of propylene glycol phenyl ethers.
- A kind of 4. fibrous woven multi-functional water-based coating according to claim 1, it is characterised in that：The organic silicone Powder is polymethylsilsesquioxane.
- A kind of 5. fibrous woven multi-functional water-based coating according to claim 1, it is characterised in that：The PH conditioning agents For one or both of dimethylethanolamine, multifunctional assistant AMP-95.
- A kind of 6. fibrous woven multi-functional water-based coating according to claim 1, it is characterised in that：The defoamer is Phosphoric acid lipid hydrophobicity defoams foam inhibitor.
- A kind of 7. fibrous woven multi-functional water-based coating according to claim 1, it is characterised in that：The dispersant is Polyester modification polyphosphoric acid esters dispersant.
- A kind of 8. fibrous woven multi-functional water-based coating according to claim 1, it is characterised in that：The base material wetting Agent is the wetting agent of Siloxane-Oxyalkylene Copolymers class.
- 9. a kind of preparation method of fibrous woven multi-functional water-based coating, it is characterised in that comprise the following steps：Step a：Claimed according to claim 1 to 8 any one of them fibrous woven with the formula ratio of multi-functional water-based coating Take, take first 1/2 deionized water in formula ratio, 1/2 PH conditioning agents, 1/2 defoamer and whole amount dispersant, receive It is nano-barium sulfate, nano zine oxide, mint extract, Ludox, pigment, wax emulsion, organic silicone powder, Camphora extract, fire-retardant Agent is put into blender, is stirred 10-20 minutes with the speed of 900-1200r/min, then takes out mixture by grinding Machine is ground, spare；Step b：Blender mixing speed is adjusted to 400-600r/min, is sequentially added under the stirring remaining in formula ratio 1/2 deionized water, 1/2 pH value conditioning agent, the ethylene and vinyl acetate copolymer moisture of 1/2 defoamer and whole amount Lotion, organosilicon-modified acrylic emulsion, coalescents, substrate wetting agents are dissipated, then the mixing speed of blender is adjusted to 900- 1200r/min, is stirred 5-15 minutes at such speeds；Then the mixture in step a is added, 600-700r/min's 5-15 minutes are stirred under speed, finally using obtaining finished product after the filter-cloth filtering of 300 mesh.
- A kind of 10. preparation method of fibrous woven multi-functional water-based coating according to claim 9, it is characterised in that： In step a, after the ground machine grinding of mixture, fineness must be less than 10 μm.
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN109233518A (en) * | 2018-08-22 | 2019-01-18 | 河北晨阳工贸集团有限公司 | A kind of repelling mosquitoes and preventing insects elastic coating and preparation method thereof |
| CN110760259A (en) * | 2019-11-05 | 2020-02-07 | 深圳市百泉河实业有限公司 | Aluminum-plastic film smooth coating liquid and coating process thereof |
| CN114775293A (en) * | 2022-04-13 | 2022-07-22 | 广东安捷伦新材料科技有限公司 | Water-based coating for airbag |
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| CN104725951A (en) * | 2013-12-23 | 2015-06-24 | 惠州市绿孔雀科技有限公司 | High-hardness single-component water-based paint |
| CN106675138A (en) * | 2016-07-27 | 2017-05-17 | 董荣琴 | Novel acrylic ester aqueous paint used for weaving |
| CN107033748A (en) * | 2017-04-27 | 2017-08-11 | 河北晨阳工贸集团有限公司 | A kind of multi-functional woodenware sealing wax and preparation method thereof |
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| CN104725951A (en) * | 2013-12-23 | 2015-06-24 | 惠州市绿孔雀科技有限公司 | High-hardness single-component water-based paint |
| CN106675138A (en) * | 2016-07-27 | 2017-05-17 | 董荣琴 | Novel acrylic ester aqueous paint used for weaving |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN109233518A (en) * | 2018-08-22 | 2019-01-18 | 河北晨阳工贸集团有限公司 | A kind of repelling mosquitoes and preventing insects elastic coating and preparation method thereof |
| CN110760259A (en) * | 2019-11-05 | 2020-02-07 | 深圳市百泉河实业有限公司 | Aluminum-plastic film smooth coating liquid and coating process thereof |
| CN114775293A (en) * | 2022-04-13 | 2022-07-22 | 广东安捷伦新材料科技有限公司 | Water-based coating for airbag |
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