CN107936650A - A kind of functional form footwear coating composition - Google Patents
A kind of functional form footwear coating composition Download PDFInfo
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- CN107936650A CN107936650A CN201711359065.5A CN201711359065A CN107936650A CN 107936650 A CN107936650 A CN 107936650A CN 201711359065 A CN201711359065 A CN 201711359065A CN 107936650 A CN107936650 A CN 107936650A
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- CN
- China
- Prior art keywords
- coating composition
- functional form
- fungicide
- dispersant
- defoamer
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention provides a kind of functional form footwear coating composition, it is characterised in that includes the component of following parts by weight：Styrene butadiene latices 16 24, methyl methacrylate 19 35,3,5 dimethyl sulphur-based, 2,4 toluenediamine 13 21, azodiisobutyronitrile 9 14, mannitol 8 17, dispersant 59, thickener 28, fungicide 23 57, defoamer 13, pH adjusting agent 4 11,31 molecular sieves 59 73 of nanometer SAPO, polyoxyalkylene amine 16 28, distilled water 33 56.The present invention can significantly improve article of footwear to being lost, wearing and the resistance of other damages, durability and anti-microbial property, used suitable for large-scale promotion.
Description
Technical field
The present invention relates to footwear applications technical field of coatings, and in particular to a kind of coating for footwear.
Background technology
Coating composition is used in numerous industry.These industry can include, but not limited to land transport vehicle for example
Car, truck, sport vehicle, motorcycle；Marine equipment such as ship, ship and submarine；Aircraft such as aircraft
And helicopter；Industrial such as business equipment and structure, including wall and roof；Build such as Construction traffic and structure, bag
Include wall and roof, military such as military vehicle, such as tank and brave horse transport vehicle, and military structure body, including wall and roof,
Such as caisson and battery case etc..
In these industry, coating for example protects various parts from because of corrosion, wear, impact, change for numerous purposes
Damage caused by product, ultraviolet light, flame and heat and other environmental exposures, and for their components deposited thereon well
Assign shellproof and explosion-proof buffering performance (balllistic and blast mitigation properties).Therefore,
Huge effort is taken to develop the coating composition for having and improving performance.
Coating usually can be used for footwear industry.Footwear (footwear) generally fall into two parts, vamp and sole.
Vamp is the part for being designed as cosily encapsulating foot of footwear, and the attachment that is designed as providing that sole is footwear rubs
Wipe power (traction), protection, damping and/or the part on endurable surface.
Vamp is typically made of many different components, these components are usually made from a variety of materials.The material
Including, such as natural leather, synthetic leather, vinyl material and fabric such as nylon；Other fabrics can also be used.Even in
During the normal use of footwear, many upper members, particularly " toe-cap " may experience loss and/or abrasions.
Similarly, sole generally includes the different components being made from a different material.Midsole typically by foam for example
Ethylene vinyl acetate (EVA) foam or polyurethane such as TPU foams are made.These materials application load, for example exist
By elastic compression under foot and the power of leg generation during body movement.Many footwear, particularly sport footwear are included in another shoes department part example
Filling damping element or bladder in such as midsole, footwear outer bottom.The bladder can be by that can show resistance to compression
To provide expandable insert made of the polymeric material of additional cushioning effect for footwear wearer.These bladders can use-case
As plasma, water or other fluids such as air or nitrogen are filled.Footwear outer bottom is usually by synthesizing and/or natural rubber, such as
Silica-filled rubber composition is made.During the normal use of footwear, footwear outer bottom may also undergo loss and/or
Abrasion.
Therefore, it is intended that article of footwear to being lost, wearing and improved resistance, durability and the antibiotic property of other damages
Energy.
The content of the invention
In view of this, the present invention provides a kind of new functional form footwear coating composition, and the present invention can significantly improve
Article of footwear to being lost, wearing and the resistance of other damages, durability and anti-microbial property, make suitable for large-scale promotion
With.
The technical scheme is that：A kind of functional form footwear coating composition, includes the component of following parts by weight：Benzene
Ethylene-butylene latex 16-24, methyl methacrylate 19-35,3,5- dimethyl sulphur-based -2,4- toluenediamines 13-21, idol
Nitrogen bis-isobutyronitrile 9-14, mannitol 8-17, dispersant 5-9, thickener 2-8, fungicide 23-57, defoamer 1-3, pH
Conditioning agent 4-11, nano SAPO-31 molecular sieve 59-73, polyoxyalkylene amine 16-28, distilled water 33-56.
Further, the functional form footwear coating composition includes the component of following parts by weight：Styrene-butadiene
Latex 19-22, methyl methacrylate 24-31,3,5- dimethyl sulphur-based -2,4- toluenediamines 15-19, azodiisobutyronitrile
10-12, mannitol 11-15, dispersant 6-7, thickener 4-7, fungicide 31-46, defoamer 2-3, pH adjusting agent 5-
9th, nano SAPO-31 molecular sieve 63-70, polyoxyalkylene amine 21-25, distilled water 39-45.
Further, the functional form footwear coating composition includes the component of following parts by weight：Styrene-butadiene
Latex 21, methyl methacrylate 27,3,5- dimethyl sulphur-baseds -2,4- toluenediamine 17, azodiisobutyronitrile 11, mannitol
13rd, dispersant 6, thickener 5, fungicide 39, defoamer 2, pH adjusting agent 8, nano SAPO-31 molecular sieve 67, poly suboxygen
Alkylamine 23, distilled water 42.
Further, the fungicide is chitin fiber.
Further, the coalescents are propane diols, methoxybutanol, ethylene glycol monobutyl ether, propandiol butyl ether, dipropyl
One kind in glycol dimethyl ether, diethylene glycol monoethyl ether, tripropylene glycol butyl ether.
Further, the dispersant is lauryl sodium sulfate, methyl anyl alcohol, polyacrylamide, guar gum, aliphatic acid
One kind in macrogol ester.The poly- diethanol that the dispersant is the poly- diethanol that molecular weight is 5000 and molecular weight is 4000
4:The mixture of 5 mass ratioes, can reach more preferable dispersion effect.
Further, the thickener is hydroxyethyl ether cellulose, and defoamer is tributyl phosphate, and pH adjusting agent is diethyl
Hydramine.
The preparation method of coating of the present invention is：S1. by butyl acrylate, methyl methacrylate, 3,5- dimethyl sulphur-based -2,
Shaken up after 4- toluenediamines, azodiisobutyronitrile, mannitol dissolving, wherein acrylic monomers uses after newly steaming.After shaking up
Solution is heated to 40-50 DEG C, and stirs 60-90min with 60r/min, obtains mixed solution；S2. by polyimides tiny balloon
Mixed with fungicide；S3. remaining component of the component in S1 and S2 and coating is mixed according to mass fraction, with 4000-
The rate of dispersion of 5500r/min disperses 20-40min.
The present invention can significantly improve article of footwear to being lost, wearing and the resistance of other damages, durability and anti-
Bacterium performance, uses suitable for large-scale promotion.
Embodiment
Technical scheme is clearly and completely described below in conjunction with embodiment, it is clear that described reality
It is only part of the embodiment of the present invention to apply example, instead of all the embodiments.
Embodiment 1
The present embodiment provides a kind of functional form footwear coating composition, the functional form footwear coating composition includes following weight
The component of number：Styrene-butadiene latex 21, methyl methacrylate 27,3,5- dimethyl sulphur-based -2,4- toluenediamines
17th, azodiisobutyronitrile 11, mannitol 13, dispersant 6, thickener 5, fungicide 39, defoamer 2, pH adjusting agent 8,
Nano SAPO-31 molecular sieve 67, polyoxyalkylene amine 23, distilled water 42.
Further, the fungicide is chitin fiber.
Particularly, fungicide of the invention is mixed to enter in nano SAPO-31 molecular sieve and adsorbed, and forms slowly releasing effect,
Long-acting antibacterial layer is formed in coating surface.
Further, the coalescents are propandiol butyl ether.
Further, the dispersant is methyl anyl alcohol, can reach more preferable dispersion effect.
Further, the thickener is hydroxyethyl ether cellulose, and defoamer is tributyl phosphate, and pH adjusting agent is diethyl
Hydramine.
The preparation method of coating of the present invention is：S1. by butyl acrylate, methyl methacrylate, 3,5- dimethyl sulphur-based -2,
Shaken up after 4- toluenediamines, azodiisobutyronitrile, mannitol dissolving, wherein acrylic monomers uses after newly steaming.After shaking up
Solution is heated to 40-50 DEG C, and stirs 60-90min with 60r/min, obtains mixed solution；S2. by polyimides tiny balloon
Mixed with fungicide；S3. remaining component of the component in S1 and S2 and coating is mixed according to mass fraction, with 4000-
The rate of dispersion of 5500r/min disperses 20-40min.
Embodiment 2
A kind of functional form footwear coating composition, includes the component of following parts by weight：Styrene-butadiene latex 21, methyl
Methyl acrylate 27,3,5- dimethyl sulphur-baseds -2,4- toluenediamine 17, azodiisobutyronitrile 11, mannitol 13, dispersant
6th, thickener 5, fungicide 39, defoamer 2, pH adjusting agent 8, nano SAPO-31 molecular sieve 67, polyoxyalkylene amine 23,
Distilled water 42.
Further, the fungicide is chitin fiber.
Further, the coalescents are propane diols.
Further, the dispersant is the poly- diethanol that molecular weight is 5000 and the poly- diethanol that molecular weight is 4000
4:The mixture of 5 mass ratioes, can reach more preferable dispersion effect.
Further, the thickener is hydroxyethyl ether cellulose, and defoamer is tributyl phosphate, and pH adjusting agent is diethyl
Hydramine.
Embodiment 3
A kind of functional form footwear coating composition, includes the component of following parts by weight：The functional form footwear coating composition
Include the component of following parts by weight：Styrene-butadiene latex 19, methyl methacrylate 24,3,5- dimethyl sulphur-based -2,
4- toluenediamines 15, azodiisobutyronitrile 10, mannitol 11, dispersant 6, thickener 4, fungicide 31, defoamer 2,
PH adjusting agent 5, nano SAPO-31 molecular sieve 63, polyoxyalkylene amine 21, distilled water 39.
Further, the fungicide is chitin fiber.
Further, the coalescents are ethylene glycol monobutyl ether.
Further, the dispersant is lauryl sodium sulfate, can reach more preferable dispersion effect.
Further, the thickener is hydroxyethyl ether cellulose, and defoamer is tributyl phosphate, and pH adjusting agent is diethyl
Hydramine.
Embodiment 4
A kind of functional form footwear coating composition, includes the component of following parts by weight：Styrene-butadiene latex 24, methyl
Methyl acrylate 35,3,5- dimethyl sulphur-baseds -2,4- toluenediamine 21, azodiisobutyronitrile 14, mannitol 17, dispersant
9th, thickener 8, fungicide 57, defoamer 3, pH adjusting agent 11, nano SAPO-31 molecular sieve 73, polyoxyalkylene amine
28th, distilled water 56.
Further, the fungicide is chitin fiber.
Further, the coalescents are propane diols.
Further, the dispersant is methyl anyl alcohol, can reach more preferable dispersion effect.
Further, the thickener is hydroxyethyl ether cellulose, and defoamer is tributyl phosphate, and pH adjusting agent is diethyl
Hydramine.
Embodiment 5
A kind of functional form footwear coating composition, includes the component of following parts by weight：Styrene-butadiene latex 22, methyl
Methyl acrylate 31,3,5- dimethyl sulphur-baseds -2,4- toluenediamine 19, azodiisobutyronitrile 12, mannitol 15, dispersant
7th, thickener 7, fungicide 46, defoamer 3, pH adjusting agent 9, nano SAPO-31 molecular sieve 70, polyoxyalkylene amine 25,
Distilled water 45.
Further, the fungicide is chitin fiber.
Further, the coalescents are ethylene glycol monobutyl ether.
Further, the dispersant is polyacrylamide, can reach more preferable dispersion effect.
Further, the thickener is hydroxyethyl ether cellulose, and defoamer is tributyl phosphate, and pH adjusting agent is diethyl
Hydramine.
Embodiment 6
A kind of functional form footwear coating composition, includes the component of following parts by weight：Styrene-butadiene latex 16, methyl
Methyl acrylate 19,3,5- dimethyl sulphur-baseds -2,4- toluenediamine 13, azodiisobutyronitrile 9, mannitol 8, dispersant 5,
Thickener 2, fungicide 23, defoamer 1, pH adjusting agent 4, nano SAPO-31 molecular sieve 59, polyoxyalkylene amine 16, steaming
Distilled water 33.
Further, the fungicide is chitin fiber.
Further, the coalescents are dimethyl ether.
Further, the dispersant is guar gum, can reach more preferable dispersion effect.
Further, the thickener is hydroxyethyl ether cellulose, and defoamer is tributyl phosphate, and pH adjusting agent is diethyl
Hydramine.
Comparative example 1
A kind of functional form footwear coating composition, includes the component of following parts by weight：Styrene-butadiene latex 21, methyl
Methyl acrylate 27,3,5- dimethyl sulphur-baseds -2,4- toluenediamine 17, azodiisobutyronitrile 11, mannitol 13, dispersant
6th, thickener 5, defoamer 2, pH adjusting agent 8, nano SAPO-31 molecular sieve 67, polyoxyalkylene amine 23, distilled water 42.
Further, the coalescents are diethylene glycol monoethyl ether.
Further, the dispersant is fatty acid polyethylene glycol ester, can reach more preferable dispersion effect.
Further, the thickener is hydroxyethyl ether cellulose, and defoamer is tributyl phosphate, and pH adjusting agent is diethyl
Hydramine.
Comparative example 2
A kind of functional form footwear coating composition, includes the component of following parts by weight：Styrene-butadiene latex 21, methyl
Methyl acrylate 27,3,5- dimethyl sulphur-baseds -2,4- toluenediamine 17, azodiisobutyronitrile 11, mannitol 13, dispersant
6th, thickener 5, fungicide 39, defoamer 2, pH adjusting agent 8, nano SAPO-31 molecular sieve 67, distilled water 42.
Further, the fungicide is chitin fiber.
Further, the coalescents are tripropylene glycol butyl ether.
Further, the dispersant is polyacrylamide.
Further, the thickener is hydroxyethyl ether cellulose, and defoamer is tributyl phosphate, and pH adjusting agent is diethyl
Hydramine.
Comparative example 3
A kind of functional form footwear coating composition, includes the component of following parts by weight：Styrene-butadiene latex 21, methyl
Methyl acrylate 27,3,5- dimethyl sulphur-baseds -2,4- toluenediamine 17, azodiisobutyronitrile 11, mannitol 13, dispersant
6th, thickener 5, fungicide 39, defoamer 2, pH adjusting agent 8, polyoxyalkylene amine 23, distilled water 42.
Further, the fungicide is chitin fiber.
Further, the coalescents are propane diols.
Further, the dispersant is methyl anyl alcohol.
Further, the thickener is hydroxyethyl ether cellulose, and defoamer is tributyl phosphate, and pH adjusting agent is diethyl
Hydramine.
Coating property is tested
Salt spray resistance
Coating in embodiment and comparative example is coated on wooden test piece respectively and in aluminium alloy test piece, aluminium alloy test piece is selected
6063.After paint spraying, tested when standing 48 is small after film forming is fully cured in coating.Adhesive force survey is carried out to above-mentioned coating
Examination, neutral salt spray test, test method according to《GB/T 1720-1979 paint film adhesion determination methods》、《GB/T 10125-2012
Artificial atmosphere corrosion test salt spray test》Carry out；Anti-microbial property test is carried out according to GB/T 21866-2008, test result is such as
Following table.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, Er Qie
In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter
From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power
Profit requires rather than described above limits, it is intended that all in the implication and scope of the equivalency of claim by falling
Change is included in the present invention.
Moreover, it will be appreciated that although the present specification is described in terms of embodiments, not each embodiment is only wrapped
Containing an independent technical solution, this narrating mode of specification is only that those skilled in the art should for clarity
Using specification as an entirety, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art
It is appreciated that other embodiment.It is noted that the technical characteristic not being described in detail in the present invention, can pass through this
Field any prior art is realized.
Claims (7)
1. a kind of functional form footwear coating composition, it is characterised in that include the component of following parts by weight：Styrene-fourth two
Alkene latex 16-24, methyl methacrylate 19-35,3,5- dimethyl sulphur-based -2,4- toluenediamines 13-21, azodiisobutyronitrile
9-14, mannitol 8-17, dispersant 5-9, thickener 2-8, fungicide 23-57, defoamer 1-3, pH adjusting agent 4-11,
Nano SAPO-31 molecular sieve 59-73, polyoxyalkylene amine 16-28, distilled water 33-56.
2. functional form footwear coating composition according to claim 1, it is characterised in that include the group of following parts by weight
Point：Styrene-butadiene latex 19-22, methyl methacrylate 24-31,3,5- dimethyl sulphur-based -2,4- toluenediamines 15-
19th, azodiisobutyronitrile 10-12, mannitol 11-15, dispersant 6-7, thickener 4-7, fungicide 31-46, defoamer
2-3, pH adjusting agent 5-9, nano SAPO-31 molecular sieve 63-70, polyoxyalkylene amine 21-25, distilled water 39-45.
3. functional form footwear coating composition according to claim 1, it is characterised in that include the group of following parts by weight
Point：Styrene-butadiene latex 21, methyl methacrylate 27,3,5- dimethyl sulphur-baseds -2,4- toluenediamine 17, azo two
Isobutyronitrile 11, mannitol 13, dispersant 6, thickener 5, fungicide 39, defoamer 2, pH adjusting agent 8, nanometer SAPO-
31 molecular sieves 67, polyoxyalkylene amine 23, distilled water 42.
4. functional form footwear coating composition according to claim 1, it is characterised in that the fungicide is fine for chitin
Dimension.
5. functional form footwear coating composition according to claim 1, it is characterised in that the coalescents are the third two
Alcohol, methoxybutanol, ethylene glycol monobutyl ether, propandiol butyl ether, dimethyl ether, diethylene glycol monoethyl ether, tripropylene glycol
One kind in butyl ether.
6. functional form footwear coating composition according to claim 1, it is characterised in that the dispersant is dodecyl
One kind in sodium sulphate, methyl anyl alcohol, polyacrylamide, guar gum, fatty acid polyethylene glycol ester.
7. functional form footwear coating composition according to claim 1, it is characterised in that the thickener is fine for ethoxy
The plain ether of dimension, defoamer is tributyl phosphate, and pH adjusting agent is diethanol amine.
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| CN201711359065.5A CN107936650A (en) | 2017-12-17 | 2017-12-17 | A kind of functional form footwear coating composition |
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| CN1042171A (en) * | 1988-10-27 | 1990-05-16 | 山东省文登县合成里革厂 | A kind of high-molecular coating glue and application thereof |
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Application publication date: 20180420 |