CN107805420A - A kind of footwear protective coating - Google Patents
A kind of footwear protective coating Download PDFInfo
- Publication number
- CN107805420A CN107805420A CN201711359067.4A CN201711359067A CN107805420A CN 107805420 A CN107805420 A CN 107805420A CN 201711359067 A CN201711359067 A CN 201711359067A CN 107805420 A CN107805420 A CN 107805420A
- Authority
- CN
- China
- Prior art keywords
- protective coating
- footwear
- bactericide
- thickener
- defoamer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D105/00—Coating compositions based on polysaccharides or on their derivatives, not provided for in groups C09D101/00 or C09D103/00
- C09D105/08—Chitin; Chondroitin sulfate; Hyaluronic acid; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
- C08K2003/327—Aluminium phosphate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention provides a kind of footwear protective coating, it is characterised in that includes the component of following parts by weight：Carboxyl fourth cyanogen latex 16 24, the diamino hexane 13 21 of methyl methacrylate 19 35,1,6, azodiisobutyronitrile 9 14, mannitol 8 17, dispersant 59, thickener 28, bactericide 23 57, defoamer 13, pH adjusting agent 4 11, nano-aluminum phosphate molecular sieve 59 73, polyoxyalkylene amine 16 28, distilled water 33 56.The present invention can significantly improve article of footwear to being lost, wearing and the resistance of other damages, durability and anti-microbial property, used suitable for large-scale promotion.
Description
Technical field
The present invention relates to footwear applications technical field of coatings, and in particular to a kind of coating for footwear.
Background technology
Coating composition is used in numerous industry.These industry can include, but not limited to land transport vehicle for example
Car, truck, sport vehicle, motorcycle；Marine equipment such as ship, ship and submarine；Airborne vehicle such as aircraft
And helicopter；Industrial such as business equipment and structure, including wall and roof；Build such as Construction traffic and structure, bag
Include wall and roof, military such as military vehicle, such as tank and brave horse transport vehicle, and military structure body, including wall and roof,
Such as caisson and battery case etc..
In these industry, coating for example protects various parts from because of corrosion, wear, impact, change for numerous purposes
Damaged caused by product, ultraviolet light, flame and heat and other environmental exposures, and for their parts deposited thereon well
Assign shellproof and explosion-proof buffering performance (balllistic and blast mitigation properties).Therefore,
Take huge effort has the coating composition for improving performance to develop.
Coating usually can be used for footwear industry.Footwear (footwear) generally fall into two parts, vamp and sole.
Vamp is the part for being designed as cosily encapsulating foot of footwear, and the attachment that is designed as providing that sole is footwear rubs
Wipe power (traction), protection, damping and/or the part on endurable surface.
Vamp is typically made up of many different parts, and these parts are usually made from a variety of materials.The material
Including, such as natural leather, synthetic leather, vinyl material and fabric such as nylon；Other fabrics can also be used.Even in
During the normal use of footwear, many upper members, particularly " toe-cap " may experience loss and/or abrasions.
Similarly, sole generally includes the different parts being made from a different material.Midsole typically by foam for example
Ethylene vinyl acetate (EVA) foam or polyurethane such as TPU foams are made.These materials application load, for example exist
Elastic compression under the power as caused by pin and leg during body movement.Many footwear, particularly sport footwear are included in another shoes department part example
Filling damping element or bladder in such as midsole, footwear outer bottom.The bladder can be by that can show resistance to compression
To provide expandable insert made of the polymeric material of additional cushioning effect for footwear wearer.These bladders can use-case
As plasma, water or other fluids such as air or nitrogen are filled.Footwear outer bottom is generally by synthesizing and/or natural rubber, such as
Silica-filled rubber composition is made.During the normal use of footwear, footwear outer bottom may also undergo loss and/or
Abrasion.
Therefore, it is intended that article of footwear to being lost, wearing and improved resistance, durability and the antibiotic property of other damages
Energy.
The content of the invention
In view of this, the present invention provides a kind of new footwear protective coating, and the present invention can significantly improve article of footwear
To being lost, wearing and the resistance of other damages, durability and anti-microbial property, used suitable for large-scale promotion.
The technical scheme is that：A kind of footwear protective coating, include the component of following parts by weight：Carboxyl fourth cyanogen glue
Newborn 16-24, methyl methacrylate 19-35,1,6- diamino hexanes 13-21, azodiisobutyronitrile 9-14, mannitol 8-
17th, dispersant 5-9, thickener 2-8, bactericide 23-57, defoamer 1-3, pH adjusting agent 4-11, nano-aluminum phosphate molecule
Sieve 59-73, polyoxyalkylene amine 16-28, distilled water 33-56.
Further, the footwear protective coating includes the component of following parts by weight：Carboxyl fourth cyanogen latex 19-22, first
It is base methyl acrylate 24-31,1,6- diamino hexanes 15-19, azodiisobutyronitrile 10-12, mannitol 11-15, scattered
Agent 6-7, thickener 4-7, bactericide 31-46, defoamer 2-3, pH adjusting agent 5-9, nano-aluminum phosphate molecular sieve 63-70,
Polyoxyalkylene amine 21-25, distilled water 39-45.
Further, the footwear protective coating includes the component of following parts by weight：Carboxyl fourth cyanogen latex 21, methyl-prop
E pioic acid methyl ester 27,1,6- diamino hexanes 17, azodiisobutyronitrile 11, mannitol 13, dispersant 6, thickener 5, kill
Microbial inoculum 39, defoamer 2, pH adjusting agent 8, nano-aluminum phosphate molecular sieve 67, polyoxyalkylene amine 23, distilled water 42.
Further, the bactericide is chitin fiber.
Further, the coalescents are propane diols, methoxybutanol, ethylene glycol monobutyl ether, propandiol butyl ether, dipropyl
One kind in glycol dimethyl ether, diethylene glycol monoethyl ether, tripropylene glycol butyl ether.
Further, the dispersant is lauryl sodium sulfate, methyl anyl alcohol, polyacrylamide, guar gum, aliphatic acid
One kind in macrogol ester.The poly- diethanol that the dispersant is the poly- diethanol that molecular weight is 5000 and molecular weight is 4000
4:The mixture of 5 mass ratioes, more preferable dispersion effect can be reached.
Further, the thickener is hydroxyethyl ether cellulose, and defoamer is tributyl phosphate, and pH adjusting agent is diethyl
Hydramine.
The preparation method of coating of the present invention is：S1. by butyl acrylate, methyl methacrylate, 1,6- diamino hexanes,
Shaken up after azodiisobutyronitrile, mannitol dissolving, wherein acrylic monomers uses after newly steaming.Rear solution will be shaken up to be heated to
40-50 DEG C, and 60-90min is stirred with 60r/min, obtain mixed solution；S2. polyimides tiny balloon is mixed with bactericide
Close；S3. remaining component of the component in S1 and S2 and coating is mixed according to mass fraction, with 4000-5500r/min point
Dissipate Rate Dispersion 20-40min.
The present invention can significantly improve article of footwear to being lost, wearing and the resistance of other damages, durability and anti-
Bacterium performance, used suitable for large-scale promotion.
Embodiment
Technical scheme is clearly and completely described below in conjunction with embodiment, it is clear that described reality
It is only part of the embodiment of the present invention to apply example, rather than whole embodiments.
Embodiment 1
The present embodiment provides a kind of footwear protective coating, and the footwear protective coating includes the component of following parts by weight：Carboxyl
It is fourth cyanogen latex 21, methyl methacrylate 27,1,6- diamino hexanes 17, azodiisobutyronitrile 11, mannitol 13, scattered
Agent 6, thickener 5, bactericide 39, defoamer 2, pH adjusting agent 8, nano-aluminum phosphate molecular sieve 67, polyoxyalkylene amine
23rd, distilled water 42.
Further, the bactericide is chitin fiber.
Particularly, mixed enter in nano-aluminum phosphate molecular sieve of bactericide of the invention is adsorbed, and forms slowly releasing effect,
Coating surface forms long-acting antibacterial layer.
Further, the coalescents are propandiol butyl ether.
Further, the dispersant is methyl anyl alcohol, can reach more preferable dispersion effect.
Further, the thickener is hydroxyethyl ether cellulose, and defoamer is tributyl phosphate, and pH adjusting agent is diethyl
Hydramine.
The preparation method of coating of the present invention is：S1. by butyl acrylate, methyl methacrylate, 1,6- diamino hexanes,
Shaken up after azodiisobutyronitrile, mannitol dissolving, wherein acrylic monomers uses after newly steaming.Rear solution will be shaken up to be heated to
40-50 DEG C, and 60-90min is stirred with 60r/min, obtain mixed solution；S2. polyimides tiny balloon is mixed with bactericide
Close；S3. remaining component of the component in S1 and S2 and coating is mixed according to mass fraction, with 4000-5500r/min point
Dissipate Rate Dispersion 20-40min.
Embodiment 2
A kind of footwear protective coating, include the component of following parts by weight：Carboxyl fourth cyanogen latex 21, methyl methacrylate 27,
1,6- diamino hexane 17, azodiisobutyronitrile 11, mannitol 13, dispersant 6, thickener 5, bactericide 39, defoaming
Agent 2, pH adjusting agent 8, nano-aluminum phosphate molecular sieve 67, polyoxyalkylene amine 23, distilled water 42.
Further, the bactericide is chitin fiber.
Further, the coalescents are propane diols.
Further, the dispersant is the poly- diethanol that molecular weight is 5000 and the poly- diethanol that molecular weight is 4000
4:The mixture of 5 mass ratioes, more preferable dispersion effect can be reached.
Further, the thickener is hydroxyethyl ether cellulose, and defoamer is tributyl phosphate, and pH adjusting agent is diethyl
Hydramine.
Embodiment 3
A kind of footwear protective coating, include the component of following parts by weight：The footwear protective coating includes following parts by weight
Component：It is carboxyl fourth cyanogen latex 19, methyl methacrylate 24,1,6- diamino hexanes 15, azodiisobutyronitrile 10, sweet
Reveal alcohol 11, dispersant 6, thickener 4, bactericide 31, defoamer 2, pH adjusting agent 5, nano-aluminum phosphate molecular sieve 63, poly-
Oxyalkylene amine 21, distilled water 39.
Further, the bactericide is chitin fiber.
Further, the coalescents are ethylene glycol monobutyl ether.
Further, the dispersant is lauryl sodium sulfate, can reach more preferable dispersion effect.
Further, the thickener is hydroxyethyl ether cellulose, and defoamer is tributyl phosphate, and pH adjusting agent is diethyl
Hydramine.
Embodiment 4
A kind of footwear protective coating, include the component of following parts by weight：Carboxyl fourth cyanogen latex 24, methyl methacrylate 35,
1,6- diamino hexane 21, azodiisobutyronitrile 14, mannitol 17, dispersant 9, thickener 8, bactericide 57, defoaming
Agent 3, pH adjusting agent 11, nano-aluminum phosphate molecular sieve 73, polyoxyalkylene amine 28, distilled water 56.
Further, the bactericide is chitin fiber.
Further, the coalescents are propane diols.
Further, the dispersant is methyl anyl alcohol, can reach more preferable dispersion effect.
Further, the thickener is hydroxyethyl ether cellulose, and defoamer is tributyl phosphate, and pH adjusting agent is diethyl
Hydramine.
Embodiment 5
A kind of footwear protective coating, include the component of following parts by weight：Carboxyl fourth cyanogen latex 22, methyl methacrylate 31,
1,6- diamino hexane 19, azodiisobutyronitrile 12, mannitol 15, dispersant 7, thickener 7, bactericide 46, defoaming
Agent 3, pH adjusting agent 9, nano-aluminum phosphate molecular sieve 70, polyoxyalkylene amine 25, distilled water 45.
Further, the bactericide is chitin fiber.
Further, the coalescents are ethylene glycol monobutyl ether.
Further, the dispersant is polyacrylamide, can reach more preferable dispersion effect.
Further, the thickener is hydroxyethyl ether cellulose, and defoamer is tributyl phosphate, and pH adjusting agent is diethyl
Hydramine.
Embodiment 6
A kind of footwear protective coating, include the component of following parts by weight：Carboxyl fourth cyanogen latex 16, methyl methacrylate 19,
1,6- diamino hexane 13, azodiisobutyronitrile 9, mannitol 8, dispersant 5, thickener 2, bactericide 23, defoamer
1st, pH adjusting agent 4, nano-aluminum phosphate molecular sieve 59, polyoxyalkylene amine 16, distilled water 33.
Further, the bactericide is chitin fiber.
Further, the coalescents are dimethyl ether.
Further, the dispersant is guar gum, can reach more preferable dispersion effect.
Further, the thickener is hydroxyethyl ether cellulose, and defoamer is tributyl phosphate, and pH adjusting agent is diethyl
Hydramine.
Comparative example 1
A kind of footwear protective coating, include the component of following parts by weight：Carboxyl fourth cyanogen latex 21, methyl methacrylate 27,
1,6- diamino hexane 17, azodiisobutyronitrile 11, mannitol 13, dispersant 6, thickener 5, defoamer 2, pH regulations
Agent 8, nano-aluminum phosphate molecular sieve 67, polyoxyalkylene amine 23, distilled water 42.
Further, the coalescents are diethylene glycol monoethyl ether.
Further, the dispersant is fatty acid polyethylene glycol ester, can reach more preferable dispersion effect.
Further, the thickener is hydroxyethyl ether cellulose, and defoamer is tributyl phosphate, and pH adjusting agent is diethyl
Hydramine.
Comparative example 2
A kind of footwear protective coating, include the component of following parts by weight：Carboxyl fourth cyanogen latex 21, methyl methacrylate 27,
1,6- diamino hexane 17, azodiisobutyronitrile 11, mannitol 13, dispersant 6, thickener 5, bactericide 39, defoaming
Agent 2, pH adjusting agent 8, nano-aluminum phosphate molecular sieve 67, distilled water 42.
Further, the bactericide is chitin fiber.
Further, the coalescents are tripropylene glycol butyl ether.
Further, the dispersant is polyacrylamide.
Further, the thickener is hydroxyethyl ether cellulose, and defoamer is tributyl phosphate, and pH adjusting agent is diethyl
Hydramine.
Comparative example 3
A kind of footwear protective coating, include the component of following parts by weight：Carboxyl fourth cyanogen latex 21, methyl methacrylate 27,
1,6- diamino hexane 17, azodiisobutyronitrile 11, mannitol 13, dispersant 6, thickener 5, bactericide 39, defoaming
Agent 2, pH adjusting agent 8, polyoxyalkylene amine 23, distilled water 42.
Further, the bactericide is chitin fiber.
Further, the coalescents are propane diols.
Further, the dispersant is methyl anyl alcohol.
Further, the thickener is hydroxyethyl ether cellulose, and defoamer is tributyl phosphate, and pH adjusting agent is diethyl
Hydramine.
Coating property is tested
Salt spray resistance
Coating in embodiment and comparative example is coated on wooden test piece respectively and in aluminium alloy test piece, aluminium alloy test piece is selected
6063.After paint spraying, stand 48 hours and tested after film forming is fully cured in coating.Adhesive force survey is carried out to above-mentioned coating
Examination, neutral salt spray test, method of testing according to《GB/T 1720-1979 paint film adhesion determination methods》、《GB/T 10125-2012
Artificial atmosphere corrosion test salt spray test》Carry out；Anti-microbial property test is carried out according to GB/T 21866-2008, test result is such as
Following table.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, Er Qie
In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter
From the point of view of which point, embodiment all should be regarded as exemplary, and be nonrestrictive, the scope of the present invention is by appended power
Profit requires rather than described above limits, it is intended that all in the implication and scope of the equivalency of claim by falling
Change is included in the present invention.
Moreover, it will be appreciated that although the present specification is described in terms of embodiments, not each embodiment is only wrapped
Containing an independent technical scheme, this narrating mode of specification is only that those skilled in the art should for clarity
Using specification as an entirety, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art
It is appreciated that other embodiment.It is noted that the technical characteristic not being described in detail in the present invention, can pass through this
Field any prior art is realized.
Claims (7)
1. a kind of footwear protective coating, it is characterised in that include the component of following parts by weight：Carboxyl fourth cyanogen latex 16-24, first
Base methyl acrylate 19-35,1,6- diamino hexanes 13-21, azodiisobutyronitrile 9-14, mannitol 8-17, dispersant
It is 5-9, thickener 2-8, bactericide 23-57, defoamer 1-3, pH adjusting agent 4-11, nano-aluminum phosphate molecular sieve 59-73, poly-
Oxyalkylene amine 16-28, distilled water 33-56.
2. footwear protective coating according to claim 1, it is characterised in that include the component of following parts by weight：Carboxyl
It is fourth cyanogen latex 19-22, methyl methacrylate 24-31,1,6- diamino hexanes 15-19, azodiisobutyronitrile 10-12, sweet
Reveal alcohol 11-15, dispersant 6-7, thickener 4-7, bactericide 31-46, defoamer 2-3, pH adjusting agent 5-9, nanometer phosphorus
Sour aluminum molecular screen 63-70, polyoxyalkylene amine 21-25, distilled water 39-45.
3. footwear protective coating according to claim 1, it is characterised in that include the component of following parts by weight：Carboxyl
It is fourth cyanogen latex 21, methyl methacrylate 27,1,6- diamino hexanes 17, azodiisobutyronitrile 11, mannitol 13, scattered
Agent 6, thickener 5, bactericide 39, defoamer 2, pH adjusting agent 8, nano-aluminum phosphate molecular sieve 67, polyoxyalkylene amine
23rd, distilled water 42.
4. footwear protective coating according to claim 1, it is characterised in that the bactericide is chitin fiber.
5. footwear protective coating according to claim 1, it is characterised in that the coalescents are propane diols, methoxyl group
One in butanol, ethylene glycol monobutyl ether, propandiol butyl ether, dimethyl ether, diethylene glycol monoethyl ether, tripropylene glycol butyl ether
Kind.
6. footwear protective coating according to claim 1, it is characterised in that the dispersant be lauryl sodium sulfate,
One kind in methyl anyl alcohol, polyacrylamide, guar gum, fatty acid polyethylene glycol ester.
7. footwear protective coating according to claim 1, it is characterised in that the thickener is hydroxyethyl ether cellulose,
Defoamer is tributyl phosphate, and pH adjusting agent is diethanol amine.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711359067.4A CN107805420A (en) | 2017-12-17 | 2017-12-17 | A kind of footwear protective coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711359067.4A CN107805420A (en) | 2017-12-17 | 2017-12-17 | A kind of footwear protective coating |
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| CN107805420A true CN107805420A (en) | 2018-03-16 |
Family
ID=61579997
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| CN201711359067.4A Pending CN107805420A (en) | 2017-12-17 | 2017-12-17 | A kind of footwear protective coating |
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Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1042171A (en) * | 1988-10-27 | 1990-05-16 | 山东省文登县合成里革厂 | A kind of high-molecular coating glue and application thereof |
| CN1653144A (en) * | 2002-05-08 | 2005-08-10 | 纳幕尔杜邦公司 | Non-yellowing polyester coating composition |
| CN1656134A (en) * | 2002-04-19 | 2005-08-17 | Ppg工业俄亥俄公司 | Coating compositions containing polyurethane dispersions and highly crosslinked polymer particles |
| CN101914261A (en) * | 2010-08-12 | 2010-12-15 | 河北科技大学 | Polyurethane oil/polyacrylate latex interpenetrating network polymer emulsion material and synthesizing process thereof |
| CN102757705A (en) * | 2011-04-27 | 2012-10-31 | 张宝庆 | Waterproof coating |
| CN104927422A (en) * | 2014-03-21 | 2015-09-23 | 荆春芳 | Latex coating composition |
| CN105121033A (en) * | 2013-02-21 | 2015-12-02 | 伯宁布什集团有限公司 | Method for applying high performance silicon-based coating compositions |
| CN106967340A (en) * | 2017-04-10 | 2017-07-21 | 北京宜刚鞋业有限公司 | A kind of outward appearance has the fashion rubber boot of photochromism, fashion rubber boot coating and preparation method thereof |
| CN107418418A (en) * | 2017-06-01 | 2017-12-01 | 湖南新力华纳米科技有限公司 | A kind of aqueous polyurethane spray painting for being used for fabric and footwear material and preparation method thereof |
-
2017
- 2017-12-17 CN CN201711359067.4A patent/CN107805420A/en active Pending
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1042171A (en) * | 1988-10-27 | 1990-05-16 | 山东省文登县合成里革厂 | A kind of high-molecular coating glue and application thereof |
| CN1656134A (en) * | 2002-04-19 | 2005-08-17 | Ppg工业俄亥俄公司 | Coating compositions containing polyurethane dispersions and highly crosslinked polymer particles |
| CN1653144A (en) * | 2002-05-08 | 2005-08-10 | 纳幕尔杜邦公司 | Non-yellowing polyester coating composition |
| CN101914261A (en) * | 2010-08-12 | 2010-12-15 | 河北科技大学 | Polyurethane oil/polyacrylate latex interpenetrating network polymer emulsion material and synthesizing process thereof |
| CN102757705A (en) * | 2011-04-27 | 2012-10-31 | 张宝庆 | Waterproof coating |
| CN105121033A (en) * | 2013-02-21 | 2015-12-02 | 伯宁布什集团有限公司 | Method for applying high performance silicon-based coating compositions |
| CN104927422A (en) * | 2014-03-21 | 2015-09-23 | 荆春芳 | Latex coating composition |
| CN106967340A (en) * | 2017-04-10 | 2017-07-21 | 北京宜刚鞋业有限公司 | A kind of outward appearance has the fashion rubber boot of photochromism, fashion rubber boot coating and preparation method thereof |
| CN107418418A (en) * | 2017-06-01 | 2017-12-01 | 湖南新力华纳米科技有限公司 | A kind of aqueous polyurethane spray painting for being used for fabric and footwear material and preparation method thereof |
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Application publication date: 20180316 |