CN107930825A - A kind of method that separation colour developing mineral improve product quality from porcelain stone - Google Patents

A kind of method that separation colour developing mineral improve product quality from porcelain stone Download PDF

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Publication number
CN107930825A
CN107930825A CN201711187294.3A CN201711187294A CN107930825A CN 107930825 A CN107930825 A CN 107930825A CN 201711187294 A CN201711187294 A CN 201711187294A CN 107930825 A CN107930825 A CN 107930825A
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CN
China
Prior art keywords
ball
porcelain stone
product quality
milling
ball milling
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Pending
Application number
CN201711187294.3A
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Chinese (zh)
Inventor
赖永贤
曹泽亮
郭阿明
黄波
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Longyan Kaolin Ltd By Share Ltd
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Longyan Kaolin Ltd By Share Ltd
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Priority to CN201711187294.3A priority Critical patent/CN107930825A/en
Publication of CN107930825A publication Critical patent/CN107930825A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B02CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
    • B02CCRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
    • B02C21/00Disintegrating plant with or without drying of the material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B02CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
    • B02CCRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
    • B02C23/00Auxiliary methods or auxiliary devices or accessories specially adapted for crushing or disintegrating not provided for in preceding groups or not specially adapted to apparatus covered by a single preceding group
    • B02C23/08Separating or sorting of material, associated with crushing or disintegrating
    • B02C23/16Separating or sorting of material, associated with crushing or disintegrating with separator defining termination of crushing or disintegrating zone, e.g. screen denying egress of oversize material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B02CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
    • B02CCRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
    • B02C23/00Auxiliary methods or auxiliary devices or accessories specially adapted for crushing or disintegrating not provided for in preceding groups or not specially adapted to apparatus covered by a single preceding group
    • B02C23/08Separating or sorting of material, associated with crushing or disintegrating
    • B02C23/16Separating or sorting of material, associated with crushing or disintegrating with separator defining termination of crushing or disintegrating zone, e.g. screen denying egress of oversize material
    • B02C2023/165Screen denying egress of oversize material

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  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Disintegrating Or Milling (AREA)

Abstract

The invention discloses a kind of method that separation colour developing mineral improve product quality from porcelain stone, including ball milling refinement, screening, by rational parameter setting, colour developing mineral are separated from porcelain stone, obtain the higher porcelain stone product of quality.The present invention is had main steps that using traditional ball-milling technology, producer only need to be according to the needs of itself product quality, reasonably adjusting the grading of ball-milling medium and control Ball-milling Time can meet to produce needs, and newly-increased input is small, can largely adapt to the application demand of different manufacturers;Handled after ball milling refinement by simple sieve sieving technology, it can reach the purpose that separation substance that show color improves product quality, largely alleviate the difficulty of later stage magnetic separation removal technique, or product quality can reach producer's requirement after screened processing, then the later stage can save the input of magnetic separation removal, and method is simple and convenient effectively.

Description

A kind of method that separation colour developing mineral improve product quality from porcelain stone
Technical field
The present invention relates to the manufacture field of nonmetallic ore, more particularly to one kind separation colour developing mineral from porcelain stone to improve product The method of quality.
Background technology
Porcelain stone largely exists under the Eastern Palace of Longyan in kaolin ore body, and reserves are about 100 ~ 2,000,000 tons, since its origin cause of formation is special Property porcelain stone ore deposit in be usually associated with the colour developing mineral such as a small amount of biotite, leverage the quality of product.At present, the processing of porcelain stone Method of purification mainly uses machine treadle-operated tilt hammer for hulling rice hydraulic beneficiation method(1. Chen Wen is auspicious, the exploitation of porcelain stone under the Eastern Palace of Guo A Ming nonmetallic ore Longyan Utilize [J] 2001,24 (2):44-45.)With permanent-magnet concentration purifying technique(2. the bright nonmetallic ores porcelain stones refinement purifications of Cao Ze Experimental study [J] 2017 (1):62-63.)Also all it is to be arrived porcelain stone ball milling using the method for ball milling Deng, the most producer of in the market Certain fineness(Control is tailed over below 1%)After carry out magnetic separation removal, which results in porcelain stone some colour developing mineral such as black clouds Mothers etc. are also mixed into product by ball milling refinement together, and some colour developing mineral are probably non magnetic or weak magnetic mineral, use Magnetic separation process, which is handled, can not also be separated, so that the quality of product reduces.Therefore, how using each in porcelain stone A kind of characteristic of kind mineral, method that separation colour developing mineral improve product quality from porcelain stone of research, was producing for producer Product quality increase company benefit is improved in journey to be of great significance.
There is part of the manufacturer by porcelain stone, water and high aluminium ball by 14 currently on the market:7:In 15 mass ratios input 20t ball mills When ball milling 12 is small, wherein ball-milling medium mass ratio is φ 60mm:φ50mm:φ40mm:φ30mm =1:1.5:2:10;Porcelain stone ball Ball milling slurry is from flowing to slurry pool after levigateization, is diluted with water the control of ball milling slurry concentration 25 ~ 30%, ball milling refines 200 mesh sieves Remaining control is below 1%;Then magnetic separation removal processing, result of the test twice is carried out to show:The porcelain stone 1280 after this method is handled DEG C firing whiteness(Piece)69.1%, porcelain stone sample observation is less than obvious stain, but the technique processing loss is 15% ~ 20%.
Document 2(Bright nonmetallic ores porcelain stones refinement purification experimental study [J] 2017 (1) of Cao Ze:62-63.)Middle use Technique only carry out screening process with 250 mesh sieve nets and cannot remove biotite completely, product still can be seen obvious black after processing Point, although the good processing loss of effect is handled as 8 ~ 10% with magnetic separation process, and magnetic separation cost needs about 40 yuan/ton, it is required Cost is higher.
The content of the invention
It is an object of the invention to provide a kind of method that separation colour developing mineral improve product quality from porcelain stone, in ball milling Ball-milling medium uses rational grading during refinement, by controlling rational Ball-milling Time in conjunction with rational sieving technology, effectively Ground improves the quality of product.
Technical problem solved by the invention can be realized using following technical scheme:
A kind of method that separation colour developing mineral improve product quality from porcelain stone, it is characterized in that:Comprise the following steps:
Step 1:Porcelain stone is fitted into ball mill after crushing, carries out ball milling micronization processes;
Step 2:Porcelain stone is diluted with water ball milling slurry after ball milling refines, and then carries out screening process using sieve.
Preferably, in step 1, the ball-milling medium proportioning being equipped with the ball mill is φ 70mm:25 ~ 50%, φ 50mm:25 ~ 30%, φ 30mm:25~50%.
Preferably, in step 1, the time of the ball milling micronization processes is 18 ~ 22h.
Preferably, in step 2, the concentration for being diluted with water ball milling slurry is 10 ~ 20%;Sieve used by screening Mesh number is the mesh of 325 mesh ~ 500.
The present invention had main steps that using traditional ball-milling technology, and producer only need to be according to the needs of itself product quality, rationally The grading and control Ball-milling Time of ground adjustment ball-milling medium can meet production needs, and newly-increased input is small, can largely fit Answer the application demand of different manufacturers;Handled after ball milling refinement by simple sieve sieving technology, you can reach separation colour developing thing Matter improves the purpose of product quality, largely alleviates the difficulty of later stage magnetic separation removal technique, or after screened processing Product quality can reach producer's requirement, then the later stage can save the input of magnetic separation removal, method is simple and convenient effectively.
Embodiment
The present invention is described in further detail with reference to embodiment, but the implementation of the present invention is not limited to this.
A kind of method that separation colour developing mineral improve product quality from porcelain stone, is made of successively the following steps:
(1) porcelain stone is fitted into ball mill after crushing, carries out ball milling micronization processes;The ball-milling medium being equipped with ball mill matches φ70mm:25 ~ 50%, φ 50mm:25 ~ 30%, φ 30mm:25~50%;Ball-milling Time is 18 ~ 22h;
(2) porcelain stone is diluted with water ball milling slurry after ball milling refines, and then carries out screening process using sieve.It is diluted with water ball The concentration of defibrination material is 10 ~ 20%;Sieve mesh number is the mesh of 325 mesh ~ 500 used by screening.
It is below the specific embodiment of the present invention:
Embodiment 1:
Porcelain stone, water and high aluminium ball are pressed 1:0.8:When ball milling 18 is small in 1.8 mass ratios input 3t ball mills, wherein ball-milling medium Mass ratio is φ 70mm:φ50mm:φ30mm=50%:25%:25%;Ball milling slurry adds from slurry pool is flow to after the refinement of porcelain stone ball milling The control of ball milling slurry concentration is carried out screening process by water dilution after 15%, ball milling pulp dilution with vibrating screen, used by screening Sieve mesh number is 325 mesh;Result of the test shows:1280 DEG C of firing whiteness of porcelain stone after this method is handled(Piece)Carried by 67.1% Up to 69.1%, porcelain stone sample observation is less than obvious stain.
Embodiment 2:
Porcelain stone, water and high aluminium ball are pressed 1:0.8:When ball milling 22 is small in 1.8 mass ratios input 3t ball mills, wherein ball-milling medium Mass ratio is φ 70mm:φ50mm:φ30mm=50%:25%:25%;Ball milling slurry adds from slurry pool is flow to after the refinement of porcelain stone ball milling The control of ball milling slurry concentration is carried out screening process by water dilution after 10%, ball milling pulp dilution with vibrating screen, used by screening Sieve mesh number is 325 mesh;Result of the test shows:1280 DEG C of firing whiteness of porcelain stone after this method is handled(Piece)Carried by 67.1% Up to 70.8%, porcelain stone sample observation is less than obvious stain.
Embodiment 3:
Porcelain stone, water and high aluminium ball are pressed 1:0.8:When ball milling 12 is small in 1.8 mass ratios input 3t ball mills, wherein ball-milling medium Mass ratio is φ 70mm:φ50mm:φ30mm=50%:25%:25%;Ball milling slurry adds from slurry pool is flow to after the refinement of porcelain stone ball milling The control of ball milling slurry concentration is carried out screening process by water dilution after 15%, ball milling pulp dilution with vibrating screen, used by screening Sieve mesh number is 325 mesh;Result of the test shows:1280 DEG C of firing whiteness of porcelain stone after this method is handled(Piece)Carried by 67.1% Up to 67.5%, porcelain stone sample observation is less than obvious stain.
Embodiment 4:
Porcelain stone, water and high aluminium ball are pressed 1:0.8:When ball milling 14 is small in 1.8 mass ratios input 3t ball mills, wherein ball-milling medium Mass ratio is φ 70mm:φ50mm:φ30mm=50%:25%:25%;Ball milling slurry adds from slurry pool is flow to after the refinement of porcelain stone ball milling The control of ball milling slurry concentration is carried out screening process by water dilution after 15%, ball milling pulp dilution with vibrating screen, used by screening Sieve mesh number is 325 mesh;Result of the test shows:1280 DEG C of firing whiteness of porcelain stone after this method is handled(Piece)Carried by 67.1% Up to 66.7%, porcelain stone sample observation is less than obvious stain.
Embodiment 5:
Porcelain stone, water and high aluminium ball are pressed 1:0.8:When ball milling 20 is small in 1.8 mass ratios input 3t ball mills, wherein ball-milling medium Mass ratio is φ 70mm:φ50mm:φ30mm=50%:25%:25%;Ball milling slurry adds from slurry pool is flow to after the refinement of porcelain stone ball milling The control of ball milling slurry concentration is carried out screening process by water dilution after 15%, ball milling pulp dilution with vibrating screen, used by screening Sieve mesh number is 325 mesh;Result of the test shows:1280 DEG C of firing whiteness of porcelain stone after this method is handled(Piece)Carried by 67.1% Up to 68.7%, porcelain stone sample observation is less than obvious stain.
The experimental data such as table 1 of the ball milling micronization processes time of the present invention:
Ball-milling Time 1280 DEG C of firing whiteness(Piece) Porcelain stone sample Processing loss(325 mesh screen residues)
It is undressed 67.1% It is observed that obvious stain /
12h 67.5% Obvious stain is not observed 11.25%
14h 66.7% Obvious stain is not observed 9.63%
16h 67.9% Obvious stain is not observed 6.66%
18h 69.1% Obvious stain is not observed 6.48%
20h 68.7% Obvious stain is not observed 5.03%
22h 70.8% Obvious stain is not observed 4.01%
Table 1:
It can be seen that from upper table, Ball-milling Time is in 18 ~ 22h, 1280 DEG C of firing whiteness(Piece)Height, porcelain stone sample observation is less than bright Aobvious stain, and it is minimum to process damage.Using most of black clouds can be removed in porcelain stone when processing method ball milling 22 is small described in example 2 Mother, product has not observed obvious stain after processing.
A stain, which will result in later stage ceramic product, in porcelain mud product becomes substandard products, the porcelain stone processed using the present invention Sample observation is less than obvious stain, and process loss is relatively low, therefore the product being processed using the method can applicable part The requirement of producer.
The above, is only present pre-ferred embodiments, is not intended to limit the scope of the present invention, therefore Any subtle modifications, equivalent variations and modifications that every technical spirit according to the present invention makees above example, still fall within Protection scope of the present invention.

Claims (4)

1. a kind of method that separation colour developing mineral improve product quality from porcelain stone, it is characterized in that:Comprise the following steps:
Step 1:Porcelain stone is fitted into ball mill after crushing, carries out ball milling micronization processes;
Step 2:Porcelain stone is diluted with water ball milling slurry after ball milling refines, and then carries out screening process using sieve.
2. a kind of method that separation colour developing mineral improve product quality from porcelain stone according to claim 1, its feature exist In:In step 1, the ball-milling medium proportioning being equipped with the ball mill is φ 70mm:25 ~ 50%, φ 50mm:25 ~ 30%, φ 30mm:25~50%.
3. a kind of method that separation colour developing mineral improve product quality from porcelain stone according to claim 1, its feature exist In:In step 1, the time of the ball milling micronization processes is 18 ~ 22h.
4. a kind of method that separation colour developing mineral improve product quality from porcelain stone according to claim 1, its feature exist In:In step 2, the concentration for being diluted with water ball milling slurry is 10 ~ 20%;Used by screening sieve mesh number for 325 mesh ~ 500 mesh.
CN201711187294.3A 2017-11-24 2017-11-24 A kind of method that separation colour developing mineral improve product quality from porcelain stone Pending CN107930825A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112374868A (en) * 2020-11-26 2021-02-19 汝州市小微结构陶瓷有限公司 Microcrystal high-alumina ball, preparation method thereof and method for grinding ceramic blank by using microcrystal high-alumina ball

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB162481A (en) * 1920-03-08 1921-05-05 William Furnival Malkin Improvements in grinding mills employed for grinding flint, china stone and other materials
JPS59184761A (en) * 1983-04-01 1984-10-20 株式会社イナックス Low hydration swelling porous tile
CN101585014A (en) * 2009-05-27 2009-11-25 龙岩高岭土有限公司 Method for improving washing rate of kaolin clay raw ore
CN102584212A (en) * 2012-01-31 2012-07-18 厦门大学 Low-dielectric-loss ceramic material and preparation method thereof
CN105218070A (en) * 2015-11-13 2016-01-06 景德镇市大瓷庄瓷业有限公司 New feldspathic china of a kind of intermediate sintering temperature and preparation method thereof
CN105801081A (en) * 2016-02-29 2016-07-27 董克勤 Color petuntse fired at temperature not higher than 1,150 DEG C and preparation method thereof
CN205816177U (en) * 2016-07-04 2016-12-21 安徽博硕科技有限公司 A kind of mining screening installation
CN106699108A (en) * 2016-11-18 2017-05-24 张帅 Porcelain material and production method thereof

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB162481A (en) * 1920-03-08 1921-05-05 William Furnival Malkin Improvements in grinding mills employed for grinding flint, china stone and other materials
JPS59184761A (en) * 1983-04-01 1984-10-20 株式会社イナックス Low hydration swelling porous tile
CN101585014A (en) * 2009-05-27 2009-11-25 龙岩高岭土有限公司 Method for improving washing rate of kaolin clay raw ore
CN102584212A (en) * 2012-01-31 2012-07-18 厦门大学 Low-dielectric-loss ceramic material and preparation method thereof
CN105218070A (en) * 2015-11-13 2016-01-06 景德镇市大瓷庄瓷业有限公司 New feldspathic china of a kind of intermediate sintering temperature and preparation method thereof
CN105801081A (en) * 2016-02-29 2016-07-27 董克勤 Color petuntse fired at temperature not higher than 1,150 DEG C and preparation method thereof
CN205816177U (en) * 2016-07-04 2016-12-21 安徽博硕科技有限公司 A kind of mining screening installation
CN106699108A (en) * 2016-11-18 2017-05-24 张帅 Porcelain material and production method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
曹泽亮: "瓷石细化提纯试验研究", 《非金属矿》 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112374868A (en) * 2020-11-26 2021-02-19 汝州市小微结构陶瓷有限公司 Microcrystal high-alumina ball, preparation method thereof and method for grinding ceramic blank by using microcrystal high-alumina ball

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Application publication date: 20180420