CN107916028A - A kind of environment-friendlyink ink - Google Patents
A kind of environment-friendlyink ink Download PDFInfo
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- CN107916028A CN107916028A CN201711294903.5A CN201711294903A CN107916028A CN 107916028 A CN107916028 A CN 107916028A CN 201711294903 A CN201711294903 A CN 201711294903A CN 107916028 A CN107916028 A CN 107916028A
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- ink
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- friendlyink
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
- C09D11/103—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds of aldehydes, e.g. phenol-formaldehyde resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/06—Printing inks based on fatty oils
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The present invention relates to ink-printing techniques field, disclose a kind of environment-friendlyink ink, it is slow to improve traditional soybean ink setting speed, the problem of color fugitive color, the ink being prepared deinking easier than existing ink, and apply the infringement for fiber on paper minimum, maximum recovery utilization rate can be reached, at the same time, ink after deinking can pass through reprocessing and utilize, it is added in new ink and is used in mixed way, performance is not interfered with, not only contribute to environmental protection, production cost can also be reduced, spent ink residue after deinking processing is readily obtained degraded, beneficial to sewage disposal, reduce cost of sewage disposal.
Description
Technical field
The invention belongs to ink-printing techniques field, and in particular to a kind of environment-friendlyink ink.
Background technology
Ink is the important materials for packaging material printing, it is shown pattern, word on stock by printing
Ink includes main component and auxiliary element, they equably mix and form a kind of sticky colloidal fluid through repeat-rolling.
Ink is constantly riseing as necessary raw material during color printing, demand, and China's ink industry production in 2010, which has reached, goes through
History highest level,《Chinese ink industry production and marketing demand is looked forward to the prospect with investment forecasting analysis report》Statistics, national ink gross annual output amount
58.99 ten thousand tons altogether, exceed Germany first, Japan occupies the second in the world.Come according to about 4,100,000 tons of world's ink annual output then
Calculate, Chinese Printing ink producing scale accounts for the 14% of the whole world.
Present Printing ink producing business sends signal and represents since the cost of raw material is skyrocketing, will further improve production and adds
Expense in terms of work.This is mainly due to a series of shortage of chemicals in global range, and they are in the production of ink
It is critical materials.Cut-off till now, crude oil and petrochemical industry derivative price it is constantly soaring, be cause ink rise in price main
Reason.But even if oil price is fallen after rise, because ink industry is by the strike of chemical raw material shortage, especially nitrocellulose, third
The raw materials such as olefin(e) acid, acetic acid and titanium dioxide, ink price still can keep rising.
The sustainable development of ink industry result in that the environmental pollution produced in the sector is also increasingly severe, and people are pursuing
It often have ignored the harm brought in ink manufacture to environment and the mankind while ink performance, substantial amounts of synthesis of organic substance has
It is difficult to the characteristic degraded, is if things go on like this unfavorable for the deep development of ink industry.
The content of the invention
The purpose of the present invention is for it is existing the problem of, there is provided a kind of environment-friendlyink ink, selects the raw material easily degraded
Processing and fabricating binder, obtains the environment-friendlyink ink of excellent performance.
The present invention is achieved by the following technical solutions：
A kind of environment-friendlyink ink, is made of following component in parts by weight：50-60 parts of rosin modified phenolic resin, soybean oil
20-25 parts, 15-20 parts of mineral oil, 18-20 parts of pigment, 1.2-1.4 parts of dispersant, 1.0-1.2 parts of antioxidant, antisettling agent
0.6-0.8 parts, 0.3-0.5 parts of defoamer, 0.2-0.4 parts of thickener, 20-30 parts of solvent；
Preparation method comprises the following steps：
（1）By rosin modified phenolic resin, soybean oil, mineral oil, 110-120 DEG C, when stirring 1-2 is small is heated to, is added
Antioxidant and defoamer, are cooled to 50-60 DEG C under stirring, stand 2-3 it is small when after cure at 30-40 DEG C 4-5 it is small when obtain
Ink base fluid；
（2）Ink base fluid, pigment, dispersant, antisettling agent, thickener, solvent are mixed, in 550-600 revs/min of speed
Under pre-dispersed pulp, then under 1800-2000 revs/min of speed disperse stirring 40-60 minutes, be transferred to three-roll grinder
Grinding 2-3 times, is ground to particle size between 1-10 microns, up to the ink when cold curing 1-2 is small at 0-5 DEG C.
Further described as to such scheme, the dispersant is by sodium lignin sulfonate, alkyl sulfate sodium, gathers
Ethylene oxide ring group ether, titanate coupling agent are 10-12 according to mass ratio:7-9:6-7:What the ratio of 3-4 was mixed with.
Further described as to such scheme, the antioxidant is by pentaerythritol ester, thio-2 acid laruyl alcohol
Ester is according to 3-4:1 ratio composition.
Further described as to such scheme, the filler is made according to mass percent meter of following component：Sulphur
Sour potassium accounts for 30-40%, magnesium carbonate accounts for 15-20%, aluminium hydroxide accounts for 10-15%, remaining as calcium carbonate.
Further described as to such scheme, the rotating ratio of three rollers of three-roll grinder is set as 1-2:3-
5:8-9。
The present invention has the following advantages compared with prior art：Made to solve the material that generation is difficult to degrade in existing ink processing
Into the problem of environmental pollution, the present invention provides a kind of environment-friendlyink ink, it is slow to improve traditional soybean ink setting speed, color
The problem of fugitive color, the ink being prepared deinking easier than existing ink, and apply on paper for the damage of fiber
Evil is minimum, can reach maximum recovery utilization rate, meanwhile, the ink after deinking can pass through reprocessing and utilize, and be added to new
It is used in mixed way in ink, does not interfere with performance, not only contribute to environmental protection, moreover it is possible to production cost is reduced, after deinking processing
Spent ink residue is readily obtained degraded, beneficial to sewage disposal, reduces cost of sewage disposal.
Embodiment
With reference to specific embodiment, the invention will be further described.
Embodiment 1
A kind of environment-friendlyink ink, is made of following component in parts by weight：50 parts of rosin modified phenolic resin, soybean oil 20
Part, 15 parts of mineral oil, 18 parts of pigment, 1.2 parts of dispersant, 1.0 parts of antioxidant, 0.6 part of antisettling agent, 0.3 part of defoamer, increase
Thick dose 0.2 part, 20 parts of solvent；
Preparation method comprises the following steps：
（1）By rosin modified phenolic resin, soybean oil, mineral oil, 110 DEG C, when stirring 1 is small are heated to, is added anti-oxidant
Agent and defoamer, are cooled to 50 DEG C under stirring, stand 2 it is small when after cure at 30 DEG C 4 it is small when obtain ink base fluid；
（2）Ink base fluid, pigment, dispersant, antisettling agent, thickener, solvent are mixed, it is pre- under 550 revs/min of speed
Scattered pulp, then disperses stirring 40 minutes under 1800 revs/min of speed, is transferred to three-roll grinder and grinds 2 times, grinding
To particle size between 1-10 microns, up to the ink when cold curing 1 is small at 0 DEG C.
Further described as to such scheme, the dispersant is by sodium lignin sulfonate, alkyl sulfate sodium, gathers
Ethylene oxide ring group ether, titanate coupling agent are 10 according to mass ratio:7:6:What 3 ratio was mixed with.
Further described as to such scheme, the antioxidant is by pentaerythritol ester, thio-2 acid laruyl alcohol
Ester is according to 3:1 ratio composition.
Further described as to such scheme, the filler is made according to mass percent meter of following component：Sulphur
Sour potassium, which accounts for 30%, magnesium carbonate and accounts for 15%, aluminium hydroxide, accounts for 10%, remaining as calcium carbonate.
Further described as to such scheme, the rotating ratio of three rollers of three-roll grinder is set as 1:3:8.
Embodiment 2
A kind of environment-friendlyink ink, is made of following component in parts by weight：55 parts of rosin modified phenolic resin, soybean oil 22
Part, 18 parts of mineral oil, 19 parts of pigment, 1.3 parts of dispersant, 1.1 parts of antioxidant, 0.7 part of antisettling agent, 0.4 part of defoamer, increase
Thick dose 0.3 part, 25 parts of solvent；
Preparation method comprises the following steps：
（1）By rosin modified phenolic resin, soybean oil, mineral oil, 115 DEG C, when stirring 1.5 is small are heated to, adds antioxygen
Agent and defoamer, are cooled to 55 DEG C under stirring, stand 2.5 it is small when after cure at 35 DEG C 4.5 it is small when obtain ink base fluid；
（2）Ink base fluid, pigment, dispersant, antisettling agent, thickener, solvent are mixed, it is pre- under 580 revs/min of speed
Scattered pulp, then disperses stirring 50 minutes under 1900 revs/min of speed, is transferred to three-roll grinder and grinds 2 times, grinding
To particle size between 1-10 microns, up to the ink when cold curing 1.5 is small at 2 DEG C.
Further described as to such scheme, the dispersant is by sodium lignin sulfonate, alkyl sulfate sodium, gathers
Ethylene oxide ring group ether, titanate coupling agent are 11 according to mass ratio:8:6.5:What 3.5 ratio was mixed with.
Further described as to such scheme, the antioxidant is by pentaerythritol ester, thio-2 acid laruyl alcohol
Ester is according to 3.5:1 ratio composition.
Further described as to such scheme, the filler is made according to mass percent meter of following component：Sulphur
Sour potassium, which accounts for 35%, magnesium carbonate and accounts for 18%, aluminium hydroxide, accounts for 12%, remaining as calcium carbonate.
Further described as to such scheme, the rotating ratio of three rollers of three-roll grinder is set as 1.5:4:
8.5。
Embodiment 3
A kind of environment-friendlyink ink, is made of following component in parts by weight：60 parts of rosin modified phenolic resin, soybean oil 25
Part, 20 parts of mineral oil, 20 parts of pigment, 1.4 parts of dispersant, 1.2 parts of antioxidant, 0.8 part of antisettling agent, 0.5 part of defoamer, increase
Thick dose 0.4 part, 30 parts of solvent；
Preparation method comprises the following steps：
（1）By rosin modified phenolic resin, soybean oil, mineral oil, 120 DEG C, when stirring 1-2 is small are heated to, adds antioxygen
Agent and defoamer, are cooled to 60 DEG C under stirring, stand 3 it is small when after cure at 40 DEG C 5 it is small when obtain ink base fluid；
（2）Ink base fluid, pigment, dispersant, antisettling agent, thickener, solvent are mixed, it is pre- under 600 revs/min of speed
Scattered pulp, then disperses stirring 60 minutes under 2000 revs/min of speed, is transferred to three-roll grinder and grinds 3 times, grinding
To particle size between 1-10 microns, up to the ink when cold curing 2 is small at 5 DEG C.
Further described as to such scheme, the dispersant is by sodium lignin sulfonate, alkyl sulfate sodium, gathers
Ethylene oxide ring group ether, titanate coupling agent are 12 according to mass ratio:9:7:What 4 ratio was mixed with.
Further described as to such scheme, the antioxidant is by pentaerythritol ester, thio-2 acid laruyl alcohol
Ester is according to 4:1 ratio composition.
Further described as to such scheme, the filler is made according to mass percent meter of following component：Sulphur
Sour potassium, which accounts for 40%, magnesium carbonate and accounts for 20%, aluminium hydroxide, accounts for 15%, remaining as calcium carbonate.
Further described as to such scheme, the rotating ratio of three rollers of three-roll grinder is set as 2:5:9.
Claims (5)
1. a kind of environment-friendlyink ink, it is characterised in that be made in parts by weight of following component：Rosin modified phenolic resin
50-60 parts, 20-25 parts of soybean oil, 15-20 parts of mineral oil, 18-20 parts of pigment, 1.2-1.4 parts of dispersant, antioxidant 1.0-
1.2 parts, 0.6-0.8 parts of antisettling agent, 0.3-0.5 parts of defoamer, 0.2-0.4 parts of thickener, 20-30 parts of solvent；
Preparation method comprises the following steps：
（1）By rosin modified phenolic resin, soybean oil, mineral oil, 110-120 DEG C, when stirring 1-2 is small is heated to, is added
Antioxidant and defoamer, are cooled to 50-60 DEG C under stirring, stand 2-3 it is small when after cure at 30-40 DEG C 4-5 it is small when obtain
Ink base fluid；
（2）Ink base fluid, pigment, dispersant, antisettling agent, thickener, solvent are mixed, in 550-600 revs/min of speed
Under pre-dispersed pulp, then under 1800-2000 revs/min of speed disperse stirring 40-60 minutes, be transferred to three-roll grinder
Grinding 2-3 times, is ground to particle size between 1-10 microns, up to the ink when cold curing 1-2 is small at 0-5 DEG C.
2. a kind of environment-friendlyink ink as claimed in claim 1, it is characterised in that the dispersant is by sodium lignin sulfonate, alkane
Base sodium sulfovinate, polyoxyethylene ring group ether, titanate coupling agent are 10-12 according to mass ratio:7-9:6-7:The ratio mixing of 3-4
Prepare.
3. a kind of environment-friendlyink ink as claimed in claim 1, it is characterised in that the antioxidant is by pentaerythritol ester, thio
Dipropionic acid bay alcohol ester is according to 3-4:1 ratio composition.
4. a kind of environment-friendlyink ink as claimed in claim 1, it is characterised in that the filler is according to mass percent meter by following
Component is made：Potassium sulfate accounts for 30-40%, magnesium carbonate accounts for 15-20%, aluminium hydroxide accounts for 10-15%, remaining as calcium carbonate.
A kind of 5. environment-friendlyink ink as claimed in claim 1, it is characterised in that the rotating ratio of three rollers of three-roll grinder
It is set as 1-2:3-5:8-9.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711294903.5A CN107916028A (en) | 2017-12-08 | 2017-12-08 | A kind of environment-friendlyink ink |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711294903.5A CN107916028A (en) | 2017-12-08 | 2017-12-08 | A kind of environment-friendlyink ink |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107916028A true CN107916028A (en) | 2018-04-17 |
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ID=61892943
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711294903.5A Pending CN107916028A (en) | 2017-12-08 | 2017-12-08 | A kind of environment-friendlyink ink |
Country Status (1)
| Country | Link |
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| CN (1) | CN107916028A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112795232A (en) * | 2020-12-30 | 2021-05-14 | 嘉兴沃兹玩具有限公司 | Environment-friendly printing process, paperboard prepared by environment-friendly printing process and application of paperboard |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101671505A (en) * | 2009-10-17 | 2010-03-17 | 太原印科油墨有限公司 | Single-sheet non-skinning oil ink |
| CN101671504A (en) * | 2009-09-30 | 2010-03-17 | 太原印科油墨有限公司 | Soybean oil type offset printing color ink |
-
2017
- 2017-12-08 CN CN201711294903.5A patent/CN107916028A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101671504A (en) * | 2009-09-30 | 2010-03-17 | 太原印科油墨有限公司 | Soybean oil type offset printing color ink |
| CN101671505A (en) * | 2009-10-17 | 2010-03-17 | 太原印科油墨有限公司 | Single-sheet non-skinning oil ink |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112795232A (en) * | 2020-12-30 | 2021-05-14 | 嘉兴沃兹玩具有限公司 | Environment-friendly printing process, paperboard prepared by environment-friendly printing process and application of paperboard |
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Application publication date: 20180417 |
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