CN107915962A - A kind of imitative ceramic flame-proof polyester/ABS resin composition and preparation method thereof - Google Patents
A kind of imitative ceramic flame-proof polyester/ABS resin composition and preparation method thereof Download PDFInfo
- Publication number
- CN107915962A CN107915962A CN201711251868.9A CN201711251868A CN107915962A CN 107915962 A CN107915962 A CN 107915962A CN 201711251868 A CN201711251868 A CN 201711251868A CN 107915962 A CN107915962 A CN 107915962A
- Authority
- CN
- China
- Prior art keywords
- temperature
- resin composition
- area
- abs resin
- imitative ceramic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0856—Iron
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a kind of imitative ceramic flame-proof polyester/ABS resin composition and preparation method thereof, which includes following components and parts by weight：60.3 parts of polyester resin 13.3 part, 47 parts of ABS resin 2 part, 10 parts of toughener 0 part；20 parts of bromide fire retardant 10 part；5 parts of fire retarding synergist 3 part；40 parts of filler 20 part；10 parts of metal powder 5 part；0.5 part of coupling agent；0.6 part of weather resisting agent；0.6 part of antioxidant.The features such as imitative ceramic flame-proof polyester/ABS resin composition of the present invention has high glaze, and density is big, good weatherability, good toughness, the use of ceramic product can be substituted in certain field.
Description
Technical field
The invention belongs to polymeric material field, and in particular to a kind of imitative ceramic flame-proof polyester/ABS resin composition and its
Preparation method.
Background technology
The ceramic used in daily life, is that the mixture by clay or containing clay makees pug mixing mostly, passes through
Helical vacuum extruder is molded, and cuts into mud embryo and then calcining forms.Ceramic is natural, beautiful, durable, inexpensive etc. with its
Feature, is favored by people, and is seen everywhere in life.But ceramics there is also firing high energy consumption, poor toughness is frangible the shortcomings of,
And manufacturing process needs valuable soil resource of using up, and also to consume the substantial amounts of energy, produces substantial amounts of discarded object,
Destroy natural, ecological.
, therefore, how will processing and plastic products have the advantages that light, good toughness, convenient formation, are easily recycled
Performance more excellent plastics copy ceramics, are always the direction that people make great efforts.Such as addition toner can in the plastic
Plastic material appearance is adjusted to various ceramic appearances, or realizes that plastics imitate the effect of ceramics by technologies such as surface lacquers, but
These measures are only the change of plastic products appearance, but without ceramic is thick and heavy, damage resistant, it is weather-proof etc. the advantages of.
101608055 B of Chinese patent CN disclose a kind of imitated ceramic plastic material, take in poly terephthalic acid fourth two
The method of the substantial amounts of barium sulfate of addition realizes the purpose for imitating ceramics in alcohol ester plastics (PBT).The shortcomings that this method is that it is terrible
To the density of similar ceramics, up to 71% barium sulfate is filled with plastic material.And the characteristics of due to barium sulfate itself, this
Sample, which is done, not only easily makes plastic material become difficult processing, and is easy to cause the decline of plastic material shock resistance, the system made
Product are easily broken.And Chinese patent CN102321363 B disclose one kind and use based on polyamide and zinc oxide, iron powder is as increasing
The imitative ceramic product of heavy material, although this method can obtain the heavier imitative ceramic product of quality, since polyamide is poor
Weatherability, can cause the weather resistance of this product poor far beyond ceramic product, not a kind of really imitative ceramic product.
Therefore, in the exploitation of imitative ceramic product, the apparent high glaze for reaching ceramics is not only wanted, in density and weatherability side
Face is required for reaching the level close to ceramics, and far above ceramics in terms of toughness, it is convenient to prepare, and so can be only achieved replacement
The purpose of ceramics.
The content of the invention
The purpose of the present invention, exactly in order to solve the defects of current ceramic material processes are complicated, be not easily recycled, frangible, carries
There is impact resistance, surface high glaze, easily molded, the larger imitative ceramic flame-proof polyester/ABS resin composition of density and its system for one kind
Preparation Method.
The object of the present invention is achieved like this：
A kind of imitative ceramic flame-proof polyester/ABS resin composition of the present invention includes following components and parts by weight：
The repetitive unit of polyester resin is by with the following group in a kind of above-mentioned imitative ceramic flame-proof polyester/ABS resin composition
Divide and form：
Component A：Account for the dicarboxylic acid units of the repetitive unit 45-55mol% of resin；
Component B：Account for the diol units of the repetitive unit 45-55mol% of resin；
Wherein component A is by accounting for the terephthalic acid units of its 80-100mol% or to how dioctyl phthalate unit A1 and to account for its 0-
M-phthalic acid or O-phthalic acid unit the A2 composition of 20mol%；Component B be the aliphatic diol that carbon number is 2-9 or
Alicyclic diol, be preferably Isosorbide-5-Nitrae-ethylene glycol, 1,3-PD, 1,4-butanediol, 1,6- hexylene glycols, Isosorbide-5-Nitrae-cyclohexane diol or
Isosorbide-5-Nitrae-hexamethylene methylene glycol, and these mixture.
Polyester resin is derived from 2-6 carbon atom in a kind of above-mentioned imitative ceramic flame-proof polyester/ABS resin composition
Aliphatic diol or alicyclic diol polyalkylene terephthalates；Particularly preferably poly terephthalic acid second two
Alcohol ester (PET), polypropylene terephthalate (PTT), polybutylene terephthalate (PBT) (PBT), poly terephthalic acid ring
Hexane diformazan alcohol ester (PCT), and these mixture.
ABS resin is acrylonitrile-butadiene-benzene in a kind of above-mentioned imitative ceramic flame-proof polyester/ABS resin composition
Ethylene copolymer, acrylonitrile-butadiene-acrylate copolymer, Methyl Methacrylate-Butadiene-Styrene Copolymer or
One or more of mixtures in acrylonitrile-ethylene propylene diene rubber-styrol copolymer.It is preferred that acrylonitrile-butadiene-benzene second
Alkene copolymer.
Toughener is ethylene-vinyl acetate, second in a kind of above-mentioned imitative ceramic flame-proof polyester/ABS resin composition
Alkene-methyl acrylate, ethylene-ethylacrylate, Ethylene-butyl acrylate, low density polyethylene (LDPE), maleic anhydride grafted ethene-
Octene copolymer, ethylene-ethylacrylate-glycidyl ester copolymer, Ethylene-butyl acrylate-glycidyl ester copolymer
In one or more of mixing.
Brominated flame-retardant is selected from brominated Polystyrene, decabrominated dipheny in above-mentioned one kind imitates ceramic ABS resin composition
One or more of mixing in ethane, brominated polycarbonate, brominated epoxy etc..
Fire retarding synergist is a kind of antimony containing compounds, preferably three oxygen in above-mentioned one kind imitates ceramic ABS resin composition
Change one kind or its mixture in two antimony or sodium antimonate.
In a kind of above-mentioned imitative ceramic ABS resin composition filler be barium sulfate, in zinc oxide, titanium dioxide extremely
Few one kind.
Metal powder is at least one of iron powder, aluminium powder, copper powder in above-mentioned one kind imitates ceramic ABS resin composition.
Coupling agent is silane coupling agent or titanate coupling agent in above-mentioned one kind imitates ceramic ABS resin composition, excellent
Elect silane coupling agent as.
Weather resisting agent is ultraviolet absorber and hindered amine as light stabilizer in a kind of above-mentioned imitative ceramic ABS resin composition
Mixture, ultraviolet absorber are a kind of hydroxy benzophenone ketone or hydroxy-phenyl benzotriazole class material, preferably hydroxyphenyl benzo three
Azole.The preferred macromolecular class hindered amine material of hindered amine as light stabilizer.
Antioxidant is the mixing of pentaerythritol ester and phosphite ester in a kind of above-mentioned imitative ceramic ABS resin composition
Thing.
The present invention also provides a kind of preparation method of imitative ceramic flame-proof polyester/ABS resin composition, comprise the following steps：
(1) raw material is prepared by following components and parts by weight：
(2) by filler, metal powder, coupling agent add homogenizer in, stirring 5-10 minutes after, by polyester resin,
ABS resin, toughener, fire retardant, fire retarding synergist, weather resisting agent and antioxidant add enters twin-screw extrusion after mixing
Machine, processing temperature is between 220-290 DEG C；300-400 revs/min of engine speed；
(3) discharge, extrusion postcooling, drying, pelletizing.
Imitative ceramic flame-proof polyester/ABS resin composition of the present invention has preferable impact resistance, surface high glaze, density
It is larger, the features such as good weatherability, good toughness, the use of ceramic product can be substituted in certain field.
Embodiment
Below in conjunction with embodiment, the invention will be further described.
Material is as follows used by the embodiment of the present invention 1~12：
Polyester resin is selected from：
PBT resin, inherent viscosity 1.05, using 50mol% terephthalic acid (TPA)s and 50mol% butanediol copolymerizations,
The trade mark is GX121, engineering plastics factory of Yizheng branch company of Sinopec Group asset management Co., Ltd.
PET resin, inherent viscosity 0.8, using 50mol% terephthalic acid (TPA)s and 50mol% ethylene glycol copolymerizations, board
Number it is BG80, engineering plastics factory of Yizheng branch company of Sinopec Group asset management Co., Ltd.
PTT resins, the trade mark 3301, using 50mol% terephthalic acid (TPA)s and 50mol% propane diols copolymerizations, the U.S.
E.I.Du Pont Company.
PCT resins, trade mark 0502HC, using 50mol% terephthalic acid (TPA)s and 50mol% cyclohexanediol copolymerizations,
SK companies of South Korea.
ABS resin：Inherent viscosity is 0.8, trade mark BG80, Sinopec Group asset management Co., Ltd Yizheng
Engineering plastics factory of branch company；
Toughener：Ethylene-butyl Acrylate-methacrylic Acid Glycerin Ester Copolymer, trade mark PTW, U.S. Du
Company of nation；
Brominated flame-retardant：The trade mark is PBS-64HW, brominated polystyrene, U.S.'s Chemtura；
The trade mark is BC-52, brominated polycarbonate, U.S.'s Chemtura；
Fire retarding synergist：The trade mark is S-05N, antimony oxide, Hu'nan Chenzhou Mining Co., Ltd.；
Filler：3000 mesh blanc fixes, trade mark AB-3000N1, Guangzhou Huangpu Tian Taihuaqing Co., Ltds；Ring
Guarantor's type zinc oxide, trade mark HHB-02, Shandong Zibo sea is along Xin Ye Co., Ltds；Titanium dioxide, trade mark R103, Dupont are public
Department.
Iron powder：The trade mark is HYFE-300, Chengdu Jin Chun metal materials Co., Ltd.
Coupling agent：Silane coupling agent, chemical name are γ-(2,3- the third oxygen of epoxy) propyl trimethoxy silicane, and the trade mark is
Z-6040, Dow corning company.
Weather resisting agent：Hydroxy-phenyl benzotriazole class material, the trade mark are TINUVIN 327, BASF Corp. of Germany；Macromolecular is obstructed
Amine light stabilizer, the trade mark are CHIMASSORB 944, BASF Corp. of Germany.
Antioxidant：Chemical name is four [β-(3,5- di-tert-butyl -4- hydroxy phenyls) propionic acid] pentaerythritol esters, commodity
Name Irganox 1010, BASF Corp. of Germany.Chemical name is three [2.4- di-tert-butyl-phenyls] phosphite esters, trade name
Irganox 168, BASF Corp. of Germany.
The component of embodiment 1~12 is as shown in table 1：
The formula (parts by weight) of 1 embodiment 1-12 of table
A kind of preparation of imitative ceramic flame-proof polyester/ABS resin alloy composite of the present invention is using the production of Rhea company
75A (draw ratio 40) double screw extruder produces, and processing temperature is between 220-290 DEG C；200-400 revs/min of engine speed
Clock.
Embodiment 1
By AB-3000N1, HYFE-300, Z-6040, mixed at room temperature in super mixer 5-10 minutes；Then will
PBT GX121, ABS PA757, PBS-64HW, S-05N, TINUVIN 327, CHIMASSORB 944, Irganox 1010,
Irganox 168 adds high-speed mixer mixing, is extruded afterwards in double screw extruder.Processing conditions is：One area's temperature 235
DEG C, two 240 DEG C of area's temperature, three 245 DEG C of area's temperature, four 250 DEG C of area's temperature, five 250 DEG C of area's temperature, six 250 DEG C of area's temperature, 7th area
255 DEG C of temperature, eight 255 DEG C of area's temperature, nine 245 DEG C of area's temperature；350 revs/min of engine speed.
Embodiment 2
By AB-3000N1, HYFE-300, Z-6040, mixed at room temperature in super mixer 5-10 minutes；Then will
PET BG80, ABS PA757, PTW, PBS-64HW, S-05N, TINUVIN 327, CHIMASSORB 944, Irganox
1010, Irganox 168 add high-speed mixer mixing, are extruded afterwards in double screw extruder.Processing conditions is：One area's temperature
240 DEG C of degree, two 245 DEG C of area's temperature, three 245 DEG C of area's temperature, four 250 DEG C of area's temperature, five 250 DEG C of area's temperature, six area's temperature 250
DEG C, seven 255 DEG C of area's temperature, eight 255 DEG C of area's temperature, nine 240 DEG C of area's temperature；300 revs/min of engine speed.
Embodiment 3
By AB-3000N1, HYFE-300, Z-6040, mixed at room temperature in super mixer 5-10 minutes；Then will
PCT 0502HC, ABS PA757, PTW, PBS-64HW, S-05N, TINUVIN 327, CHIMASSORB 944, Irganox
1010, Irganox 168 add high-speed mixer mixing, are extruded afterwards in double screw extruder.Processing conditions is：One area's temperature
265 DEG C of degree, two 280 DEG C of area's temperature, three 280 DEG C of area's temperature, four 280 DEG C of area's temperature, five 280 DEG C of area's temperature, six area's temperature 280
DEG C, seven 285 DEG C of area's temperature, eight 285 DEG C of area's temperature, nine 270 DEG C of area's temperature；300 revs/min of engine speed.
Embodiment 4
By AB-3000N1, HYFE-300, Z-6040, mixed at room temperature in super mixer 5-10 minutes；Then will
PTT 3301, ABS PA757, PTW, PBS-64HW, S-05N, TINUVIN 327, CHIMASSORB 944, Irganox
1010, Irganox 168 add high-speed mixer mixing, are extruded afterwards in double screw extruder.Processing conditions is：One area's temperature
245 DEG C of degree, two 250 DEG C of area's temperature, three 250 DEG C of area's temperature, four 250 DEG C of area's temperature, five 250 DEG C of area's temperature, six area's temperature 250
DEG C, seven 250 DEG C of area's temperature, eight 250 DEG C of area's temperature, nine 240 DEG C of area's temperature；300 revs/min of engine speed.
Embodiment 5
By AB-3000N1, HYFE-300, Z-6040, mixed at room temperature in super mixer 5-10 minutes；Then will
PCT 0502HC, ABS PA757, PTW, PBS-64HW, S-05N, TINUVIN 327, CHIMASSORB 944, Irganox
1010, Irganox 168 add high-speed mixer mixing, are extruded afterwards in double screw extruder.Processing conditions is：One area's temperature
265 DEG C of degree, two 280 DEG C of area's temperature, three 280 DEG C of area's temperature, four 280 DEG C of area's temperature, five 280 DEG C of area's temperature, six area's temperature 280
DEG C, seven 285 DEG C of area's temperature, eight 285 DEG C of area's temperature, nine 270 DEG C of area's temperature；300 revs/min of engine speed.
Embodiment 6
By AB-3000N1, HYFE-300, Z-6040, mixed at room temperature in super mixer 5-10 minutes；Then will
PTT 3301, ABS PA757, PTW, PBS-64HW, S-05N, TINUVIN 327, CHIMASSORB 944, Irganox
1010, Irganox 168 add high-speed mixer mixing, are extruded afterwards in double screw extruder.Processing conditions is：One area's temperature
245 DEG C of degree, two 250 DEG C of area's temperature, three 250 DEG C of area's temperature, four 250 DEG C of area's temperature, five 250 DEG C of area's temperature, six area's temperature 250
DEG C, seven 250 DEG C of area's temperature, eight 250 DEG C of area's temperature, nine 240 DEG C of area's temperature；300 revs/min of engine speed.
Embodiment 7
By AB-3000N1, HYFE-300, Z-6040, mixed at room temperature in super mixer 5-10 minutes；Then will
PBT GX121, PTW, BC-52, S-05N, TINUVIN 327, CHIMASSORB 944, Irganox 1010, Irganox 168
High-speed mixer mixing is added, is extruded afterwards in double screw extruder.Processing conditions is：One 215 DEG C of area's temperature, two area's temperature
230 DEG C, three 235 DEG C of area's temperature, four 240 DEG C of area's temperature, five 240 DEG C of area's temperature, six 240 DEG C of area's temperature, seven 245 DEG C of area's temperature,
Eight 245 DEG C of area's temperature, nine 230 DEG C of area's temperature；350 revs/min of engine speed.
Embodiment 8
By AB-3000N1, HYFE-300, Z-6040, mixed at room temperature in super mixer 5-10 minutes；Then will
PET BG80, PCT 0502HC, ABS PA757, PTW, BC-52, S-05N, TINUVIN 327, CHIMASSORB 944,
Irganox 1010, Irganox 168 adds high-speed mixer mixing, is extruded afterwards in double screw extruder.Processing conditions
For：One 265 DEG C of area's temperature, two 280 DEG C of area's temperature, three 280 DEG C of area's temperature, four 280 DEG C of area's temperature, five 280 DEG C of area's temperature, 6th area
280 DEG C of temperature, seven 285 DEG C of area's temperature, eight 285 DEG C of area's temperature, nine 270 DEG C of area's temperature；300 revs/min of engine speed.
Embodiment 9
By HHB-02, HYFE-300, Z-6040, mixed at room temperature in super mixer 5-10 minutes；Then by PET
BG80, PTT 3301, ABS PA757, PTW, BC-52, S-05N, TINUVIN 327, CHIMASSORB 944, Irganox
1010, Irganox 168 add high-speed mixer mixing, are extruded afterwards in double screw extruder.Processing conditions is：One area's temperature
245 DEG C of degree, two 250 DEG C of area's temperature, three 250 DEG C of area's temperature, four 250 DEG C of area's temperature, five 250 DEG C of area's temperature, six area's temperature 250
DEG C, seven 250 DEG C of area's temperature, eight 250 DEG C of area's temperature, nine 240 DEG C of area's temperature；300 revs/min of engine speed.
Embodiment 10
By HHB-02, HYFE-300, Z-6040, mixed at room temperature in super mixer 5-10 minutes；Then by PBT
GX121, PTT 3301, ABS PA757, PTW, BC-52, S-05N, TINUVIN 327, CHIMASSORB 944, Irganox
1010, Irganox 168 add high-speed mixer mixing, are extruded afterwards in double screw extruder.Processing conditions is：One area's temperature
245 DEG C of degree, two 250 DEG C of area's temperature, three 250 DEG C of area's temperature, four 250 DEG C of area's temperature, five 250 DEG C of area's temperature, six area's temperature 250
DEG C, seven 250 DEG C of area's temperature, eight 250 DEG C of area's temperature, nine 240 DEG C of area's temperature；300 revs/min of engine speed.
Embodiment 11
By HHB-02, HYFE-300, Z-6040, mixed at room temperature in super mixer 5-10 minutes；Then by PET
BG80, ABS PA757, PTW, BC-52, S-05N, TINUVIN 327, CHIMASSORB 944, Irganox 1010,
Irganox 168 adds high-speed mixer mixing, is extruded afterwards in double screw extruder.Processing conditions is：One area's temperature 240
DEG C, two 245 DEG C of area's temperature, three 245 DEG C of area's temperature, four 250 DEG C of area's temperature, five 250 DEG C of area's temperature, six 250 DEG C of area's temperature, 7th area
255 DEG C of temperature, eight 255 DEG C of area's temperature, nine 240 DEG C of area's temperature；300 revs/min of engine speed.
Embodiment 12
By R103, HYFE-300, Z-6040, mixed at room temperature in super mixer 5-10 minutes；Then by PCT
0502HC, ABS PA757, PTW, BC-52, S-05N, TINUVIN 327, CHIMASSORB 944, Irganox 1010,
Irganox 168 adds high-speed mixer mixing, is extruded afterwards in double screw extruder.Processing conditions is：One area's temperature 240
DEG C, two 245 DEG C of area's temperature, three 245 DEG C of area's temperature, four 250 DEG C of area's temperature, five 250 DEG C of area's temperature, six 250 DEG C of area's temperature, 7th area
255 DEG C of temperature, eight 255 DEG C of area's temperature, nine 240 DEG C of area's temperature；300 revs/min of engine speed.
The performance test methods of embodiment 1~12 are as follows：
Notch impact strength is tested according to 180 standards of ISO, and specimen size is 80mm × 10mm × 4mm, notch A
Type is molded notch.Test equipment is the Tinius Olisen shock machines of Willow Grove companies of the U.S..
Unnotched impact strength is tested according to 180 standards of ISO, and specimen size is 80mm × 10mm × 4mm, test
Equipment is the Tinius Olisen shock machines of Willow Grove companies of the U.S..
Density measurement is tested according to 1033 standards of GB, is surveyed using the notch shock batten of injection with infusion process
Examination, test equipment are the XS104 type densimeters of Mettler Toledo Inc..
Rockwell hardness is tested according to 9342 standards of GB, and specimen size is 50mm × 50mm × 6mm, and test equipment is
3106 type hardness tester testers of German ZWICK companies.
Fire resistance is tested according to 94 standards of UL, and batten size is 125mm × 13mm × 1.6mm, and test equipment is
The HVUL2 type burning testers of ATLAS companies of the U.S..
The performance test results of embodiment 1~12 are as shown in table 2：
2 embodiment of table, 1~12 the performance test results
The above results show, product of the invention be with preferable impact resistance, surface high glaze, density it is larger, with
Imitative ceramic flame-proof polyester/ABS resin alloy composite of certain fire resistance, making for ceramic product can be substituted in certain field
With.
Above example is used for illustrative purposes only, rather than limitation of the present invention, the technology people in relation to technical field
Member, without departing from the spirit and scope of the present invention, can also make various conversion or modification, therefore all equivalent
Technical solution should also belong to scope of the invention, should be limited by each claim.
Claims (10)
1. a kind of imitative ceramic flame-proof polyester/ABS resin composition, it is characterised in that including following components and parts by weight：
A kind of 2. imitative ceramic flame-proof polyester/ABS resin composition as claimed in claim 1, it is characterised in that the polyester
The repetitive unit of resin is made of following components：
Component A：Account for the dicarboxylic acid units of the repetitive unit 45-55mo l% of resin；
Component B：Account for the diol units of the repetitive unit 45-55mo l% of resin；
Wherein, the component A is by accounting for the terephthalic acid units of its 80-100mo l% or to how dioctyl phthalate unit A1 and to account for it
M-phthalic acid or O-phthalic acid unit the A2 composition of 0-20mo l%；
Wherein, the component B is the aliphatic diol or alicyclic diol that carbon number is 2-9.
A kind of 3. imitative ceramic flame-proof polyester/ABS resin composition as claimed in claim 1, it is characterised in that the polyester
Resin is the polyalkylene terephthalates of aliphatic diol or alicyclic diol derived from 2-6 carbon atom.
A kind of 4. imitative ceramic flame-proof polyester/ABS resin composition as claimed in claim 1, it is characterised in that the ABS
Resinoid is selected from acrylonitrile-butadiene-styrene copolymer, acrylonitrile-butadiene-acrylate copolymer, methacrylic acid
It is one or more of mixed in methyl esters-butadiene-styrene copolymer or acrylonitrile-ethylene propylene diene rubber-styrol copolymer
Compound.
A kind of 5. imitative ceramic flame-proof polyester/ABS resin composition as claimed in claim 1, it is characterised in that the toughness reinforcing
Agent is ethylene-vinyl acetate, ethylene-methyl acrylate, ethylene-ethylacrylate, Ethylene-butyl acrylate, low-density are gathered
Ethene, maleic anhydride grafted ethene-octene copolymer, ethylene-ethylacrylate-glycidyl ester copolymer, ethylene-acrylic acid
One or more of mixing in butyl ester-glycidyl ester copolymer.
A kind of 6. imitative ceramic flame-proof polyester/ABS resin composition as claimed in claim 1, it is characterised in that the brominated resistance
Fire one or more of mixing of the agent in brominated Polystyrene, decabromodiphenylethane, brominated polycarbonate, brominated epoxy；
The fire retarding synergist is antimony containing compounds.
A kind of 7. imitative ceramic flame-proof polyester/ABS resin composition as claimed in claim 1, it is characterised in that the filling
Thing is at least one of barium sulfate, zinc oxide, titanium dioxide.
A kind of 8. imitative ceramic flame-proof polyester/ABS resin composition as claimed in claim 1, it is characterised in that the metal
Powder is selected from least one of iron powder, aluminium powder, copper powder.
A kind of 9. imitative ceramic flame-proof polyester/ABS resin composition as claimed in claim 1, it is characterised in that the coupling
Agent is silane coupling agent or titanate coupling agent；
The antioxidant is pentaerythritol ester and the mixture of phosphite ester；
The weather resisting agent is ultraviolet absorber and the mixture of hindered amine as light stabilizer.
10. a kind of preparation method of imitative ceramic flame-proof polyester/ABS resin composition as claimed in claim 1, its feature exist
In comprising the following steps：
(1) raw material is prepared by following components and parts by weight：
(2) filler, metal powder, coupling agent are added in homogenizer, after stirring 5-10 minutes, by polyester resin, ABS trees
Fat, toughener, fire retardant, fire retarding synergist, weather resisting agent and antioxidant add enters double screw extruder after mixing, processes
Temperature is between 220-290 DEG C；300-400 revs/min of engine speed；
(3) discharge, extrusion postcooling, drying, pelletizing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711251868.9A CN107915962A (en) | 2017-12-01 | 2017-12-01 | A kind of imitative ceramic flame-proof polyester/ABS resin composition and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711251868.9A CN107915962A (en) | 2017-12-01 | 2017-12-01 | A kind of imitative ceramic flame-proof polyester/ABS resin composition and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107915962A true CN107915962A (en) | 2018-04-17 |
Family
ID=61898209
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711251868.9A Pending CN107915962A (en) | 2017-12-01 | 2017-12-01 | A kind of imitative ceramic flame-proof polyester/ABS resin composition and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107915962A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101215409A (en) * | 2007-12-28 | 2008-07-09 | 深圳市科聚新材料有限公司 | PBT/ABS alloy material and preparation method thereof |
| CN102321363A (en) * | 2011-09-16 | 2012-01-18 | 厦门建霖工业有限公司 | Ceramic-imitated plastic composite material and preparation method thereof |
| CN105462151A (en) * | 2015-12-14 | 2016-04-06 | 广东金发科技有限公司 | ABS/PBT composition and application thereof |
-
2017
- 2017-12-01 CN CN201711251868.9A patent/CN107915962A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101215409A (en) * | 2007-12-28 | 2008-07-09 | 深圳市科聚新材料有限公司 | PBT/ABS alloy material and preparation method thereof |
| CN102321363A (en) * | 2011-09-16 | 2012-01-18 | 厦门建霖工业有限公司 | Ceramic-imitated plastic composite material and preparation method thereof |
| CN105462151A (en) * | 2015-12-14 | 2016-04-06 | 广东金发科技有限公司 | ABS/PBT composition and application thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107746554A (en) | A kind of imitative ceramic flame-proof PET/ABS resin combinations and preparation method thereof | |
| CN101020780B (en) | Preparation process of polylactic acid-base thermoplastic wood-plastic composite material | |
| CN107746555A (en) | One kind imitates ceramic PET/PC resin combinations and preparation method thereof | |
| CN102757590B (en) | Floor, manufacture method and application thereof | |
| CN102002203B (en) | Flame-retarded ASA (Acrylic ester-Styrene-Acrylonitrile) modified resin and preparation method thereof | |
| CN104558968A (en) | Wood-plastic composite material and production method thereof | |
| CN106905674B (en) | A kind of Flame-retardant PET and PC composite material and preparation method | |
| CN101168618B (en) | Light aging resisting and high-strength anti-flaming enhancement polybutylene terephthalate composition and preparation method thereof | |
| CN107936492A (en) | A kind of imitative ceramic flame-proof PBT/PET resin combinations and preparation method thereof | |
| CN107746556A (en) | A kind of imitative ceramic flame-proof PET/PC resin combinations and preparation method thereof | |
| CN107841098A (en) | A kind of imitative ceramic flame-proof PBT/PC resin combinations and preparation method thereof | |
| CN107915962A (en) | A kind of imitative ceramic flame-proof polyester/ABS resin composition and preparation method thereof | |
| CN107915963A (en) | A kind of imitative ceramic polyester/ABS resin composition and preparation method thereof | |
| CN107857979A (en) | One kind imitates ceramic PBT/PET resin combinations and preparation method thereof | |
| CN104530678B (en) | A kind of degradable flowing PC/PLA alloy materials high and preparation method thereof | |
| CN107778795A (en) | A kind of imitative ceramic flame-proof PBT/ABS resin combinations and preparation method thereof | |
| CN103709684A (en) | High impact thermoplastic alloy for electronic and electric components and preparation method thereof | |
| CN107915961A (en) | A kind of imitative ceramic polyester resin combination and preparation method thereof | |
| CN107955345A (en) | A kind of imitative ceramic flame-proof PET resin component and preparation method thereof | |
| CN104098876B (en) | A kind of weatherability PBT/AES alloy and preparation method thereof | |
| CN107857980A (en) | A kind of imitative ceramic flame-proof polyester and resin composition and preparation method thereof | |
| CN107936493A (en) | Imitative ceramic PET resin component of one kind and preparation method thereof | |
| CN107868414A (en) | One kind imitates ceramic PBT resin composition and preparation method thereof | |
| CN106893336B (en) | Wood-plastic material, aluminium packet wood moulding door and window and preparation method thereof | |
| CN107892797A (en) | A kind of imitative ceramic flame-proof PBT resin composition and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20180417 |
|
| WD01 | Invention patent application deemed withdrawn after publication |