CN105462151A - ABS/PBT composition and application thereof - Google Patents
ABS/PBT composition and application thereof Download PDFInfo
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- CN105462151A CN105462151A CN201510923114.8A CN201510923114A CN105462151A CN 105462151 A CN105462151 A CN 105462151A CN 201510923114 A CN201510923114 A CN 201510923114A CN 105462151 A CN105462151 A CN 105462151A
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- abs
- pbt
- pbt composition
- ftracture
- compatilizer
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/08—Polymer mixtures characterised by other features containing additives to improve the compatibility between two polymers
Abstract
The invention discloses an ABS/PBT composition. The ABS/PBT composition is prepared from 50-90 parts of ABS, 10-50 parts of PBT and 2-5 parts of compatilizer. The content of acrylonitrile in ABS ranges from 18% to 21%, and the content of butadiene ranges from 25% to 33%. ABS with acrylonitrile and butadiene in the specific content is selected and used, ABS, PBT, compatilizer and the like are mixed, the compatibility of ABS and PBT is improved, the ABS/PBT composition has the excellent performance of ABS and the excellent performance of PBT, and furthermore, ABS and PBT have excellent grease resistance.
Description
Technical field
The present invention relates to technical field of polymer materials, particularly a kind of ABS/PBT composition and application thereof.
Background technology
ABS resin is acrylonitrile-butadiene-styrene terpolymer, have good mechanical performance, cold-resistant, shock resistance, oil resistant, dimensional stabilizing, electrical property excellent, can electroplate, the feature such as easy-formation, become a kind of resin that output is large, purposes is wide, wide in variety.But conventional ABS resin resistance to grease performance and low temperature impact properties all poor, when being used as materials such as accumulator housings, when can cause battery jar chance grease or under low temperature environment service condition, there is serious cracking phenomena.In accumulator charging/discharging process, battery temp rises, and battery jar is met grease (machine oil, lubricating oil, brake wet goods) or when running into low temperature environment, be there will be cracking phenomena, causes store battery short circuit to be caught fire.
Polybutylene terephthalate (PBT) is a class crystalline polyester, has good organic solvent-resistant, chemical proofing, self-lubricating property and moulding processability etc., is widely used in recent years electric grade in industrial circle.ABS and PBT is carried out the blended performance such as weathering resistance, oil-proofness, solvent resistance effectively can improving ABS material.But due to ABS be a kind of non-crystalline type polymkeric substance, and PBT is crystalline polyester, is typical amorphous/crystalline polymer blending, and both consistencies are poor.
But the ABS prepared in prior art and PBT alloy do not possess good resistance to grease performance, still cannot meet the requirement of accumulator housing materials application.
Summary of the invention
The object of the invention is to solve the deficiencies in the prior art, providing a kind of ABS/PBT composition, it has excellent resistance to grease performance.
The present invention is achieved through the following technical solutions foregoing invention object.
A kind of ABS/PBT composition, described ABS/PBT composition comprises the following component calculated by weight:
ABS50 ~ 90 part;
PBT10 ~ 50 part;
Compatilizer 2 ~ 5 parts;
In wherein said ABS, vinyl cyanide mass content is 18% ~ 21%, divinyl mass content is 25% ~ 33%.
In ABS, vinyl cyanide provides higher hardness, preferably thermotolerance, stronger chemical resistance for ABS resin, 1,3-divinyl provides low temperature ductility and shock resistance for ABS resin, vinylbenzene provides hardness, the mobility of processing and product surface best bright finish for ABS resin, along with the adjustment of three kinds of component proportionss, the physicals of resin has certain change.Contriver finds, in the ABS of employing, the content of vinyl cyanide and 1,3-butadiene is in above-mentioned scope, and the resistance to grease performance of ABS and resistance to low temperature can be made to be balanced; PBT has good organic solvent-resistant, chemical proofing, self-lubricating property and moulding processability.Contriver found through experiments, and selects ABS and PBT of the acrylonitrile and butadiene with above-mentioned content to combine, and it is mixed with compatilizer, and the ABS/PBT composition of acquisition has excellent resistance to grease performance.
Preferably, described ABS/PBT composition comprises the following component calculated by weight:
ABS50 ~ 90 part;
PBT10 ~ 50 part;
Compatilizer 2 ~ 5 parts;
Toughner 5 ~ 15 parts;
In wherein said ABS, vinyl cyanide mass content is 18% ~ 21%, 1,3-butadiene mass content is 25% ~ 33%;
The intrinsic viscosity of described PBT is for being not less than 0.95dl/g.
Intrinsic viscosity of the present invention carries out testing determining according to ASTMD-2857.
Contriver finds, adopts the PBT of above-mentioned scope and above-mentioned ABS to combine under the existence of compatilizer, toughner, and its resistance to grease performance not only with excellence of the ABS/PBT composition of acquisition also has excellent resistance to low temperature.
Preferably, described ABS/PBT composition preferably includes the following component calculated by weight:
ABS60 ~ 70 part;
PBT20 ~ 35 part;
Compatilizer 2 ~ 3 parts;
Toughner 8 ~ 10 parts;
In wherein said ABS, vinyl cyanide mass content is 18% ~ 21%, divinyl mass content is 25% ~ 33%;
The intrinsic viscosity of described PBT is for being not less than 0.95dl/g.
In above-mentioned preferably scope, the ABS/PBT composition of acquisition not only has excellent resistance to grease and excellent resistance to low temperature, also has excellent mechanical property.
In the present invention, described compatilizer can be the compatilizer that this area is commonly used.Preferably, described compatilizer is one or more in maleic anhydride graft acrylonitrile-butadiene-styrene (ABS) (ABS-g-MAH), acrylonitrile-styrene-glycidyl methacrylate, Zelan 338.Be more preferably Zelan 338.
In the present invention, described toughner can be the toughner that this area is commonly used.Preferably, described toughner is one or more in MBS, high glue powder, Ethylene-butyl Acrylate-methacrylic Acid Glycerin Ester Copolymer, silicon system toughner.Be more preferably silicon system toughner.
Described ABS/PBT composition also can contain auxiliary agent further, and preferably, the addition of described auxiliary agent is no more than 5 parts.
In the present invention, described auxiliary agent can be lubricant, oxidation inhibitor, nucleator, one or more in tinting material that this area is commonly used.
In the present invention, described lubricant can be the lubricant that this area is commonly used.Preferably, described lubricant is stearic amide, methylene bis stearic amide, N, N-ethylene bis stearic acid amide or pentaerythritol stearate.
In the present invention, described oxidation inhibitor can be the oxidation inhibitor that this area is commonly used.Preferably, described oxidation inhibitor is organophosphite, the alkylation reaction product of alkylating monohydric phenol or polyphenol, polyphenol and diene, p-cresol or the butylation reaction product of Dicyclopentadiene (DCPD), alkylating hydroquinones, hydroxylated thiodiphenvl ethers, alkylidene group-bis-phenol, benzyl compounds or polyol ester kind antioxidant.
In the present invention, described nucleator can be the nucleator that this area is commonly used.Preferably, in described ABS/PBT composition, nucleator is linear carboxylic acid calcium salt, calcium carbonate or talcum powder.
Preferably, described tinting material is pigment or dyestuff.
Usually, the intrinsic viscosity of conventional PBT is not higher than 1.3dl/g.Therefore, the intrinsic viscosity of PBT of the present invention is preferably not less than 0.95dl/g extremely not higher than 1.3dl/g.
This patent also discloses the preparation method of described ABS/PBT composition, and its preparation process is: after described ABS, PBT, compatilizer, toughner (if there is) and auxiliary agent proportionally being weighed, blended, extrudes, cooling, granulation.
Compared with prior art, the present invention has following beneficial effect:
The present invention is by selecting the ABS of the acrylonitrile and butadiene of certain content, it is mixed with PBT, compatilizer etc., make ABS/PBT composition have the premium properties of ABS and PBT simultaneously, and make ABS and PBT have excellent resistance to grease performance further, further, the intrinsic viscosity of PBT is carried out preferably, and adds toughner, the ABS/PBT composition simultaneously with excellent resistance to grease performance and resistance to low temperature can be obtained.Again further, preferred by what form formula, obtain a kind of resistance to low temperature not only with excellent resistance to grease and excellence, also there is the ABS/PBT composition of excellent mechanical property.
Embodiment
Set forth the present invention below in conjunction with specific embodiment, but protection scope of the present invention is not only confined to following examples, the explanation of embodiment just understands method of the present invention and core concept thereof for helping.Any amendment done within all spirit at this patent and principle, equivalently to replace and improvement etc., within the protection domain that all should be included in application claims.
Low temperature resistant and the resistance to grease performance that the present invention proposes, test by the following method:
Resistance to low temperature is tested: after the square plate of 2mm is placed 8 hours in the refrigerator of-30 DEG C, pound with the iron ball of 2kg from 60cm height, observe its cracking situation.
Resistance to grease performance test 1: spread upon in the tensile bars of bending certain angle by the various greases that GB/T11547-2008 " mensuration of plastics resistant to liquid chemical reagent performance " records, to place in the baking oven of 70 DEG C 48 hours, observes its cracking situation.
Resistance to grease performance test 2: spread upon in the tensile bars of bending certain angle by brake solution braking fluid DOT3, DOT4, DOT5, to place in the baking oven of 70 DEG C 48 hours, observes its cracking situation.
When any one grease of employing is tested, there is wrinkling situation in spline surfaces, is then designated as slight cracking; When there is cracking situation, be then designated as cracking; When employing grease used is tested, when all there is not cracking situation, be designated as and do not ftracture.
Mechanics Performance Testing of the present invention is tested by the following method: the ABS/PBT composition prepared is placed in dry 2 ~ 4 hours of the air dry oven that temperature is 70 ~ 80 DEG C, sample preparation on injection moulding machine.Cooling placement 24 was as a child tested afterwards, and Mechanics Performance Testing standard is iso standard.
The ABS used in the present invention:
Component a-1:ABS1PA-747S(Taiwan is very beautiful), wherein AN(vinyl cyanide) content 20.5%, rubber (divinyl) content 32.1%;
Component a-2:ABS2D-120A(Zhenjiang is very beautiful), wherein AN(vinyl cyanide) content 19.6%, rubber (divinyl) content 37.6%;
Dagu, component a-3:ABS3DG-MG29(Tianjin), wherein AN(vinyl cyanide) content 22.8%, rubber (divinyl) content 38.9%;
The PBT used in the present invention:
Components b-1:PBT1PBT1084(Nantong stars), intrinsic viscosity is 0.8 ± 0.02dl/g;
Changchun, components b-2:PBT2PBT1100-211M(Taiwan), intrinsic viscosity is 1 ± 0.02dl/g;
Changchun, components b-3:PBT3PBT1100-211S(Taiwan), intrinsic viscosity is 1.2 ± 0.02dl/g;
The compatilizer used in the present invention:
Amount of component b: cloud tints electronics novel material company limited of SMA700(Shanghai China);
The toughner used in the present invention:
The beautiful sun of component d:S-2001(Mitsubishi)
Other auxiliary agent used in the present invention:
Component e-1: four [β-(3,5-di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol ester and three [2.4-di-tert-butyl-phenyl] phosphorous acid ester is composite as oxidation inhibitor;
Component e-2: pentaerythritol stearate is as lubricant.
Embodiment 1 ~ 6 and comparative example 1 ~ 6
After above-mentioned ABS, PBT, compatilizer and other auxiliary agent proportionally being weighed by the formula of table 1, complete blended, extrude by high mixer or mixing machine, cross water cooling, granulation obtains the ABS/PBT composition of cylindrical particle; Carry out low temperature resistant and resistance to grease performance test to said composition, data are in table 2.
From embodiment 1 ~ 6, it, by selecting suitable ABS matrix, mixes with PBT, compatilizer by the present invention, and the ABS/PBT composition of preparation has excellent resistance to grease performance, better to the tolerance of brake solution braking fluid specifically.As can be seen from comparative example 1 ~ 6, when the character of the ABS selected is not in scope of the present invention, even if then it possesses the resistance to grease performance of GB/T11547-2008, brake solution braking fluid can not be tolerated.
The concrete proportioning (weight part) of table 1 embodiment 1 ~ 6 and comparative example 1 ~ 6
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Embodiment 6 | Comparative example 1 | Comparative example 2 | Comparative example 3 | Comparative example 4 | Comparative example 5 | Comparative example 6 | |
| Component a-1 | 84.2 | 55.2 | 84.2 | 55.2 | 84.2 | 55.2 | 0 | 0 | 0 | 0 | 0 | 0 |
| Component a-2 | 0 | 0 | 0 | 0 | 0 | 0 | 84.2 | 55.2 | 84.2 | 55.2 | 0 | 0 |
| Component a-3 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 84.2 | 55.2 |
| Components b-1 | 13 | 39 | 0 | 0 | 0 | 0 | 13 | 39 | 0 | 0 | 13 | 39 |
| Components b-2 | 0 | 0 | 13 | 39 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 |
| Components b-3 | 0 | 0 | 0 | 0 | 13 | 39 | 0 | 0 | 13 | 39 | 0 | 0 |
| Amount of component b | 2 | 5 | 2 | 5 | 2 | 5 | 2 | 5 | 2 | 5 | 2 | 5 |
| Component e-1 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 |
| Component e-2 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 |
The performance test results of table 2 embodiment 1 ~ 6 and comparative example 1 ~ 6
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Embodiment 6 | Comparative example 1 | Comparative example 2 | Comparative example 3 | Comparative example 4 | Comparative example 5 | Comparative example 6 | |
| Low temperature ball falling impact | Cracking | Cracking | Cracking | Cracking | Cracking | Cracking | Cracking | Cracking | Cracking | Cracking | Cracking | Cracking |
| Resistance to grease performance 1 | Do not ftracture | Do not ftracture | Do not ftracture | Do not ftracture | Do not ftracture | Do not ftracture | Do not ftracture | Do not ftracture | Do not ftracture | Do not ftracture | Do not ftracture | Do not ftracture |
| Resistance to grease performance 2 | Do not ftracture | Do not ftracture | Do not ftracture | Do not ftracture | Do not ftracture | Do not ftracture | Cracking | Cracking | Cracking | Cracking | Cracking | Cracking |
Embodiment 7 ~ 12 and comparative example 7 ~ 12
Further, after above-mentioned ABS, PBT, compatilizer, toughner and other auxiliary agent proportionally being weighed, complete blended, extrude by high mixer or mixing machine by the formula of table 3, cross water cooling, granulation obtains the ABS/PBT composition of cylindrical particle; Carry out the test of mechanical property and low temperature resistant and resistance to grease performance test to said composition, data are in table 4.
As can be seen from the Performance comparision of embodiment 7 ~ 12 and comparative example 7 ~ 12, the present invention is by selecting suitable ABS and PBT matrix, add toughner simultaneously, the ABS/PBT composition of preparation can be made to have resistance to grease performance while, have resistance to low temperature, be applicable to environment for use and require higher occasion.Further, as can be seen from embodiment 9 and embodiment 12, do further to optimize to the proportioning of component, the mechanical property of composition can also be improved.
The concrete proportioning (weight part) of table 3 embodiment 7 ~ 12 and comparative example 7 ~ 12
| Embodiment 7 | Embodiment 8 | Embodiment 9 | Embodiment 10 | Embodiment 11 | Embodiment 12 | Comparative example 7 | Comparative example 8 | Comparative example 9 | Comparative example 10 | Comparative example 11 | Comparative example 12 | |
| Component a-1 | 79.2 | 55.2 | 62.2 | 79.2 | 55.2 | 62.2 | 79.2 | 55.2 | 62.2 | 0 | 0 | 0 |
| Component a-2 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 79.2 | 55.2 | 62.2 |
| Component a-3 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 |
| Components b-1 | 0 | 0 | 0 | 0 | 0 | 0 | 13 | 29 | 26 | 0 | 0 | 0 |
| Components b-2 | 13 | 29 | 26 | 0 | 0 | 0 | 0 | 0 | 0 | 13 | 29 | 26 4 --> |
| Components b-3 | 0 | 0 | 0 | 13 | 29 | 26 | 0 | 0 | 0 | 0 | 0 | 0 |
| Amount of component b | 2 | 5 | 3 | 2 | 5 | 3 | 2 | 5 | 3 | 2 | 5 | 3 |
| Component d | 5 | 10 | 8 | 5 | 10 | 8 | 5 | 10 | 8 | 5 | 10 | 8 |
| Component e-1 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 |
| Component e-2 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 |
The performance test results of table 4 embodiment 7 ~ 12 and comparative example 7 ~ 12
| Embodiment 7 | Embodiment 8 | Embodiment 9 | Embodiment 10 | Embodiment 11 | Embodiment 12 | Comparative example 7 | Comparative example 8 | Comparative example 9 | Comparative example 10 | Comparative example 11 | Comparative example 12 | |
| Notched Izod impact strength, kJ/m 2 | 40.2 | 47.6 | 52.3 | 41.1 | 48.6 | 54.2 | 39.6 | 41.4 | 43.7 | 43.6 | 44.2 | 50.1 |
| Flexural strength, MPa | 46 | 51 | 53 | 47 | 52 | 59 | 45 | 47 | 50 | 45 | 50 | 52 |
| Modulus in flexure, MPa | 1658 | 1736 | 1852 | 1670 | 1756 | 1896 | 1629 | 1710 | 1731 | 1634 | 1712 | 1804 |
| Tensile strength, MPa | 39.3 | 40.2 | 40.9 | 41.1 | 41.7 | 42.3 | 38.9 | 39.4 | 40.2 | 39.8 | 40.1 | 40.5 |
| Elongation at break, % | 18 | 20 | 25 | 20 | 24 | 32 | 17 | 19 | 20 | 19 | 21 | 22 |
| Low temperature ball falling impact | Slight cracking | Do not ftracture | Do not ftracture | Slight cracking | Do not ftracture | Do not ftracture | Cracking | Cracking | Cracking | Do not ftracture | Do not ftracture | Do not ftracture |
| Resistance to grease performance 1 | Do not ftracture | Do not ftracture | Do not ftracture | Do not ftracture | Do not ftracture | Do not ftracture | Do not ftracture | Do not ftracture | Do not ftracture | Do not ftracture | Do not ftracture | Do not ftracture |
| Resistance to grease performance 2 | Do not ftracture | Do not ftracture | Do not ftracture | Do not ftracture | Do not ftracture | Do not ftracture | Do not ftracture | Do not ftracture | Do not ftracture | Cracking | Cracking | Cracking |
Claims (10)
1. an ABS/PBT composition, described ABS/PBT composition comprises the following component calculated by weight:
ABS50 ~ 90 part;
PBT10 ~ 50 part;
Compatilizer 2 ~ 5 parts;
In wherein said ABS, vinyl cyanide mass content is 18% ~ 21%, divinyl mass content is 25% ~ 33%.
2., according to ABS/PBT composition described in claim 1, described ABS/PBT composition comprises the following component calculated by weight:
ABS50 ~ 90 part;
PBT10 ~ 50 part;
Compatilizer 2 ~ 5 parts;
Toughner 5 ~ 15 parts;
In wherein said ABS, vinyl cyanide mass content is 18% ~ 21%, divinyl mass content is 25% ~ 33%;
The intrinsic viscosity of described PBT is for being not less than 0.95dl/g.
3. ABS/PBT composition according to claim 2, described ABS/PBT composition comprises the following component calculated by weight:
ABS60 ~ 70 part;
PBT20 ~ 35 part;
Compatilizer 2 ~ 3 parts;
Toughner 8 ~ 10 parts;
In wherein said ABS, vinyl cyanide mass content is 18% ~ 21%, divinyl mass content is 25% ~ 33%;
The intrinsic viscosity of described PBT is for being not less than 0.95dl/g.
4. ABS/PBT composition according to claims 1 to 3 any one, is characterized in that described compatilizer is one or more in maleic anhydride graft acrylonitrile-butadiene-styrene (ABS), acrylonitrile-styrene-glycidyl methacrylate, Zelan 338.
5. ABS/PBT composition according to claims 1 to 3 any one, is characterized in that described toughner is one or more in MBS, high glue powder, Ethylene-butyl Acrylate-methacrylic Acid Glycerin Ester Copolymer, silicon system toughner.
6. ABS/PBT composition according to claims 1 to 3 any one, is characterized in that described ABS/PBT composition contains auxiliary agent; Described auxiliary agent is one or more in lubricant, oxidation inhibitor, nucleator, tinting material.
7. ABS/PBT composition according to claim 6, is characterized in that described lubricant is stearic amide, methylene bis stearic amide, N, N-ethylene bis stearic acid amide or pentaerythritol stearate.
8. ABS/PBT composition according to claim 6, is characterized in that described oxidation inhibitor is organophosphite, the alkylation reaction product of alkylating monohydric phenol or polyphenol, polyphenol and diene, p-cresol or the butylation reaction product of Dicyclopentadiene (DCPD), alkylating hydroquinones, hydroxylated thiodiphenvl ethers, alkylidene group-bis-phenol, benzyl compounds or polyol ester kind antioxidant.
9. ABS/PBT composition according to claim 6, is characterized in that described nucleator is linear carboxylic acid calcium salt, calcium carbonate or talcum powder.
10. ABS/PBT composition described in any one of claim 1 to 9 is as the application in accumulator housing material.
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| CN105670210A (en) * | 2016-03-31 | 2016-06-15 | 山东同道电源科技有限公司 | High-strength oil-resistant storage battery case material and preparation method thereof |
| CN106117954A (en) * | 2016-07-28 | 2016-11-16 | 广东天保新材料有限责任公司 | A kind of oil resistant, low temperature resistant regeneration ABS/PBT alloy material |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101469107A (en) * | 2007-12-25 | 2009-07-01 | 上海普利特复合材料股份有限公司 | Glass fiber reinforced PBT / ABS composite material with excellent surface and high fluidity |
| CN102108191A (en) * | 2009-12-28 | 2011-06-29 | 上海日之升新技术发展有限公司 | Antistatic polybutylece terephthalate (PBT)/acrylonitrile butadiene styrene (ABS) compound material and preparation method thereof |
| CN102993648A (en) * | 2012-08-22 | 2013-03-27 | 广东威林工程塑料有限公司 | Anti-static high-gloss flame-retardant PBT/ABS composite material and preparation method thereof |
-
2015
- 2015-12-14 CN CN201510923114.8A patent/CN105462151A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101469107A (en) * | 2007-12-25 | 2009-07-01 | 上海普利特复合材料股份有限公司 | Glass fiber reinforced PBT / ABS composite material with excellent surface and high fluidity |
| CN102108191A (en) * | 2009-12-28 | 2011-06-29 | 上海日之升新技术发展有限公司 | Antistatic polybutylece terephthalate (PBT)/acrylonitrile butadiene styrene (ABS) compound material and preparation method thereof |
| CN102993648A (en) * | 2012-08-22 | 2013-03-27 | 广东威林工程塑料有限公司 | Anti-static high-gloss flame-retardant PBT/ABS composite material and preparation method thereof |
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| CN105670210A (en) * | 2016-03-31 | 2016-06-15 | 山东同道电源科技有限公司 | High-strength oil-resistant storage battery case material and preparation method thereof |
| CN106117954A (en) * | 2016-07-28 | 2016-11-16 | 广东天保新材料有限责任公司 | A kind of oil resistant, low temperature resistant regeneration ABS/PBT alloy material |
| CN106117954B (en) * | 2016-07-28 | 2018-11-09 | 广东天保新材料有限责任公司 | A kind of oil resistant, low temperature resistant regeneration ABS/PBT alloy materials |
| CN106987102A (en) * | 2017-05-06 | 2017-07-28 | 广东威林工程塑料股份有限公司 | Low floating fine short fiber enhanced PBT/ABS alloy material of a kind of heat-resisting impact resistance available for electric appliance casing and preparation method thereof |
| CN107523002A (en) * | 2017-08-03 | 2017-12-29 | 长兴天晟能源科技有限公司 | A kind of special high oil resistant high-performance ABS alloy material of battery cell case |
| CN107746557A (en) * | 2017-12-01 | 2018-03-02 | 上海金发科技发展有限公司 | One kind imitates ceramic PBT/ABS resin combinations and preparation method thereof |
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| CN107892797A (en) * | 2017-12-01 | 2018-04-10 | 上海金发科技发展有限公司 | A kind of imitative ceramic flame-proof PBT resin composition and preparation method thereof |
| CN107915963A (en) * | 2017-12-01 | 2018-04-17 | 上海金发科技发展有限公司 | A kind of imitative ceramic polyester/ABS resin composition and preparation method thereof |
| CN107915962A (en) * | 2017-12-01 | 2018-04-17 | 上海金发科技发展有限公司 | A kind of imitative ceramic flame-proof polyester/ABS resin composition and preparation method thereof |
| CN107915961A (en) * | 2017-12-01 | 2018-04-17 | 上海金发科技发展有限公司 | A kind of imitative ceramic polyester resin combination and preparation method thereof |
| CN107936492A (en) * | 2017-12-01 | 2018-04-20 | 上海金发科技发展有限公司 | A kind of imitative ceramic flame-proof PBT/PET resin combinations and preparation method thereof |
| CN107841098A (en) * | 2017-12-01 | 2018-03-27 | 上海金发科技发展有限公司 | A kind of imitative ceramic flame-proof PBT/PC resin combinations and preparation method thereof |
| CN108164917A (en) * | 2017-12-28 | 2018-06-15 | 长沙善道新材料科技有限公司 | A kind of accumulator housing material and preparation method thereof |
| CN109135158A (en) * | 2018-07-27 | 2019-01-04 | 会通新材料股份有限公司 | A kind of high tenacity, ABS/PBT alloy of scratch-resistant and preparation method thereof |
| CN109679302A (en) * | 2018-12-19 | 2019-04-26 | 中广核俊尔新材料有限公司 | A kind of water-fastness PBT zipper material of high-modulus and its application |
| CN109749347A (en) * | 2018-12-27 | 2019-05-14 | 会通新材料股份有限公司 | A kind of resistance to grease ABS composite material of low linear expansion coefficient and preparation method thereof |
| CN111205589A (en) * | 2019-11-28 | 2020-05-29 | 上海普利特复合材料股份有限公司 | Stress cracking resistant high-fluidity electroplating-grade ABS/PBT alloy material and preparation method thereof |
| CN111205589B (en) * | 2019-11-28 | 2022-06-28 | 上海普利特复合材料股份有限公司 | Stress-cracking-resistant high-fluidity electroplating-grade ABS/PBT alloy material and preparation method thereof |
| CN115975333A (en) * | 2022-09-20 | 2023-04-18 | 广东拓亿信息科技有限公司 | Corrosion-resistant environment-friendly plastic shell and preparation method thereof |
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Application publication date: 20160406 |