CN107915944A - It is a kind of that there is bright pearly-lustre, high flowing, the translucent ABS material of high intensity - Google Patents
It is a kind of that there is bright pearly-lustre, high flowing, the translucent ABS material of high intensity Download PDFInfo
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- CN107915944A CN107915944A CN201711106434.XA CN201711106434A CN107915944A CN 107915944 A CN107915944 A CN 107915944A CN 201711106434 A CN201711106434 A CN 201711106434A CN 107915944 A CN107915944 A CN 107915944A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
- C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2355/00—Characterised by the use of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08J2323/00 - C08J2353/00
- C08J2355/02—Acrylonitrile-Butadiene-Styrene [ABS] polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2425/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
- C08J2425/02—Homopolymers or copolymers of hydrocarbons
- C08J2425/04—Homopolymers or copolymers of styrene
- C08J2425/08—Copolymers of styrene
- C08J2425/12—Copolymers of styrene with unsaturated nitriles
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2451/00—Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2451/00—Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
- C08J2451/04—Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers grafted on to rubbers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2455/00—Characterised by the use of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08J2423/00 - C08J2453/00
- C08J2455/02—Acrylonitrile-Butadiene-Styrene [ABS] polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/06—Pretreated ingredients and ingredients covered by the main groups C08K3/00 - C08K7/00
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/10—Encapsulated ingredients
Abstract
The present invention provides a kind of translucent ABS material and preparation method thereof, the translucent ABS material is made using ABS resin, SAN as base material by adding color masterbatch, function additive, metal powder, pearl powder；The compounding of different ABS can effectively reduce material cost and improve mechanical property；The mechanical property, translucency and material flowability energy of material can rationally be adjusted by adding SAN；The compounding of metal powder, pearl powder, can make the bright effect of alloy material reach product appearance requirement；Flow ability modifying agent also serves as anti-scratch and draws agent, you can changes the mobility of material, also material can be enable to possess certain rub resistance；Add lubricant, can have good lubricity, reduce surface tension, reduce friction, enhancing glossiness, also can reinforcing material rub resistance energy；The addition of toughener rationally adjusts the mechanical property of material, bright pearly-lustre, high flowing, the high intensity trnaslucent materials of preparation is disclosure satisfy that household appliances exempt to spray appearance and other decoration functions demands.
Description
Technical field
The invention belongs to macromolecule engineering plastics arts, and in particular to there is one kind bright pearly-lustre, height to flow, is high-strength
Translucent ABS material of degree and preparation method thereof.
Background technology
Household appliances appearance is mostly using techniques such as injections in spray opalescent lacquers+Lacquer finish, plating, film at present, to comply with household electrical appliances
The new demand of industry " low-carbon, environmental protection, energy saving, emission reduction ", it is proposed that in order to avoid the innovative technology solution party based on spraying, intensive etc.
Case, injects sustainable development power for household electric appliances.Realize that bright pearl effect is different from traditional technique, by once noting
It is moulded into type and can obtain beautiful, high glaze, and the resin with bright pearl effect, and the resin possesses energy printing opacity and shows
Show, colored translucent effect, such as diamond cut face, colorful bright flicker effect is presented under light.Can be extensively using being in
On the looking products such as electricity, small household appliances, handheld device, it is with a wide range of applications exempting from spraying field.
105482352 A of Chinese invention document CN propose a kind of novel macreous ABS material and processing method, described new
The raw material of type pearly-lustre ABS material includes ABS, compatilizer, toughener, pearlescent pigment, lubricant, the ABS material which provides
With preferable pearl effect, but mechanical performance is not ideal enough.Chinese invention document CN 103923429 proposes a kind of imitative
Height flowing ABS resin and preparation method thereof, it is more excellent with processing fluidity that the resin that the document provides has obtained mechanical property
Product, on the premise of impact resistance is not lost, improve mobility, but the no pearl effect of the invention.Middle promulgated by the State Council
In plain text offer 105038095 A of CN propose one kind exempt from spraying, without current mark ABS composite material and preparation method thereof, be prepared
Composite fluidity is high, hardness is high, pearl effect is notable, but the strength of materials is not reported.Chinese invention document CN
105199294 A propose a kind of high glaze with special-effect and exempt to spray ABS composite material and preparation method thereof, the invention
The preparation method of offer is simple, and pearl effect is notable, but the mechanical property such as the tensile strength of material, elongation at break is not appeared in the newspapers
Road.104845014 A of Chinese invention document CN propose a kind of with high flowing, the metal of high heat-resisting, high appearance or pearl
Light effect exempts to spray ABS material and preparation method thereof, and the material which provides has excellent mobility, heat resistance, metal
Texture and pearl effect, but the performance such as transparency has no elaboration.
Mainly reach pearl effect in the following manner at present, i.e., using ABS as base material, add a certain proportion of pearly-lustre face
Material is granulated by twin-screw blending, then the granular materials for being granulated production with being blended is molded into appliance shell, its pearly-lustre face added
It is mica surface one layer of metal oxide of cladding in sheet to expect main component, changes the grain of metal oxide and pearlescent pigment
Footpath, you can reach different pearl effects.But since pearlescent pigment and ABS resin compatibility are poor, after being blended with ABS resin not
But hardly possible obtains preferable pearl effect, and larger to ABS resin Effect on Mechanical Properties, major diameter need to be used long and sheared stronger
Twin-screw carries out blending and is granulated processing.Following defect is clearly present when ABS is granulated with pearlescent pigment blending at present：1st, pearlescent pigment
With ABS resin poor compatibility, ABS material physical properties are not only influenced, can also when being molded massive article since compatibility is bad
There is pearlescent pigment and disperse bad caused open defect, be commonly called as material flower；2nd, existing processing method can reduce pearlescent pigment grain
Footpath, reduces pearl effect, since pearlescent pigment and ABS substrate compatibility are poor, existing way is after ABS is mixed with pearlescent pigment
It is granulated through the long double screw extruder blending of major diameter, such a method shearing dynamics is larger, and then pearlescent pigment is destroyed larger.
Pearlescent pigment particle diameter is diminished, and then finished product pearl effect is deteriorated；3rd, finished product machinery poor-performing, when use, are brittle.
The content of the invention
Existing in the prior art to solve the problems, such as, the object of the present invention is to provide a kind of bright pearly-lustre, high flowing, high intensity
Translucent ABS material and preparation method thereof.The present invention be directed to existing household electrical appliance appearance both to have needed bright pearl effect,
Certain translucency is needed again, is such as shown for LED, decorative lighting, and a solution proposed, it is existing for substituting
Spray painting+laser carving technique；The translucent ABS material of the present invention is using SAN, ABS resin as base material, by adding transparent masterbatch, work(
Energy auxiliary agent, metal powder, pearl powder are made；The present invention utilizes a small amount of metal powder bottoming, for strengthening metal-like effect,
Using pearl powder as interspersing, for forming the effect of bright flicker；It reasonably have adjusted ABS/SAN resin materials with toughener
Physical property, makes it meet product mechanics and light transmission requirement；Metal powder, the composite usage of pearl powder can reduce metal powder
Content, reduce injection weld mark；The lubricant of addition can effectively reduce frictional force, improve product glossiness；Present invention system
Standby obtained material, has the advantages that height flows, exempts from spraying, high intensity, texture is strong, material permeability is good, disclosure satisfy that function
Household appliances appearance requirement.
To achieve the above object, the present invention uses following technical scheme：
The present invention provides it is a kind of with bright pearly-lustre, high flowing, high intensity translucent ABS material, it includes following
Component by weight：
Preferably, it is described with bright pearly-lustre, high flowing, the translucent ABS material of high intensity include it is following by weight
The component of meter：
Preferably, the Masterbatch is transparent masterbatch, its base material is Methyl Methacrylate-Styrene acrylonitrile polymerization
Thing, toner are transparent toner.
Preferably, the mobility of the ABS resin is 30~50g/10min；Elongation at break is 6-10%；23 DEG C of room temperature
Under, its notch impact strength is in 15~25KJ/m2；Light penetration is 85%~89%.(1/8 ", ASTM D-1003).
Preferably, the ABS resin is selected from ABS 756K, ABS 756H, ABS 121H, ABS 558A and ABS 920
One or more.
Preferably, the mobility of the styrene acrylonitrile copolymer (SAN) is 30~50g/10min；Light penetration
For 88-92% (2 ", ASTM D-1003).
Preferably, the toughener is methylacrylate-butadiene (MBS) core-shell type anti-impact modifier of copolymerization, is had
There is excellent dispersiveness, and preferable low-temperature impact resistance, excellent stability, excellent coloring, wherein rubber contain
Amount>75%.
Preferably, the flow ability modifying agent is Methyl Methacrylate-Styrene acrylonitrile (MMA-SAN) polymer, its
The weight percentage of middle methyl methacrylate is 30~50%, the weight percentage of styrene-acrylonitrile for 50~
70%.
Preferably, the lubricant is alkylaryl modified silicon oil, has good lubricity, can reduce surface tension,
Reduce friction, enhancing glossiness.
Preferably, the pearl powder is handled through PE waxes cladding, is three-dimensional shape, particle size range is 50~150 μm.
Preferably, the metal powder is handled through PE waxes cladding, is sheet, particle size range is 6~50 μm.
It is further preferred that the metal powder is polishing cornflake.
Preferably, the antioxidant is 1010 and 168 by weight being (1~2)：1 compounding obtains.
The main Types of pearlescent pigment have：Natural fish scale pearlescent pigment, bismoclite crystallization pearlescent pigment and mica coating
Pearlescent pigment.Coat mica sheet pearlescent pigment using most often oxide, they are very thin mica sheets, surface covering
Titanium dioxide, titanium oxide or other metal oxides.For the size of mica from 4 μm to 120 μm, thickness is about 0.5 μm.Pearly-lustre face
Material can see interference colours according to mirrored effect reflection light in angle of reflection, and reverse in scattering angle, due to part light
Line have passed through face coat, and the complementary colours of interference colours still can see.When certain light absorbing pigment is added to pearlescent pigment, by
It is transparent in itself in pearlescent pigment, it is allowed to which light penetration simultaneously reaches light absorbing pigment and reflected again, so the color of light absorbing pigment
Thus it is reinforced, it is more bright.If light absorbing pigment is added in metallic pigments, since metallic pigments itself are opaque, light
It cannot pass through sheet metal and reach pigment, therefore color weakens.
In view of the optical characteristics of pearlescent pigment, makes the straightway disengaging paint film of light extremely important.It is any opaque or
Person, which can reduce the pigment of light or additive, can all make divergence of beam, so that weaken pearl effect, such as titanium dioxide, calcium carbonate
It will avoid using at the same time with pearlescent pigment with talcum powder etc..Present invention employs the sheet metal that particle size range is 6~50 μm
Powder and particle size range are 50~150 μm of three-dimensional shape pearl powder compoundings, can farthest play pearl powder and gold
Belong to the effect of powder, while make material that also there is translucent characteristic.
The present invention also provides it is a kind of with bright pearl effect, high flowing, high intensity translucent ABS material preparation side
Method, comprises the following steps：
(1) after drying ABS resin, styrene acrylonitrile copolymer and transparent masterbatch, it is put into homogenizer, adds
Enter lubricant and high-speed stirred；
(2) flow ability modifying agent, toughener, metal powder, pearl powder, antioxidant are added in high mixer successively, high-speed stirred
Afterwards, stirring at low speed and discharge；
(3) double screw extruder extruding pelletization is used.
Preferably, the drying temperature in step (1) is 80~90 DEG C, when drying time 2~4 is small.
Preferably, the high-speed stirred speed of step (1) is 3000~5000r/min, and the time is 1~3 minute.
Preferably, the high-speed stirred speed of step (2) is 3000~5000r/min, and the time is 1~3 minute；Stirring at low speed
Speed is 500~2000r/min, and the time is 1~3 minute.
Preferably, the discharging speed of step (2) is 500~2000r/min.
Preferably, the main-machine screw rotating speed of double screw extruder is 30~42r/s, and feed 25~35r/s of rotating speed, heating temperature
Spend for 190~235 DEG C, head temperature is 190~225 DEG C.
Invention further provides it is above-mentioned with bright pearl effect, high flowing, high intensity translucent ABS material
Injection molding forming method, comprises the following steps：
1) the high gloss mold of high/low temperature steam is provided；
2) for single-point into the product poured, using wide cast gate；For Multi-spot pouring product, using order into pouring mode；
3) glue-feeder position, wall thickness mutation, stream converge, muscle, groove, hole site high pressure low speed；
4) for hole product, generally in structure by the way of first filling-in post-processing.
The design parameter that injection molding uses is shown in Table 1：
The design parameter of 1 injection molding of table
Beneficial effects of the present invention
1st, material provided by the invention adds SAN (AS) resin (benzene mutually coordinated on the basis of using ABS as base material
Ethylene, propylene lonitrile copolymer), have the advantages that excellent flowability, permeability be good, easy coloring；
2nd, by the compounding of metal powder, pearl powder, not only make material provided by the invention that there is bright pearl effect, together
When material also there is good mechanical property；
3rd, flow ability modifying agent used in the present invention, toughener, lubricant synergistic effect, reduce the surface of material
Power, the glossiness for enhancing material, the rub resistance energy for enhancing material, the material being prepared have bright pearly-lustre, Gao Liu
Dynamic, high intensity trnaslucent materials disclosure satisfy that household appliances exempt to spray appearance and other decoration functions demands.
Embodiment
Embodiment 1
It is a kind of that there is bright pearl effect, high flowing, the preparation method of the translucent ABS material of high intensity, including following step
Suddenly：
(1) various raw materials are weighed according to 2 composition of raw materials of table, by ABS resin, styrene acrylonitrile copolymer and Transparent color
Master batch is put into homogenizer when drying 4 is small under the conditions of 80 DEG C, adds lubricant, and 1 is mixed in high-speed mixer high speed
~3min minutes；
(2) flow ability modifying agent, toughener, metal powder, pearl powder, antioxidant are sequentially added in high mixer successively, at a high speed
1~3min is stirred, then switch to 1~3min of stirring at low speed, then low speed discharging；
(3) material after mixing obtains having bright pearl effect, high flowing, high intensity translucent through fusing and pelleting
ABS material, product property detection data are shown in Table 3.
Melt pelletization condition is：Main-machine screw rotating speed 40r/s, feed rotating speed 35r/s, heating-up temperature section：1 section/190 DEG C, 2
Section/210 DEG C, 3 sections/215 DEG C, 4 sections/215 DEG C, 5 sections/215 DEG C, head temperature：220 DEG C, melt temperature：220℃.
Embodiment 2~8
The preparation method of embodiment 2~8 is same as Example 1, the specific raw material of the translucent ABS material of embodiment 1-8
Proportioning is shown in Table 2, and properties of product detection data are shown in Table 3.
Raw material proportioning (the unit of the translucent ABS material of 2 embodiment 1-8 of table：Kilogram)
The performance test results of the translucent ABS material of 3 embodiment 1-8 of table
In the present invention, tensile strength, elongation at break are tested according to national standard GB/T1040.2-2006；Bending strength,
Bending modulus is tested according to national standard GB/T934-2008；Izod notched impact strength is according to national standard GB/T1843-2008
Tested；Melt flow rate (MFR) is tested according to national standard GB/T3682-2000.
As can be seen from Table 3：
1st, independent comparing embodiment 1 and 2 is it can be found that the compounding of ABS influences significantly, using ABS material texture
The product texture that (756K) and ABS (920) compounding obtain is poor；
2nd, embodiment 1,2 and embodiment 3,4,5 are contrasted, it is possible to find the additive amount of metal powder and toughener is to material
Have a great influence in terms of performance, light transmittance；
3rd, in comparative example 7,8, the compounding of different metal powder and pearl powder can influence product appearance quality and mechanical property
Energy.
The present invention by compounding mode, rationally control formula in each component ratio and component so that material property with into
This combination is optimal；It can be obtained in the case of adding metal powder, pearl powder, toughener a kind of translucent with bright pearl effect
ABS material, thus with relatively low cost by the method for blending and modifying realize environmental protection exempt to paint, have high flowing, high intensity,
The preparation of translucent composite material, this method is easy to operate, and required raw material are easy to get.But the scope of the present invention not only limits
In this, the different realization sides such as colouring agent of degree, different-grain diameter metal powder pearl powder compounding effect and different colours thoroughly are further included
Formula, should all contain in the scope of the present invention.
Claims (10)
1. a kind of have bright pearly-lustre, high flowing, the translucent ABS material of high intensity, it is characterised in that comprising it is following by weight
The component of part meter：
2. according to claim 1 have bright pearly-lustre, high flowing, the translucent ABS material of high intensity, its feature exists
It is transparent masterbatch in, the Masterbatch, its base material is Methyl Methacrylate-Styrene acrylonitrile polymer, in Masterbatch
Toner can not only colour, but also not shading.
3. according to claim 1 have bright pearly-lustre, high flowing, the translucent ABS material of high intensity, its feature exists
In the mobility of the ABS resin is 30-50g/10min；Elongation at break is 6-10%；At 23 DEG C of room temperature, its notch shock
Intensity is in 15~25KJ/m2；Light penetration is 85%-89%.
4. according to claim 1 have bright pearly-lustre, high flowing, the translucent ABS material of high intensity, its feature exists
In the mobility of the styrene acrylonitrile copolymer is 30~50g/10min；Light penetration is 88-92%.
5. according to claim 1 have bright pearly-lustre, high flowing, the translucent ABS material of high intensity, its feature exists
In the toughener is methylacrylate-butadiene (MBS) core-shell type anti-impact modifier of copolymerization.
6. according to claim 1 have bright pearly-lustre, high flowing, the translucent ABS material of high intensity, its feature exists
In the flow ability modifying agent is Methyl Methacrylate-Styrene acrylonitrile polymer；Wherein described methyl methacrylate
Weight percentage is 30~50%, and the weight percentage of the styrene-acrylonitrile is 50~70%.
7. according to claim 1 have bright pearly-lustre, high flowing, the translucent ABS material of high intensity, its feature exists
In the lubricant is alkylaryl modified silicon oil.
8. according to claim 1 have bright pearly-lustre, high flowing, the translucent ABS material of high intensity, its feature exists
In the pearl powder is handled through PE waxes cladding, is three-dimensional shape, particle size range is 50~150 μm；The metal powder is through PE
The processing of wax cladding, is sheet, particle size range is 6~50 μm.
9. according to claim 1 have bright pearly-lustre, high flowing, the translucent ABS material of high intensity, its feature exists
In, the antioxidant be 1010 and 168 by weight being (1~2)：1 compounding obtains.
10. according to it is according to any one of claims 1 to 9 with bright pearly-lustre, high flowing, high intensity translucent ABS materials
The preparation method of material, it is characterised in that comprise the following steps：
(1) after drying ABS resin, styrene acrylonitrile copolymer and transparent masterbatch, it is put into homogenizer, then successively
Add toughener, metal powder, pearl powder, antioxidant, lubricant, flow ability modifying agent and under 3000~5000r/min speed into
Row high-speed stirred 1~3 minute；Then stirring at low speed is carried out under 500~2000r/min speed again 1~3 minute, then 500
~2000r/min speed bottom discharges；
(2) double screw extruder extruding pelletization is used.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109320873A (en) * | 2018-09-17 | 2019-02-12 | 孔庆玲 | A kind of metal effect exempts from the lamps and lanterns plastics and preparation method thereof that paint |
| CN110885568A (en) * | 2018-09-11 | 2020-03-17 | 中山市鸿盛新材料有限公司 | Formula improvement of golden color master batch for food packaging |
| CN112852086A (en) * | 2020-12-31 | 2021-05-28 | 金发科技股份有限公司 | Spraying-free metal-like effect ASA resin for ASA/PVC double-color co-extrusion fabric and preparation method and application thereof |
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Application publication date: 20180417 |