CN107903681A - A kind of glass-film and preparation method thereof - Google Patents
A kind of glass-film and preparation method thereof Download PDFInfo
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- CN107903681A CN107903681A CN201711210062.5A CN201711210062A CN107903681A CN 107903681 A CN107903681 A CN 107903681A CN 201711210062 A CN201711210062 A CN 201711210062A CN 107903681 A CN107903681 A CN 107903681A
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- parts
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- glass
- film
- dodecyl glucoside
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/006—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
- C03C17/008—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character comprising a mixture of materials covered by two or more of the groups C03C17/02, C03C17/06, C03C17/22 and C03C17/28
- C03C17/009—Mixtures of organic and inorganic materials, e.g. ormosils and ormocers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Composite Materials (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention provides a kind of glass-film and preparation method thereof, prepared using the following raw material：5 10 parts by weight of styrenic elastomer, 27 parts by weight of butyl acrylate, 10 20 parts by weight of polypropylene, 100 300 parts by weight of silicate cullet, 15 parts by weight of talcum powder, 4 10 parts by weight of Dodecyl Glucoside, 8 16 parts by weight of allyl butyrate, 26 parts by weight of titanium dioxide, 6 12 parts by weight of Dodecyl Glucoside, 14 parts by weight of medical stone, 29 parts by weight of organic binder bond.Compared with prior art, the present invention is using styrenic elastomer, butyl acrylate, polypropylene, silicate cullet, talcum powder, Dodecyl Glucoside, allyl butyrate, titanium dioxide, Dodecyl Glucoside, medical stone, organic binder bond as raw material, each interaction between component, influence each other, the wearability of the glass-film of preparation is improved, it is with good scraping and wiping resistance performance.
Description
Technical field
The present invention relates to glass technical field of membrane, more particularly to a kind of glass-film and preparation method thereof.
Background technology
Glass-film, refers to a kind of pad pasting in household building materials market, its color is various, energy conservation and environmental protection, is mainly used in dress
Adorn indoor and outdoor glass.This adhering film to glass can not only change the dull transparent image of simple glass, increase aesthetic feeling for indoor and outdoor,
Can be cold with heat-insulated resistance, explosion-proof antidetonation is warming while add security insurance for room.
In the prior art, glass-film and preparation method thereof has obtained extensive report, for example, Application No.
201510886492.3 Chinese patent literature report a kind of glass-film, it is composed of the following components by weight：14 part third
Olefin(e) acid butyl ester, 1-2 parts of propane diols, 0.2 part of calcium phosphate, 1.4 parts of aluminum nitride powders, 1.3 parts of acrylic acid, 3.4 parts of silica, 2.3
Part aluminum phosphate, 4.5 parts of Dodecyl Glucosides.The Chinese patent literature of Application No. 201610978158.5 reports glass-film,
It is prepared from the following raw materials in parts by weight：3-8 parts of isopropanol, 2-6 parts of potassium hydroxide, 6-9 parts of calcium dihydrogen phosphate, quartz sand 3-5
Part, 2-4 parts of ethanol, 7-10 parts of myristyl glucosides, 9-16 parts of styrenic elastomer, 3-6 parts of sodium chloride, 2-5 parts of hydrofluoric acid, hydrogen
6-10 parts of aluminium oxide, 1-4 parts of borax, 5-7 parts of adhesive, 5-10 parts of polylactic acid based resin, 3-6 parts of aliphatic polyester based resin,
1-4 parts of additive, 6-8 parts of solvent.It is cold that the Chinese patent literature of Application No. 201510886490.4 reports a kind of heat-insulated resistance
Glass-film, it is composed of the following components by weight：13 parts of alkyd resins, 1-2 parts of aklylene glycol phenyl ethers, 2.5 parts of alkyl
Sodium sulfonate, 1.4 parts of methyl methacrylates, 1.3 parts of aluminium oxide, 2.4 parts of sodium propionates, 1.3 parts of 4- methyl guaiacol and 4s, 5.6 parts
Antimony oxide.
But the scraping and wiping resistance performance of the glass-film of above-mentioned report is poor.
The content of the invention
Present invention solves the technical problem that being to provide a kind of glass-film and preparation method thereof, there is good scratch resistance
Energy.
In view of this, the present invention provides a kind of glass-film, prepared using the following raw material：Styrenic elastomer 5-10 weight
Part, butyl acrylate 2-7 parts by weight, polypropylene 10-20 parts by weight, silicate cullet 100-300 parts by weight, talcum powder 1-5
Parts by weight, Dodecyl Glucoside 4-10 parts by weight, allyl butyrate 8-16 parts by weight, titanium dioxide 2-6 parts by weight, dodecyl sugar
Glycosides 6-12 parts by weight, medical stone 1-4 parts by weight, organic binder bond 2-9 parts by weight.
Preferably, styrenic elastomer 5-8 parts by weight.
Preferably, butyl acrylate 4-7 parts by weight.
Preferably, polypropylene 10-15 parts by weight.
Preferably, talcum powder 1-3 parts by weight.
Preferably, Dodecyl Glucoside 4-8 parts by weight.
Preferably, allyl butyrate 10-16 parts by weight.
Preferably, titanium dioxide 4-6 parts by weight.
Preferably, medical stone 1-3 parts by weight.
Correspondingly, the present invention also provides a kind of preparation method of glass-film, comprise the following steps：By styrenic elastomer 5-
10 parts by weight, butyl acrylate 2-7 parts by weight, polypropylene 10-20 parts by weight, silicate cullet 100-300 parts by weight, talcum
Powder 1-5 parts by weight, Dodecyl Glucoside 4-10 parts by weight, allyl butyrate 8-16 parts by weight, titanium dioxide 2-6 parts by weight, 12
Alkyl glycosides 6-12 parts by weight, medical stone 1-4 parts by weight and the mixing of organic binder bond 2-9 parts by weight, add at 1030-1160 DEG C
Heat, cooling is dry coated on substrate surface, forms precursor film；The precursor film is peeled off from the substrate, is fired, forms glass
Film.
The present invention provides a kind of glass-film and preparation method thereof, is prepared using the following raw material：Styrenic elastomer 5-10 weights
Measure part, butyl acrylate 2-7 parts by weight, polypropylene 10-20 parts by weight, silicate cullet 100-300 parts by weight, talcum powder 1-
5 parts by weight, Dodecyl Glucoside 4-10 parts by weight, allyl butyrate 8-16 parts by weight, titanium dioxide 2-6 parts by weight, dodecyl
Glucosides 6-12 parts by weight, medical stone 1-4 parts by weight, organic binder bond 2-9 parts by weight.Compared with prior art, the present invention is with benzene
Ethylene elastomer, butyl acrylate, polypropylene, silicate cullet, talcum powder, Dodecyl Glucoside, allyl butyrate, titanium white
Powder, Dodecyl Glucoside, medical stone, organic binder bond are raw material, and each interaction between component, influence each other, and improves preparation
Glass-film wearability, it is with good scraping and wiping resistance performance.
Embodiment
For a further understanding of the present invention, the preferred embodiment of the invention is described with reference to embodiment, still
It should be appreciated that these descriptions are simply further explanation the features and advantages of the present invention, rather than to the claims in the present invention
Limitation.
The embodiment of the invention discloses a kind of glass-film, prepared using the following raw material：Styrenic elastomer 5-10 parts by weight,
Butyl acrylate 2-7 parts by weight, polypropylene 10-20 parts by weight, silicate cullet 100-300 parts by weight, talcum powder 1-5 weight
Part, Dodecyl Glucoside 4-10 parts by weight, allyl butyrate 8-16 parts by weight, titanium dioxide 2-6 parts by weight, Dodecyl Glucoside 6-
12 parts by weight, medical stone 1-4 parts by weight, organic binder bond 2-9 parts by weight.
Preferably, styrenic elastomer 5-8 parts by weight, butyl acrylate 4-7 parts by weight, polypropylene 10-15 weights
Measure part, talcum powder 1-3 parts by weight, Dodecyl Glucoside 4-8 parts by weight, allyl butyrate 10-16 parts by weight, titanium dioxide 4-6 weights
Measure part, medical stone 1-3 parts by weight.
Correspondingly, the present invention also provides a kind of preparation method of glass-film, comprise the following steps：By styrenic elastomer 5-
10 parts by weight, butyl acrylate 2-7 parts by weight, polypropylene 10-20 parts by weight, silicate cullet 100-300 parts by weight, talcum
Powder 1-5 parts by weight, Dodecyl Glucoside 4-10 parts by weight, allyl butyrate 8-16 parts by weight, titanium dioxide 2-6 parts by weight, 12
Alkyl glycosides 6-12 parts by weight, medical stone 1-4 parts by weight and the mixing of organic binder bond 2-9 parts by weight, add at 1030-1160 DEG C
Heat, cooling is dry coated on substrate surface, forms precursor film；The precursor film is peeled off from the substrate, is fired, forms glass
Film.
From above scheme as can be seen that the present invention is with styrenic elastomer, butyl acrylate, polypropylene, the broken glass of silicate
Glass, talcum powder, Dodecyl Glucoside, allyl butyrate, titanium dioxide, Dodecyl Glucoside, medical stone, organic binder bond are original
Material, each interaction between component, influence each other, and improves the wearability of the glass-film of preparation, it is with good scratch resistance
Energy.
For a further understanding of the present invention, technical solution provided by the invention is carried out specifically with reference to embodiment
Bright, protection scope of the present invention is not limited by the following examples.
The raw material that the embodiment of the present invention uses is purchased in market.
Embodiment 1
By 5 parts by weight of styrenic elastomer, 7 parts by weight of butyl acrylate, 10 parts by weight of polypropylene, silicate cullet
300 parts by weight, 1 parts by weight of talcum powder, 10 parts by weight of Dodecyl Glucoside, 8 parts by weight of allyl butyrate, 6 parts by weight of titanium dioxide,
6 parts by weight of Dodecyl Glucoside, 4 parts by weight of medical stone and the mixing of 2 parts by weight of organic binder bond, are heated at 1030-1160 DEG C,
Cooling, it is dry coated on substrate surface, form precursor film；
The precursor film is peeled off from the substrate, is fired, forms glass-film.
Embodiment 2
By 10 parts by weight of styrenic elastomer, 2 parts by weight of butyl acrylate, 20 parts by weight of polypropylene, silicate cullet
100 parts by weight, 5 parts by weight of talcum powder, 4 parts by weight of Dodecyl Glucoside, 16 parts by weight of allyl butyrate, 2 parts by weight of titanium dioxide,
12 parts by weight of Dodecyl Glucoside, 1 parts by weight of medical stone and the mixing of 9 parts by weight of organic binder bond, add at 1030-1160 DEG C
Heat, cooling is dry coated on substrate surface, forms precursor film；
The precursor film is peeled off from the substrate, is fired, forms glass-film.
Embodiment 3
By 6 parts by weight of styrenic elastomer, 5 parts by weight of butyl acrylate, 12 parts by weight of polypropylene, silicate cullet
200 parts by weight, 3 parts by weight of talcum powder, 5 parts by weight of Dodecyl Glucoside, 10 parts by weight of allyl butyrate, 4 parts by weight of titanium dioxide,
10 parts by weight of Dodecyl Glucoside, 3 parts by weight of medical stone and the mixing of 2 parts by weight of organic binder bond, add at 1030-1160 DEG C
Heat, cooling is dry coated on substrate surface, forms precursor film；
The precursor film is peeled off from the substrate, is fired, forms glass-film.
Embodiment 4
By 8 parts by weight of styrenic elastomer, 6 parts by weight of butyl acrylate, 15 parts by weight of polypropylene, silicate cullet
200 parts by weight, 4 parts by weight of talcum powder, 8 parts by weight of Dodecyl Glucoside, 14 parts by weight of allyl butyrate, 3 parts by weight of titanium dioxide,
6 parts by weight of Dodecyl Glucoside, 3 parts by weight of medical stone and the mixing of 5 parts by weight of organic binder bond, are heated at 1030-1160 DEG C,
Cooling, it is dry coated on substrate surface, form precursor film；
The precursor film is peeled off from the substrate, is fired, forms glass-film.
Embodiment 5
By 6 parts by weight of styrenic elastomer, 3 parts by weight of butyl acrylate, 18 parts by weight of polypropylene, silicate cullet
150 parts by weight, 3 parts by weight of talcum powder, 5 parts by weight of Dodecyl Glucoside, 11 parts by weight of allyl butyrate, 5 parts by weight of titanium dioxide,
7 parts by weight of Dodecyl Glucoside, 2 parts by weight of medical stone and the mixing of 3 parts by weight of organic binder bond, are heated at 1030-1160 DEG C,
Cooling, it is dry coated on substrate surface, form precursor film；
The precursor film is peeled off from the substrate, is fired, forms glass-film.
The explanation of above example is only intended to help to understand method and its core concept of the invention.It should be pointed out that pair
For those skilled in the art, without departing from the principle of the present invention, the present invention can also be carried out
Some improvement and modification, these are improved and modification is also fallen into the protection domain of the claims in the present invention.
The foregoing description of the disclosed embodiments, enables professional and technical personnel in the field to realize or use the present invention.
A variety of modifications to these embodiments will be apparent for those skilled in the art, as defined herein
General Principle can be realized in other embodiments without departing from the spirit or scope of the present invention.Therefore, it is of the invention
The embodiments shown herein is not intended to be limited to, and is to fit to and the principles and novel features disclosed herein phase one
The most wide scope caused.
Claims (10)
1. a kind of glass-film, it is characterised in that prepared using the following raw material：
Styrenic elastomer 5-10 parts by weight, butyl acrylate 2-7 parts by weight, polypropylene 10-20 parts by weight, silicate cullet
100-300 parts by weight, talcum powder 1-5 parts by weight, Dodecyl Glucoside 4-10 parts by weight, allyl butyrate 8-16 parts by weight, titanium
White powder 2-6 parts by weight, Dodecyl Glucoside 6-12 parts by weight, medical stone 1-4 parts by weight, organic binder bond 2-9 parts by weight.
2. glass-film according to claim 1, it is characterised in that styrenic elastomer 5-8 parts by weight.
3. glass-film according to claim 1, it is characterised in that butyl acrylate 4-7 parts by weight.
4. glass-film according to claim 1, it is characterised in that polypropylene 10-15 parts by weight.
5. glass-film according to claim 1, it is characterised in that talcum powder 1-3 parts by weight.
6. glass-film according to claim 1, it is characterised in that Dodecyl Glucoside 4-8 parts by weight.
7. glass-film according to claim 1, it is characterised in that allyl butyrate 10-16 parts by weight.
8. glass-film according to claim 1, it is characterised in that titanium dioxide 4-6 parts by weight.
9. glass-film according to claim 1, it is characterised in that medical stone 1-3 parts by weight.
10. a kind of preparation method of glass-film, it is characterised in that comprise the following steps：
By styrenic elastomer 5-10 parts by weight, butyl acrylate 2-7 parts by weight, polypropylene 10-20 parts by weight, the broken glass of silicate
Glass 100-300 parts by weight, talcum powder 1-5 parts by weight, Dodecyl Glucoside 4-10 parts by weight, allyl butyrate 8-16 parts by weight,
Titanium dioxide 2-6 parts by weight, Dodecyl Glucoside 6-12 parts by weight, medical stone 1-4 parts by weight and organic binder bond 2-9 parts by weight are mixed
Close, heated at 1030-1160 DEG C, cooled down, it is dry coated on substrate surface, form precursor film；
The precursor film is peeled off from the substrate, is fired, forms glass-film.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711210062.5A CN107903681A (en) | 2017-11-27 | 2017-11-27 | A kind of glass-film and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711210062.5A CN107903681A (en) | 2017-11-27 | 2017-11-27 | A kind of glass-film and preparation method thereof |
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| Publication Number | Publication Date |
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| CN107903681A true CN107903681A (en) | 2018-04-13 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201711210062.5A Pending CN107903681A (en) | 2017-11-27 | 2017-11-27 | A kind of glass-film and preparation method thereof |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101410337A (en) * | 2006-03-27 | 2009-04-15 | 3M创新有限公司 | Production of self-supporting glass film |
| CN104445999A (en) * | 2014-11-04 | 2015-03-25 | 张桂华 | Heat-insulating heat-preserving glass film |
| CN105331156A (en) * | 2015-12-07 | 2016-02-17 | 常熟市赛蒂镶嵌玻璃制品有限公司 | Glass film |
| CN105907037A (en) * | 2016-06-29 | 2016-08-31 | 明光市富域玻璃有限公司 | Insulated explosion-proof glass film |
-
2017
- 2017-11-27 CN CN201711210062.5A patent/CN107903681A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101410337A (en) * | 2006-03-27 | 2009-04-15 | 3M创新有限公司 | Production of self-supporting glass film |
| CN104445999A (en) * | 2014-11-04 | 2015-03-25 | 张桂华 | Heat-insulating heat-preserving glass film |
| CN105331156A (en) * | 2015-12-07 | 2016-02-17 | 常熟市赛蒂镶嵌玻璃制品有限公司 | Glass film |
| CN105907037A (en) * | 2016-06-29 | 2016-08-31 | 明光市富域玻璃有限公司 | Insulated explosion-proof glass film |
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Application publication date: 20180413 |