CN107903107A - A kind of composite organic-inorganic fertilizer and preparation method thereof - Google Patents

A kind of composite organic-inorganic fertilizer and preparation method thereof Download PDF

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Publication number
CN107903107A
CN107903107A CN201711134920.2A CN201711134920A CN107903107A CN 107903107 A CN107903107 A CN 107903107A CN 201711134920 A CN201711134920 A CN 201711134920A CN 107903107 A CN107903107 A CN 107903107A
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amino acid
raw material
mixture
inorganic fertilizer
composite organic
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刘其海
朱小花
贾振宇
王荣辉
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ZHANJIANG BOTAI BIOCHEMICAL INDUSTRY Co Ltd
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ZHANJIANG BOTAI BIOCHEMICAL INDUSTRY Co Ltd
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Priority to CN201711134920.2A priority Critical patent/CN107903107A/en
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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05CNITROGENOUS FERTILISERS
    • C05C11/00Other nitrogenous fertilisers

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Fertilizers (AREA)

Abstract

The invention discloses a kind of production method of composite organic-inorganic fertilizer, including:Raw material A and raw material B is provided, wherein, raw material A is dewatered sludge, and raw material B is shell;Raw material A and raw material B are mixed, is placed in calcining kiln and is calcined, obtains mixture C;Mixture C is crushed and is sieved;Amino acid and polysaccharide are added into mixture C, and is mixed.The present invention makes composite organic-inorganic fertilizer using dewatered sludge and shell as raw material, and dewatered sludge and shell are carried out recycling treatment, not only environmentally friendly, but also can increase economic efficiency.

Description

A kind of composite organic-inorganic fertilizer and preparation method thereof
Technical field
The present invention relates to chemical industry technical field of fertilizers, more particularly to a kind of composite organic-inorganic fertilizer and preparation method thereof.
Background technology
According to statistics, the dewatered sludge that national urban wastewater treatment firm produces every year is up to more than one hundred million tons, since dewatered sludge contains A certain amount of heavy metal, therefore dewatered sludge needs just be filled after stablizing harmless treatment.Managed to mitigate Cost, the method that many sewage treatment plants always search for recycling sludge processing and disposal.
Marine product discarded object of the oyster shell as southern coastal cities, on farm periphery, pile up like a mountain, only Zhanjiang The discarded oyster shell produced every year is just up to millions of tons, but there has been no good processing method at present.
The content of the invention
The technical problems to be solved by the invention are, there is provided a kind of composite organic-inorganic fertilizer and preparation method thereof, uses Dewatered sludge and oyster shell make a kind of composite organic-inorganic fertilizer as raw material, and dewatered sludge and oyster shell are provided Sourceization processing, it is not only environmentally friendly, but also can increase economic efficiency.
In order to solve the above technical problem, the present invention provides a kind of production method of composite organic-inorganic fertilizer, including:
Raw material A and raw material B is provided, wherein, raw material A is dewatered sludge, and raw material B is shell;
Raw material A and raw material B are mixed, is placed in calcining kiln and is calcined, obtains mixture C;
Mixture C is crushed and is sieved;
Amino acid and polysaccharide are added into mixture C, and is mixed.
As the improvement of such scheme, the shell is oyster shell or conch shell.
As the improvement of such scheme, the proportioning of the raw material A and raw material B are 1:1-30:1 (wt%).
As the improvement of such scheme, calcining heat is 200-500 degree, when calcination time is 5-9 small.
As the improvement of such scheme, the amino acid is shrimp protein hydrolysis amino acid.
As the improvement of such scheme, the shrimp protein hydrolysis amino acid is to be hydrolyzed made of prawn processing fent Amino acid, made of discarded shrimp head hydrolysis amino acid, made of disease dead shrimp hydrolysis amino acid, be made of poultry animal Protein hydrolytic amino acid in one or more.
As the improvement of such scheme, the polysaccharide for amino acid-glucose hydrochloride, amino acid-glucose acetate, Amino acid-glucose sulfate, amino acid-glucose nitrate, amino acid-glucose phosphate, one kind in chitosan oligosaccharide or several Kind.
As the improvement of such scheme, the molecular weight of the chitosan oligosaccharide is 200-5000Da, and the chitosan oligosaccharide is chitosan oligosaccharide One or more in hydrochloride, chitosan oligosaccharide acetate, chitosan oligosaccharide sulphate.
As the improvement of such scheme, the addition of the amino acid is the 2-15% of the weight of the mixture C, institute The addition for stating polysaccharide is the 0.1-3% of the weight of the mixture C.
Correspondingly, present invention also offers a kind of composite organic-inorganic fertilizer, by any of the above-described organo-mineral complexing The production method of fertilizer is made.
Implement the present invention, have the advantages that:
1st, the present invention provides a kind of production method of composite organic-inorganic fertilizer, including:Raw material A and raw material are provided B, wherein, raw material A is dewatered sludge, and raw material B is shell;Raw material A and raw material B are mixed, are placed on calcining Calcined in kiln, obtain mixture C;Mixture C is crushed and is sieved;Amino acid and more is added into mixture C Sugar, and mixed.The present invention makes composite organic-inorganic fertilizer using dewatered sludge and shell as raw material, will Dewatered sludge and shell carry out recycling treatment, not only environmentally friendly, but also can increase economic efficiency.
2nd, the present invention provides a kind of production method of composite organic-inorganic fertilizer, the dewatered sludge and oyster shell to forge The mixture C formed after burning can not only provide the inorganic nutritive element for plant, can be with absorption carrier by plant growth The amino acid and polysaccharide needed is adsorbed in mixture C, when by the composite organic-inorganic fertilizer use of the present invention in soil, institute Stating mixture C can be slowly released into amino acid and polysaccharide in soil, prevent that amino acid and polysaccharide are rapidly losing, cause wave Take.
3rd, the present invention provides a kind of production method of composite organic-inorganic fertilizer, the amino acid is as organic composition The inside of the mixture C is attached to, in use, the amino acid is slowly discharged into soil from the inside of the mixture C In.Due to the characteristic of amino acid in itself, there is unique facilitation to plant growth particularly photosynthesis, it can increase Add chlorophyll content of plant, improve the activity of enzyme, promote the infiltration of carbon dioxide, make photosynthesis more vigorous, make to improving The content of article matter, increase Vc and sugar suffers from important function.In addition, amino acid can also play the role of complexing agent, with N, P, chelatropic reaction occurs for the trace element such as a great number of elements such as K and Ga, Mg, Na, Zn, Fe, Cu, Mn, B, Mo, to first needed for plant Element produces protective effect, and generates the chelate that solubility is good, is easily absorbed by plants, so as to be conducive to plant absorption.
4th, the present invention provides a kind of production method of composite organic-inorganic fertilizer, the polysaccharide are attached as organic composition In the inside of the mixture C, in use, the amino acid is slowly discharged into soil from the inside of the mixture C In.Due to the characteristic of polysaccharide in itself, polysaccharide can help plant absorption nutrition as the bio signal of plant.Due to described more Sugar is attached in the mixture C, therefore polysaccharide ability promotes the nutrient in plant absorption mixture C.
Embodiment
To make the object, technical solutions and advantages of the present invention clearer, present invention work is further retouched in detail below State.
A kind of production method of composite organic-inorganic fertilizer provided by the invention, including:
Raw material A and raw material B is provided, wherein, raw material A is dewatered sludge, and raw material B is shell;
Raw material A and raw material B are mixed, is placed in calcining kiln and is calcined, obtains mixture C;
Mixture C is crushed and is sieved;
Amino acid and polysaccharide are added into mixture C, and is mixed.
The present invention using dewatered sludge and shell makes composite organic-inorganic fertilizer as raw material, by dewatered sludge and Oyster shell carries out recycling treatment, not only environmentally friendly, but also can increase economic efficiency.Wherein, the dewatered sludge and shell be after firing The mixture C of formation can not only provide the inorganic nutritive element for plant, can be needed plant growth with absorption carrier Amino acid and polysaccharide adsorb in mixture C, when by the present invention composite organic-inorganic fertilizer use in soil when, it is described mix Amino acid and polysaccharide can be slowly released into soil by compound C, prevented that amino acid and polysaccharide are rapidly losing, caused to waste.
It should be noted that the dewatered sludge is the dewatered sludge of domestic sewage factory, the moisture content of the dewatered sludge For 60-80%.The shell is oyster shell or conch shell.Wherein, it is described containing elements such as substantial amounts of N, P, K in dewatered sludge Oyster shell or conch shell contain the elements such as substantial amounts of Ga, Mg, Na, Zn, Fe, Cu, Mn, B, Mo, and above-mentioned element is all plant growth Required nutrient.In the other embodiment of the application, the dewatered sludge can also be that the dehydration of other sewage plants is dirty Mud, the shell can also be other seashells, such as scallop can, blue or green mouth shell, white shell.
Specifically, the proportioning of the raw material A and raw material B is 1:1—30:1 (wt%).Preferably, the raw material The proportioning of A and raw material B are 3:1—10:1 (wt%).In calcining, calcining heat is by the raw material A and raw material B 200-600 degree, when calcination time is 4-12 small.Preferably, calcining heat is 250-500 degree, when calcination time is 5-9 small.Its In, the proportioning of the raw material A and raw material B are more than 30:When 1, the dosage of oyster shell is very few, and sludge dosage is higher, during calcining Between it is longer, obtained mixture C adsorption capacity is relatively low after firing, and the element such as N, P, K contained in mixture C is excessive.It is described The proportioning of raw material A and raw material B are less than 1:When 1, the dosage of oyster shell is excessive, and sludge dosage is relatively low, and calcining heat is higher, Obtained mixture C adsorption capacity is relatively low after firing, Ga, Mg, Na, Zn, Fe, Cu, Mn, B, Mo contained in mixture C etc. Element is excessive.When calcining heat is less than 200 degree, raw material A and raw material the B reaction is insufficient, it is impossible to forms mixture C;When calcining heat is more than 600 degree, temperature is excessive, destroys the internal structure of the mixture C, reduces the suction of mixture Attached ability.When being less than 4 hours between upon calcination, raw material A and raw material the B reaction is insufficient, it is impossible to forms mixture C; When being more than 12 hours between upon calcination, the reaction time is long, destroys the internal structure of the mixture C, reduces mixture Adsorption capacity, and waste of energy.
It is adsorbed onto for the ease of the amino acid and polysaccharide in mixture C, the mesh number of the mixture C sieving is 5-20 Mesh.When the mixture C sieving mesh number be less than 5 mesh when, the particle diameter of mixture C is excessive, be unfavorable for adsorb amino acid with it is more Sugar.When the mesh number of mixture C sieving is more than 20 mesh, the particle diameter of mixture C is too small, easily molten when being applied to soil Solution is lost in.
The amino acid is shrimp protein hydrolysis amino acid.Specifically, in order to reduce cost, make a silk purse out of a sow's ear, the shrimp protein Hydrolysis amino acid be made of the prawn processing fent hydrolysis amino acid, made of discarded shrimp head hydrolysis amino acid, by disease Kill hydrolysis amino acid made of shrimp, by the one or more in protein hydrolytic amino acid made of poultry animal.In the application Other embodiment in, the amino acid can also be the mixture of shrimp protein hydrolysis amino acid and amino acid yeast waste liquor.
The amino acid is attached to the inside of the mixture C as organic composition, in use, the amino acid delays Slowly it is discharged into from the inside of the mixture C in soil.Due to the characteristic of amino acid in itself, to plant growth particularly light Cooperation is used with unique facilitation, it can increase chlorophyll content of plant, improves the activity of enzyme, promotes carbon dioxide Infiltration, make photosynthesis more vigorous, to improve crop quality, increase Vc and sugar content suffer from important function.This Outside, amino acid can also play the role of complexing agent, with a great number of elements and Ga, Mg, Na, Zn, Fe, Cu, Mn, B, the Mo such as N, P, K Chelatropic reaction occurs Deng trace element, protective effect is produced to element needed for plant, and generate that solubility is good, is easily inhaled by plant The chelate of receipts, so as to be conducive to plant absorption.
The polysaccharide for amino acid-glucose hydrochloride, amino acid-glucose acetate, amino acid-glucose sulfate, One or more in amino acid-glucose nitrate, amino acid-glucose phosphate, chitosan oligosaccharide.
The molecular weight of the chitosan oligosaccharide is 200-5000Da.More preferably, the chitosan oligosaccharide is chitosan oligosaccharide hydrochloride, shell widow One or more in acetate, chitosan oligosaccharide sulphate.
The polysaccharide is attached to the inside of the mixture C as organic composition, in use, the amino slow acid Ground is discharged into soil from the inside of the mixture C.Due to the characteristic of polysaccharide in itself, polysaccharide can be as the biology of plant Signal, helps plant absorption nutrition.Since the polysaccharide is attached in the mixture C, polysaccharide ability promotes plant to inhale Receive the nutrient in mixture C.
Specifically, 2-15% of the addition of the amino acid for the weight of the mixture C, the addition of the polysaccharide Measure the 0.1-3% of the weight for the mixture C.More, the addition of the amino acid is the weight of the mixture C 4-8%, the addition of the polysaccharide for the weight of the mixture C 0.1-0.5%.When the addition of the amino acid Less than the 2% of the weight of the mixture C, when the addition of the polysaccharide is less than the 0.1% of the weight of the mixture C, institute Effective synergistic effect cannot be played with the mixture C by stating amino acid and polysaccharide, the ammonia being adsorbed in the mixture C Base acid and polysaccharide cannot promote absorption of the plant to effective nutrient;In addition, described in being less than when the addition of the amino acid The 2% of the weight of mixture C, when the addition of the polysaccharide is less than the 0.1% of the weight of the mixture C, the amino acid It can not meet the growth needs of plant with polysaccharide.When the addition of the amino acid is more than the weight of the mixture C 15%, when the addition of the polysaccharide is more than the 2% of the weight of the mixture C, the amino acid and polysaccharide cannot be with institutes State mixture C and play effective synergistic effect, the amino acid and polysaccharide being adsorbed in the mixture C influence plant to having Imitate the absorption of nutrient;In addition, when 15% of the addition of the amino acid more than the weight of the mixture C, it is described more When the addition of sugar is more than the 2% of the weight of the mixture C, excess of ammonia base acid and polysaccharide can not be absorbed by plants, so that Cause to waste, excess of ammonia base acid and polysaccharide are lost to rivers, be easy to cause the eutrophication of water body.
With specific embodiment, the present invention is further explained below
Embodiment 1
A kind of production method of composite organic-inorganic fertilizer, including:
100g raw material A and 4g raw material B are provided, wherein, raw material A is dewatered sludge, and raw material B is oyster shell;
Raw material A and raw material B are mixed, is placed in calcining kiln and is calcined, obtains mixture C, wherein, Calcining heat is 200 degree, when calcination time is 9 small;
Mixture C is crushed and is sieved, the mesh number of the mixture C sieving is 5 mesh;
3g amino acid and 0.2g polysaccharide are added into mixture C, and is mixed, wherein, the amino acid is shrimp Protein hydrolytic amino acid, the polysaccharide are amino acid-glucose hydrochloride.
Embodiment 2
A kind of production method of composite organic-inorganic fertilizer, including:
100g raw material A and 5g raw material B are provided, wherein, raw material A is dewatered sludge, and raw material B is shell;
Raw material A and raw material B are mixed, is placed in calcining kiln and is calcined, obtains mixture C, wherein, Calcining heat is 350 degree, when calcination time is 8 small;
Mixture C is crushed and is sieved, the mesh number of the mixture C sieving is 10 mesh;
5g amino acid and 0.5g polysaccharide are added into mixture C, and is mixed, wherein, the amino acid is shrimp Protein hydrolytic amino acid, the amino acid-glucose acetate and amino acid-glucose sulfate.
Embodiment 3
A kind of production method of composite organic-inorganic fertilizer, including:
100g raw material A and 7g raw material B are provided, wherein, raw material A is dewatered sludge, and raw material B is shell;
Raw material A and raw material B are mixed, is placed in calcining kiln and is calcined, obtains mixture C, wherein, Calcining heat is 400 degree, when calcination time is 7 small;
Mixture C is crushed and is sieved, the mesh number of the mixture C sieving is 15 mesh;
8g amino acid and 1g polysaccharide are added into mixture C, and is mixed, wherein, the amino acid is shrimp egg White hydrolysis amino acid, the polysaccharide is amino acid-glucose hydrochloride, amino acid-glucose acetate, amino acid-glucose sulphur Hydrochlorate, amino acid-glucose nitrate and amino acid-glucose phosphate.
Embodiment 4
A kind of production method of composite organic-inorganic fertilizer, including:
100g raw material A and 10g raw material B are provided, wherein, raw material A is dewatered sludge, and raw material B is shell;
Raw material A and raw material B are mixed, is placed in calcining kiln and is calcined, obtains mixture C, wherein, Calcining heat is 450 degree, when calcination time is 6 small;
Mixture C is crushed and is sieved, the mesh number of the mixture C sieving is 15 mesh;
11g amino acid and 1.6g polysaccharide are added into mixture C, and is mixed, wherein, the amino acid is Shrimp protein hydrolysis amino acid, the polysaccharide are chitosan oligosaccharide, and the molecular weight of the chitosan oligosaccharide is 500Da, and the chitosan oligosaccharide is few for shell One or more in sugared hydrochloride, chitosan oligosaccharide acetate, chitosan oligosaccharide sulphate.
Embodiment 5
A kind of production method of composite organic-inorganic fertilizer, including:
100g raw material A and 12g raw material B are provided, wherein, raw material A is dewatered sludge, and raw material B is shell;
Raw material A and raw material B are mixed, is placed in calcining kiln and is calcined, obtains mixture C, wherein, Calcining heat is 500 degree, when calcination time is 5 small;
Mixture C is crushed and is sieved, the mesh number of the mixture C sieving is 20 mesh;
12g amino acid and 2g polysaccharide are added into mixture C, and is mixed, wherein, the amino acid is shrimp Protein hydrolytic amino acid and amino acid yeast waste liquor, the polysaccharide are chitosan oligosaccharide, and the molecular weight of the chitosan oligosaccharide is 2000Da, The chitosan oligosaccharide is chitosan oligosaccharide hydrochloride, the one or more in chitosan oligosaccharide acetate, chitosan oligosaccharide sulphate.
Embodiment 6
A kind of production method of composite organic-inorganic fertilizer, including:
100g raw material A and 20g raw material B are provided, wherein, raw material A is dewatered sludge, and raw material B is shell;
Raw material A and raw material B are mixed, is placed in calcining kiln and is calcined, obtains mixture C, wherein, Calcining heat is 400 degree, when calcination time is 6 small;
Mixture C is crushed and is sieved, the mesh number of the mixture C sieving is 20 mesh;
15g amino acid and 2.5g polysaccharide are added into mixture C, and is mixed, wherein, the amino acid is Shrimp protein hydrolysis amino acid and amino acid yeast waste liquor, the polysaccharide are chitosan oligosaccharide, and the molecular weight of the chitosan oligosaccharide is 3000Da, the chitosan oligosaccharide is chitosan oligosaccharide hydrochloride, the one or more in chitosan oligosaccharide acetate, chitosan oligosaccharide sulphate.
Embodiment 7
A kind of production method of composite organic-inorganic fertilizer, including:
100g raw material A and 30g raw material B are provided, wherein, raw material A is dewatered sludge, and raw material B is shell;
Raw material A and raw material B are mixed, is placed in calcining kiln and is calcined, obtains mixture C, wherein, Calcining heat is 400 degree, when calcination time is 5 small;
Mixture C is crushed and is sieved, the mesh number of the mixture C sieving is 20 mesh;
15g amino acid and 3g polysaccharide are added into mixture C, and is mixed, wherein, the amino acid is shrimp Protein hydrolytic amino acid and amino acid yeast waste liquor, the polysaccharide are chitosan oligosaccharide, and the molecular weight of the chitosan oligosaccharide is 4000Da, The chitosan oligosaccharide is chitosan oligosaccharide hydrochloride, the one or more in chitosan oligosaccharide acetate, chitosan oligosaccharide sulphate.
Composite organic-inorganic fertilizer is fabricated to according to the method for above-described embodiment 1-7, and to the main of composite organic-inorganic fertilizer Component is tested, as a result as follows:
Table 1 is that the method for embodiment 1-7 is fabricated to the main component (unit wt%) of composite organic-inorganic fertilizer
The using effect that the present invention is further explained is come with specifically used embodiment below
Use embodiment 1
Zhanyi, Yunnan great Po Ma streets 50 mu of model fields of son, after total crop failure in continuous 3 years, organic nothing using the present invention in 2016 Machine composite fertilizer, it is specific as follows:
Treatment group is:Apply 60Kg/ mus of composite organic-inorganic fertilizer in the present embodiment 4;
Control group is:Apply special complex fertilizer (N:P2O5:KO2=15:5:25) 30kg/ mus;
Wherein, treatment group and control group field management and watering it is consistent.
With control group, 2 times are improved using the composite organic-inorganic fertilizer yield of tobacco of the present invention, quality of tobacco reaches international High Quality Tobacco is horizontal, and tobacco leaf chlorinity reduces 7-9 times.
Use embodiment 2
Guangdong Yangjiang and Huizhou progress wet rice cultivation Applied D emonstration, composite organic-inorganic fertilizer using the present invention, specifically such as Under:
Treatment group is:Apply 60Kg/ mus of composite organic-inorganic fertilizer in the present embodiment 4;
Control group is:Apply special complex fertilizer (N:P2O5:KO2=15:5:25) 30kg/ mus;
Wherein, treatment group and control group field management and watering it is consistent.
Compared with the control group, 8-10% is improved using the composite organic-inorganic fertilizer rice average product of the present invention.
Use embodiment 3
It is specific as follows in the maritime progress grape Applied D emonstration in Yunnan, composite organic-inorganic fertilizer using the present invention:
Treatment group is:Using the composite organic-inorganic fertilizer of the present invention during wine-growing, amount of application is 2kg/ plants;
Treatment group is:Apply 2kg/ plants of composite organic-inorganic fertilizer in the present embodiment 4;
Control group is:Apply special complex fertilizer (N:P2O5:KO2=15:5:25) 2kg/ plants;
Wherein, treatment group and control group field management and watering it is consistent.
As a result such as following table:
Table 2 is grape fruit exterior quality test result
As can be seen from Table 2, using treatment group spike weight, regularity and the degree of packing of composite organic-inorganic fertilizer of the present invention Control group is above, single fringe weightening 7.6%, regularity is slightly above control group, and treatment group fruit size is more uniform, the degree of packing Also slightly it is better than control group.But fruit shape index is suitable with control group, the composite organic-inorganic fertilizer using the present invention can generally increase fruit It is real, but do not change fruit shapes.
As can be seen from Table 3, using composite organic-inorganic fertilizer of the present invention treatment group total reducing sugar, titration total acid and sugar Sour ratio is above control group, and wherein treatment group increases respectively than the soluble solid, total Soluble Sugar, sugar-acid ratio of control group Relative percentages 8.3%, 19.15% and 17.86%, can be significantly using composite organic-inorganic fertilizer of the present invention compared with control group Improve soluble solid, total Soluble Sugar and the sugar-acid ratio of grape berry.
Table 3 is grape interior quality test structure
Above disclosed be only a kind of preferred embodiment of the present invention, cannot limit the present invention's with this certainly Interest field, therefore equivalent variations made according to the claims of the present invention, are still within the scope of the present invention.

Claims (10)

1. a kind of production method of composite organic-inorganic fertilizer, including:
Raw material A and raw material B is provided, wherein, raw material A is dewatered sludge, and raw material B is shell;
Raw material A and raw material B are mixed, is placed in calcining kiln and is calcined, obtains mixture C;
Mixture C is crushed and is sieved;
Amino acid and polysaccharide are added into mixture C, and is mixed.
2. the production method of composite organic-inorganic fertilizer according to claim 1, it is characterised in that the shell is oyster shell Or conch shell.
3. the production method of composite organic-inorganic fertilizer according to claim 2, it is characterised in that the raw material A and original The proportioning of material B is 1:1—30:1 (wt%).
4. the production method of composite organic-inorganic fertilizer according to claim 3, it is characterised in that calcining heat 200- 500 degree, when calcination time is 5-9 small.
5. the production method of composite organic-inorganic fertilizer according to claim 1, it is characterised in that the amino acid is shrimp egg White hydrolysis amino acid.
6. the production method of composite organic-inorganic fertilizer according to claim 5, it is characterised in that the shrimp protein hydrolyzes ammonia Base acid be made of the prawn processing fent hydrolysis amino acid, made of discarded shrimp head hydrolysis amino acid, by disease dead shrimp Manufactured hydrolysis amino acid, by the one or more in protein hydrolytic amino acid made of poultry animal.
7. the production method of composite organic-inorganic fertilizer according to claim 1, it is characterised in that the polysaccharide is amino acid Glucosamine salt hydrochlorate, amino acid-glucose acetate, amino acid-glucose sulfate, amino acid-glucose nitrate, amino acid One or more in glucose phosphate salt, chitosan oligosaccharide.
8. the production method of composite organic-inorganic fertilizer according to claim 7, it is characterised in that the molecule of the chitosan oligosaccharide It is chitosan oligosaccharide hydrochloride, chitosan oligosaccharide acetate, one kind in chitosan oligosaccharide sulphate or several to measure as 200-5000Da, the chitosan oligosaccharide Kind.
9. the production method of composite organic-inorganic fertilizer according to claim 1, it is characterised in that the addition of the amino acid The 2-15% of the weight for the mixture C is measured, the addition of the polysaccharide is the 0.1-3% of the weight of the mixture C.
A kind of 10. composite organic-inorganic fertilizer, by the production method system of any composite organic-inorganic fertilizer in claim 1-9 Form.
CN201711134920.2A 2017-11-16 2017-11-16 A kind of composite organic-inorganic fertilizer and preparation method thereof Pending CN107903107A (en)

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CN105831430A (en) * 2016-03-29 2016-08-10 湛江市博泰生物化工科技实业有限公司 Marine polysaccharide composition for earthworm ecological management or culture and preparation method thereof
CN106076241A (en) * 2016-06-06 2016-11-09 东南大学 A kind of waterworks sludge is utilized to remove the method for dyestuff in water
CN106350073A (en) * 2016-08-08 2017-01-25 湛江市博泰生物化工科技实业有限公司 Soil conditioner based on oyster shell powder and marine polysaccharides and preparation method thereof
CN106905076A (en) * 2017-03-14 2017-06-30 广西壮族自治区农业科学院农业资源与环境研究所 A kind of selenium-enriched high-calcium organic fertilizer and preparation method and application
CN107162727A (en) * 2017-05-25 2017-09-15 江苏沃纳生物科技有限公司 The preparation of one planting fruit-trees special bacteria agent and application process

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