CN107890254A - A kind of super print through flower crystal spills gold stand cloth and its double attaching process - Google Patents
A kind of super print through flower crystal spills gold stand cloth and its double attaching process Download PDFInfo
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- CN107890254A CN107890254A CN201710992574.5A CN201710992574A CN107890254A CN 107890254 A CN107890254 A CN 107890254A CN 201710992574 A CN201710992574 A CN 201710992574A CN 107890254 A CN107890254 A CN 107890254A
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- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47G—HOUSEHOLD OR TABLE EQUIPMENT
- A47G11/00—Table linen
- A47G11/003—Table-cloths
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M3/00—Printing processes to produce particular kinds of printed work, e.g. patterns
- B41M3/06—Veined printings; Fluorescent printings; Stereoscopic images; Imitated patterns, e.g. tissues, textiles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/025—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet
- B41M5/035—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet by sublimation or volatilisation of pre-printed design, e.g. sublistatic
- B41M5/0358—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet by sublimation or volatilisation of pre-printed design, e.g. sublistatic characterised by the mechanisms or artifacts to obtain the transfer, e.g. the heating means, the pressure means or the transport means
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M2205/00—Printing methods or features related to printing methods; Location or type of the layers
- B41M2205/02—Dye diffusion thermal transfer printing (D2T2)
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- General Health & Medical Sciences (AREA)
- Textile Engineering (AREA)
- Vascular Medicine (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Artificial Filaments (AREA)
Abstract
The present invention relates to tablecloth technical field, and in particular to a kind of super print through flower crystal spills gold stand cloth and its double attaching process, and the super print through flower crystal, which spills gold stand cloth, includes the raw material of following parts by weight：50 65 parts of polyvinyl chloride resin, 23 parts of heat stabilizer, 0.01 0.16 parts of the powder that adds lustre to, 0.01 0.15 parts of titanium dioxide, 50 60 parts of DOTP, 34 parts of fire retardant, 0.15 0.70 parts of other auxiliary agents.The super print through flower crystal of the present invention spills gold stand cloth environmentally-friendly transparent, the feel with preferable three-dimensional stereo effect and soft comfortable；And good flame retardation effect, also there is good chemical stability, insulation, acid-fast alkali-proof, waterproof and dampproof, anticorrosion, stretching resistance, anti-aging and antistatic, excellent combination property.
Description
Technical field
The present invention relates to tablecloth technical field, and in particular to a kind of super print through flower crystal spills gold stand cloth and its double applying closes work
Skill.
Background technology
With the development of society, the raising of human living standard and the constantly pursuit to material, are currently used for household day
It is attractive in appearance with arts also more and more convenient fashion.The transparent attractive in appearance, soft texture of soft PVC sheet material, has been widely used for
Some home decorations of everyday articles field, such as tablecloth, mat applying and table mat, ground cushion.This based article is usually in printed patterns
Another side enclose hyaline membrane, when being covered in furniture especially on glass furniture, can both show the printing figure on hyaline membrane
Case, the pattern that hyaline membrane observes furniture can be passed through again, plays good decorative effect.But existing pattern is all generally flat
Face pattern, appreciative value are smaller；And existing sheet material mechanical and physical performance is poor.
The content of the invention
In order to overcome shortcoming and defect present in prior art, it is an object of the invention to provide a kind of super print through flower water
Crystalline substance spills gold stand cloth, and super print through flower crystal spills gold stand cloth environmentally-friendly transparent, has preferable three-dimensional stereo effect and soft comfortable
Feel；And good flame retardation effect, also with good chemical stability, insulation, acid-fast alkali-proof, waterproof and dampproof, anticorrosion, tension
The advantages that power, anti-aging and antistatic, excellent combination property.
Double attaching process of gold stand cloth are spilt another object of the present invention is to provide a kind of super print through flower crystal, the double applying closes
Processing step is simple, convenient operation and control, steady quality, and production efficiency is high, and production cost is low, can large-scale industrial production.
The purpose of the present invention is achieved through the following technical solutions：A kind of super print through flower crystal spills gold stand cloth, the super print through
Flower crystal, which spills gold stand cloth, includes the raw material of following parts by weight：
The present invention strictly controls the weight proportion of each raw material by using above-mentioned raw materials, obtained super print through flower crystal
Gold stand cloth environmentally-friendly transparent is spilt, the feel with preferable three-dimensional stereo effect and soft comfortable；And good flame retardation effect, also have very
It is the advantages that chemical stability well, insulation, acid-fast alkali-proof, waterproof and dampproof, anticorrosion, stretching resistance, anti-aging and antistatic, comprehensive
Excellent performance.
Preferably, the polyvinyl chloride resin is ethylene process polyvinyl chloride resin of the average degree of polymerization in 1000-2000.
The present invention by using average degree of polymerization 1000-2000 ethylene process polyvinyl chloride resin so that material plasticizing rate
It hurry up, be easily worked.
Preferably, the heat stabilizer is with weight ratio 1 by calcium stearate, barium stearate, zinc stearate and hydrotalcite:
0.8-1.2:0.8-1.2：The mixture of 0.4-0.8 compositions.
The present invention by using calcium stearate, barium stearate, zinc stearate as main body heat stabilizer, using neatly masonry
For auxiliary heat stabilizer, main body heat stabilizer and auxiliary heat stabilizer compounding use, make material good heat stability, have efficient
Weatherability, material can also be made to have good dispersiveness, compatibility and processing fluidity in process.
Preferably, the powder that adds lustre to is to compare 0.5-1.5 by Tissuemat E and microcrystalline wax with weight:The mixture of 1 composition.
The present invention, as powder compounding use of adding lustre to, and controls its weight ratio to be by using Tissuemat E and microcrystalline wax
0.5-1.5:1, the gloss of the tablecloth can be strengthened.
Preferably, the titanium dioxide surface treated, its preparation method are：By rutile type titanium white in 100-120 DEG C
Lower high-speed stirred 15-25min removes the moisture content absorbed, is then added in the styrene and silicon oil solution for being mixed with initiator, continues
Cooling is completed to prepare after mixing 8-12min；The rutile type titanium white, styrene, dimethicone, dicetyl peroxydicarbonate two
The weight ratio of isopropyl ester is 100：0.4-0.8：1.2-1.6：0.04-0.08.
The titanium dioxide of the present invention strictly controls the weight proportion of each raw material by using above-mentioned processing, obtained titanium white
Powder has superior whiteness, tinting strength, tinting power, covering power, weatherability, heat resistance and chemical stability, particularly no toxicity.
Preferably, the fire retardant is with weight ratio 1 by brominated Polystyrene, melamine phosphate and aluminium hydroxide:
0.8-1.2:1.4-2.2 the mixture of composition.
The present invention makes by using brominated Polystyrene, melamine phosphate and aluminium hydroxide as fire retardant compounding
With, and it is 1 to control its weight ratio:0.8-1.2:1.4-2.2, its fire-retardant and flameproof effect is good, and smoke suppressing effect is good.
Preferably, other auxiliary agents are to compare 0.8-1.2 by UV resistant agent and antioxidant with weight：The mixing of 1 composition
Thing；The UV resistant agent is by 4- benzoyloxys -2,2,6,6- tetramethyl piperidines, 2- hydroxyl -4- n-octyloxy hexichol first
Ketone and 2,4,6- tri- (2 ' n-butoxyphenyl) -1,3,5- triazines compare 1.5-2.5 with weight:0.5-1.5:The mixture of 1 composition.
Species, compounding and proportioning of the invention by strictly controlling UV resistant agent, ultraviolet can be absorbed strongly, and compound
There is excellent cooperative effect during use.
The antioxidant be by four [methylene -3,5- (di-t-butyl -4- hydroxy-phenies) propionic ester] pentaerythritol esters,
Three [2,4- di-tert-butyl-phenyls] phosphite esters and β-positive octadecanol ester of (3,5- di-tert-butyl-hydroxy phenyls) propionic acid are with weight
Measure ratio 1:0.2-0.6:The mixture of 0.4-0.8 compositions.
Species, compounding and proportioning of the invention by strictly controlling antioxidant, it can delay or suppress material oxidation process
Progress, so as to prevent the aging of material and extend its service life.
Preferably, the super print through flower crystal, which spills gold stand cloth, also includes aliphatic polyketone 15-35 parts, polyester staple fiber 5-15
Part and modified POE resin 4-8 parts.
The present invention can form alloy material by adding aliphatic polyketone with PVC, can improve super print through flower crystal and spill
The intensity and shock resistance of gold stand cloth, also with excellent wearability, chemical resistance, fuel resistance and hydrolytic resistance.
The present invention can significantly inhibit the mechanical property caused by a large amount of inorganic matters add and drop by adding polyester staple fiber
It is poorly efficient to answer, it can also improve the heat-resisting quantity of material.
The modified POE resin is polypropylene/ethylene-octene copolymer that polypropylene and POE resin blending and modifying obtain；
The ethylene-octene copolymer is ethylene-octene copolymer of the octene monomers content in 20%-30%.
Polypropylene/ethylene-octene copolymer conduct that the present invention obtains by using polypropylene and POE resin blending and modifying
Modified POE resin, the normal temperature and low-temperature impact toughness of material can be significantly improved.The present invention exists by using octene monomers content
20%-30% ethylene-octene copolymer, can significantly improve the impact strength and heat resistance of material, and tensile strength, tear
The Main Mechanicals such as resistance to spalling all have significant improvement.
The polypropylene is that have COPP and HOPP to compare 1.4-2.2 with weight：The mixture of 1 composition；Institute
It is COPP of the melt index in 10-50g/10min to state COPP；The HOPP is that melt index exists
60-100g/10min HOPP.
The present invention by using melt index 10-50g/10min COPP and melt index in 60-100g/
10min HOPP is as polypropylene compounding use, and it is 1.4-2.2 to control its weight ratio：1, material can be significantly improved
Impact strength and heat distortion temperature.
Preferably, the super print through flower crystal spill gold stand cloth also include cold-resistant toughened dose of 2-6 part, intensity modifier 1-5 parts,
Compatilizer 1-3 parts, slipping agent 0.5-1.5 parts.
Described cold-resistant toughened dose is with weight ratio 1 by amide-type beta crystal-type nucleater and dicarboxylic acids salt beta crystal-type nucleater：
1.2-1.8 the mixture of composition.
The present invention is by using amide-type beta crystal-type nucleater and dicarboxylic acids salt beta crystal-type nucleater as cold-resistant toughened dose
Compounding use, and it is 1 to control its weight ratio：1.2-1.8 so that material toughening effect in -20 DEG C of low temperature is obvious, more than normal temperature
When impact strength, while rigidly significantly improved under normal temperature.
The intensity modifier is in the magnesium salts of 4-8 μm of basalt fibre and filament diameter at 6-10 μm by filament diameter
Whisker compares 1.6-2.4 with weight:The mixture of 1 composition.
Basalt fibre is basalt building stones after 1450 DEG C~1500 DEG C meltings, and it is high to pass through platinum-rhodium alloy bushing
Speed draws the continuous fiber formed.Similar to glass fibre, its performance is between high intensity S glass fibres and alkali-free E glass fibres
Between, not only stability is good for basalt continuous fiber, but also a variety of with electrical insulating property, anticorrosive, flame resistant, high temperature resistant etc.
Excellent properties.Using basalt building stones as intensity modifier, compared with glass fibre, have intensity height, impact strength high, resistance to
The advantages that warm nature is excellent.
Magnesium salt whisker is single palpus fibre structure, and for diameter in nano-scale range, magnesium salt whisker has very high physical machine
Tool performance, the intensity of nylon material can be strengthened after addition；It is good with the compatibility of resin and magnesium salt whisker is easily scattered, it is obtained
Nylon product surface scratch resistance capability is strong, dimensionally stable is not easy buckling deformation, and can improve the ageing resistace of nylon product.
The present invention, as intensity modifier compounding use, and controls its weight by using basalt fibre and magnesium salt whisker
Than for 1.6-2.4:1, it can significantly mention the intensity of PVC material.
The compatilizer is with weight ratio by maleic anhydride grafted polyvinyl chloride and ethlyene dichloride-vinyl acetate copolymer
1：1.4-2.2 the mixture of composition.
The present invention is by using maleic anhydride grafted polyvinyl chloride and ethlyene dichloride-vinyl acetate copolymer as compatible
Agent compounding use, and it is 1 to control its weight ratio：1.4-2.2, inorganic filler and polyvinyl chloride resin compatibility can be improved, improve product
Stretching, impact strength, high filling is realized, reduces resin demand, improves rheological performance, improves surface smoothness.
The slipping agent is to compare 1.5-2.5 by erucyl amide, oleamide and N, N'- ethylene bis stearamide with weight：
0.8-1.2：The mixture of 1 composition.
The present invention as slipping agent and controls by using erucyl amide, oleamide and N, N'- ethylene bis stearamide
Its weight ratio is 1.5-2.5：0.8-1.2：1, mechanical resistant stirring capacity and fingerprinting stress, finished product good forming effect, table can be strengthened
Face is bright and clean, moreover it is possible to strengthen the extensibility of finished product, it is easy-to-draw not easily broken.
A kind of super print through flower crystal spills double attaching process of gold stand cloth, comprises the following steps：
(1) above-mentioned raw materials are weighed by weight ratio, are put into high speed blender, and 8- is stirred at a temperature of 110-120 DEG C
12min, the rotating speed of stirring is 580-1160RPM, obtains compound；
(2) raw material after stirring is subjected to first time plasticizing through planetary extruder at a temperature of 140-160 DEG C, obtains glue
Grain；
(3) micelle after first time is plastified carries out second of plasticizing through pricking turbine at a temperature of 130-150 DEG C, until
It is even；
(4) micelle after second is plastified uses 20 mesh nets, 60 mesh nets and 150 net filtrations successively by filter, filters
The screw speed of machine is 20-60RPM；
(5) micelle after filtering is obtained into sheet material through calender calendering formation；
(6) by sheet material enter to pass through printing machine carry out printing treatment；
(7) sheet material after printing and flower bud are penetrated into film at a temperature of 75-85 DEG C to preheat, pasted at a temperature of 140-160 DEG C
Close, spill gold, demoulding；
(6) sheet material after shaping is subjected to cooling and shaping through drawing cooling wheel, then rolling machine is wound, and is made super
Stamp crystal spills gold stand cloth.
The beneficial effects of the present invention are：The super print through flower crystal of the present invention spills gold stand cloth environmentally-friendly transparent, has preferable
The feel of three-dimensional stereo effect and soft comfortable；And good flame retardation effect, also with good chemical stability, insulation, acidproof resistance to
The advantages that alkali, waterproof and dampproof, anticorrosion, stretching resistance, anti-aging and antistatic, excellent combination property.
The double applying conjunction processing step of the present invention is simple, and convenient operation and control, steady quality, production efficiency is high, production cost
It is low, can large-scale industrial production.
Embodiment
For the ease of the understanding of those skilled in the art, with reference to embodiment, the present invention is further illustrated, real
The content that the mode of applying refers to not is limitation of the invention.
Embodiment 1
A kind of super print through flower crystal spills gold stand cloth, and the super print through flower crystal, which spills gold stand cloth, includes the original of following parts by weight
Material：
The polyvinyl chloride resin is ethylene process polyvinyl chloride resin of the average degree of polymerization 1000.
The heat stabilizer is with weight ratio 1 by calcium stearate, barium stearate, zinc stearate and hydrotalcite:0.8:0.8：
The mixture of 0.4 composition.
The powder that adds lustre to is with weight ratio 0.5 by Tissuemat E and microcrystalline wax:The mixture of 1 composition.
The titanium dioxide surface treated, its preparation method are：By rutile type titanium white at 100 DEG C high-speed stirred
15min removes the moisture content absorbed, is then added in the styrene and silicon oil solution for being mixed with initiator, continues to cool down after mixing 8min
Complete to prepare；The rutile type titanium white, styrene, dimethicone, the weight ratio of di-isopropyl peroxydicarbonate are
100：0.4：1.2：0.04.
The fire retardant is with weight ratio 1 by brominated Polystyrene, melamine phosphate and aluminium hydroxide:0.8:1.4
The mixture of composition.
Other auxiliary agents are with weight ratio 0.8 by UV resistant agent and antioxidant：The mixture of 1 composition.
The UV resistant agent is by 4- benzoyloxys -2,2,6,6- tetramethyl piperidines, 2- hydroxyl -4- n-octyloxies two
Benzophenone and 2,4,6- tri- (2 ' n-butoxyphenyl) -1,3,5- triazines are with weight than 1.5:0.5:The mixture of 1 composition.
The antioxidant be by four [methylene -3,5- (di-t-butyl -4- hydroxy-phenies) propionic ester] pentaerythritol esters,
Three [2,4- di-tert-butyl-phenyls] phosphite esters and β-positive octadecanol ester of (3,5- di-tert-butyl-hydroxy phenyls) propionic acid are with weight
Measure ratio 1:0.2:The mixture of 0.4 composition.
A kind of super print through flower crystal spills double attaching process of gold stand cloth, comprises the following steps：
(1) above-mentioned raw materials are weighed by weight ratio, are put into high speed blender, 8min is stirred at a temperature of 110 DEG C, are stirred
Rotating speed be 580RPM, obtain compound；
(2) raw material after stirring is subjected to first time plasticizing through planetary extruder at a temperature of 140 DEG C, obtains micelle；
(3) micelle after first time is plastified carries out second of plasticizing through pricking turbine at a temperature of 130 DEG C, until uniformly；
(4) micelle after second is plastified uses 20 mesh nets, 60 mesh nets and 150 net filtrations successively by filter, filters
The screw speed of machine is 20RPM；
(5) micelle after filtering is obtained into sheet material through calender calendering formation；
(6) by sheet material enter to pass through printing machine carry out printing treatment；
(7) sheet material after printing and flower bud are penetrated into film at a temperature of 75 DEG C to preheat, are bonded at a temperature of 140 DEG C, spill gold,
Demoulding；
(6) sheet material after shaping is subjected to cooling and shaping through drawing cooling wheel, then rolling machine is wound, and is made super
Stamp crystal spills gold stand cloth.
Embodiment 2
A kind of super print through flower crystal spills gold stand cloth, and the super print through flower crystal, which spills gold stand cloth, includes the original of following parts by weight
Material：
The polyvinyl chloride resin is ethylene process polyvinyl chloride resin of the average degree of polymerization 1200.
The heat stabilizer is with weight ratio 1 by calcium stearate, barium stearate, zinc stearate and hydrotalcite:0.9:0.9：
The mixture of 0.5 composition.
The powder that adds lustre to is with weight ratio 0.8 by Tissuemat E and microcrystalline wax:The mixture of 1 composition.
The titanium dioxide surface treated, its preparation method are：By rutile type titanium white at 105 DEG C high-speed stirred
18min removes the moisture content absorbed, is then added in the styrene and silicon oil solution for being mixed with initiator, continues to cool down after mixing 9min
Complete to prepare；The rutile type titanium white, styrene, dimethicone, the weight ratio of di-isopropyl peroxydicarbonate are
100：0.5：1.3：0.05.
The fire retardant is with weight ratio 1 by brominated Polystyrene, melamine phosphate and aluminium hydroxide:0.9:1.6
The mixture of composition.
Other auxiliary agents are with weight ratio 0.9 by UV resistant agent and antioxidant：The mixture of 1 composition.
The UV resistant agent is by 4- benzoyloxys -2,2,6,6- tetramethyl piperidines, 2- hydroxyl -4- n-octyloxies two
Benzophenone and 2,4,6- tri- (2 ' n-butoxyphenyl) -1,3,5- triazines are with weight than 1.8:0.8:The mixture of 1 composition.
The antioxidant be by four [methylene -3,5- (di-t-butyl -4- hydroxy-phenies) propionic ester] pentaerythritol esters,
Three [2,4- di-tert-butyl-phenyls] phosphite esters and β-positive octadecanol ester of (3,5- di-tert-butyl-hydroxy phenyls) propionic acid are with weight
Measure ratio 1:0.3:The mixture of 0.5 composition.
A kind of super print through flower crystal spills double attaching process of gold stand cloth, comprises the following steps：
(1) above-mentioned raw materials are weighed by weight ratio, are put into high speed blender, 9min is stirred at a temperature of 112 DEG C, are stirred
Rotating speed be 700RPM, obtain compound；
(2) raw material after stirring is subjected to first time plasticizing through planetary extruder at a temperature of 145 DEG C, obtains micelle；
(3) micelle after first time is plastified carries out second of plasticizing through pricking turbine at a temperature of 135 DEG C, until uniformly；
(4) micelle after second is plastified uses 20 mesh nets, 60 mesh nets and 150 net filtrations successively by filter, filters
The screw speed of machine is 30RPM；
(5) micelle after filtering is obtained into sheet material through calender calendering formation；
(6) by sheet material enter to pass through printing machine carry out printing treatment；
(7) sheet material after printing and flower bud are penetrated into film at a temperature of 78 DEG C to preheat, are bonded at a temperature of 145 DEG C, spill gold,
Demoulding；
(6) sheet material after shaping is subjected to cooling and shaping through drawing cooling wheel, then rolling machine is wound, and is made super
Stamp crystal spills gold stand cloth.
Embodiment 3
A kind of super print through flower crystal spills gold stand cloth, and the super print through flower crystal, which spills gold stand cloth, includes the original of following parts by weight
Material：
The polyvinyl chloride resin is ethylene process polyvinyl chloride resin of the average degree of polymerization 1500.
The heat stabilizer is with weight ratio 1 by calcium stearate, barium stearate, zinc stearate and hydrotalcite:1:1：0.6 group
Into mixture.
The powder that adds lustre to is with weight ratio 1 by Tissuemat E and microcrystalline wax:The mixture of 1 composition.
The titanium dioxide surface treated, its preparation method are：By rutile type titanium white at 110 DEG C high-speed stirred
20min remove absorb moisture content, be then added in the styrene and silicon oil solution for being mixed with initiator, continue mix 10min after it is cold
But complete to prepare；The rutile type titanium white, styrene, dimethicone, the weight ratio of di-isopropyl peroxydicarbonate
For 100：0.6：1.4：0.06.
The fire retardant is with weight ratio 1 by brominated Polystyrene, melamine phosphate and aluminium hydroxide:1:1.8 group
Into mixture.
Other auxiliary agents are with weight ratio 1 by UV resistant agent and antioxidant：The mixture of 1 composition.
The UV resistant agent is by 4- benzoyloxys -2,2,6,6- tetramethyl piperidines, 2- hydroxyl -4- n-octyloxies two
Benzophenone and 2,4,6- tri- (2 ' n-butoxyphenyl) -1,3,5- triazines are with weight than 2:1:The mixture of 1 composition.
The antioxidant be by four [methylene -3,5- (di-t-butyl -4- hydroxy-phenies) propionic ester] pentaerythritol esters,
Three [2,4- di-tert-butyl-phenyls] phosphite esters and β-positive octadecanol ester of (3,5- di-tert-butyl-hydroxy phenyls) propionic acid are with weight
Measure ratio 1:0.4:The mixture of 0.6 composition.
A kind of super print through flower crystal spills double attaching process of gold stand cloth, comprises the following steps：
(1) above-mentioned raw materials are weighed by weight ratio, are put into high speed blender, are stirred 10min at a temperature of 115 DEG C, are stirred
The rotating speed mixed is 800RPM, obtains compound；
(2) raw material after stirring is subjected to first time plasticizing through planetary extruder at a temperature of 150 DEG C, obtains micelle；
(3) micelle after first time is plastified carries out second of plasticizing through pricking turbine at a temperature of 140 DEG C, until uniformly；
(4) micelle after second is plastified uses 20 mesh nets, 60 mesh nets and 150 net filtrations successively by filter, filters
The screw speed of machine is 40RPM；
(5) micelle after filtering is obtained into sheet material through calender calendering formation；
(6) by sheet material enter to pass through printing machine carry out printing treatment；
(7) sheet material after printing and flower bud are penetrated into film at a temperature of 80 DEG C to preheat, are bonded at a temperature of 150 DEG C, spill gold,
Demoulding；
(6) sheet material after shaping is subjected to cooling and shaping through drawing cooling wheel, then rolling machine is wound, and is made super
Stamp crystal spills gold stand cloth.
Embodiment 4
A kind of super print through flower crystal spills gold stand cloth, and the super print through flower crystal, which spills gold stand cloth, includes the original of following parts by weight
Material：
The polyvinyl chloride resin is ethylene process polyvinyl chloride resin of the average degree of polymerization 1800.
The heat stabilizer is with weight ratio 1 by calcium stearate, barium stearate, zinc stearate and hydrotalcite:1.1:1.1：
The mixture of 0.7 composition.
The powder that adds lustre to is with weight ratio 1.2 by Tissuemat E and microcrystalline wax:The mixture of 1 composition.
The titanium dioxide surface treated, its preparation method are：By rutile type titanium white at 115 DEG C high-speed stirred
22min remove absorb moisture content, be then added in the styrene and silicon oil solution for being mixed with initiator, continue mix 11min after it is cold
But complete to prepare；The rutile type titanium white, styrene, dimethicone, the weight ratio of di-isopropyl peroxydicarbonate
For 100：0.7：1.5：0.07.
The fire retardant is with weight ratio 1 by brominated Polystyrene, melamine phosphate and aluminium hydroxide:1.1:2 groups
Into mixture.
Other auxiliary agents are with weight ratio 1.1 by UV resistant agent and antioxidant：The mixture of 1 composition.
The UV resistant agent is by 4- benzoyloxys -2,2,6,6- tetramethyl piperidines, 2- hydroxyl -4- n-octyloxies two
Benzophenone and 2,4,6- tri- (2 ' n-butoxyphenyl) -1,3,5- triazines are with weight than 2.2:1.2:The mixture of 1 composition.
The antioxidant be by four [methylene -3,5- (di-t-butyl -4- hydroxy-phenies) propionic ester] pentaerythritol esters,
Three [2,4- di-tert-butyl-phenyls] phosphite esters and β-positive octadecanol ester of (3,5- di-tert-butyl-hydroxy phenyls) propionic acid are with weight
Measure ratio 1:0.5:The mixture of 0.7 composition.
A kind of super print through flower crystal spills double attaching process of gold stand cloth, comprises the following steps：
(1) above-mentioned raw materials are weighed by weight ratio, are put into high speed blender, are stirred 11min at a temperature of 118 DEG C, are stirred
The rotating speed mixed is 1000RPM, obtains compound；
(2) raw material after stirring is subjected to first time plasticizing through planetary extruder at a temperature of 155 DEG C, obtains micelle；
(3) micelle after first time is plastified carries out second of plasticizing through pricking turbine at a temperature of 145 DEG C, until uniformly；
(4) micelle after second is plastified uses 20 mesh nets, 60 mesh nets and 150 net filtrations successively by filter, filters
The screw speed of machine is 50RPM；
(5) micelle after filtering is obtained into sheet material through calender calendering formation；
(6) by sheet material enter to pass through printing machine carry out printing treatment；
(7) sheet material after printing and flower bud are penetrated into film at a temperature of 82 DEG C to preheat, are bonded at a temperature of 155 DEG C, spill gold,
Demoulding；
(6) sheet material after shaping is subjected to cooling and shaping through drawing cooling wheel, then rolling machine is wound, and is made super
Stamp crystal spills gold stand cloth.
Embodiment 5
A kind of super print through flower crystal spills gold stand cloth, and the super print through flower crystal, which spills gold stand cloth, includes the original of following parts by weight
Material：
The polyvinyl chloride resin is ethylene process polyvinyl chloride resin of the average degree of polymerization 2000.
The heat stabilizer is with weight ratio 1 by calcium stearate, barium stearate, zinc stearate and hydrotalcite:1.2:1.2：
The mixture of 0.8 composition.
The powder that adds lustre to is with weight ratio 1.5 by Tissuemat E and microcrystalline wax:The mixture of 1 composition.
The titanium dioxide surface treated, its preparation method are：By rutile type titanium white at 120 DEG C high-speed stirred
25min remove absorb moisture content, be then added in the styrene and silicon oil solution for being mixed with initiator, continue mix 12min after it is cold
But complete to prepare；The rutile type titanium white, styrene, dimethicone, the weight ratio of di-isopropyl peroxydicarbonate
For 100：0.8：1.6：0.08.
The fire retardant is with weight ratio 1 by brominated Polystyrene, melamine phosphate and aluminium hydroxide:1.2:2.2
The mixture of composition.
Other auxiliary agents are with weight ratio 1.2 by UV resistant agent and antioxidant：The mixture of 1 composition.
The UV resistant agent is by 4- benzoyloxys -2,2,6,6- tetramethyl piperidines, 2- hydroxyl -4- n-octyloxies two
Benzophenone and 2,4,6- tri- (2 ' n-butoxyphenyl) -1,3,5- triazines are with weight than 2.5:1.5:The mixture of 1 composition.
The antioxidant be by four [methylene -3,5- (di-t-butyl -4- hydroxy-phenies) propionic ester] pentaerythritol esters,
Three [2,4- di-tert-butyl-phenyls] phosphite esters and β-positive octadecanol ester of (3,5- di-tert-butyl-hydroxy phenyls) propionic acid are with weight
Measure ratio 1:0.6:The mixture of 0.8 composition.
A kind of super print through flower crystal spills double attaching process of gold stand cloth, comprises the following steps：
(1) above-mentioned raw materials are weighed by weight ratio, are put into high speed blender, are stirred 12min at a temperature of 120 DEG C, are stirred
The rotating speed mixed is 1160RPM, obtains compound；
(2) raw material after stirring is subjected to first time plasticizing through planetary extruder at a temperature of 160 DEG C, obtains micelle；
(3) micelle after first time is plastified carries out second of plasticizing through pricking turbine at a temperature of 150 DEG C, until uniformly；
(4) micelle after second is plastified uses 20 mesh nets, 60 mesh nets and 150 net filtrations successively by filter, filters
The screw speed of machine is 60RPM；
(5) micelle after filtering is obtained into sheet material through calender calendering formation；
(6) by sheet material enter to pass through printing machine carry out printing treatment；
(7) sheet material after printing and flower bud are penetrated into film at a temperature of 85 DEG C to preheat, are bonded at a temperature of 160 DEG C, spill gold,
Demoulding；
(6) sheet material after shaping is subjected to cooling and shaping through drawing cooling wheel, then rolling machine is wound, and is made super
Stamp crystal spills gold stand cloth.
Embodiment 6
The difference of the present embodiment and above-described embodiment 1 is：
The super print through flower crystal, which spills gold stand cloth, also includes 15 parts of aliphatic polyketone, 5 parts of polyester staple fiber and modified POE trees
4 parts of fat.
The modified POE resin is polypropylene/ethylene-octene copolymer that polypropylene and POE resin blending and modifying obtain；
The ethylene-octene copolymer is ethylene-octene copolymer of the octene monomers content 20%.
The polypropylene is that have COPP and HOPP with weight ratio 1.4：The mixture of 1 composition；It is described common
Poly- polypropylene is COPP of the melt index in 10g/10min；The HOPP is melt index in 60g/10min
HOPP.
The super print through flower crystal spill gold stand cloth also include cold-resistant toughened dose 2 parts, 1 part of intensity modifier, 1 part of compatilizer,
0.5 part of slipping agent.
Described cold-resistant toughened dose is with weight ratio 1 by amide-type beta crystal-type nucleater and dicarboxylic acids salt beta crystal-type nucleater：
The mixture of 1.2 compositions.
The intensity modifier is in the magnesium salt whisker of 4 μm of basalt fibre and filament diameter at 6 μm by filament diameter
With weight than 1.6：The mixture of 1 composition.
The compatilizer is with weight ratio by maleic anhydride grafted polyvinyl chloride and ethlyene dichloride-vinyl acetate copolymer
1：The mixture of 1.4 compositions.
The slipping agent is than 1.5 by erucyl amide, oleamide and N, N'- ethylene bis stearamide with weight：0.8：1
The mixture of composition.
Embodiment 7
The difference of the present embodiment and above-described embodiment 2 is：
The super print through flower crystal, which spills gold stand cloth, also includes 20 parts of aliphatic polyketone, 8 parts of polyester staple fiber and modified POE trees
5 parts of fat.
The modified POE resin is polypropylene/ethylene-octene copolymer that polypropylene and POE resin blending and modifying obtain；
The ethylene-octene copolymer is ethylene-octene copolymer of the octene monomers content 22%.
The polypropylene is that have COPP and HOPP with weight ratio 1.6：The mixture of 1 composition；It is described common
Poly- polypropylene is COPP of the melt index in 20g/10min；The HOPP is melt index in 70g/10min
HOPP.
The super print through flower crystal spill gold stand cloth also include cold-resistant toughened dose 3 parts, 2 parts of intensity modifier, compatilizer 1.5
Part, 0.8 part of slipping agent.
Described cold-resistant toughened dose is with weight ratio 1 by amide-type beta crystal-type nucleater and dicarboxylic acids salt beta crystal-type nucleater：
The mixture of 1.4 compositions.
The intensity modifier is in the magnesium salt whisker of 5 μm of basalt fibre and filament diameter at 7 μm by filament diameter
With weight than 1.8：The mixture of 1 composition.
The compatilizer is with weight ratio by maleic anhydride grafted polyvinyl chloride and ethlyene dichloride-vinyl acetate copolymer
1：The mixture of 1.6 compositions.
The slipping agent is than 1.8 by erucyl amide, oleamide and N, N'- ethylene bis stearamide with weight：0.9：1
The mixture of composition.
Embodiment 8
The difference of the present embodiment and above-described embodiment 3 is：
The super print through flower crystal, which spills gold stand cloth, also includes 25 parts of aliphatic polyketone, 10 parts of polyester staple fiber and modified POE
6 parts of resin.
The modified POE resin is polypropylene/ethylene-octene copolymer that polypropylene and POE resin blending and modifying obtain；
The ethylene-octene copolymer is ethylene-octene copolymer of the octene monomers content 25%.
The polypropylene is that have COPP and HOPP with weight ratio 1.8：The mixture of 1 composition；It is described common
Poly- polypropylene is COPP of the melt index in 30g/10min；The HOPP is melt index in 80g/10min
HOPP.
The super print through flower crystal, which spills gold stand cloth, also includes 3 parts of 40 parts of Vitrified powder, 3 parts of fire retardant and smoke suppressant.
The super print through flower crystal spill gold stand cloth also include cold-resistant toughened dose 4 parts, 3 parts of intensity modifier, 2 parts of compatilizer,
1 part of slipping agent.
Described cold-resistant toughened dose is with weight ratio 1 by amide-type beta crystal-type nucleater and dicarboxylic acids salt beta crystal-type nucleater：
The mixture of 1.5 compositions.
The intensity modifier is in the magnesium salt whisker of 6 μm of basalt fibre and filament diameter at 8 μm by filament diameter
With weight than 2：The mixture of 1 composition.
The compatilizer is with weight ratio by maleic anhydride grafted polyvinyl chloride and ethlyene dichloride-vinyl acetate copolymer
1：1.8 the mixture of composition.
The slipping agent is than 2 by erucyl amide, oleamide and N, N'- ethylene bis stearamide with weight：1：1 composition
Mixture.
Embodiment 9
The difference of the present embodiment and above-described embodiment 4 is：
The super print through flower crystal, which spills gold stand cloth, also includes 30 parts of aliphatic polyketone, 12 parts of polyester staple fiber and modified POE
7 parts of resin.
The modified POE resin is polypropylene/ethylene-octene copolymer that polypropylene and POE resin blending and modifying obtain；
The ethylene-octene copolymer is ethylene-octene copolymer of the octene monomers content 28%.
The polypropylene is that have COPP and HOPP with weight ratio 2：The mixture of 1 composition；The copolymerization
Polypropylene is COPP of the melt index in 40g/10min；The HOPP is melt index 90g/10min's
HOPP.
The super print through flower crystal, which spills gold stand cloth, also includes 4 parts of 50 parts of Vitrified powder, 4 parts of fire retardant and smoke suppressant.
The super print through flower crystal spill gold stand cloth also include cold-resistant toughened dose 5 parts, 4 parts of intensity modifier, compatilizer 2.5
Part, 1.2 parts of slipping agent.
Described cold-resistant toughened dose is with weight ratio 1 by amide-type beta crystal-type nucleater and dicarboxylic acids salt beta crystal-type nucleater：
The mixture of 1.6 compositions.
The intensity modifier is in the magnesium salt whisker of 7 μm of basalt fibre and filament diameter at 9 μm by filament diameter
With weight than 2.2：The mixture of 1 composition.
The compatilizer is with weight ratio by maleic anhydride grafted polyvinyl chloride and ethlyene dichloride-vinyl acetate copolymer
1：The mixture of 2 compositions.
The slipping agent is than 2.2 by erucyl amide, oleamide and N, N'- ethylene bis stearamide with weight：1.1：1
The mixture of composition.
Embodiment 10
The difference of the present embodiment and above-described embodiment 5 is：
The super print through flower crystal, which spills gold stand cloth, also includes 35 parts of aliphatic polyketone, 15 parts of polyester staple fiber and modified POE
8 parts of resin.
The modified POE resin is polypropylene/ethylene-octene copolymer that polypropylene and POE resin blending and modifying obtain；
The ethylene-octene copolymer is ethylene-octene copolymer of the octene monomers content 30%.
The polypropylene is that have COPP and HOPP with weight ratio 2.2：The mixture of 1 composition；It is described common
Poly- polypropylene is COPP of the melt index in 50g/10min；The HOPP is melt index in 100g/
10min HOPP.
The super print through flower crystal spill gold stand cloth also include cold-resistant toughened dose 6 parts, 5 parts of intensity modifier, 3 parts of compatilizer,
1.5 parts of slipping agent.
Described cold-resistant toughened dose is with weight ratio 1 by amide-type beta crystal-type nucleater and dicarboxylic acids salt beta crystal-type nucleater：
The mixture of 1.8 compositions.
The intensity modifier is in the magnesium salt whisker of 8 μm of basalt fibre and filament diameter at 10 μm by filament diameter
With weight than 2.4：The mixture of 1 composition.
The compatilizer is with weight ratio by maleic anhydride grafted polyvinyl chloride and ethlyene dichloride-vinyl acetate copolymer
1：The mixture of 2.2 compositions.
The slipping agent is than 2.5 by erucyl amide, oleamide and N, N'- ethylene bis stearamide with weight：1.2：1
The mixture of composition.
Super print through flower crystal produced by the present invention spills gold stand cloth environmentally-friendly transparent, has preferable three-dimensional stereo effect and softness
Comfortable feel；Intensity is high, and tensile strength can reach more than 26.2MPa, and bending strength can reach more than 58.3MPa, breaks
More than 340% can be reached by splitting elongation, excellent shock resistance, and good flame retardation effect, also with good chemical stability,
The advantages that insulation, acid-fast alkali-proof, waterproof and dampproof, anticorrosion, stretching resistance, anti-aging and antistatic, excellent combination property.
Above-described embodiment is the preferable implementation of the present invention, and in addition, the present invention can be realized with other manner,
Do not depart from and any on the premise of present inventive concept obviously replace within protection scope of the present invention.
Claims (10)
1. a kind of super print through flower crystal spills gold stand cloth, it is characterised in that：The super print through flower crystal, which spills gold stand cloth, includes following weight
Measure the raw material of part：
2. a kind of super print through flower crystal according to claim 1 spills gold stand cloth, it is characterised in that：The polyvinyl chloride resin is flat
The right ethylene process polyvinyl chloride resin in 1000-2000 of homopolymerization.
3. a kind of super print through flower crystal according to claim 1 spills gold stand cloth, it is characterised in that：The heat stabilizer be by
Calcium stearate, barium stearate, zinc stearate and hydrotalcite are with weight ratio 1:0.8-1.2:0.8-1.2：The mixing of 0.4-0.8 compositions
Thing.
4. a kind of super print through flower crystal according to claim 1 spills gold stand cloth, it is characterised in that：The powder that adds lustre to is by gathering
Ethylene waxes and microcrystalline wax compare 0.5-1.5 with weight:The mixture of 1 composition.
5. a kind of super print through flower crystal according to claim 1 spills gold stand cloth, it is characterised in that：The titanium dioxide is through surface
Processing, its preparation method are：By rutile type titanium white, high-speed stirred 15-25min removes the water absorbed at 100-120 DEG C
Part, it is then added in the styrene and silicon oil solution for being mixed with initiator, continues cooling after mixing 8-12min and complete to prepare；It is described
Rutile type titanium white, styrene, dimethicone, the weight ratio of di-isopropyl peroxydicarbonate are 100：0.4-0.8：
1.2-1.6：0.04-0.08.
6. a kind of super print through flower crystal according to claim 1 spills gold stand cloth, it is characterised in that：The fire retardant is by bromine
Change polystyrene, melamine phosphate and aluminium hydroxide with weight ratio 1:0.8-1.2:1.4-2.2 the mixture of composition.
7. a kind of super print through flower crystal according to claim 1 spills gold stand cloth, it is characterised in that：Other auxiliary agents be by
UV resistant agent and antioxidant compare 0.8-1.2 with weight：The mixture of 1 composition.
8. a kind of super print through flower crystal according to claim 7 spills gold stand cloth, it is characterised in that：The UV resistant agent is
By 4- benzoyloxys -2,2,6,6- tetramethyl piperidines, 2-hydroxy-4-n-octoxybenzophenone and 2,4,6- tri- (2 ' positive fourths
Phenyl) -1,3,5- triazines compare 1.5-2.5 with weight:0.5-1.5:The mixture of 1 composition.
9. a kind of super print through flower crystal according to claim 7 spills gold stand cloth, it is characterised in that：The antioxidant is by four
[methylene -3,5- (di-t-butyl -4- hydroxy-phenies) propionic ester] pentaerythritol ester, three [2,4- di-tert-butyl-phenyls] phosphorous
Acid esters and β-positive octadecanol ester of (3,5- di-tert-butyl-hydroxy phenyls) propionic acid are with weight than 1:0.2-0.6:0.4-0.8 groups
Into mixture.
10. a kind of super print through flower crystal according to claim any one of 1-9 spills double attaching process of gold stand cloth, its feature
It is：Comprise the following steps：
(1) above-mentioned raw materials are weighed by weight ratio, are put into high speed blender, and 8-12min is stirred at a temperature of 110-120 DEG C,
The rotating speed of stirring is 580-1160RPM, obtains compound；
(2) raw material after stirring is subjected to first time plasticizing through planetary extruder at a temperature of 140-160 DEG C, obtains micelle；
(3) micelle after first time is plastified carries out second of plasticizing through pricking turbine at a temperature of 130-150 DEG C, until uniformly；
(4) micelle after second is plastified uses 20 mesh nets, 60 mesh nets and 150 net filtrations successively by filter, filter
Screw speed is 20-60RPM；
(5) micelle after filtering is obtained into sheet material through calender calendering formation；
(6) by sheet material enter to pass through printing machine carry out printing treatment；
(7) sheet material after printing and flower bud are penetrated into film at a temperature of 75-85 DEG C to preheat, is bonded, spilt at a temperature of 140-160 DEG C
Gold, demoulding；
(6) sheet material after shaping is subjected to cooling and shaping through drawing cooling wheel, then rolling machine is wound, and super print through flower is made
Crystal spills gold stand cloth.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN110754889A (en) * | 2019-11-19 | 2020-02-07 | 东莞市悠悠美居家居制造有限公司 | Production process of cloth-imitated PVC tablecloth |
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Application publication date: 20180410 |