CN107868359A - A kind of lace burr hollow out colorful gold plaque material and its preparation technology - Google Patents
A kind of lace burr hollow out colorful gold plaque material and its preparation technology Download PDFInfo
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- CN107868359A CN107868359A CN201710992575.XA CN201710992575A CN107868359A CN 107868359 A CN107868359 A CN 107868359A CN 201710992575 A CN201710992575 A CN 201710992575A CN 107868359 A CN107868359 A CN 107868359A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/06—Pretreated ingredients and ingredients covered by the main groups C08K3/00 - C08K7/00
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/001—Combinations of extrusion moulding with other shaping operations
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/001—Combinations of extrusion moulding with other shaping operations
- B29C48/0023—Combinations of extrusion moulding with other shaping operations combined with printing or marking
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/12—Esters; Ether-esters of cyclic polycarboxylic acids
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2007/00—Flat articles, e.g. films or sheets
- B29L2007/002—Panels; Plates; Sheets
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- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
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- C08K2201/00—Specific properties of additives
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- C08K2201/003—Additives being defined by their diameter
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- C08L2201/04—Antistatic
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- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
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Abstract
The present invention relates to sheet technology field, and in particular to a kind of lace burr hollow out colorful gold plaque material and its preparation technology, the lace burr hollow out colorful gold plaque material include the raw material of following parts by weight：40 50 parts of polyvinyl chloride resin, 60 65 parts of filler, 30 38 parts of diisononyl phthalate, 2.0 2.5 parts of heat stabilizer, 0.2 0.25 parts of toner material, 0.15 0.20 parts of titanium dioxide, 0.03 0.04 parts of other auxiliary agents.The lace burr hollow out colorful gold plaque material of the present invention has the feel of preferable three-dimensional stereo effect and soft comfortable；Also there is good chemical stability, fire retardant insulating, acid-fast alkali-proof, waterproof and dampproof, anticorrosion, stretching resistance, anti-aging and antistatic, excellent combination property.
Description
Technical field
The present invention relates to sheet technology field, and in particular to a kind of lace burr hollow out colorful gold plaque material and its preparation work
Skill.
Background technology
With the development of society, the raising of human living standard and the constantly pursuit to material, are currently used for household day
It is attractive in appearance with arts also more and more convenient fashion.The transparent attractive in appearance, soft texture of soft PVC sheet material, has been widely used for
Some home decorations of everyday articles field, such as tablecloth, mat applying and table mat, ground cushion.This based article is usually in printed patterns
Another side enclose hyaline membrane, when being covered in furniture especially on glass furniture, can both show the printing figure on hyaline membrane
Case, the pattern that hyaline membrane observes furniture can be passed through again, plays good decorative effect.But existing pattern is all generally flat
Face pattern, appreciative value are smaller；And existing sheet material mechanical and physical performance is poor.
The content of the invention
In order to overcome shortcoming and defect present in prior art, it is an object of the invention to provide a kind of lace burr to engrave
Empty colorful gold plaque material, the lace burr hollow out colorful gold plaque material have the feel of preferable three-dimensional stereo effect and soft comfortable；
Also there is good chemical stability, fire retardant insulating, acid-fast alkali-proof, waterproof and dampproof, anticorrosion, stretching resistance, anti-aging and anti-quiet
The advantages that electric, excellent combination property.
Another object of the present invention is to provide a kind of preparation technology of lace burr hollow out colorful gold plaque material, the preparation work
Skill step is simple, convenient operation and control, steady quality, and production efficiency is high, and production cost is low, can large-scale industrial production.
The purpose of the present invention is achieved through the following technical solutions：A kind of lace burr hollow out colorful gold plaque material, the lace
Burr hollow out colorful gold plaque material includes the raw material of following parts by weight：
The present invention strictly controls the weight proportion of each raw material by using above-mentioned raw materials, obtained lace burr hollow out
Colorful gold plaque material has the feel of preferable three-dimensional stereo effect and soft comfortable；Also there is good chemical stability, fire-retardant
The advantages that insulation, acid-fast alkali-proof, waterproof and dampproof, anticorrosion, stretching resistance, anti-aging and antistatic, excellent combination property.
Preferably, the polyvinyl chloride resin is ethylene process polyvinyl chloride resin of the average degree of polymerization in 1000-2000.
The present invention by using average degree of polymerization 1000-2000 ethylene process polyvinyl chloride resin so that material plasticizing rate
It hurry up, be easily worked.
Preferably, the filler is at 10-50 μm and the lightweight carbon through higher fatty acid salt modification by particle diameter
Sour calcium and particle diameter are at 100-500 μm and the powdered whiting through high-grade aliphatic ester modification compares 0.5-1.5 with weight:1
The mixture of composition.
The present invention is by the way that by the size controlling of precipitated calcium carbonate, at 10-50 μm, its crystal structure and Electronic Structure are sent out
Change has been given birth to, has generated quantum size effect, small-size effect, skin effect and macroscopic view that common powdered whiting does not have
Quantum effect, therefore with good toughened and reinforced effect, its add in the polyvinyl chloride resin of the present invention can improve bending strength and
The stability of the modulus of elasticity in static bending and heat distortion temperature and size；Filler is to play its effect with the good compatibility of resin
With the key of control addition, the present invention uses the precipitated calcium carbonate through higher fatty acid salt modification, can put forward lightweight
The compatibility of calcium carbonate and polyvinyl chloride resin, so as to improve the intensity of material.
The present invention by by the size controlling of powdered whiting at 100-500 μm, its crystal structure and Electronic Structure
Changed, generate quantum size effect, small-size effect, skin effect that common powdered whiting do not have and grand
Quantum effect is seen, therefore with good toughened and reinforced effect, it, which is added in the polyvinyl chloride resin of the present invention, can improve bending strength
With the modulus of elasticity in static bending and the stability of heat distortion temperature and size；Filler is to play its work with the good compatibility of resin
With the key with control addition, the present invention uses the powdered whiting through high-grade aliphatic ester modification, can carry weight
The compatibility of matter calcium carbonate and polyvinyl chloride resin, so as to improve the intensity of material.
Preferably, the heat stabilizer is with weight ratio 1 by calcium stearate, barium stearate, zinc stearate and hydrotalcite:
0.8-1.2:0.8-1.2：The mixture of 0.4-0.8 compositions.
The present invention by using calcium stearate, barium stearate, zinc stearate as main body heat stabilizer, using neatly masonry
For auxiliary heat stabilizer, main body heat stabilizer and auxiliary heat stabilizer compounding use, make material good heat stability, have efficient
Weatherability, material can also be made to have good dispersiveness, compatibility and processing fluidity in process.
Preferably, the toner material is to compare 0.8-1.2 by phthalocyanine blue and ultramarine toner with weight:The mixture of 1 composition.
The present invention is by using phthalocyanine blue and ultramarine toner as toner material compounding use, and it is 0.8- to control its weight ratio
1.2:1, the transparency of glued membrane can be improved.
The titanium dioxide of the present invention strictly controls the weight proportion of each raw material by using above-mentioned processing, obtained titanium white
Powder has superior whiteness, tinting strength, tinting power, covering power, weatherability, heat resistance and chemical stability, particularly no toxicity.
Preferably, other auxiliary agents are to compare 0.8-1.2 by UV resistant agent and antioxidant with weight：The mixing of 1 composition
Thing；The UV resistant agent is by 4- benzoyloxys -2,2,6,6- tetramethyl piperidines, 2- hydroxyl -4- n-octyloxy hexichol first
Ketone and 2,4,6- tri- (2 ' n-butoxyphenyl) -1,3,5- triazines compare 1.5-2.5 with weight:0.5-1.5:The mixture of 1 composition.
Species, compounding and proportioning of the invention by strictly controlling UV resistant agent, ultraviolet can be absorbed strongly, and compound
There is excellent cooperative effect during use.
The antioxidant be by four [methylene -3,5- (di-t-butyl -4- hydroxy-phenies) propionic ester] pentaerythritol esters,
Three [2,4- di-tert-butyl-phenyls] phosphite esters and β-positive octadecanol ester of (3,5- di-tert-butyl-hydroxy phenyls) propionic acid are with weight
Measure ratio 1:0.2-0.6:The mixture of 0.4-0.8 compositions.
Species, compounding and proportioning of the invention by strictly controlling antioxidant, it can delay or suppress material oxidation process
Progress, so as to prevent the aging of material and extend its service life.
Preferably, the lace burr hollow out colorful gold plaque material also includes aliphatic polyketone 15-35 parts, polyester staple fiber 5-
15 parts and modified POE resin 4-8 parts.
The present invention can form alloy material with PVC, can improve lace burr hollow out and dazzle by adding aliphatic polyketone
The intensity and shock resistance of handsel sheet material, also with excellent wearability, chemical resistance, fuel resistance and hydrolytic resistance.
The present invention can significantly inhibit the mechanical property caused by a large amount of inorganic matters add and drop by adding polyester staple fiber
It is poorly efficient to answer, it can also improve the heat-resisting quantity of material.
The modified POE resin is polypropylene/ethylene-octene copolymer that polypropylene and POE resin blending and modifying obtain；
The ethylene-octene copolymer is ethylene-octene copolymer of the octene monomers content in 20%-30%.
Polypropylene/ethylene-octene copolymer conduct that the present invention obtains by using polypropylene and POE resin blending and modifying
Modified POE resin, the normal temperature and low-temperature impact toughness of material can be significantly improved.The present invention exists by using octene monomers content
20%-30% ethylene-octene copolymer, can significantly improve the impact strength and heat resistance of material, and tensile strength, tear
The Main Mechanicals such as resistance to spalling all have significant improvement.
The polypropylene is that have COPP and HOPP to compare 1.4-2.2 with weight：The mixture of 1 composition；Institute
It is COPP of the melt index in 10-50g/10min to state COPP；The HOPP is that melt index exists
60-100g/10min HOPP.
The present invention by using melt index 10-50g/10min COPP and melt index in 60-100g/
10min HOPP is as polypropylene compounding use, and it is 1.4-2.2 to control its weight ratio：1, material can be significantly improved
Impact strength and heat distortion temperature.
Preferably, the lace burr hollow out colorful gold plaque material also includes cold-resistant toughened dose of 2-6 part, intensity modifier 1-5
Part, compatilizer 1-3 parts, slipping agent 0.5-1.5 parts.
Described cold-resistant toughened dose is with weight ratio 1 by amide-type beta crystal-type nucleater and dicarboxylic acids salt beta crystal-type nucleater：
1.2-1.8 the mixture of composition.
The present invention is by using amide-type beta crystal-type nucleater and dicarboxylic acids salt beta crystal-type nucleater as cold-resistant toughened dose
Compounding use, and it is 1 to control its weight ratio：1.2-1.8 so that material toughening effect in -20 DEG C of low temperature is obvious, more than normal temperature
When impact strength, while rigidly significantly improved under normal temperature.
The intensity modifier is in the magnesium salts of 4-8 μm of basalt fibre and filament diameter at 6-10 μm by filament diameter
Whisker compares 1.6-2.4 with weight:The mixture of 1 composition.
Basalt fibre is basalt building stones after 1450 DEG C~1500 DEG C meltings, and it is high to pass through platinum-rhodium alloy bushing
Speed draws the continuous fiber formed.Similar to glass fibre, its performance is between high intensity S glass fibres and alkali-free E glass fibres
Between, not only stability is good for basalt continuous fiber, but also a variety of with electrical insulating property, anticorrosive, flame resistant, high temperature resistant etc.
Excellent properties.Using basalt building stones as intensity modifier, compared with glass fibre, have intensity height, impact strength high, resistance to
The advantages that warm nature is excellent.
Magnesium salt whisker is single palpus fibre structure, and for diameter in nano-scale range, magnesium salt whisker has very high physical machine
Tool performance, the intensity of nylon material can be strengthened after addition；It is good with the compatibility of resin and magnesium salt whisker is easily scattered, it is obtained
Nylon product surface scratch resistance capability is strong, dimensionally stable is not easy buckling deformation, and can improve the ageing resistace of nylon product.
The present invention, as intensity modifier compounding use, and controls its weight by using basalt fibre and magnesium salt whisker
Than for 1.6-2.4:1, it can significantly mention the intensity of PVC material.
The compatilizer is with weight ratio by maleic anhydride grafted polyvinyl chloride and ethlyene dichloride-vinyl acetate copolymer
1：1.4-2.2 the mixture of composition.
The present invention is by using maleic anhydride grafted polyvinyl chloride and ethlyene dichloride-vinyl acetate copolymer as compatible
Agent compounding use, and it is 1 to control its weight ratio：1.4-2.2, inorganic filler and polyvinyl chloride resin compatibility can be improved, improve product
Stretching, impact strength, high filling is realized, reduces resin demand, improves rheological performance, improves surface smoothness.
The slipping agent is to compare 1.5-2.5 by erucyl amide, oleamide and N, N'- ethylene bis stearamide with weight：
0.8-1.2：The mixture of 1 composition.
The present invention as slipping agent and controls by using erucyl amide, oleamide and N, N'- ethylene bis stearamide
Its weight ratio is 1.5-2.5：0.8-1.2：1, mechanical resistant stirring capacity and fingerprinting stress, finished product good forming effect, table can be strengthened
Face is bright and clean, moreover it is possible to strengthen the extensibility of finished product, it is easy-to-draw not easily broken.
A kind of preparation technology of lace burr hollow out colorful gold plaque material, comprises the following steps：
(1) above-mentioned raw materials are weighed by weight ratio, are put into high speed blender, and 4- is stirred at a temperature of 110-120 DEG C
6min, the rotating speed of stirring is 580-1160RPM, obtains compound；
(2) raw material after stirring is subjected to first time plasticizing at a temperature of 165-175 DEG C, obtains micelle；
(3) micelle after first time is plastified carries out second at a temperature of 175-185 DEG C through lace die head and plastified, until
Plasticizing forming, obtain sheet material, thickness 0.45-0.60mm；
(4) sheet material after shaping is subjected to printing treatment；
(5) sheet material after printing is subjected to gold stamping processing；
(6) sheet material after shaping is subjected to cooling and shaping through drawing cooling wheel, then rolling machine is wound, and lace is made
Burr hollow out colorful gold plaque material.
The beneficial effects of the present invention are：The lace burr hollow out colorful gold plaque material of the present invention has preferable 3 D stereo
The feel of effect and soft comfortable；Also there is good chemical stability, fire retardant insulating, acid-fast alkali-proof, waterproof and dampproof, anti-corrosion
The advantages that erosion, stretching resistance, anti-aging and antistatic, excellent combination property.
The step of preparation process of the present invention is simple, convenient operation and control, steady quality, and production efficiency is high, and production cost is low,
Can large-scale industrial production.
Embodiment
For the ease of the understanding of those skilled in the art, with reference to embodiment, the present invention is further illustrated, real
The content that the mode of applying refers to not is limitation of the invention.
Embodiment 1
A kind of lace burr hollow out colorful gold plaque material, the lace burr hollow out colorful gold plaque material include following parts by weight
Raw material：
The polyvinyl chloride resin is ethylene process polyvinyl chloride resin of the average degree of polymerization 1000.
The filler is at 10 μm and precipitated calcium carbonate and particle diameter through higher fatty acid salt modification by particle diameter
At 100 μm and the powdered whiting through high-grade aliphatic ester modification with weight than 0.5:The mixture of 1 composition.
The heat stabilizer is with weight ratio 1 by calcium stearate, barium stearate, zinc stearate and hydrotalcite:0.8:0.8：
The mixture of 0.4 composition.
The toner material is with weight ratio 0.8 by phthalocyanine blue and ultramarine toner:The mixture of 1 composition.
The titanium dioxide surface treated, its preparation method are：By rutile type titanium white at 100 DEG C high-speed stirred
15min removes the moisture content absorbed, is then added in the styrene and silicon oil solution for being mixed with initiator, continues to cool down after mixing 8min
Complete to prepare；The rutile type titanium white, styrene, dimethicone, the weight ratio of di-isopropyl peroxydicarbonate are
100：0.4：1.2：0.04.
Other auxiliary agents are with weight ratio 0.8 by UV resistant agent and antioxidant：The mixture of 1 composition.
The UV resistant agent is by 4- benzoyloxys -2,2,6,6- tetramethyl piperidines, 2- hydroxyl -4- n-octyloxies two
Benzophenone and 2,4,6- tri- (2 ' n-butoxyphenyl) -1,3,5- triazines are with weight than 1.5:0.5:The mixture of 1 composition.
The antioxidant be by four [methylene -3,5- (di-t-butyl -4- hydroxy-phenies) propionic ester] pentaerythritol esters,
Three [2,4- di-tert-butyl-phenyls] phosphite esters and β-positive octadecanol ester of (3,5- di-tert-butyl-hydroxy phenyls) propionic acid are with weight
Measure ratio 1:0.2:The mixture of 0.4 composition.
A kind of preparation technology of lace burr hollow out colorful gold plaque material, comprises the following steps：
(1) above-mentioned raw materials are weighed by weight ratio, are put into high speed blender, 4min is stirred at a temperature of 110 DEG C, are stirred
Rotating speed be 580RPM, obtain compound；
(2) raw material after stirring is subjected to first time plasticizing at a temperature of 165 DEG C, obtains micelle；
(3) micelle after first time is plastified carries out second at a temperature of 175 DEG C through lace die head and plastified, until plasticizing
Shaping, obtains sheet material, thickness 0.45mm；
(4) sheet material after shaping is subjected to printing treatment；
(5) sheet material after printing is subjected to gold stamping processing；
(6) sheet material after shaping is subjected to cooling and shaping through drawing cooling wheel, then rolling machine is wound, and lace is made
Burr hollow out colorful gold plaque material.
Embodiment 2
A kind of lace burr hollow out colorful gold plaque material, the lace burr hollow out colorful gold plaque material include following parts by weight
Raw material：
The polyvinyl chloride resin is ethylene process polyvinyl chloride resin of the average degree of polymerization 1200.
The filler is at 2 μm and precipitated calcium carbonate and particle diameter through higher fatty acid salt modification by particle diameter
At 200 μm and the powdered whiting through high-grade aliphatic ester modification with weight than 0.8:The mixture of 1 composition.
The heat stabilizer is with weight ratio 1 by calcium stearate, barium stearate, zinc stearate and hydrotalcite:0.9:0.9：
The mixture of 0.5 composition.
The toner material is with weight ratio 0.9 by phthalocyanine blue and ultramarine toner:The mixture of 1 composition.
The titanium dioxide surface treated, its preparation method are：By rutile type titanium white at 105 DEG C high-speed stirred
18min removes the moisture content absorbed, is then added in the styrene and silicon oil solution for being mixed with initiator, continues to cool down after mixing 9min
Complete to prepare；The rutile type titanium white, styrene, dimethicone, the weight ratio of di-isopropyl peroxydicarbonate are
100：0.5：1.3：0.05.
Other auxiliary agents are with weight ratio 0.9 by UV resistant agent and antioxidant：The mixture of 1 composition.
The UV resistant agent is by 4- benzoyloxys -2,2,6,6- tetramethyl piperidines, 2- hydroxyl -4- n-octyloxies two
Benzophenone and 2,4,6- tri- (2 ' n-butoxyphenyl) -1,3,5- triazines are with weight than 1.8:0.8:The mixture of 1 composition.
The antioxidant be by four [methylene -3,5- (di-t-butyl -4- hydroxy-phenies) propionic ester] pentaerythritol esters,
Three [2,4- di-tert-butyl-phenyls] phosphite esters and β-positive octadecanol ester of (3,5- di-tert-butyl-hydroxy phenyls) propionic acid are with weight
Measure ratio 1:0.3:The mixture of 0.5 composition.
A kind of preparation technology of lace burr hollow out colorful gold plaque material, comprises the following steps：
(1) above-mentioned raw materials are weighed by weight ratio, are put into high speed blender, are stirred 4.5min at a temperature of 112 DEG C, are stirred
The rotating speed mixed is 70RPM, obtains compound；
(2) raw material after stirring is subjected to first time plasticizing at a temperature of 168 DEG C, obtains micelle；
(3) micelle after first time is plastified carries out second at a temperature of 178 DEG C through lace die head and plastified, until plasticizing
Shaping, obtains sheet material, thickness 0.48mm；
(4) sheet material after shaping is subjected to printing treatment；
(5) sheet material after printing is subjected to gold stamping processing；
(6) sheet material after shaping is subjected to cooling and shaping through drawing cooling wheel, then rolling machine is wound, and lace is made
Burr hollow out colorful gold plaque material.
Embodiment 3
A kind of lace burr hollow out colorful gold plaque material, the lace burr hollow out colorful gold plaque material include following parts by weight
Raw material：
The polyvinyl chloride resin is ethylene process polyvinyl chloride resin of the average degree of polymerization 1500.
The filler is at 30 μm and precipitated calcium carbonate and particle diameter through higher fatty acid salt modification by particle diameter
At 300 μm and the powdered whiting through high-grade aliphatic ester modification with weight than 1:The mixture of 1 composition.
The heat stabilizer is with weight ratio 1 by calcium stearate, barium stearate, zinc stearate and hydrotalcite:1:1：0.6 group
Into mixture.
The toner material is with weight ratio 1 by phthalocyanine blue and ultramarine toner:The mixture of 1 composition.
The titanium dioxide surface treated, its preparation method are：By rutile type titanium white at 110 DEG C high-speed stirred
20min remove absorb moisture content, be then added in the styrene and silicon oil solution for being mixed with initiator, continue mix 10min after it is cold
But complete to prepare；The rutile type titanium white, styrene, dimethicone, the weight ratio of di-isopropyl peroxydicarbonate
For 100：0.6：1.4：0.06.
Other auxiliary agents are with weight ratio 1 by UV resistant agent and antioxidant：The mixture of 1 composition.
The UV resistant agent is by 4- benzoyloxys -2,2,6,6- tetramethyl piperidines, 2- hydroxyl -4- n-octyloxies two
Benzophenone and 2,4,6- tri- (2 ' n-butoxyphenyl) -1,3,5- triazines are with weight than 2:1:The mixture of 1 composition.
The antioxidant be by four [methylene -3,5- (di-t-butyl -4- hydroxy-phenies) propionic ester] pentaerythritol esters,
Three [2,4- di-tert-butyl-phenyls] phosphite esters and β-positive octadecanol ester of (3,5- di-tert-butyl-hydroxy phenyls) propionic acid are with weight
Measure ratio 1:0.4:The mixture of 0.6 composition.
A kind of preparation technology of lace burr hollow out colorful gold plaque material, comprises the following steps：
(1) above-mentioned raw materials are weighed by weight ratio, are put into high speed blender, 5min is stirred at a temperature of 115 DEG C, are stirred
Rotating speed be 80RPM, obtain compound；
(2) raw material after stirring is subjected to first time plasticizing at a temperature of 170 DEG C, obtains micelle；
(3) micelle after first time is plastified carries out second at a temperature of 180 DEG C through lace die head and plastified, until plasticizing
Shaping, obtains sheet material, thickness 0.52mm；
(4) sheet material after shaping is subjected to printing treatment；
(5) sheet material after printing is subjected to gold stamping processing；
(6) sheet material after shaping is subjected to cooling and shaping through drawing cooling wheel, then rolling machine is wound, and lace is made
Burr hollow out colorful gold plaque material.
Embodiment 4
A kind of lace burr hollow out colorful gold plaque material, the lace burr hollow out colorful gold plaque material include following parts by weight
Raw material：
The polyvinyl chloride resin is ethylene process polyvinyl chloride resin of the average degree of polymerization 1800.
The filler is at 40 μm and precipitated calcium carbonate and particle diameter through higher fatty acid salt modification by particle diameter
At 400 μm and the powdered whiting through high-grade aliphatic ester modification with weight than 1.2:The mixture of 1 composition.
The heat stabilizer is with weight ratio 1 by calcium stearate, barium stearate, zinc stearate and hydrotalcite:1.1:1.1：
The mixture of 0.7 composition.
The toner material is with weight ratio 1.1 by phthalocyanine blue and ultramarine toner:The mixture of 1 composition.
The titanium dioxide surface treated, its preparation method are：By rutile type titanium white at 115 DEG C high-speed stirred
22min remove absorb moisture content, be then added in the styrene and silicon oil solution for being mixed with initiator, continue mix 11min after it is cold
But complete to prepare；The rutile type titanium white, styrene, dimethicone, the weight ratio of di-isopropyl peroxydicarbonate
For 100：0.7：1.5：0.07.
Other auxiliary agents are with weight ratio 1.1 by UV resistant agent and antioxidant：The mixture of 1 composition.
The UV resistant agent is by 4- benzoyloxys -2,2,6,6- tetramethyl piperidines, 2- hydroxyl -4- n-octyloxies two
Benzophenone and 2,4,6- tri- (2 ' n-butoxyphenyl) -1,3,5- triazines are with weight than 2.2:1.2:The mixture of 1 composition.
The antioxidant be by four [methylene -3,5- (di-t-butyl -4- hydroxy-phenies) propionic ester] pentaerythritol esters,
Three [2,4- di-tert-butyl-phenyls] phosphite esters and β-positive octadecanol ester of (3,5- di-tert-butyl-hydroxy phenyls) propionic acid are with weight
Measure ratio 1:0.5:The mixture of 0.7 composition.
A kind of preparation technology of lace burr hollow out colorful gold plaque material, comprises the following steps：
(1) above-mentioned raw materials are weighed by weight ratio, are put into high speed blender, are stirred 5.5min at a temperature of 118 DEG C, are stirred
The rotating speed mixed is 1000RPM, obtains compound；
(2) raw material after stirring is subjected to first time plasticizing at a temperature of 172 DEG C, obtains micelle；
(3) micelle after first time is plastified carries out second at a temperature of 182 DEG C through lace die head and plastified, until plasticizing
Shaping, obtains sheet material, thickness 0.55mm；
(4) sheet material after shaping is subjected to printing treatment；
(5) sheet material after printing is subjected to gold stamping processing；
(6) sheet material after shaping is subjected to cooling and shaping through drawing cooling wheel, then rolling machine is wound, and lace is made
Burr hollow out colorful gold plaque material.
Embodiment 5
A kind of lace burr hollow out colorful gold plaque material, the lace burr hollow out colorful gold plaque material include following parts by weight
Raw material：
The polyvinyl chloride resin is ethylene process polyvinyl chloride resin of the average degree of polymerization 2000.
The filler is at 50 μm and precipitated calcium carbonate and particle diameter through higher fatty acid salt modification by particle diameter
At 500 μm and the powdered whiting through high-grade aliphatic ester modification with weight than 1.5:The mixture of 1 composition.
The heat stabilizer is with weight ratio 1 by calcium stearate, barium stearate, zinc stearate and hydrotalcite:1.2:1.2：
The mixture of 0.8 composition.
The toner material is with weight ratio 1.2 by phthalocyanine blue and ultramarine toner:The mixture of 1 composition.
The titanium dioxide surface treated, its preparation method are：By rutile type titanium white at 120 DEG C high-speed stirred
25min remove absorb moisture content, be then added in the styrene and silicon oil solution for being mixed with initiator, continue mix 12min after it is cold
But complete to prepare；The rutile type titanium white, styrene, dimethicone, the weight ratio of di-isopropyl peroxydicarbonate
For 100：0.8：1.6：0.08.
Other auxiliary agents are with weight ratio 1.2 by UV resistant agent and antioxidant：The mixture of 1 composition.
The UV resistant agent is by 4- benzoyloxys -2,2,6,6- tetramethyl piperidines, 2- hydroxyl -4- n-octyloxies two
Benzophenone and 2,4,6- tri- (2 ' n-butoxyphenyl) -1,3,5- triazines are with weight than 2.5:1.5:The mixture of 1 composition.
The antioxidant be by four [methylene -3,5- (di-t-butyl -4- hydroxy-phenies) propionic ester] pentaerythritol esters,
Three [2,4- di-tert-butyl-phenyls] phosphite esters and β-positive octadecanol ester of (3,5- di-tert-butyl-hydroxy phenyls) propionic acid are with weight
Measure ratio 1:0.6:The mixture of 0.8 composition.
A kind of preparation technology of lace burr hollow out colorful gold plaque material, comprises the following steps：
(1) above-mentioned raw materials are weighed by weight ratio, are put into high speed blender, 6min is stirred at a temperature of 120 DEG C, are stirred
Rotating speed be 1160RPM, obtain compound；
(2) raw material after stirring is subjected to first time plasticizing at a temperature of 175 DEG C, obtains micelle；
(3) micelle after first time is plastified carries out second at a temperature of 185 DEG C through lace die head and plastified, until plasticizing
Shaping, obtains sheet material, thickness 0.60mm；
(4) sheet material after shaping is subjected to printing treatment；
(5) sheet material after printing is subjected to gold stamping processing；
(6) sheet material after shaping is subjected to cooling and shaping through drawing cooling wheel, then rolling machine is wound, and lace is made
Burr hollow out colorful gold plaque material.
Embodiment 6
The difference of the present embodiment and above-described embodiment 1 is：
The lace burr hollow out colorful gold plaque material also includes 15 parts of aliphatic polyketone, 5 parts of polyester staple fiber and modified POE
4 parts of resin.
The modified POE resin is polypropylene/ethylene-octene copolymer that polypropylene and POE resin blending and modifying obtain；
The ethylene-octene copolymer is ethylene-octene copolymer of the octene monomers content 20%.
The polypropylene is that have COPP and HOPP with weight ratio 1.4：The mixture of 1 composition；It is described common
Poly- polypropylene is COPP of the melt index in 10g/10min；The HOPP is melt index in 60g/10min
HOPP.
The lace burr hollow out colorful gold plaque material also include cold-resistant toughened dose 2 parts, 1 part of intensity modifier, compatilizer 1
Part, 0.5 part of slipping agent.
Described cold-resistant toughened dose is with weight ratio 1 by amide-type beta crystal-type nucleater and dicarboxylic acids salt beta crystal-type nucleater：
The mixture of 1.2 compositions.
The intensity modifier is in the magnesium salt whisker of 4 μm of basalt fibre and filament diameter at 6 μm by filament diameter
With weight than 1.6：The mixture of 1 composition.
The compatilizer is with weight ratio by maleic anhydride grafted polyvinyl chloride and ethlyene dichloride-vinyl acetate copolymer
1：The mixture of 1.4 compositions.
The slipping agent is than 1.5 by erucyl amide, oleamide and N, N'- ethylene bis stearamide with weight：0.8：1
The mixture of composition.
Embodiment 7
The difference of the present embodiment and above-described embodiment 2 is：
The lace burr hollow out colorful gold plaque material also includes 20 parts of aliphatic polyketone, 8 parts of polyester staple fiber and modified POE
5 parts of resin.
The modified POE resin is polypropylene/ethylene-octene copolymer that polypropylene and POE resin blending and modifying obtain；
The ethylene-octene copolymer is ethylene-octene copolymer of the octene monomers content 22%.
The polypropylene is that have COPP and HOPP with weight ratio 1.6：The mixture of 1 composition；It is described common
Poly- polypropylene is COPP of the melt index in 20g/10min；The HOPP is melt index in 70g/10min
HOPP.
The lace burr hollow out colorful gold plaque material also include cold-resistant toughened dose 3 parts, 2 parts of intensity modifier, compatilizer 1.5
Part, 0.8 part of slipping agent.
Described cold-resistant toughened dose is with weight ratio 1 by amide-type beta crystal-type nucleater and dicarboxylic acids salt beta crystal-type nucleater：
The mixture of 1.4 compositions.
The intensity modifier is in the magnesium salt whisker of 5 μm of basalt fibre and filament diameter at 7 μm by filament diameter
With weight than 1.8：The mixture of 1 composition.
The compatilizer is with weight ratio by maleic anhydride grafted polyvinyl chloride and ethlyene dichloride-vinyl acetate copolymer
1：The mixture of 1.6 compositions.
The slipping agent is than 1.8 by erucyl amide, oleamide and N, N'- ethylene bis stearamide with weight：0.9：1
The mixture of composition.
Embodiment 8
The difference of the present embodiment and above-described embodiment 3 is：
The lace burr hollow out colorful gold plaque material also includes 25 parts of aliphatic polyketone, 10 parts of polyester staple fiber and is modified
6 parts of POE resin.
The modified POE resin is polypropylene/ethylene-octene copolymer that polypropylene and POE resin blending and modifying obtain；
The ethylene-octene copolymer is ethylene-octene copolymer of the octene monomers content 25%.
The polypropylene is that have COPP and HOPP with weight ratio 1.8：The mixture of 1 composition；It is described common
Poly- polypropylene is COPP of the melt index in 30g/10min；The HOPP is melt index in 80g/10min
HOPP.
The lace burr hollow out colorful gold plaque material also includes 3 parts of 40 parts of Vitrified powder, 3 parts of fire retardant and smoke suppressant.
The lace burr hollow out colorful gold plaque material also include cold-resistant toughened dose 4 parts, 3 parts of intensity modifier, compatilizer 2
Part, 1 part of slipping agent.
Described cold-resistant toughened dose is with weight ratio 1 by amide-type beta crystal-type nucleater and dicarboxylic acids salt beta crystal-type nucleater：
The mixture of 1.5 compositions.
The intensity modifier is in the magnesium salt whisker of 6 μm of basalt fibre and filament diameter at 8 μm by filament diameter
With weight than 2：The mixture of 1 composition.
The compatilizer is with weight ratio by maleic anhydride grafted polyvinyl chloride and ethlyene dichloride-vinyl acetate copolymer
1：The mixture of 1.8 compositions.
The slipping agent is than 2 by erucyl amide, oleamide and N, N'- ethylene bis stearamide with weight：1：1 composition
Mixture.
Embodiment 9
The difference of the present embodiment and above-described embodiment 4 is：
The lace burr hollow out colorful gold plaque material also includes 30 parts of aliphatic polyketone, 12 parts of polyester staple fiber and is modified
7 parts of POE resin.
The modified POE resin is polypropylene/ethylene-octene copolymer that polypropylene and POE resin blending and modifying obtain；
The ethylene-octene copolymer is ethylene-octene copolymer of the octene monomers content 28%.
The polypropylene is that have COPP and HOPP with weight ratio 2：The mixture of 1 composition；The copolymerization
Polypropylene is COPP of the melt index in 40g/10min；The HOPP is melt index 90g/10min's
HOPP.
The lace burr hollow out colorful gold plaque material also includes 4 parts of 50 parts of Vitrified powder, 4 parts of fire retardant and smoke suppressant.
The lace burr hollow out colorful gold plaque material also include cold-resistant toughened dose 5 parts, 4 parts of intensity modifier, compatilizer 2.5
Part, 1.2 parts of slipping agent.
Described cold-resistant toughened dose is with weight ratio 1 by amide-type beta crystal-type nucleater and dicarboxylic acids salt beta crystal-type nucleater：
The mixture of 1.6 compositions.
The intensity modifier is in the magnesium salt whisker of 7 μm of basalt fibre and filament diameter at 9 μm by filament diameter
With weight than 2.2：The mixture of 1 composition.
The compatilizer is with weight ratio by maleic anhydride grafted polyvinyl chloride and ethlyene dichloride-vinyl acetate copolymer
1：The mixture of 2 compositions.
The slipping agent is than 2.2 by erucyl amide, oleamide and N, N'- ethylene bis stearamide with weight：1.1：1
The mixture of composition.
Embodiment 10
The difference of the present embodiment and above-described embodiment 5 is：
The lace burr hollow out colorful gold plaque material also includes 35 parts of aliphatic polyketone, 15 parts of polyester staple fiber and is modified
8 parts of POE resin.
The modified POE resin is polypropylene/ethylene-octene copolymer that polypropylene and POE resin blending and modifying obtain；
The ethylene-octene copolymer is ethylene-octene copolymer of the octene monomers content 30%.
The polypropylene is that have COPP and HOPP with weight ratio 2.2：The mixture of 1 composition；It is described common
Poly- polypropylene is COPP of the melt index in 50g/10min；The HOPP is melt index in 100g/
10min HOPP.
The lace burr hollow out colorful gold plaque material also include cold-resistant toughened dose 6 parts, 5 parts of intensity modifier, compatilizer 3
Part, 1.5 parts of slipping agent.
Described cold-resistant toughened dose is with weight ratio 1 by amide-type beta crystal-type nucleater and dicarboxylic acids salt beta crystal-type nucleater：
The mixture of 1.8 compositions.
The intensity modifier is in the magnesium salt whisker of 8 μm of basalt fibre and filament diameter at 10 μm by filament diameter
With weight than 2.4：The mixture of 1 composition.
The compatilizer is with weight ratio by maleic anhydride grafted polyvinyl chloride and ethlyene dichloride-vinyl acetate copolymer
1：The mixture of 2.2 compositions.
The slipping agent is than 2.5 by erucyl amide, oleamide and N, N'- ethylene bis stearamide with weight：1.2：1
The mixture of composition.
Lace burr hollow out colorful gold plaque material produced by the present invention has preferable three-dimensional stereo effect and soft comfortable
Feel；Intensity is high, and tensile strength can reach more than 28.2MPa, and bending strength can reach more than 57.8MPa, extension at break
Rate can reach more than 335%, excellent shock resistance, also with good chemical stability, fire retardant insulating, acid-fast alkali-proof,
The advantages that waterproof and dampproof, anticorrosion, stretching resistance, anti-aging and antistatic, excellent combination property.
Above-described embodiment is the preferable implementation of the present invention, and in addition, the present invention can be realized with other manner,
Do not depart from and any on the premise of present inventive concept obviously replace within protection scope of the present invention.
Claims (10)
- A kind of 1. lace burr hollow out colorful gold plaque material, it is characterised in that：The lace burr hollow out colorful gold plaque material is included such as The raw material of lower parts by weight：
- A kind of 2. lace burr hollow out colorful gold plaque material according to claim 1, it is characterised in that：The polyvinyl chloride resin is Ethylene process polyvinyl chloride resin of the average degree of polymerization in 1000-2000.
- A kind of 3. lace burr hollow out colorful gold plaque material according to claim 1, it is characterised in that：The filler be by Particle diameter is at 10-50 μm and the precipitated calcium carbonate through higher fatty acid salt modification and particle diameter are at 100-500 μm and through height The powdered whiting of level fatty acid ester modification compares 0.5-1.5 with weight:The mixture of 1 composition.
- A kind of 4. lace burr hollow out colorful gold plaque material according to claim 1, it is characterised in that：The heat stabilizer is By calcium stearate, barium stearate, zinc stearate and hydrotalcite with weight ratio 1:0.8-1.2:0.8-1.2：0.4-0.8 compositions mix Compound.
- A kind of 5. lace burr hollow out colorful gold plaque material according to claim 1, it is characterised in that：The toner material be by Phthalocyanine blue and ultramarine toner compare 0.8-1.2 with weight:The mixture of 1 composition.
- A kind of 6. lace burr hollow out colorful gold plaque material according to claim 1, it is characterised in that：The titanium dioxide is through table Face is handled, and its preparation method is：By rutile type titanium white, high-speed stirred 15-25min removes the water absorbed at 100-120 DEG C Part, it is then added in the styrene and silicon oil solution for being mixed with initiator, continues cooling after mixing 8-12min and complete to prepare；It is described Rutile type titanium white, styrene, dimethicone, the weight ratio of di-isopropyl peroxydicarbonate are 100：0.4-0.8： 1.2-1.6：0.04-0.08.
- A kind of 7. lace burr hollow out colorful gold plaque material according to claim 1, it is characterised in that：Other auxiliary agents are 0.8-1.2 is compared with weight by UV resistant agent and antioxidant：The mixture of 1 composition.
- A kind of 8. lace burr hollow out colorful gold plaque material according to claim 7, it is characterised in that：The UV resistant agent It is that (2 ' just by 4- benzoyloxys -2,2,6,6- tetramethyl piperidines, 2-hydroxy-4-n-octoxybenzophenone and 2,4,6- tri- Butoxy phenyl) -1,3,5- triazines compare 1.5-2.5 with weight:0.5-1.5:The mixture of 1 composition.
- A kind of 9. lace burr hollow out colorful gold plaque material according to claim 7, it is characterised in that：The antioxidant be by Four [methylene -3,5- (di-t-butyl -4- hydroxy-phenies) propionic ester] pentaerythritol esters, three [2,4- di-tert-butyl-phenyls] are sub- Phosphate and β-positive octadecanol ester of (3,5- di-tert-butyl-hydroxy phenyls) propionic acid are with weight than 1:0.2-0.6:0.4-0.8 The mixture of composition.
- 10. a kind of preparation technology of lace burr hollow out colorful gold plaque material according to claim any one of 1-9, its feature It is：Comprise the following steps：(1) above-mentioned raw materials are weighed by weight ratio, are put into high speed blender, 4-6min is stirred at a temperature of 110-120 DEG C, are stirred The rotating speed mixed is 580-1160RPM, obtains compound；(2) raw material after stirring is subjected to first time plasticizing at a temperature of 165-175 DEG C, obtains micelle；(3) micelle after first time is plastified carries out second at a temperature of 175-185 DEG C through lace die head and plastified, until plasticizing Shaping, obtains sheet material；(4) sheet material after shaping is subjected to printing treatment；(5) sheet material after printing is subjected to gold stamping processing；(6) sheet material after shaping is subjected to cooling and shaping through drawing cooling wheel, then rolling machine is wound, and lace burr is made Hollow out colorful gold plaque material.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110834460A (en) * | 2019-11-18 | 2020-02-25 | 东莞市悠悠美居家居制造有限公司 | Production process of double-sided lace tablecloth |
| CN112694692A (en) * | 2020-12-25 | 2021-04-23 | 东莞市悠悠美居家居制造有限公司 | Counterpoint gold-transferring gold-covering printing film and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101288988A (en) * | 2008-04-29 | 2008-10-22 | 刘承发 | Lace PVC tablecloth manufacturing method |
-
2017
- 2017-10-23 CN CN201710992575.XA patent/CN107868359A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101288988A (en) * | 2008-04-29 | 2008-10-22 | 刘承发 | Lace PVC tablecloth manufacturing method |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110834460A (en) * | 2019-11-18 | 2020-02-25 | 东莞市悠悠美居家居制造有限公司 | Production process of double-sided lace tablecloth |
| CN112694692A (en) * | 2020-12-25 | 2021-04-23 | 东莞市悠悠美居家居制造有限公司 | Counterpoint gold-transferring gold-covering printing film and preparation method thereof |
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Application publication date: 20180403 |