CN107841872A - A kind of wool fabric antifouling and antibiosis finishing technique - Google Patents
A kind of wool fabric antifouling and antibiosis finishing technique Download PDFInfo
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- CN107841872A CN107841872A CN201711204842.9A CN201711204842A CN107841872A CN 107841872 A CN107841872 A CN 107841872A CN 201711204842 A CN201711204842 A CN 201711204842A CN 107841872 A CN107841872 A CN 107841872A
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- Prior art keywords
- wool fabric
- antifouling
- finishing technique
- lanolin
- antibiosis
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/325—Amines
- D06M13/332—Di- or polyamines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B21/00—Successive treatments of textile materials by liquids, gases or vapours
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B3/00—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
- D06B3/10—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics
- D06B3/18—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics combined with squeezing, e.g. in padding machines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/68—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof
- D06M11/70—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof with oxides of phosphorus; with hypophosphorous, phosphorous or phosphoric acids or their salts
- D06M11/71—Salts of phosphoric acids
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
- D06M13/51—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/10—Animal fibres
- D06M2101/12—Keratin fibres or silk
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/01—Stain or soil resistance
Abstract
The invention discloses a kind of wool fabric antifouling and antibiosis finishing technique, the technique includes carrying out the steps such as advance alkali process, antibiotic finish, soil resistant finish to wool fabric.Compared with prior art, the present invention has advantages below：(1) the wool fabric soil resistance after technique of the present invention arranges is up to 4 grades, and anti-microbial property significantly improves；(2) wool fabric after technique of the present invention arranges has excellent durability and washability.
Description
Technical field
The invention belongs to textile technology field, is related to a kind of feature wool fabric, and specially a kind of wool fabric is antifouling
Antibacterial finishing process.
Background technology
In the prior art, the antifouling and antibiosis of wool fabric is arranged mainly using quaternized pyridinium salt, melamine methylol
Derivative, stearate chromium complex etc. are arranged.It is although poor with certain effect, washability.
In addition, recently as the further investigation of high polymer material performance, its application on the textile also increasingly by
To the attention of researcher, unlike common material, it refuses the great surface-active of oil, has traditional material unexistent
Superiority, therefore there is good durability and washability.The three of a kind of wool fabrics of Chinese patent CN201010127074.3
Anti- method for sorting, disclose a kind of priority and wool fabric is entered using organosilicon quaternary ammonium salt, fluoro containing polymerses copolymer dispersion
The method that row arranges.This method uses the macromolecule fluorinated copolymer of high surface, so that water, oil etc. are in wool fabric
Surface can not moisten, and have Water-proof and oil-proof, anti-pollution function.
But above-mentioned prior art is difficult to cause organosilicone quaternary ammonium in the case where not adding synergist and soft crosslinking agent
Salt is played effectiveness jointly with fluoro containing polymerses copolymer.It is right and the increase of synergist and soft crosslinking agent has Reverse transcriptase
Adverse effect be present in the three proofings effect of final wool fabric.
The content of the invention
The purpose of the present invention is：The defects of in order to overcome prior art, obtain a kind of antifouling, antibacterial functions with stablizing
Wool fabric, the invention provides a kind of wool fabric antifouling and antibiosis finishing technique.
Technical scheme：A kind of wool fabric antifouling and antibiosis finishing technique, the technique comprise the following steps：
(1) wool fabric is immersed in ethylenediamine solution, 8~30min is reacted under the conditions of 2~4 DEG C, is then added
Sodium cyanoborohydride, continue reaction 8~12 hours, reaction is washed after terminating with dimethyl sulfoxide；
(2) wool fabric after step (1) processing is handled using the immersing and rolling of quaternary ammonium salt finishing agent one, temperature for 80~
1~3min of preliminary drying under the conditions of 110 DEG C, then 120~160 DEG C bake 3~8min；
(3) acylated lanolin or alkoxylated lanolin, room are coated to the wool fabric surface after step (2) antibiotic finish
Temperature is immersed in potassium phosphate buffer after drying, 40~52 DEG C of 20~45min of processing, then pre- under the conditions of 80~110 DEG C
1~3min is dried, 120~160 DEG C bake 3~8min.
Preferably, the mol ratio of wool fabric and ethylenediamine is 13~25 in step (1):1.
Preferably, the mol ratio of wool fabric and sodium cyanoborohydride is 8~13 in step (1):1.
Preferably, quaternary ammonium salt described in step (2) is aromatic series quaternary ammonium salt, is cetyl pyridinium ammonium chloride, hexadecane
Base dimethyl benzyl ammonium chloride or dodecyl benzyl dimethyl ammonium chloride.
Preferably, the speed of padding when being padded in step (2) is 15-40m/min, and it is 2-2.5kg/cm to pad pressure2, leaching
It is 65-75% to roll raffinate rate.
Preferably, acylated lanolin or the mass ratio of alkylation lanolin and wool fabric are 1 in step (3):8~15.
Beneficial effect：(1) the wool fabric soil resistance after technique of the present invention arranges is up to 4 grades, and anti-microbial property shows
Write and improve；(2) wool fabric after technique of the present invention arranges has excellent durability and washability.
Embodiment
Embodiment 1
A kind of wool fabric antifouling and antibiosis finishing technique, the technique comprise the following steps：
(1) wool fabric is immersed in ethylenediamine solution, 8min is reacted under the conditions of 2 DEG C, then add cyano group boron
Sodium hydride, continues reaction 8 hours, and reaction is washed after terminating with dimethyl sulfoxide；
(2) wool fabric after step (1) processing is handled using the immersing and rolling of quaternary ammonium salt finishing agent one, is 80 DEG C in temperature
Under the conditions of preliminary drying 1min, then 120 DEG C bake 3min；
(3) acylated lanolin or alkoxylated lanolin, room are coated to the wool fabric surface after step (2) antibiotic finish
Temperature is immersed in potassium phosphate buffer after drying, 40 DEG C of processing 20min, then preliminary drying 1min under the conditions of 80 DEG C, 120 DEG C of roastings
Dry 3min.
The mol ratio of wool fabric and ethylenediamine is 13 in step (1):1.
The mol ratio of wool fabric and sodium cyanoborohydride is 8 in step (1):1.
Quaternary ammonium salt described in step (2) is aromatic series quaternary ammonium salt, is cetyl pyridinium ammonium chloride, hexadecyldimethyl benzyl ammonium
Benzyl ammonium chloride or dodecyl benzyl dimethyl ammonium chloride.
Speed of padding when being padded in step (2) is 15m/min, and it is 2kg/cm to pad pressure2, padding raffinate rate is
65%.
Acylated lanolin or the mass ratio of alkylation lanolin and wool fabric are 1 in step (3):8.
Embodiment 2
A kind of wool fabric antifouling and antibiosis finishing technique, the technique comprise the following steps：
(1) wool fabric is immersed in ethylenediamine solution, 20min is reacted under the conditions of 3 DEG C, then add cyano group boron
Sodium hydride, continues reaction 8 hours, and reaction is washed after terminating with dimethyl sulfoxide；
(2) wool fabric after step (1) processing is handled using the immersing and rolling of quaternary ammonium salt finishing agent one, is 100 in temperature
Preliminary drying 2min under the conditions of DEG C, then 140 DEG C bake 5min；
(3) acylated lanolin or alkoxylated lanolin, room are coated to the wool fabric surface after step (2) antibiotic finish
Temperature is immersed in potassium phosphate buffer after drying, 45 DEG C of processing 30min, then preliminary drying 2min under the conditions of 100 DEG C, 140 DEG C
Bake 6min.
The mol ratio of wool fabric and ethylenediamine is 20 in step (1):1.
The mol ratio of wool fabric and sodium cyanoborohydride is 10 in step (1):1.
Quaternary ammonium salt described in step (2) is aromatic series quaternary ammonium salt, is cetyl pyridinium ammonium chloride, hexadecyldimethyl benzyl ammonium
Benzyl ammonium chloride or dodecyl benzyl dimethyl ammonium chloride.
Speed of padding when being padded in step (2) is 25m/min, and it is 2.5kg/cm to pad pressure2, padding raffinate rate is
70%.
Acylated lanolin or the mass ratio of alkylation lanolin and wool fabric are 1 in step (3):12.
Embodiment 3
A kind of wool fabric antifouling and antibiosis finishing technique, the technique comprise the following steps：
(1) wool fabric is immersed in ethylenediamine solution, 30min is reacted under the conditions of 4 DEG C, then add cyano group boron
Sodium hydride, continues reaction 12 hours, and reaction is washed after terminating with dimethyl sulfoxide；
(2) wool fabric after step (1) processing is handled using the immersing and rolling of quaternary ammonium salt finishing agent one, is 110 in temperature
Preliminary drying 3min under the conditions of DEG C, then 160 DEG C bake 8min；
(3) acylated lanolin or alkoxylated lanolin, room are coated to the wool fabric surface after step (2) antibiotic finish
Temperature is immersed in potassium phosphate buffer after drying, 52 DEG C of processing 45min, then preliminary drying 3min under the conditions of 110 DEG C, 160 DEG C
Bake 8min.
The mol ratio of wool fabric and ethylenediamine is 25 in step (1):1.
The mol ratio of wool fabric and sodium cyanoborohydride is 13 in step (1):1.
Quaternary ammonium salt described in step (2) is aromatic series quaternary ammonium salt, is cetyl pyridinium ammonium chloride, hexadecyldimethyl benzyl ammonium
Benzyl ammonium chloride or dodecyl benzyl dimethyl ammonium chloride.
Speed of padding when being padded in step (2) is 40m/min, and it is 2.5kg/cm to pad pressure2, padding raffinate rate is
75%.
Acylated lanolin or the mass ratio of alkylation lanolin and wool fabric are 1 in step (3):15.
The wool fabric obtained is arranged to 1~3 technique of embodiment and carries out performance test, wherein：Finished tensile strength
Determined according to national standard GB/T3923.1-1997 galley proofs method；Antibacterial fabric performance test, according to national sector standard FZ/T01021-
92 (antibacterial fabric performance test methods) are detected, and its principle is, by sample fabric and control fabric (without antibiotic finish
Fabric) it is put in respectively in conical flask, it is inoculated with test organisms, after inoculation, the bacterium in control fabric is washed and determined immediately
Bacterial number, by sample it is incubated after, washing bacterium simultaneously determine bacterial number, then calculate sample bacterium reduce percentage
Rate.Concrete outcome is as shown in the table：
Claims (6)
1. a kind of wool fabric antifouling and antibiosis finishing technique, it is characterised in that the technique comprises the following steps：
(1) wool fabric is immersed in ethylenediamine solution, 8~30min is reacted under the conditions of 2~4 DEG C, then adds cyano group
Sodium borohydride, continue reaction 8~12 hours, reaction is washed after terminating with dimethyl sulfoxide；
(2) wool fabric after step (1) processing is handled using the immersing and rolling of quaternary ammonium salt finishing agent one, is 80~110 in temperature
1~3min of preliminary drying under the conditions of DEG C, then 120~160 DEG C bake 3~8min；
(3) coat acylated lanolin to the wool fabric surface after step (2) antibiotic finish or alkoxylated lanolin, room temperature are dried in the air
Be immersed in after dry in potassium phosphate buffer, 40~52 DEG C of 20~45min of processing, then preliminary drying 1 under the conditions of 80~110 DEG C~
3min, 120~160 DEG C bake 3~8min.
A kind of 2. wool fabric antifouling and antibiosis finishing technique according to claim 1, it is characterised in that sheep in step (1)
The mol ratio of wool fabric and ethylenediamine is 13~25:1.
A kind of 3. wool fabric antifouling and antibiosis finishing technique according to claim 1, it is characterised in that sheep in step (1)
The mol ratio of wool fabric and sodium cyanoborohydride is 8~13:1.
A kind of 4. wool fabric antifouling and antibiosis finishing technique according to claim 1, it is characterised in that institute in step (2)
It is aromatic series quaternary ammonium salt to state quaternary ammonium salt, is cetyl pyridinium ammonium chloride, cetalkonium chloride or dodecane
Base dimethyl benzyl ammonium chloride.
5. a kind of wool fabric antifouling and antibiosis finishing technique according to claim 1, it is characterised in that soaked in step (2)
Speed of padding when rolling is 15-40m/min, and it is 2-2.5kg/cm to pad pressure2, it is 65-75% to pad raffinate rate.
A kind of 6. wool fabric antifouling and antibiosis finishing technique according to claim 1, it is characterised in that acyl in step (3)
It is 1 to change lanolin or be alkylated lanolin and the mass ratio of wool fabric:8~15.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711204842.9A CN107841872A (en) | 2017-11-27 | 2017-11-27 | A kind of wool fabric antifouling and antibiosis finishing technique |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711204842.9A CN107841872A (en) | 2017-11-27 | 2017-11-27 | A kind of wool fabric antifouling and antibiosis finishing technique |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107841872A true CN107841872A (en) | 2018-03-27 |
Family
ID=61680300
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711204842.9A Pending CN107841872A (en) | 2017-11-27 | 2017-11-27 | A kind of wool fabric antifouling and antibiosis finishing technique |
Country Status (1)
| Country | Link |
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| CN (1) | CN107841872A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101187160A (en) * | 2007-12-06 | 2008-05-28 | 浙江理工大学 | Silk functional fiber preparation method |
| CN101831807A (en) * | 2010-03-18 | 2010-09-15 | 品德实业(太原)有限公司 | Three-prevention finishing method of wool fabric |
| CN107011793A (en) * | 2011-08-18 | 2017-08-04 | 阿克佐诺贝尔国际涂料股份有限公司 | Antifouling composition containing acylated lanolin, alkoxylated lanolin or lanolin oil |
-
2017
- 2017-11-27 CN CN201711204842.9A patent/CN107841872A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101187160A (en) * | 2007-12-06 | 2008-05-28 | 浙江理工大学 | Silk functional fiber preparation method |
| CN101831807A (en) * | 2010-03-18 | 2010-09-15 | 品德实业(太原)有限公司 | Three-prevention finishing method of wool fabric |
| CN107011793A (en) * | 2011-08-18 | 2017-08-04 | 阿克佐诺贝尔国际涂料股份有限公司 | Antifouling composition containing acylated lanolin, alkoxylated lanolin or lanolin oil |
Non-Patent Citations (2)
| Title |
|---|
| 王雪燕等: "《蛋白质化学及其应用》", 31 January 2016, 中国纺织出版社 * |
| 陈美云: "羊毛乙二胺预处理及其染色工艺", 《纺织学报》 * |
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